ABSTRACT New whole-rock major and trace element data, coupled with Sr–Nd isotopic ratios data, zircon Hf isotopes, and U–Pb geochronology are presented for three alkaline intrusions (Hashroud, Sisan, and Sarab) in the Zanjan-Takab complex in northwestern Iran, to investigate their sources, petrogenesis, and tectonic implications of emplacement. The Hashroud and Sisan plutons are mainly composed of silica-saturated granite and syenogranite, respectively, whereas the Sarab region consists of nepheline-bearing syenite, and associated undersaturated lavas ranging in composition from tephri-phonolite to trachy-basalt/andesite. Zircon U–Pb geochronology gives emplacement ages of 38 and 36 Ma for the Hashroud and Sisan silica-saturated rocks, which are slightly younger than the Sarab silica-undersaturated rocks (40 Ma). Silica-undersaturated and silica-saturated rocks differ from each other mostly in terms of their silica content, but show comparable incompatible trace element distributions, typical of subduction-related magmatic rocks. The undersaturated rocks display higher LILE/HFSE (Ba/Th: up to 365), but relatively similar LILE/LREE (Ba/La: 13–44) values to those of saturated rocks (Ba/Th: up to 38; Ba/La: up to 27). Silica-undersaturated and -saturated rocks also show distinct Sr–Nd–Pb isotopic compositions, with the former having less radiogenic Sr (87Sr/86Sr, 0.70452–0.70510) and Pb (206Pb/204Pb, 18.61–18.67; 207Pb/204Pb, 15.57–15.60; 208Pb/204Pb, 38.64–38.74) and more radiogenic Nd (143Nd/144Nd, 0.512648–0.512674) than the latter (87Sr/86Sr, 0.70619–0.71409; 206Pb/204Pb, 18.78–18.82; 207Pb/204Pb, 15.60–15.63; 208Pb/204Pb, 38.78–38.82; 143Nd/144Nd, 0.512613–0.512620). Geochemical and isotopic compositions of the silica-undersaturated rocks suggest the involvement of fluids derived from subducted oceanic crust and subordinate sediment as metasomatizing agents in their mantle source. On the other hand, the studied silica-saturated units, which crystallized from mafic parental melts modified by crustal assimilation and fractional crystallization, originated from a lithospheric mantle source that had been metasomatized via a relatively high volume of terrigenous subducted sediment melts. Both the Eocene saturated and undersaturated igneous rocks formed in a post-collisional extensional setting. Our study, along with compiled data, also finally settles the long-standing debate about the geodynamic evolution of the NW Iranian belt, showing that a compressive to extensional tectonic regime existed during the Arabia–Eurasia collision. This was related to the Neo-Tethyan slab roll-back, which generated alkali-rich magmatic rocks throughout the NW Iranian belt.
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