Thermal Characteristics Research Articles

The extraction of inorganic phase-change materials from sugar industry wastes with the purpose of solid waste management

ABSTRACT This study focused on the feasibility of identifying and recycling inorganic phase-change materials (PCMs) from sugar industry wastes in two cities of Qazvin and Hamadan in Iran. In this study, dry sugar beet pomace, sugar beet pomace, sugar beet molasses, leaves and plant residues of sugar beet and sugarcane bagasse were investigated. The inorganic materials were identified by X-ray Diffraction (XRD), thermal characteristics were determined by differential scanning calorimetry (DSC), and morphological characteristics were determined by scanning electron microscopy (SEM). Additionally, physical and thermal properties of molasses and bagasse samples were analyzed to determine their suitability as inorganic PCMs. The results of this study demonstrated that molasses and bagasse have the potential to be used as mineral PCMs in thermal energy storage applications. The results of this study demonstrated that in the wet sugar beet pomace the highest and lowest concentrations of inorganic PCMs were silicon dioxide (SiO2) and sodium chloride (NaCl), respectively. Moreover, the highest calcium fluoride (CaF₂) composition was reported in dry sugar beet pomace. In the samples of leaves and residues of sugar beet and sugarcane bagasse, the highest concentration of was NaCl. The detection and recycling of mineral PCMs from sugar industry wastes offer a sustainable solution for waste management and provide a renewable source of thermal energy storage materials. Implications: This study demonstrated the potential for the extraction of inorganic phase-change materials from sugar industry wastes as a means of solid waste management. By repurposing these materials, we can reduce the environmental impact of sugar production and contribute to sustainable practices in the industry.

Investigation of flow boiling phenomenon in micro-pin-fin heat sinks adapted to actively direction-changing moving systems

Thermal management via boiling phenomenon in micro domain is one of the promising techniques for different types of aircrafts being continuously subjected to direction-changed movement. Therefore, in this paper, different from the literature, flow boiling phenomenon in expanding micro-pin-fin heat sinks with micro cavities (EH) continuously making angular motion is experimentally examined. To reveal effects of decreasing fin number (or increasing cross sectional area) along the heat sink and existence of micro cavities, the results, also, are compared to those obtained for conventional heat sink (CH). Angular range of motion (ARM = 0°↔15°, 0°↔30° and 0°↔45°), period of angular movement (PAM = 10 s, 30 s, and 60 s) and heating power (220 W and 300 W) are the variable parameters. Mass flux (G) and inlet temperature (Ti) are constants as 120 kgm−2 s−1 and 74 °C, respectively. It is concluded that the EH can successfully damp possible effect of variation in angular orientation on thermal characteristics, and thus, the EH leads to more stable thermal performance compared to CH. The key mechanism determining deviation characteristics is interaction between gravitational force and fluid inertia force. By enhancing wicking phenomenon and suppressing evaporation momentum force, the influence of angular variation can be minimized.

Investigation of the Influence of Environmental Thermal Characteristics on Thermal Modes of Transparent Boxes

This paper presents the results of experiments to investigate the influence of thermal characteristics of the environment on the thermal modes of transparent boxes. To conduct experiments on the non-stationary thermal model of solar greenhouses developed by us, two identical transparent boxes with dimensions of 0.80 x 0.65 x 0.80 m were constructed. The transparent boxes have rectangular shapes. One transparent box has glass walls and the other with polyethylene walls. The influence of the thermal characteristics of the environment and the thermal conditions inside the transparent boxes with film and glass transparent walls are investigated. The experimental results show that at a maximum ambient air temperature of 42 °C on 27.06.2024 at 13:48 hours, the air temperature increases to 10% and 23% in transparent boxes with polyethylene and with glass walls, respectively, and at 05:10 hours, the humidity decreases to 8% and 11%, respectively. Thus, the influence of the thermal characteristics of the environment on the thermal conditions of transparent boxes with glass walls, at the maximum ambient temperature, is greater by 1.2 times than in transparent boxes with polyethylene walls, and humidity decreases by half.

