Tectonic Thermal Event Research Articles

Pan-African and Early Paleozoic Orogenic Events in Southern Tibet: Evidence from Geochronology and Geochemistry of the Kangbuzhenri Gneissic Granite in the Zhegu Area

The Zhegu area in southern Tibet is situated in the central and eastern part of the Tethys Himalayan tectonic belt, with the Kangbuzhenri area being abundant in gneissic granites. This study examines the petrology, chronology, and geochemistry of the Kangbuzhenri gneissic granite, providing insights into its Pan-African and Early Paleozoic geological evolution. The zircon U-Pb chronology indicates an upper intercept age of ~539 Ma, reflecting Pan-African orogenic events in the eastern part of the Tethys Himalayan tectonic belt, and a lower intercept age of ~144 Ma, representing a late tectonic–thermal event. Geochemically, the gneissic granites are calc-alkaline peraluminous rocks with high SiO2 and Al2O3 contents and low TiO2, P2O5, MgO, and FeOT contents. The gneissic granites are enriched in LREE and LILEs (Rb, Pb, Th, U, etc.), but relatively depleted in HREE and HFSEs (Nb, Ti, P, etc.). Most of them show a weak negative δEu anomaly, except for two samples which show a significant negative δEu anomaly due to the crystallization of plagioclase. Based on the above study, most of the gneissic granites exhibited the characteristics of an I-type granite, while two of the samples were a highly differentiated I-type granite with S-type affinities. All the above characteristics indicate that the gneissic granite likely originated from the partial melting of crustal materials and sediments with a minor involvement of mantle-derived materials. Combined with the previous chronological studies, the Kangbuzhenri gneissic granites were formed in an extensional tectonic environment during post-collision orogeny and then they were influenced by the Kerguelen mantle plume tectonic–thermal event around ~144 Ma and the subsequent Southern Tibet Detachment System (STDS).

New Rock Magnetism and Magnetic Fabrics Studies on the Late Triassic Volcanic Rocks from Qaidam Block, Northern Tibetan Plateau

The Qaidam Block, located at the northern Qinghai–Tibet Plateau, is a pivotal area in unraveling the closure time of the Kunlun Ocean basin which might have recorded the transformation process between the Proto-Tethys and Paleo-Tethys Ocean basins. However, the late Triassic position of the Qaidam Block remains enigmatic, largely due to the scarcity of paleomagnetic data essential for quantitatively determining its paleolatitude. The widespread presence of the Elashan formation, particularly along the southern periphery of the Qaidam block, presents good material for conducting paleomagnetic work. Nevertheless, the primary magnetic carriers preserved within the Elashan formation might be influenced by multiple tectonic thermal events, particularly those associated with collisions between southern blocks and the Qaidam Block. Here we present rock magnetism and magnetic fabrics studies to identify the content and composition of magnetic minerals within the Elashan formation. The rock magnetic and petrologic results show that the magnetic carriers in the samples from the Elashan formation are dominated by magnetite with a small amount of goethite, pyrrhotite, and hematite. The results of Anisotropy in Magnetic Susceptibility indicate that the south of the Longwalangku section might not be obviously influenced by the tectonic events. Our results also provided guidance for future paleomagnetic research, emphasizing the importance of conducting further sampling away from adjacent faults, particularly in the southern Longwalangku area.

Thermochronology of the Laojunshan–Song Chai Granite Gneiss Massif (North Vietnam, South China)

A reconstruction of the tectonothermal evolution of the Laojunshan–Song Chai granite gneiss massif (North Vietnam, South China) was carried out, based on summaries of the latest isotopic and fission-track dating results. The recorded wide range (420–465 Ma) of the age of granite gneiss rocks testifies to the long-term existence of a partially molten layer at a depth of 20–30 km for several tens of Ma. By the Devonian–early Carboniferous, a section of the excessively thickened crust was denudated, the massif was exhumated to the level of the upper crust, and isotope systems were “frozen”. The rate of uplift of the rocks of the massif is estimated to be about 0.2–0.5 mm/year. In the further history of the granite gneiss massif, episodes of repeated burial to a depth of about 13 km are recorded, associated with the Indosinian collision. The rocks have experienced metamorphism of the amphibolite-green schist facies, accompanied by tectonic transport in the form of a thrust sheet. Over the next 200 Ma, the uplift of the massif and the erosion of the overlying strata occurred in discrete pulses, during a sequence of active tectonic events. Thus, the thermochronological and P-T history of the Laojunshan–Song Chai massif is a kind of chronicle of regional tectonic–thermal events. In the history of the massif, traces of two orogenic cycles associated with the collision of the Cathaysia and Yangtze blocks in the Lower Paleozoic and the Indosinian collision in the Triassic are recorded.

