Thermodynamic Analysis of the Absorption of Common Refrigerants in Fluorinated Deep Eutectic Solvents

This study aimed to quantitatively assess the environmental impacts of different methods used for treating excavated soil and rock (ESR) in Shenzhen, namely landfilling, sintering, and non-sintering, using the life cycle assessment (LCA) method. The findings indicate that recycling ESR through sintering or non-sintering processes offers more sustainable alternatives than landfilling. The recycled products derived from ESR can effectively replace traditional building materials, thereby reducing their environmental impacts. However, when comparing the environmental impacts of sintering and non-sintering processes, the latter demonstrated more significant impacts, particularly in terms of global warming potential (GWP), acidification potential (AP), and eutrophication potential (EP). Furthermore, it is worth noting that the environmental impacts of the sintering processes are influenced by fuel type and exhaust gas emissions, with natural gas combustion yielding more substantial overall environmental benefits. Moreover, ESR landfilling poses constraints on sustainable development and land resource occupation. This study contributes to a better understanding of the environmental impacts associated with ESR landfilling and recycling, provides management departments with optimal ESR management suggestions, and alleviates environmental pressure from urban development.

Comparative life cycle assessment of light frame timber and reinforced concrete masonry structural systems for single-family houses in Luxembourg

Study of life cycle assessment: Transforming microalgae to biofuel through hydrothermal liquefaction and upgrading in organic or aqueous medium

The iron and steel industry is of great strategic importance in Indonesia and is expected to continue its growth. One sector within this industry that is projected to see increased production is the steel pipe manufacturing sector. However, the significant emissions produced during steel pipe production have prompted many countries to seek ways to reduce these emissions. One such method is the implementation of the Life Cycle Assessment (LCA) technique, which assesses the environmental impact and serves as a valuable decision-making tool alongside other important methods. This approach aims to enhance sustainable production and consumption effectively and efficiently. In a specific case study, two types of steel pipe products were analyzed using LCA, focusing on various stages from material transportation to steel pipe production and delivery. The study assessed the environmental impact using the midpoint impact category, which includes factors like Global Warming Potential (GWP), Photochemical Ozone Creation Potential (POCP), Acidification Potential (AP), and Ecological Toxicity Potential (ETP) using the CML2001 characterization methods. The findings revealed that the production of SAWH pipes has a higher environmental impact in terms of GWP, AP, and POCP compared to HFW pipes, while HFW pipes had a greater ETP value. GWP was identified as the most significant potential impact for both products, with the pipeline production stage contributing the most to GWP. Overall, these results offer an initial understanding of the sustainability levels of steel pipe production, serving as a foundation for the development of pollution control measures to maintain the competitiveness of the industrial plant.

Enhancing performance and sustainability: CRB600H high-strength reinforcement in recycled concrete

Prospective life cycle environmental impact assessment of renewable energy-based methanol production system: A case study in China

One popular methodology for assessing the environmental impact of livestock sector is Life Cycle Assessment (LCA), that quantifies the environmental impact of a product. Ecological Footprint (EF) performs an environmental sustainability assessment, by comparing the demand for natural capital by an economic activity with the offer of such capital within a certain territory. The aim of the study was the comparison between LCA and EF in assessing the environmental performances of milk production, assuming as case study three cattle farms with increasing levels of production intensity. Different metrics and functional units (FU) (i.e., fat and protein corrected milk, FPCM and hectare) were adopted for LCA analysis, considering some of the major impact categories. For greenhouse gases emissions, the Global Warming Potential (GWP) and the Global Temperature Potential (GTP) were considered. Both metrics were calculated assuming or not the distinction between biogenic and fossil methane. Adopting GWP as a metric, the results per kg of FPCM provided by the LCA highlighted a different trade off compared to the EF method: the farm with the highest productive intensity produced the least impactful milk in terms of GWP but had the most negative Ecological Balance (EB). The same occurred for the other impact categories. When GTP was adopted, or the hectare was considered as FU, the least intensive farm, characterized by greater feed self-sufficiency, became the one that produced the least impactful milk and had the least negative EB. The study highlighted the scientific significance of the integration between the two approaches for creating a comprehensive representation of the effects of human activities on the environment. The LCA method evaluates impacts intensity referred to a specific functional unit and its results are strongly influenced by productive efficiency; the EF method evaluates environmental sustainability of productions in relation to the territory that supports them.