Thermal Characteristics of the Extreme Cases of Tropopause Over the Tropics

ABSTRACTThe anomalous variability of extreme cases of the tropical tropopause provides insight into the stratosphere‐troposphere exchange process crucial for understanding climate change. The present study analyses the extreme variability of the tropopause and its thermal structure over the tropics using GPS radio occultation data over the period 2006–2019. The extremely cold and warm tropopauses and extremely high and low tropopauses are identified based on the cold point tropopause temperature and height, respectively, when their values exceed two standard deviations with respect to their climatological means. The analyses revealed frequent occurrence of extreme cases of tropopause over the Atlantic Ocean compared to the Western Pacific Ocean. Individually, extremely warm and low cases occur more frequently over the subtropics, while extremely cold and high cases occur frequently over the deep tropics. These extreme cases pose different thermal structures bounded within the extremely low and high tropopauses throughout the tropics. The height difference between the extremely high and low tropopause cases is wider over the Atlantic Ocean and adjoining areas compared to the western Pacific Ocean. The temperature difference between the extremely warm and cold tropopause cases is higher in the Atlantic, Central Pacific, and Indonesian regions compared to the American, Indian Ocean, and western Pacific Ocean regions. The relationship between the El Niño Southern Oscillation (ENSO) phases and extreme tropopause cases is also investigated which reveals a higher occurrence of extremely high tropopause cases during the El Niño phase while low tropopause cases during the La Niña phase. Our analysis also revealed the thermal patterns of the extreme cases characterising colder and sharper tropopause over the convective regions compared to subsidence regions.

Fracture and fractal characteristics of high-temperature granite under confined space water jet impact

In the application of jet assisted deep drilling technology, the fracture mode and rock fragment characteristics of high-temperature rock in the confined space of jet drilling are not yet clear. We analyzed the fragmentation and debris distribution of high-temperature granite under confined space jet action using 3D reconstruction technology and statistical fractal theory to examine their fragmentation patterns and fractal characteristics. The results show that high-temperature rocks exhibit obvious thermal fracturing characteristics under the impact of confined water jet, and as the rock temperature increases, vertical compression shear cracks connect with radial tensile cracks. The maximum damage area is located near the bottom of the confined hole, and the distribution of cracks is more complex. As the degree of jet confinement decreases, the rock cracking form changes from radial tensile cracking to vertical compression shear cracking. As the rock temperature increases and the confined space size decreases, the total mass and large debris mass percentages of rock debris increase. The particle size distribution of rock debris follows an Rosin-Rammler (R-R) distribution and has obvious fractal characteristics. The fracture and fragmentation of high-temperature rocks under confined water jet impact are mainly caused by the combination of jet impact stress waves and thermal stress. The temperature difference of rocks affects the heat transfer between jet and rock, and the confined space size directly affects the heat transfer efficiency between jet and rock, which is manifested in different numbers of fracture cracks, internal damage area, and rock debris size distribution. These findings can provide a theoretical and parameter optimization basis for jet-assisted deep reservoir drilling applications.

Investigation of the mineral profile, structural and thermal properties of blends of trapiá powder with tropical fruits

Trapiá is widely distributed throughout Brazilian territory and in Latin American countries, yet its commercial potential is overlooked due to insuficiente knowledge of its bioactive properties and a lack of studies on pulp processing. Aiming to enhance the value of Trapiá by improving its nutraceutical properties through the incorporation of minerals, vitamins, and the popularity of tropical fruits, this study investigated the mineral potential, structural properties, and thermal characteristics of mixtures of trapiá pulp with orange, lemon, and pineapple pulps, which were converted into powders through spray drying and freeze-drying. The powders were evaluated for their mineral profile; structural properties were assessed through scanning electron microscopy (SEM), crystallinity was determined by X-ray diffraction (XRD), and the analysis of absorption spectroscopy in the infrared region (FTIR). Finally, the thermal profile was evaluated using thermogravimetry (TG/DTG). The trapiá powders combined with orange, lemon, and pineapple were found to be sources of magnesium and potassium, with appreciable levels of calcium. The powders containing lemon also provided copper, while those mixed with pineapple were sources of manganese. SEM images revealed spherical particles with smooth surfaces in the powders obtained from spray drying, whereas the freeze-dried powders exhibited larger particle sizes with irregular dimensions and rough surfaces. The thermogravimetric analysis demonstrated that the powders possessed high thermal stability, making them suitable for use in the food industry. The data from this study indicate that these powders are promising for use in various industrial formulations, characterized by their high mineral content and notable thermal stability.