Meso-Neoproterozoic tectonic-thermal events in the Qaidam Block, NW China and their geological significance: Constraints from drill cores geochronology and geochemistry studies

As a micro-continent lying at the junction of the North China, Yangtze, and Tarim Cratons in northwest China, the composition and tectonic-thermal history of the Qaidam Block not only are crucial for determining its tectonic attribute and relationships with surrounding cratons, but also can provide key constraints on convergence, fragmentation, and paleogeographic reconstruction of Columbia and Rodinia. In this study, systematic petrology, geochemistry, and zircon U–Pb–Hf isotope analyses were conducted on newly discovered Meso-Neoproterozoic granitic rocks from drill cores in the Qaidam basin and three stages granitic magmatism at ca. 1420 Ma, ca. 900 Ma and 780–750 Ma are yielded. The ca. 1420 Ma granitic rocks exhibit characteristics of highly fractionated I-type granites, with high Yb but low Sr contents, low Sr/Y and La/Yb ratios, high zircon saturation temperatures (774–831 ℃), and positive εHf(t) values (–0.04 to +11.35) with TDM2 values of 2178–1468 Ma, suggesting that they were mainly derived from the ancient crust with mantle magma input under an extensional setting. The ca. 900 Ma granitic rocks have high A/CNK values (1.01–1.21) and variable zircon εHf(t) values (–1.93 to + 6.58) with TDM2 ages between 1402 and 1910 Ma, indicating they are S-type granites formed by partial melting of sedimentary rocks in thickened crust. The ca. 780–750 Ma granites have high Zr + Nb + Ce + Y contents, 10000* Ga/Al ratios, and crystallization temperatures (mean = 808 ℃), belonging to the A1-type granite formed in a continental rift setting.Combined with the previous researches, the Meso-Neoproterozoic tectonic-thermal events in the Qaidam Block can be divided into three stages, 1.8–1.1 Ga, 1.0–0.9 Ga and 850–750 Ma, corresponding to the fragmentation of Columbia, and the assembly and breakup of Rodinia, respectively. Comparing the Qaidam Block with the surrounding blocks and the major cratons in Columbia and Rodinia, it is considered that the Qaidam Block was splited from the Tarim Craton and they may have occupied an interior position in Columbia but a peripheral position in Rodinia, connecting to the India and East Antarctica.

Geochemical properties, mechanism of formation, and source of solid bitumen in the Ediacaran Dengying Formation from the central to northern Sichuan Basin, China

Several large gas reservoirs, including the Weiyuan and Anyue gas fields, have been discovered in the Ediacaran Dengying Formation in the Sichuan Basin, indicating vast opportunities for deep-petroleum exploration. Understanding the origin and evolution process of these gas reservoirs is crucial for further petroleum exploration and development. Although the burial history of the Sichuan Basin and its surrounding areas is basically dominated by Paleozoic burial and preservation, and Meso-Cenozoic uplift and erosion. However, the source of the Dengying Formation natural gas in the Sichuan Basin is still a subject of controversy between the Ediacaran and Cambrian source rocks due to high thermal maturity, secondary alteration, and multistage tectonic activities. This study aims to examine the investigation on the properties and genetics of Dengying solid bitumens that existed in the central to northern Sichuan Basin, in order to provide insights into the source and evolution history of the Dengying paleo-oil reservoirs. For this purpose, petrologic, elemental, and organic geochemical analyses were used to investigate the properties, origin, and formation mechanism of solid bitumens. The results indicate that these solid bitumens have suffered intense thermal alteration (EqVRo 2.1%–5.3%), and are classified as pyrobitumens. Solid bitumens in the Gaoshiti bulge and the north slope area were subjected to tectonic thermal events (e.g., Emeishan igneous province) and relatively strong thermochemical sulfate reduction (TSR) alteration. These solid bitumens were assumed to be pyrolysis products of light (condensate) oil. In contrast, solid bitumens in the Weiyuan bulge and the Micangshan uplift area were not influenced by tectonic thermal events but experienced weak TSR alteration, and originated from either normal or heavy crude oil. Moreover, a systematic bitumen-source correlation was carried out using δ13Corg values, bound steranes, and trace element distributions. Results reveal that the solid bitumens in the central Sichuan paleo-uplift were mainly derived from the lower Cambrian Maidiping Formation, those in the north slope area originated from the lower Cambrian Qiongzhusi Formation, while those in the Micangshan area were sourced from the Ediacaran Doushantuo Formation. Structural and burial history analysis implies that the differences in the source of the Dengying paleo-oil reservoir (i.e., solid bitumen) between these study areas are attributed to the distribution of source rocks and their contact relationship with reservoirs. This research successfully obtained insights into the source and genetic mechanism of paleo-oil reservoirs by analyzing the properties of high-maturity solid bitumens, which can guide further exploration and development of deep petroleum resources.

Thermal evolution and hydrocarbon generation history of the Weibei uplift in the Ordos Basin