Hydrogen fuel and electricity are energy carriers viewed as promising alternatives for the modernization and decarbonization of public bus transportation fleets. In order to choose development pathways that will lead transportation systems toward a sustainable future, the authors developed an environmental model based on the Life Cycle Assessment approach. The model tested the impact of energy carrier consumption during driving as well as the electricity origin employed to power electric buses and produce hydrogen. Energy sources such as wind, solar, waste and grid electricity were investigated. The scope of the study included the life cycles of the energy carrier and the necessary infrastructure. The results were presented from two perspectives: the total environmental impact and global warming potential. In order to create a roadmap, an original method for choosing sustainable development pathways was prepared. It was shown that the modernization of conventional bus fleets using hydrogen and electrical pathways can provide significant environmental benefits from both perspectives, but especially in terms of global warming potential. It was emphasized that attention should be paid to the use of low- and zero-emission energy sources, because their impact often strongly influenced the final environmental judgment. The energy carrier consumption also had a strong impact on the results obtained, and that is why efforts should be made to reduce it. In addition, it was confirmed that hydrogen and electricity production systems based on electricity generated by a waste-to-energy plant could be an environmentally reasonable dual solution for both sustainable waste management and meeting transport needs.

ABSTRACT In the last decade, research is pushing forward the use of innovative techniques and environmentally friendly materials aiming at sustainable development in the road sector. In the present paper, a 100% RAP mixture is proposed through an innovative cold recycling in-situ technique for road pavement maintenance of small damaged sections and repairing distresses. The localized patching is developed through an innovative milling machine that is capable of directly and simultaneously milling and mixing the RAP produced. The innovative machine develops repairs that guarantee the safety and comfort of users. For obtaining the final mixture, RAP is combined with cement and a chemical additive. The experimental program was divided into a laboratory study of the milled material and a trial field campaign. After these phases, the environmental impacts that affect the repaired road sections are also evaluated through Life Cycle Assessment (LCA) tool. Tests from the laboratory and field phase highlighted positive results and downsides that need to be optimized to obtain a good quality intervention. The LCA analysis showed a positive impact in terms of global warming potential. Thanks to the use of this innovative machine, it is possible to mitigate the negative environmental impact associated with road pavement maintenance.

Assessing technological properties and environmental impact of fired bricks made by partially adding bottom ash from an industrial approach

In this study, the life cycle assessment (LCA) method has been used to evaluate the environmental impacts of various municipal solid waste (MSW) management system scenarios in Banepa municipality, Nepal, in terms of global warming potential (GWP), acidification potential (AP), eutrophication potential (EP), human toxicity potential (HTP), abiotic depletion potential (ADP), and photochemical ozone creation potential (POCP). There are at least six possible scenarios of MSW management in Banepa: the current or baseline scenario (Scenario 1); composting with landfilling (Scenario 2); material recovery facility (MRF) recycling, composting, and landfilling (Scenario 3); MRF and anaerobic digestion (AD); composting, and landfilling (Scenario 4); MRF, composting, AD, and landfilling (Scenario 5); and, finally, incineration with landfilling (Scenario 6). Using both information from Ecoinvent 3.6 (2019) and published research articles, a spreadsheet tool based on the LCA approach was created. The impact of the recycling rate on each of the six abovementioned scenarios was evaluated using sensitivity analysis, which showed that the recycling rate can considerably decrease the life-cycle emissions from the MSW management system. Scenario 3 was found to have the least overall environmental impact with a GWP of 974.82 kg CO2 eq. per metric ton (t), EP of 0.04 kg PO4 eq./t, AP of 0.15 kg SO2 eq./t, HTP of 4.55 kg 1,4 DB eq./t, ADP of −0.03 kg Sb eq./t, and POCP of 0.06 kg C2H4 eq./t. By adoption of MRF and biological treatments such as composting and AD, environmental impact categories such as AP, EP, HTP, ADP, POCP, and GWP can be significantly reduced. The findings of this study can potentially serve as a reference for cities in the developing world in order to aid in both the planning and the operation of environmentally friendly MSW management systems.