Dipodal silane‐treated ramie woven matt reinforced polylactic acid biocomposites for improved mechanical and thermal properties

AbstractHot compression molding was used to produce biocomposites from ramie plain‐woven fabric‐reinforced polylactic acid (PLA). Prior to composite fabrication, alkali and dipodal silane (bis(3‐trimethoxysilylpropyl) amine) (BAS) were applied to improve fiber‐matrix adhesion. Mechanical tests revealed improvements in tensile and flexural strength due to interfacial adhesion. The flexural strength of ramie PLA composite samples treated only with silane (SR‐PLA) was the highest, at 136.35 MPa. Young's modulus was 7.51 GPa. BAS treatment was crucial for ensuring strong adhesion between the fabric and the PLA matrix. In combined alkali‐BAS‐treated composites (ASR‐PLA), the glass transition and crystallization temperatures disappeared completely, affecting PLA morphology. The maximum heat of absorption (373°C) was found in SR‐PLA composites, suggesting electrostatic interactions created a three‐dimensional network. In conclusion, the initial incorporation of dipodal silane resulted in the formation of six silanol linkages with ramie fabric, leading to enhancements in the mechanical and thermal characteristics of ramie–PLA composites.Highlights Alkali and BAS treated Fabrics ironed to remove treatment‐induced wrinkles. Carded PLA fiber with consistent density and weighted in four equal portions. Fabric and PLA lay alternatively in warp direction before compression molding. SR‐PLA composites exhibited improved thermal and mechanical properties.

Research on the design and thermal performance of vacuum insulation panel composite insulation materials

This study introduces a novel design methodology for composite insulation material aimed at reducing the operational energy consumption of buildings. Vacuum Insulation Panels (VIPs) are recognized for their excellent insulating properties due to their vacuum-sealed nature that minimizes thermal transmittance. However, VIPs are susceptible to damage from temperature stress and abrasion, which can compromise vacuum integrity and degrade performance over time. To mitigate this, a protective layer of rock wool board is adhered to the exterior of the VIP to create a composite insulation material. The thermal conductivity characteristics of the composite insulation materials are experimentally measured and then corroborated with simulations using ANSYS software to affirm the precision of finite element analysis methods. A composite Insulation wall model is constructed using ANSYS to analyze the impact of varying the thickness of the composite insulation materials and the pressure within the VIP on thermal performance. The findings demonstrate that the thermal transmittance coefficient of the composite insulated wall diminishes with increased insulation material thickness and rises with increased pressure within the VIP. Additionally, rock wool boards significantly enhance the durability of the composite insulation material.

Multiphysics Modeling of Heat Pipe Microreactor with Critical Control Drum Position Search

A multiphysics coupling methodology for heat pipe microreactors is presented in this work that includes a focus on a critical control drum position search routine and burnup capabilities. As the Serpent code is used for neutronics calculations, the recently developed GRsecant method for finding critical control drum positions is employed, which has explicit measures to manage the uncertainty introduced from the Monte Carlo calculation method. This work complements existing multiphysics modeling tools for heat pipe microreactors because it can be used to generate cross sections with fuel compositions determined by depletion with critical control drum positions. These methods are applied to a microreactor design motivated by the eVinciTM heat pipe microreactor. The convergence of the multiphysics coupling routine is analyzed at multiple burnup points. The multiphysics iterations with critical control drum search were observed to converge for all calculations performed in this work. Overall, the multiphysics coupling procedure enables the calculation of both thermal and neutronics characteristics with control drums in their critical positions for the core lifetime.

A control-oriented comprehensive model of PEM electrolyzer considering double-layer capacitance

The modeling of electrochemical and thermal characteristics of proton exchange membrane (PEM) electrolyzer is significant in the hydrogen production process. However, the calculation of electrode impedance and double-layer capacitance during operation is not accurate enough currently, and the electrothermal coupling characteristics of hydrogen production devices are not fully considered. In this paper, the multi-stage equivalent circuit of the PEM electrolyzer is designed using electrochemical impedance spectroscopy (EIS) and the time-constant fitting method. In addition, according to the temperature control system of the actual hydrogen production device, the electro-thermal model of the PEM electrolyzer is established, in which the fuzzy PID control is used to maintain the temperature stability. Moreover, the electrical characteristics and temperature characteristics are simulated in different time scales. Finally, compared to the existing models, the proposed model is more accurate, and it indicates that the proposed model has better accuracy against the existing models.