The Weibei uplift in the Ordos Basin has a distinctive tectonic setting and intricate evolutionary history. Along these lines, we have used the stratum temperature, apatite fission track, and vitrinite reflectance data to restore the thermal and hydrocarbon generation histories of the Weibei uplift. The average value of the present geothermal gradient of the Weibei uplift was 27.9°C/km, and the heat flow was 64.9 mW/m2. The Weibei uplift exhibited a moderate geothermal field. Three uplift cooling events occurred in the Weibei uplift during the Mesozoic era: the late Jurassic-early Cretaceous (162–125 Ma), the late Cretaceous (105–65 Ma), and the Eocene-Oligocene (40–27 Ma). The uplift history indicates an early uplift in the south region and a late uplift in the later stage. The thermal evolution history simulation demonstrates that the lower Palaeozoic Ordovician source rocks began to enter the hydrocarbon generation threshold in the middle Permian-late Permian (270 Ma) era and joined the hydrocarbon generation peak in the early-middle Jurassic event (180 Ma). The upper Palaeozoic Carboniferous-Permian source rocks began to enter the hydrocarbon generation threshold in the later period of the middle Permian period (235 Ma). They joined the hydrocarbon generation peak in the late Jurassic-early Cretaceous period (150 Ma). In addition, Triassic source rocks entered the hydrocarbon generation threshold in the early Cretaceous era (135 Ma) and did not enter the hydrocarbon generation peak until now. The low geothermal gradient of the Weibei uplift in the Palaeozoic-early Mesozoic reached the maximum paleotemperature in the early Mesozoic era (100 Ma) because of tectonic thermal events. The highest geothermal gradient of the early Cretaceous reached 51.5°C/km. The peak period of the hydrocarbon generation of source rocks of the different horizons in the Weibei uplift was regulated by the geothermal field of the early Cretaceous event. Since the late Cretaceous period, the stratum has been uplifted and cooled rapidly, and the hydrocarbon generation process of the source rocks has ceased.

Carbonate U-Pb Geochronology and Clumped Isotope Constraints on the Origin of Hydrothermal Dolomites: A Case Study in the Middle Permian Qixia Formation, Sichuan Basin, South China

Reservoirs in the dolomites of the Middle Permian Qixia Formation in the Sichuan Basin are currently important oil and gas exploration objects in China. However, the questions concerning the sources of the dolomitized fluids and the control factors of the Qixia hydrothermal dolomites remain unclear. In this study, the original hydrothermal dolomites (the replacement dolomites (RDs) and saddle dolomites (SDs)) from the Qixia Formation in the southwestern Sichuan Basin (the PR1 well and Baoxing section) were mainly examined using novel in situ carbonate U-Pb dating with clumped isotopes (∆47). Our results show that the U-Pb ages of the latest SDs from the PR1 well (located in the middle zone of the Emeishan large igneous province (ELIP) and distanced from the Orogenic Belt of Longmenshan) are 257.9–251.0 Ma, coincident with the period of main activity of the ELIP. Combined with the previous U-Pb dating, we propose that the high-temperature T∆47 (82.2–108.4 °C and 127.5–205.9 °C) recorded for SDs from the PR1 well and Baoxing section may have responded to ELIP activity and Longmenshan orogeny activity, respectively. In addition, in the entire southwestern Sichuan Basin, the RDs and SDs yield similar δ13C and δ18O values, indicating that the dolomites were formed by hydrothermal fluids of similar sources, with marine hydrothermal fluids being a highly possible source. Finally, this study proposes a new hydrothermal dolomite genesis model for the Qixia Formation, emphasizing that the formation of hydrothermal dolomites mainly depends on the proximity to tectonic thermal events in space and time.

Deep electrical structure of the hinterland of Yunkai magmatic arc in South China and the seismogenic environment of the 2019 Beiliu earthquake

The Yunkai Magmatic Arc (YKMA) is located southwest of the South China Block. It has experienced the amalgamation, splitting, and intracontinental orogeny caused by multistage tectonic thermal events. It is also a concentrated area of strong earthquakes in South China. On 12 October 2019, the Beiliu M5.2 earthquake occurred in the hinterland of the YKMA. To reveal the deep electrical structure of the YKMA and the seismogenic environment of the Beiliu earthquake, 101 high-quality data from the magnetotelluric (MT) survey points were acquired. The deep electrical structure images were obtained by three-dimensional electromagnetic inversion imaging. The results indicated that the deep part of the hinterland of the YKMA is characterized by a mushroom-shaped electrical structure composed of ultra-high resistance (R1, with a resistivity value exceeding 10,000 Ωm) and sub-high resistance (R2, with a resistivity value of about 1,000–10,000 Ωm) bodies. The epicenter of the Beiliu M5.2 earthquake was located in R1, close to the contact region between R1 and R2. There are broad low resistivity zones on the southeast and northwest sides of the YKMA. The low resistivity zones is considered to be correspond to the deep extension of the Wuchuan-Sihui and Hepu-Beiliu brittle-ductile shear zones, respectively. The brittle-ductile shearing of the boundary zones and the oblique upwelling of deep mantle-derived magma from the Leiqiong region are the main reasons for the activation of faults and the activity of moderate and strong earthquakes in the YKMA. In this geodynamic environment, local stress and strain accumulation easily occur in the brittle high resistivity body (R1). When the strain energy accumulation exceeded the threshold value that the rock could withstand, new fracture dislocations occurred in the weak region where R1 and R2 contact, which finally resulted in the 2019 Beiliu M5.2 earthquake.