Abstract Since the 1950s, 8.3 billion tonnes (Bt) of virgin plastics have been produced, of which around 5 Bt have accumulated as waste in oceans and other natural environments, posing severe threats to entire ecosystems. The need for sustainable bio‐based alternatives to traditional petroleum‐derived plastics is evident. Bioplastics produced from unprocessed biological materials have thus far suffered from heterogeneous and non‐cohesive morphologies, which lead to weak mechanical properties and lack of processability, hindering their industrial integration. Here, a fast, simple, and scalable process is presented to transform raw microalgae into a self‐bonded, recyclable, and backyard‐compostable bioplastic with attractive mechanical properties surpassing those of other biobased plastics such as thermoplastic starch. Upon hot‐pressing, the abundant and photosynthetic algae spirulina forms cohesive bioplastics with flexural modulus and strength in the range 3–5 GPa and 25.5–57 MPa, respectively, depending on pre‐processing conditions and the addition of nanofillers. The machinability of these bioplastics, along with self‐extinguishing properties, make them promising candidates for consumer plastics. Mechanical recycling and fast biodegradation in soil are demonstrated as end‐of‐life options. Finally, the environmental impacts are discussed in terms of global warming potential, highlighting the benefits of using a carbon‐negative feedstock such as spirulina to fabricate plastics.

Abstract Grass carp, Ctenopharyngodon idella, is the largest freshwater aquaculture fish species worldwide. However, its environmental impacts are increasingly controversial. In this paper, we considered the production of a 1500 g commercial grass carp as an example, analyzed through a life cycle assessment. The results showed that the indicators of global warming potential (GWP), acidification potential, eutrophication potential, freshwater eco‐toxicity potential (FAETP), land competition (LC), and fossil energy consumption of producing 1 kg of grass carp were equivalent to 5.7267 kg of CO2, 0.0648 kg of 1,4‐DCB0, 0.0010 kg of P, 0.0276 kg of SO2, 8.2951 m2, 0.3491 kg of oil, respectively, and were mainly from feed processing and water pollution. Compared with pig, beef, and sheep production, grass carp production has lower environmental impacts, but in terms of GWP, FAETP, and LC were significantly higher than chicken production, especially water pollution and discharge, which is an important consideration. This study clarifies the direction of grass carp production and key focus areas include producing low carbon and nitrogen emission feed, application of ecological engineering aquaculture system, intelligent mechanization technology and equipment.

Investigating the mitigation of greenhouse gas emissions from municipal solid waste management using ant colony algorithm, Monte Carlo simulation and LCA approach in terms of EU Green Deal

Sustainable development, one of the main challenges of our time, is a policy focused on the perfect balance between three fundamental pillars: environmental, economic and social sustainability. As regards the environmental protection, the Life Cycle Assessment (LCA) methodology allows to evaluate the sustainability profile of the overall Life-Cycle (LC) of products, processes and services, based on an inventory (in terms of materials/energy consumption and emissions/waste production) referred to all LC stages. The paper describes an application of LCA in the maritime transportation field, after a careful analysis of the state of the art. In particular, the case study consists in the environmental comparison of two alternative design solutions for the superstructure of a Azimut-Benetti yacht, designed by Corporate R&D department and manufactured in one of Benetti botyards. The competing construction options are a Glass Fiber reinforced Vinylester-isophthalic Resin (GFVR) and a Carbon Fiber reinforced Epoxy Resin (CFER) component, and they are assessed in terms of Global Warming Potential through the CML2001 Life Cyle Impact Assessment (LCIA) method. The study takes into account the entire LC of the superstructure component, divided into production (including raw materials, manufacturing and transportations), use (including both fuel consumption and exhaust air emissions) and End-of-Life (EoL). The Life Cycle Inventory (LCI) is mainly based on primary data (materials and energy consumption for manufacturing) directly provided by the construction company; missing data are retrieved from secondary sources (literature and LCI database provided by the GaBi6 environmental software). Results show that, despite the higher impact in production stage, the innovative solution allows achieving a significant quota of GWP over the entire LC (more than 16%), which is mainly associated with decreased amount of fuel needed and lowered CO2 exhaust emissions during operation. The sensitivity analysis reveals that the environmental advantage provided by the CFER design becomes bigger as both component life-time and yacht consumption increase.