NUMERICAL SIMULATION OF DOUBLE SKIN FACADES IN WINTER CLIMATES

The presented study reveals the analysis of the thermal behaviour of double skin facades (DSF) in winter conditions, using numerical simulation tools. The aim of the study is the development of a 3D simulation model, capable to evaluate the thermal behaviour of the modular elements in the DSF systems. This is essential requirement in the prediction and visualization of the facade’s thermal behaviour in the design stage and in the assessment of the real behaviour of such facade, when the specified modular elements are changed by the customer. The presented numerical simulation model aims to adequately reproduce the resulting set of thermal characteristics of the modular elements, to determine with sufficient accuracy their distribution in the real objects, implemented inthe models in DSF systems. An algorithm is developed in the study and graphical visualization of three models of double facade systems with and without DSF are analysed under winter conditions, using data from a meteorological station located in North-Eastern Bulgaria. A software product was used to represent the processes of heat and mass transfer, in which the corresponding boundary and initial conditions were set, based on which the results and analyses were obtained. The use of such numerical modelling is effective enough to predict the expected thermal behaviour of DSF systems. Thus, when selecting a DSF facade system, awareness of the thermal behaviour is ensured, and the financial efficiency of the project is more easily determined. Such a customized approach not only improves the sustainability and efficiency of buildings, but also satisfies the unique preferences and requirements of the customers.

Numerical analysis of the influence of cooling design on temperature uniformity in the large proton exchange membrane fuel cell stack

The temperature distribution has a significant influence on the performance and lifespan of proton exchange membrane fuel cell (PEMFC) stacks. However, analyzing the temperature distribution of large PEMFC stacks is challenging and has been rarely conducted. In this study, a simplified model of a large PEMFC stack is developed using computational fluid dynamics (CFD) methods, which includes 300 cells and 60 cooling plates. The influence of cooling parameters, including configurations, dimension and flow rate, is discussed. The study indicates that U-type stack exhibits better temperature uniformity than Z-type stack. Increasing the coolant flow rate can effectively reduce the stack temperature. The study proposes a modified cooling design, which effectively reduces the heat accumulation at the end of the stack. Lastly, a comparison between traditional serpentine channels and porous foam metal flow fields reveals that the porous foam metal flow field exhibits superior thermal management characteristics. The results can offer insights for thermal management of large-scale PEMFC stacks.

Thermal characteristics of LiMnxFe1-xPO4 (x = 0, 0.6) cathode materials for safe lithium-ion batteries

Lithium-ion batteries have recently gained attention as energy storage devices due to their high energy densities and various applications. Layered Ni-Mn-Co-based cathode materials are widely used for their high energy density; however, their high cost necessitates the exploration of alternatives. Consequently, olivine-type LiMnxFe1-xPO4 materials are gaining popularity and are being increasingly adopted. While the synthesis methods and electrochemical properties of these materials have been extensively studied, thermal analyses remain limited. In this study, we investigated the thermal properties of olivine-type LiMnxFe1-xPO4 by combining thermal analysis, structural analysis, and computational calculations to evaluate the safety of lithium-ion batteries. Our results show that the formation energy of LiMn0.6Fe0.4PO4 is more stable than that of LiFePO4. As temperature increases, LiFePO4 decomposes at 350 °C, whereas LiMn0.6Fe0.4PO4 begins to decompose at 450 °C. The P-O bond plays a crucial role in the thermal stability of these materials; as the temperature rises, the thermal stability of the PO4 group diminishes, leading to structural decomposition. To enhance thermal stability, it is recommended to experiment with doping small amounts of various elements at the P site. This paper provides valuable insights for the design and development of thermally stable olivine-structured cathodes for lithium-ion batteries.