Fission-track thermochronological evidence for the Yanshanian tectonic evolution of the northern Junggar Basin, northwest China

The Junggar Basin is a multicycle intracontinental sedimentary basin developed on the pre-Mesozoic deformed basement. For a long time, the Junggar Basin and its adjacent Altai orogeny have been a focus of debate for geologists studying the opening and closing history of the Paleozoic Asian Ocean and Cenozoic intracontinental deformation. However, there has been no detailed research on the intracontinental tectonic activities of northern Xinjiang since the Mesozoic, particularly the Yanshanian tectonic activities in the northern Junggar Basin. Fission-track (FT) dating was conducted on 15 apatite samples and eight zircon samples obtained from the northern Junggar Basin to better understand the Yanshanian tectonic evolution. The results showed that apatite FT (AFT) ages ranged from 131 to 42 Ma and zircon FT ages ranged from 205 to 132 Ma. Based on the AFT track thermal history modeling and the regional geological data, we proposed that the northern Junggar Basin underwent three tectonic thermal events during 165–161, 93–81, and 72–66 Ma. The thermal events of 165–161 Ma may indicate magmatic activity during the Yanshanian, while the 93–86 and 72–66 Ma events reflect Late Cretaceous uplift and cooling. This study has confirmed the tectonic evolution of the Yanshanian in the northern Junggar Basin from the perspective of thermochronology. It has also revealed that the Yanshanian orogeny, a regional tectonic event, may have also occurred in northwest China.

Key stage and model of hydrocarbon accumulation of Ordovician reservoir in Gucheng area, Tarim Basin, China

The heterogeneity of deep carbonate reservoirs is strong, it is significant for exploration and development to clarify the key stages of oil and gas accumulation. Taking the Ordovician in the Gucheng area of Tarim Basin as an example, this paper systematically investigated the key stage and model of hydrocarbon accumulation using the data of the cores, thin sections, cathode luminescence tests, laser ablation U-Pb isotope geochronometry, bitumen reflectance, and fluid inclusion tests, and seismic interpretation. (1) The Tarim Basin mainly develops three sets of effective source rocks, namely the Cambrian Yuertusi Formation, Cambrian Moheershan Formation, and Mid-Lower Ordovician Heituwa Formation, which are concentrated in the slope-basin facies of eastern Tarim Basin. (2) The Gucheng area is located in a favorable paleo-structural position. The pathway system composed of vertical faults and lateral unconformities occurs in the paleo-uplift, which is critical for hydrocarbon migration and accumulation. (3) The laser in-situ U-Pb dating, distribution and genesis of reservoir bitumen, burial-thermal maturation history, and the homogenization temperature of fluid inclusions suggest that the multi-stage tectonic thermal events of the Caledonian and Hercynian stages result in key adjustment and modification to deep hydrocarbon accumulation. Due to magmatic hydrothermal activities, the Caledonian primary oil reservoir massively evolved into oil-cracking gas reservoirs and residual paleo-oil reservoirs. (4) The paleo tectonic-fluid effect plays an important factor controlling the development of the Ordovician reservoirs. The evolution of the hydrocarbon accumulation in Gucheng area can be divided into three stages, namely formation of primary oil and gas reservoirs, oil-cracking gas reservoirs, and adjustment, destruction and reforming of gas reservoirs. To sum up, the western and northern parts of the paleo-uplift with favorable source-reservoir-cap rock assemblage and less effects of hydrothermal activities are the favorable zones for hydrocarbon exploration in the Gucheng area, the Tarim Basin.

Influence of the Emeishan basalt eruption on hydrocarbon generation and expulsion characteristics of Sinian (Ediacaran) algal dolomite in Sichuan Basin

Deep marine carbonate oil and gas resources in the Sichuan Basin are currently key exploration areas. As an important tectonic thermal event, the Emeishan mantle plume has an important influence on the source rocks under the Middle-Lower Permian in the Sichuan Basin. Therefore, the better understanding of the effect of Emeishan basalt eruption on source rock is vital for the exploration of marine oil and gas resources. On the basis of the thermal history study of the Sichuan Basin, this study restored the thermal maturity of the algal dolomite of the Sinian (Ediacaran) Dengying Formation in the Sichuan Basin in normal evolution. Using the hydrocarbon generation potential variation method, the hydrocarbon generation and expulsion characteristics of normally evolved algal dolomite and algal dolomite affected by basalt eruption were calculated. Through comparison, the influence of the Emeishan mantle plume on the algal dolomite of the Sinian Dengying Formation is analyzed. The research indicates that the thermal effect of the Emeishan mantle plume promotes the maturation of algal dolomite, which leads to the shortening of the oil generation period and the early arrival of the gas generation peak. The main hydrocarbon expulsion period of the normally evolved algal dolomite should be from the end of the Triassic to the end of the Jurassic, while the main hydrocarbon expulsion period of the algal dolomite affected by basalt eruption was advanced to the end of Silurian to the end of Triassic. In the current period, due to the high maturity of algal dolomite, the Emeishan mantle plume has little impact on the total resources.

