ABSTRACT When using pure refrigerants in heat pump, a significant temperature mismatch arises between hot and cold fluids within the evaporator and condenser, adversely impacting the thermal efficiency of system. To mitigate this issue, we incorporated non-azeotropic refrigerant blends such as R1233zd(e)/R152a, 1224 yd(z)/R152a and 1234ze(z)/R152a into heat pumps devoid of phase-change heat sinks and sources. Through rigorous examination of the temperature glide characteristics of these refrigerants, we determined an optimal R152a composition of 0.3, resulting in COPs of 3.326, 3.36, and 3.605 for the respective heat pumps. Our analysis further delved into heat pump configurations, revealing that the COP of the regenerative configuration could be substantially elevated from 3.36 (in the simple configuration) to 3.79. Additionally, the maximum temperature observed in the two-stage compression configuration was significantly lower compared to the regenerative setup. A comprehensive thermodynamic assessment = across all operating conditions indicated that COP of all configurations decreases markedly as heat production diminishes below 50% of full load. Conversely, when heat production exceeds 50% of full load, the COP remains relatively stable across different heat production levels. Notably, the COP of the regenerative configuration closely approximates that of the two-stage configuration. Considering factors such as investment cost, system complexity and operational efficiency, the regenerative configuration stands out as the optimal choice across all operating conditions.
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