Evaluation into the effect of lignocellulosic biochar on the thermal properties of shape stable composite phase change materials

Biochar is suitable for preparing shape stable composite phase change materials (sscPCMs) due to the advantages of cost-effective, environmentally, and sustainability. However, the heat properties of biochar-based sscPCMs were not consistent. To investigate how different types of biochar influence the thermal properties of sscPCMs, three types of sscPCMs were successfully prepared using peanut shell biochar (PSC), poplar wood biochar (PWC), and corn straw biochar (CSC) as framework materials and combined with stearic acid (SA). A comprehensive analysis of the thermal properties of three sscPCMs was performed, taking into account thermal conductivity, phase change latent heat, encapsulation efficiency, crystallization rate, and energy storage efficiency. The study indicated that among the three types of sscPCMs, SA/PWC sscPCMs demonstrated excellent comprehensive performance. The phase change latent heat of SA/PWC reached 100.13 J/g, and the thermal conductivity was 0.38 W/mK. Compared to SA/PSC, the phase change latent heat of SA/PWC increased by 45.96 %, with only a 28.30 % reduction in thermal conductivity. In comparison to SA/CSC, the thermal conductivity of SA/PWC improved by 18.75 %, while the phase change latent heat decreased by only 14.02 %. In addition, the proportions of cellulose, hemicellulose, and lignin played a crucial role in determining the thermal properties of sscPCMs. This study clarified the mechanism by which biochar influences the thermal characteristic of sscPCMs, offering valuable insights for choosing biochar framework materials.

Thermal and rheological behavior of aluminium-doped zinc oxide nanofluids: Experimental study and application of artificial neural network model

In this study, the influence of Al-doping concentration on the thermal and rheological characteristics of pristine zinc oxide (ZnO) nanofluids was investigated across a range of temperatures and nanoparticle concentrations. A multilayer perceptron (MLP) artificial neural network (ANN) with an optimized topology was employed to model the thermal conductivity and viscosity of nanofluids. The addition of 0.13 M of Al-doped zinc oxide nanoparticles at 1 % rate led to a remarkable 64 % increase in the thermal conductivity of the base fluid (50:50 ratio water + ethylene glycol mixture). Furthermore, incorporating 1 % of these Al-doped nanoparticles outperformed pure zinc oxide, resulting in a 44 % boost in thermal conductivity. The enhanced heat transfer capabilities of Al-doped zinc oxide were evident across different doping and nanoparticle concentrations. The viscosity of nanofluids increases with an increase in nanoparticle concentration and decreases with an increase in temperature. ZnO and Al-doped ZnO nanoparticles have been prepared and studied their structural, morphological and elemental properties using XRD, SEM and EDS respectively. The predicted thermal and rheological behaviours are in close agreement with the experimental values.

Investigations on thermal and mechanical characteristics of PDMS embedded FBG sensors for wearable sensing applications

Abstract Fiber Bragg Grating (FBG) sensors embedded in polydimethylsiloxane (PDMS) are suitable for real-time monitoring of parameters like strain, temperature, force etc. This work investigates the thermal and mechanical properties of PDMS samples at mixing ratios of 6:1, 10:1, and 15:1 with embedded FBGs. The 10:1 sample showed the highest temperature sensitivity of 22.51±0.54 pm/◦C. Young’s modulus values from mechanical characterization ranged from 2.20-8.16 MPa, 2.56-7.68 MPa, and 0.44-5.02 MPa for mixing ratios 6:1, 10:1, and 15:1, respectively. The highest force and strain sensitivities were 1.356 nm/N and 0.153 pm/µϵ for the 10:1 ratio, making it preferable for wearable sensors.

Research on thermal runaway and gas generation characteristics of NCM811 high energy density lithium-ion batteries under different triggering methods

Safety concerns, including thermal runaway and gas generation, present significant challenges for high-energy-density lithium-ion batteries. Thermal abuse, a common trigger for thermal runaway, can be induced by various methods, including heating rods, coils, plates, and lasers. This study compares the impacts of three heating techniques—heating rods, coils, and plates—on thermal runaway and gas generation in a commercially used NCM811 lithium-ion battery, which has a high energy density of 280.24 Wh/kg (the latest cylindrical 46950 model). The study found that the heating coil was the most effective, triggering thermal runaway more quickly and at a higher temperature than the heating plate and rod. Gas production analysis revealed that the heating coil method generated significantly more gas, particularly CO2, than the other methods. The concentrations of gases produced during thermal runaway (CO, CO2, H2, and CH4) varied by heating method, with the heating coil leading to a more complete battery reaction. The safety evaluation highlighted the hazardous nature of the heating rod method, which produced the widest flammable gas concentration range and the highest explosion risk among the tested heating methods. This study provides critical insights into heating techniques in lithium-ion battery thermal runaway scenarios and offers valuable data for improving safety measures in energy storage systems.