In Situ Monazite U–Pb Ages in Thin Sections from the Giant Bayan Obo Fe–REE–Nb Deposit, Inner Mongolia: Implications for Formation Sequences

The Bayan Obo deposit is the largest REE resource in the world. Although many isotopic dating methods have been applied, ages based on petrography and closure temperatures still lack discussion. In this study, three digital petrographic images were created based on full-scanning microscopy, BSE, and TESCAN integrated mineral analysis (TIMA), providing a more scientific method for analyzing the mineral types, distributions, and content of the Bayan Obo deposit. By combining the full-scan images, monazites were selected in thin sections and dated in situ. The monazite in the body ores sample yields three 207Pb intercept ages of 657 ± 25 Ma (MSWD = 1.06), 763 ± 16 Ma (MSWD = 1.3), and 689 ± 22 Ma (MSWD = 8.1), and the monazite in one section yields maximum and minimum ages of 1393 ± 142 Ma and 429 ± 24 Ma, respectively. Combined with previous studies, the earliest and major stages of carbonatites, REE, and dikes in the Bayan Obo deposit area were dated at ~1.4 Ga and ~1.3 Ga, respectively. Due to the multiple subduction and accretion events related to the Paleo-Asian Ocean and North China Craton, the Bayan Obo deposit is intensely overprinted, with a tectonic-thermal event recorded at ~1.0–0.2 Ga. The multiple or protracted isotopic ~1.4–0.4 Ga ages in the Bayan Obo deposit account for five reasons. First, the separate thermal events and the partial recrystallization of monazite. Second, the diffusion of daughter products from the host mineral over time. Third, differences in the closure temperatures of different minerals and isotopic chronologies. Four, resetting of the closure system due to high temperature and hydrothermal alteration. Five, the minerals and transformed ores that formed in the Paleozoic. The in situ monazite U–Pb ages in thin sections provide insight into formation sequences from the giant Bayan Obo Fe–REE–Nb deposit.

Correlating metamorphic mineral assemblages with metamorphic ages in rocks recording multiple tectonothermal events: A case study of the Jiaobei terrane, eastern North China Craton

Interpretations of high-grade terranes recording more than one episode of metamorphism can often be problematic due to the difficulties in assigning the metamorphic conditions to the time of metamorphism. The Jiaobei terrane as a typical Precambrian metamorphic terrane in the North China Craton (NCC) records multiple high-grade metamorphic events. Resolving the timing and features of each metamorphic event can cast light on the above issue and also play a key role in understanding the geological evolution of the Jiaobei terrane and the NCC. This study reports paired U-Pb dating with in-situ trace elements and oxygen isotope compositions of metamorphic zircons in meta-mafic rocks from the Qixia area of Jiaobei terrane. The zircons develop core-rim structures with both of them exhibiting metamorphic features. Zircon rims, although widely developed, are mostly too thin for in-situ age dating. LA-ICPMS as well as SIMS zircon U-Pb analysis of zircon cores yielded metamorphic ages of ∼ 2500 Ma, whereas the rims yielded 207Pb/206Pb ages of 1915–1717 Ma. The rare earth elements (REE) patterns and δ18O values measured in the Paleoproterozoic metamorphic zircon rims are distinct from those measured in the Archean cores. Distinct features of the cores and rims imply that the garnet-bearing (high-pressure) mineral assemblages were formed during late Paleoproterozoic metamorphic event and absent during the Neoarchean event. These new geochronological data further confirm that the Jiaobei terrane records both the late Neoarchean metamorphism and the late Paleoproterozoic tectonic thermal event. Also, our study argues for the existence of global subduction network geological records in the NCC during Paleoproterozoic, rather than during Neoarchean. The influence of the overprinted late Paleoproterozoic metamorphism should be fully considered when estimating P-T conditions of the earlier tectonothermal event (Neoarchean metamorphism).

The Early Paleozoic tectonic-thermal events in northern margin of Yili Block: Constraints from Toksai garnet amphibolite and its surrounding rocks

伊犁地块是中亚造山带西南缘的重要组成部分,其南北缘出露前寒武纪变质基底,其中伊犁地块北缘温泉岩群中识别出奥陶纪岛弧型岩浆岩,被认为是准噶尔洋向南俯冲于伊犁地块之下的物质记录,但相应的变质作用记录很少有报道。近期,从温泉县托克赛地区温泉岩群中识别出的石榴角闪岩具有顺时针<i>P-T-t</i>轨迹,可能记录了伊犁地块北缘早古生代俯冲、碰撞事件,但其形成时代和构造属性尚不清楚。本研究在详细野外地质调查和岩相学研究的基础上,对托克赛石榴角闪岩及其围岩开展详细的岩石地球化学和年代学研究。结果表明,托克赛石榴角闪岩呈透镜状分布于温泉岩群中,原岩为拉斑玄武岩,岩石TiO₂(3.10%~3.89%)含量较高,K₂O+Na₂O(0.76%~2.01%)含量低,富集大离子亲石元素,亏损高场强元素,具有陆内裂谷拉斑玄武岩的特征(Th/Ta=1.70~2.76、Ta/Hf=0.23~0.37),来源于具有OIB特征的幔源岩浆。岩石较低的MgO(4.82%~6.40%)、Cr(70.8&#215;10^-6~224&#215;10^-6)、Ni(9.68&#215;10^-6~65.7&#215;10^-6)含量及Mg^#值(34.0~41.3)、Nb/U值(14.3~36.3)、Nb/Ta值(9.70~16.2)和La/Sm值(2.01~3.28),表明岩浆经历了较强的分离结晶作用和少量的地壳混染。锆石U-Pb测年结果显示石榴角闪岩原岩形成于新元古代中晚期,峰期变质时代为晚奥陶世末期(450~440Ma),围岩中的锆石和独居石均记录了同时期的构造热事件。综合研究认为,石榴角闪岩原岩形成于板内裂谷环境,是伊犁地块响应罗迪尼亚超大陆裂解事件的物质记录,暗示伊犁地块是原塔里木地块的一部分;石榴角闪岩及其围岩中识别出的奥陶纪末期高角闪岩相变质作用事件,记录了阿克套-温泉微陆块向南与伊犁地块或哈萨克斯坦微陆块的拼贴-碰撞过程。