Coatings are essential for protecting structural steel bridges from corrosion in harsh environmental conditions. The selection of a suitable coating system can significantly impact the performance and longevity of a bridge as well as its environmental footprint. This study investigates the U.S. and Canada’s environmental ISO corrosivity map and the general environments to which bridges are exposed. Additionally, environmental data and road maintenance practices of transportation departments and the use of de-icing salts were investigated to examine the impact of micro-corrosive environments on bridge elements. The study reviews commonly examined coating systems and their expected service life in moderate and highly corrosive environments. This sheds light on factors influencing coating system selection, such as life-cycle cost analysis and maintenance practices for bridge elements. For the first time to our knowledge, an environmental life-cycle evaluation of one of the most commonly used coating systems with theoretical maintenance scheduling for a bridge project’s expected service life is presented to encourage the use of a quantitative tool for environmental impact assessment of coatings in terms of global warming potential (GWP). Additionally, perspectives on patented state-of-the-art and future steel-protective technologies and their potential role in bridge engineering are reviewed.

Rigorous environmental and energy life cycle assessment of blast furnace pig iron in Brazil: The role of carbon and iron sources, and co-product utilization

Nowadays, biogas produced from the anaerobic digestion of biowaste is considered a valuable renewable energy source to implement the transition to a climate-neutral society. Recently, biogas upgrading to biomethane, instead of the usual co-generation of heat and electricity (CHP), has been an attractive option, as biomethane can be used for different purposes. This study performed the life cycle assessment (LCA) and life cycle costing (LCC) of different scenarios for the valorization of the biogas produced from the anaerobic co-digestion (AcoD) of secondary sewage sludge (SS) and organic fraction of municipal solid waste (OFMSW), pre-treated by an anaerobic dark co-fermentation (DF) process. Four configurations were compared, exploring the recovery of one or more of the following: heat, electricity and biomethane. Furthermore, two sensitivity analyses were performed on LCA analysis, considering the use of the produced biomethane as a fuel for transport and the European electricity mix expected by 2050, respectively. The use of biogas for CHP was the most environmentally friendly solutions in 8 out of 11 impact categories provided by the CML-IA baseline method; however, biogas upgrading-based scenarios showed less impacts in relevant categories, such as global warming potential (up to −1.14E+05 kg CO2 eq. y−1) and ozone layer depletion potential (up to −4.73E-01 kg CFC-11 eq. y−1). Sensitivity analyses confirmed that the biogas upgrading processes should have generally a lower impact on climate change than CHP systems. Furthermore, the use of biomethane to replace petrol resulted to be the best option in terms of global warming potential (up to −5.67E+05 kg CO2 eq. y−1). All the proposed configurations represented economically sustainable projects, as they reported positive net present values (NPV) in 20 years (up to 10,518,291 €). Biogas upgrading-based scenarios showed the highest NPVs; nevertheless, the combined production of heat, electricity and biomethane was the most cost-effective option, thanks to biomethane revenues and electricity sales, despite the latter being modest. In conclusion, contrary to most of the previous studies in the literature, we found that CHP should not be neglected, as the optimal configuration may lie in the combined recovery of biomethane, electricity and heat.

This work is aimed at investigating the effects derived from the application of minimum amounts of two different sized biochars, obtained through biomass gasification, on the greenhouse gases and ammonia emissions from a co-composting process of the organic fraction of municipal solid waste. The chosen biochar-to-organic waste share is set to 3% w/w dry, and the results obtained are compared with a conventional composting process without biochar. Nine aerated static pilot-scale bins with a volume of 1.3 m3 were prototyped and run, three per thesis and three for the control. The trial lasted 63 days, following the same approach used in full-scale composting facilities. The testing period was divided into a forced aeration phase followed by a static phase. In terms of global warming potential, the use of fine biochar and coarse biochar resulted in 13 and 11 kg CO2eq ton-1 emitted respectively. These values are 36% and 45% lower than the 20 kg of CO2eq ton-1 emitted by the control theses. Specifically, the chosen minimum amounts of biochar produced a reduction of CH4 and N2O, while a significant reduction in NH3 emissions was not detected. Carbon dioxide showed a slight increase in biochar theses. This work has proven that fine and coarse gasification-derived biochars improve the bio-oxidative phenomena and reduce greenhouse gases emissions of the composters, regardless of the biochar particle size and regardless of the modest 3% w/w biochar-to-organic waste share used.