Buckling-induced variations in electronic, thermal, and optical properties of B[formula omitted]C[formula omitted]N[formula omitted] monolayer: DFT and AIMD computational approaches

Density functional theory is employed to study the novel properties of B3C2N3 monolayer to gain a deeper understanding of variation of electronic, thermal, and optical characteristics arising due to buckling effects. The band structure analysis reveals an energy gap reduction of the buckled B3C2N3 monolayer, causing a displacement of the band gap from the visible to the infrared range. Moreover, the buckling controls the location of the initially, and finally, direct band gap moving it from the K to the Γ point in the B3C2N3 monolayer. The phonon band structure calculations indicate that buckled B3C2N3 monolayers are dynamically stable, while ab-initio molecular dynamics simulations, AIMD, evaluate and confirm the thermal stability of both flat and buckled B3C2N3 monolayers. The buckling phenomenon at low temperatures has no a significant impact on the heat capacity contrary to what happens in the high temperature limit. The optical characteristics of the B3C2N3 monolayer, including refractive index, optical conductivity, static dielectric function, and plasmon frequency, are evaluated at different levels of the buckling parameter. The static dielectric function and plasmon frequency are enhanced with the buckling due to the screening of the electron–electron interactions, affecting the collective oscillations. Enhanced screening gives rise higher plasmon frequencies. Tuning the buckling parameter illustrates the significance of buckling as an alternative mechanism for adjusting the performance of B3C2N3 two-dimensional materials for different technological applications such as solar and optoelectronic systems.

Fully coupled thermal-structural-vibration characteristics of 3-axis machine tools with complex hybrid linear axis-spindle systems considering structural nonlinearities

For machine tools composed of functional components bonded by joints with structural nonlinearities, the load- and temperature-dependent nonlinear restoring force,stiffness, and frictional heat generationfrom the jointdetermine its complex dynamic fully coupled thermal-structural-vibration characteristics. In response, in this work, considering the vibration feedback dominated by the structural vibration and employing a partition-based closed-loop iterative algorithm, a fully coupled thermal-structural-vibration model that characterizes the nonlinear coupling between temperature and mechanical fields is developed with the joint as the link. The multi-body dynamics model of the whole machine tool, considering the flexibility of the screw shaft, spindle, and joint nonlinearity, characterizes the milling dynamics influenced by structural vibration and regeneration effects. The global thermal resistance network model with dynamic heat flux, viscosity-temperature effect, and time-varying thermal resistanceis establishedto characterize the thermal characteristics. The partition-based closed-loop iterative algorithm is employed to realize the multi-field coupling and consider the moving heat source and the load distribution change caused by the reciprocating moving joint. Considering the changes in contact angle and contact deformation caused by preload, dynamic load, and thermal effect, load- and temperature-dependent nonlinear joint restoring force and stiffnessare developed. Based on the viscosity-temperature effects and the change of contact friction caused by thermal expansion and dynamic load, the load- and temperature-dependent nonlinear joint frictional heat generation is calculated. The milling load from tool-workpiece interaction is calculated, and the influence of multi-field coupling on regenerative chatter is explored. The proposed model was experimentally verified, andthe effectof parameterswas numerically investigated. The results show that the dynamic milling load excites the whole machine tool vibration, and for every 10 μm increase in cutting depth, the radial amplitude of the tool nose increased by at least 1 μm. The nonlinear coupling between temperature and mechanical field significantly affects the system response, and the joint contact stiffness dominates the multi-field coupling behavior.

Effect of gradation on thermal and mechanical properties of reaction‐bonded silicon carbide ceramics

AbstractParticle grading is a reliable method to improve mechanical properties of reaction‐bonded silicon carbide (RBSC) ceramics. This work aims to explore the effects of particle grading on thermal and mechanical characteristics of RBSC ceramics. Results showed that the powder grading enabled to increase sintering density of silicon carbide (SiC) ceramics. The use of large particle SiC powder in grading led to a 28% increase in thermal conductivity but a 22% decrease in bending strength. Meanwhile, the addition of finer SiC powder exerted minimal effect on thermal conductivity but noticeably increased bending strength by 10%. Therefore, properly adjusting particle size in grading allows for the control of residual Si content and microstructure, thereby simultaneously increasing thermal conductivity and bending strength of the material.