In situ U-Pb dating and geochemical characterization of multi-stage dolomite cementation in the Ediacaran Dengying Formation, Central Sichuan Basin, China: Constraints on diagenetic, hydrothermal and paleo-oil filling events

Improved understanding of subsurface paleo-fluid circulation history can assist in reconstructing associated pore evolution of carbonate reservoirs. Multi-stage dolomite cements generated by basinal fluids over time were investigated using a combination of petrography, geochemistry, fluid-inclusion studies, LA-ICP-MS U-Pb geochronology, and seismic interpretation. This study aims to gain clues about diagenetic, hydrothermal and paleo-oil filling events within the Ediacaran Dengying Formation, Sichuan Basin, China.Four main phases of dolomite cementation were petrographically, geochemically and geochronologically distinguished that can be ascribed to major tectonic events throughout the basin evolution. The earliest dolomite generation occurs as fibrous dolomite crust (FDC) growing along the karst vug wall, interpreted as marine diagenetic cement formed in a submarine environment during the Late Ediacaran, most likely from the influx of seawaters following the uplift and subaerial exposure related to the Tongwang movement. In situ U-Pb ages obtained from the other three generations of cement dolomites are interpreted to coincide with the timing of repeated strike-slip fault movements as indicated by the seismic data, suggesting a direct link between cement emplacement and regional tectonic-thermal events. Sub-vertical extension dolomite veins (EDV), representing the second generation, are considered as being syntectonic, generated from slightly modified connate seawaters at a shallow to moderate burial depth in a transtensional stress regime during the Cambrian taphrogenesis. Two generations of saddle dolomite cements, SD1 and SD2, have recorded two major episodes of hot fluids circulating in the Dengying Formation. The SD1, filling in hydraulic fractures and vugs, formed during the third phase of cementation, as a result of a hydrothermal event associated with Caledonian exhumation. Deep-seated hot brines squeezed into the Dengying reservoirs along the sub-vertical strike-slip faults combined with some meteoric waters that percolated downward, are deemed responsible for precipitating SD1. The SD2 is the youngest cement present, which is interpreted to have formed during the ingress of deeper, hot, hypersaline brines arising from the late Permian hydrothermal activity likely triggered by the eruption of Emeishan flood basalts.Cross-cutting relationships between bitumen phases and different dolomite generations indirectly define the dates of two paleo-oil charging events. The first episode of paleo-oil charging occurred during the Late Ediacaran to Early Cambrian, likely sourced from underlying Ediacaran Doushantuo shales. Late oil emplacement occurred after the Late Permian, in agreement with the reported bitumen Re-Os age and the age inferred through fluid-inclusion analysis. Primary source rocks generating this phase of oil were considered as the Cambrian Qiongzhusi shales, because basin modeling-derived date of oil window matches with the second oil filling time.

Sequential leaching of silicified Archaean carbonates: A Rb-Sr, Sm-Nd and Pb-Pb isotopic contribution to their tectonic-thermal history (Kaapvaal Craton, South Africa)

Sequential leaching was completed by successive interactions of ultra-pure H2O, HAc, HCl and HNO3 with silicified/carbonated Archaean whole rocks from Barberton Greenstone belt of South Africa. The purpose of this experiment was an identification of the minerals interacting with each reagent and, therefore, a detailed succession of isotopically dated tectonic-thermal episodes recorded in these minerals. The contents of the major, trace and rare-earth elemental, together with the Sr, Nd and Pb isotopic compositions of untreated, leachate and residue triplets allowed identification and analysis of various types of carbonates and sulfates mixed with insoluble silicates. The samples yield two overall geological age milestones at 2.9 ± 0.1 and 2.1 ± 0.1 Ga, as well as varied age values, some with large uncertainties. A further event at about 1.6 ± 0.1 Ga is suggested probably in relation with the emplacement of the Bushveld complex or of further intrusive complexes of the Kaapvaal Craton.While the basics of the different used isotopic systems can be considered to be similar, the Rb-Sr method appears to be the best suited to detail the studied rocks, especially their sensitive soluble minerals. The Sm-Nd method is less flexible because of its inherent need of widely ranging Sm/Nd ratios that depend on the mineral assemblage. In the case of the Rb-Sr ages well constrained by isochron arrays, more similar ages were obtained by tentatively called isotrends that consist in data points slightly scattered along the arrays giving higher uncertainties, especially with the Sm-Nd method. The fact that these isotrends gave similar ages in addition to those of the isochrons comforts the historic evolution of the studied material.These scatters most probably correspond to slight changes in the chemical characteristics of minerals leached by the successive reagents, but analytical uncertainties cannot be completely excluded, especially in the case of the HNO3 leaching step. Finally, the Pb-Pb method appears to be of a more limited application, possibly because of possible metal contamination of the host rocks, either during their evolution in a region characterized by metal-rich concentrations or more recently during discrete surficial to sub-surficial alteration/weathering processes. In terms of leaching efficiency, that with H2O removed expectedly the lowest amounts of soluble components followed by HNO3, the two efficient removers being dilute HAc and HCl. In turn, the obtained geochronological ages consolidate previously published ages that concentrate on post-depositional tectonic-thermal events within the Kaapvaal Craton during about 1.0 Ga. However, they also suggest some reconsideration for other ages of the literature.

