The electric [Formula: see text] and magnetic [Formula: see text] Compton polarizabilities of both the charged and the neutral pion are of fundamental interest in the low-energy sector of quantum chromodynamics (QCD). Pion polarizabilities affect the shape of the [Formula: see text] Compton scattering angular distribution at back scattering angles and [Formula: see text] absolute cross sections. Theory derivations are given for the [Formula: see text] Compton scattering differential cross section, dispersion relations, and sum rules in terms of the polarizabilities. We review experimental charged and neutral polarizability studies and theoretical predictions. The [Formula: see text] polarizabilities were deduced from DESY Crystal Ball [Formula: see text] data, but with large uncertainties. The charged pion polarizabilities were deduced most recently from (1) radiative pion Primakoff scattering [Formula: see text] at CERN COMPASS, (2) two-photon pion pair production [Formula: see text] at SLAC Mark II, and (3) radiative pion photoproduction [Formula: see text] from the proton at MAMI in Mainz. A stringent test of chiral perturbation theory (ChPT) is possible based on comparisons of precision experimental charged pion polarizabilities with ChPT predictions. Only the CERN COMPASS charged pion polarizability measurement has acceptably small uncertainties. Its value [Formula: see text] agrees well with the two-loop ChPT prediction [Formula: see text], strengthening the identification of the pion with the Goldstone boson of chiral symmetry breaking in QCD.
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