Two stage of gold-bearing sulfide ores of early Proterozoic gabbroids in the north Ladoga area

In a study based on Pb isotopes, it has been shown that the formation of gold-sulfide mineralization in the Early Proterozoic gabbros of the Northern Ladoga region is associated with different tectonic phases. This conclusion is based on a comparative study of isotopic data for feldspars and lead sulfides in two Early Proterozoic intrusions; Velimäki and Alattu-Päkylä. The investigated intrusions have similar geological settings at the junction of the Svecofennian accretionary complex and the Karelian craton. Both massifs are characterized by manifestations of noble metal sulfide mineralization associated with zones of local shear deformations. The formation of the studied ore massifs is attributed to the Svecofennian and Caledonian tectonic stages. Feldspars of Velimäki intrusion have parameters and model age of Pb significantly older than U-Pb age of zircon (1.9 Ga), although they correspond to the Svecofennian time of magmatic crystallization of gabbro and clinopyroxenites, while sulfide pyrite-pyrrhotite mineralization is associated with gold in these rocks with the Caledonian stage of fluid-thermal processing of the Early Proterozoic magmatic mineral paracenteses. Feldspars and sulfides of the Alattu-Päkylä intrusion have similar lead isotopic parameters and Pb model age (~ 2 Ga), also somewhat older than the U-Pb age of zircon, but at the same time indicating the formation of rock-forming and ore sulfide associations with gold during the Svecofennian (Early Proterozoic) plutonic and tectonic-thermal events. The source of lead sulfides of the Velimäki massif is characterized by the parameters of the upper crust with high µ2 = 238U / 204Pb, while the µ2 parameter of the minerals of the Alattu-Päkylä massif is slightly lower, which indicates the participation of the mantle-lower crustal reservoir material in the formation of magma.

Discovery of rhyolitic tuffaceous slate in the southwestern margin of Yangtze Craton: Zircon U-Pb ages (2491 Ma) and tectonic-thermal events

The Mesoproterozoic Dongchuan Group that is widely exposed in Yimen area, central Yunnan Province is a series of sedimentary sort of low-grade metamorphic rocks interbedded with volcanic rocks, which are closely related to the early tectonic evolution of the Earth. However, its formation era, sedimentary filling sequence, and geotectonic characteristics have always been in dispute. In this study, several rhyolitic tuffaceous slate interlayers with a centimeter-level thickness were found in the previously determined Heishan Formation of the Dongchuan Group located to the western part of Yimen-Luoci fault zone. This paper focuses on the study of the rhyolitic tuffaceous slate in Qifulangqing Village, Tongchang Township, Yimen County. LA-ICP-MS zircon dating was conducted, achieving the crystallization age of magma of 2491 ± 15 Ma and the metamorphic ages of about 2.3 Ga, 2.0 Ga, and 1.8 Ga for the first time. Meanwhile, according to in-situ Hf isotope analysis, the zircon εHf(t) values were determined to range from −3.0 to 7.6, with an average of 2.7. Furthermore, the first-stage Hf model age (TDM1) was determined to be 2513−2916 Ma, indicating that the provenance of the rhyolitic tuffaceous slate is the depleted mantle or juvenile crust between the Middle Mesoarchean and the Late Neoarchean. Therefore, it is believed that the strata of the slate were deposited in the Late Neoarchean, instead of the Mesoproterozoic as determined by previous researchers. Accordingly, it is not appropriate to group the strata into the Mesoproterozoic Dongchuan Group. Instead, they should be classified as the Maolu Formation of the Neoarchean Puduhe Group given the lithologic association and regional information. Furthermore, the magma ages of 2491 ± 15 Ma are highly consistent with the eras of the large-scale Late Neoarchean orogenic magmatic activities on the northern margin of the Yangtze Craton, and thus reflect the orogenic process consisting of subduction and collision from Late Neoarchean to Early Paleoproterozoic. The magmatic activities during this period were possibly caused by the convergence of the supercontinent Kenorland. Meanwhile, the metamorphic ages of 2.3 Ga, 2.0 Ga, and 1.8 Ga are highly consistent with three metamorphic ages of 2.36 Ga, 1.95 Ga, and 1.85 Ga of the northern margin of the Yangtze Craton, indicating that the strata experienced Paleoproterozoic tectonic-thermal events. The study area is located on the eastern margin of Qinghai-Tibet Plateau, and thus was possibly re-transformed by magmatism subjected to the subduction of the Meso-Tethys Ocean during the Early Cretaceous. The discoveries made in this study will provide strong petrological and chronological evidence for analyzing the early crustal evolution of the Yangtze block.©2021 China Geology Editorial Office.

Mesoproterozoic tectonic-thermal events in the Oulongbuluke Block, NW China: Constraints on the transition from supercontinent Columbia to Rodinia

The Oulongbuluke Block, which is one of several ancient micro-continents on the southeast margin of Tarim in NW China, has been considered a nearly extinct fragment of the Tarim Craton. Here, zircon U-Pb, Lu-Hf isotope, petrologic and geochemical studies were carried out on the migmatites, grey felsic gneisses, mafic granulites and augen granitic gneisses from Wulan County on the eastern margin of the Oulongbuluke Block. Macroscopic and microscopic observations show that the felsic migmatite is mainly composed of plagioclase-rich leucosomes and melanosomes. The plagioclase-rich leucosomes with positive Eu and Sr anomalies occur as layers and veins, showing in situ partial melting features. Zircon U-Pb dating and Hf isotope analyses on the melanosome, grey felsic gneisses, mafic granulites and augen granitic gneisses from the Oulongbuluke Block yield three age populations at 1500–1496 Ma, 1454–1443 Ma and 1113–1104 Ma. The ca. 1.5 Ga magmatic zircon cores of the grey felsic gneiss and melanosome possess εHf(t) values between −3.5 and 3.9, with two-stage Hf model ages (TDMC) between 2.4 Ga and 2.0 Ga. The ca. 1.1 Ga zircons from samples of augen granitic gneiss have εHf(t) values of −5.2 to 0.5, and the corresponding TDMC values range from 2.2 to 1.9 Ga. Petrological, geochemical and geochronological data suggest that ca. 1.5 Ga magmatic protoliths of grey felsic gneisses were produced by dehydration melting in predominant lower crust setting and experienced metamorphism and anatexis at 1.45 Ga in a rift setting. The precursor magmas of augen granitic gneisses were derived from partial melting of mafic crustal sources in an active continental margin environment.Comparing the tectonothermal events recorded in the Oulongbuluke Block with those in other cratons, the Oulongbuluke Block, Tarim Craton and North China Craton have similar evolutionary histories before the late Mesoproterozoic, suggesting that they were linked together and involved in the assembly and break-up of the Columbia supercontinent. However, the South China Craton, Qilian Block, Oulongbuluke Block, North Qaidam and Tarim Craton were likely temporarily connected during the late Mesoproterozoic-early Neoproterozoic (1.1–0.9 Ga), which corresponded to the assembly of the Rodinia supercontinent.

Effective hydrocarbon-bearing geological conditions of the Permian strata in the South Yellow Sea Basin, China: Evidence from borehole CSDP-2

For nearly 60 years, petroleum geologists have been puzzled by oil and gas exploration in the South Yellow Sea basin, which is considered to have broad oil and gas prospects, but no commercial hydrocarbon reservoirs have been obtained. The hydrocarbon-bearing geological conditions of the Permian strata with good exploration prospects also have never been systematically investigated. To solve the problem, a series of experiments was conducted on core samples obtained from borehole CSDP-2, the first exploration well with continuous coring in the South Yellow Sea Basin, including petrology analysis, geochemical testing, pore-throat testing, hydrocarbon-charging analysis, and sealing-ability evaluation. Vitrinite reflectance (Ro), total organic carbon (TOC), pyrolysis, extractable organic matter (EOM) and kerogen microscopic examination were carried out to evaluate the quality of the Permian source rocks. Porosity, permeability, thin section, scanning electronic microscopy (SEM) and rate-controlled mercury injection (RCMI) analyses were combined to verify the effectiveness of sandstone reservoirs. The sealing capacity of caprock was mainly evaluated by the displacement pressure. And according to the fluid-inclusion analysis and oil-source correlation, the hydrocarbon accumulation events were determined. After comprehensive analysis, we clarified the effective hydrocarbon-bearing geological conditions and favorable prospects in the Permian of the South Yellow Sea Basin. Furthermore, the main controlling factors pertaining to favorable source rocks and tight sandstone reservoirs were ascertained in this paper.The results show that two sets of the Lower Permian Qixia and Gufeng Formation (P1q-g) and the Upper Permian Longtan and Dalong Formation (P2l-d) source rocks, along with the P2l-d tight sandstone reservoirs, compose two types of hydrocarbon accumulation assemblages, which are effectively sealed by the Lower Triassic Qinglong Formation (T1q) roof caprock. One type represents the ‘lower-generation and upper-accumulation’ between the P1q-g source rocks and the P2l-d sandstones, and the other type represents the ‘self-generation and self-accumulation’ in the Upper Permian strata. Vertical stacking between the Permian source rocks and sandstone reservoirs ensures the near-source hydrocarbon accumulation, and faults and microcracks can be regarded as beneficial channels for hydrocarbon migration. In addition, we find that the quality of source rocks is improved by large-scale marine transgression, high bio-productivity, and tectonic–thermal events. The quality of tight sandstone reservoirs is more dependent on throats with relatively larger radius than pores. This study provides important enlightenment for exploring marine hydrocarbons in the South Yellow Sea Basin, and can be useful in understanding the dominant geological factors affecting favorable source rocks and sandstone reservoirs.