Synthesis Of Titania Research Articles

Trigger of apoptosis in human liver cancer cell line (HepG2) by titanium dioxide nanoparticles functionalized by glutamine and conjugated with thiosemicarbazone.

The incidence of liver cancer, the third cause of cancer-associated death, has been growing, worldwide. The increasing trend of liver cancer incidence and mortality indicates the inefficiency of current therapeutic approaches, especially anticancer chemotherapy. Owing to the promising anticancer potential of Thiosemicarbazone (TSC) complexes, this work was conducted to synthesize titanium oxide nanoparticles conjugated with TSC through glutamine functionalization (TiO2@Gln-TSC NPs) and characterize their anticancer mechanism in HepG2 liver cancer cells. Physicochemical analyses of the synthesized particles, including FT-IR, XRD, SEM, TEM, Zeta potential and DLS, and EDS-mapping confirmed the proper synthesis and conjugation of TiO2@Gln-TSC NPs. The synthesized NPs were almost spherical, with a size range of 10-80nm, a zeta potential of -57.8mV, a hydrodynamic size of 127nm, and without impurities. Investigation of the cytotoxic effect of TiO2@Gln-TSC in HepG2 and HEK293 human normal cells indicated significantly higher toxicity in cancer cells (IC50 = 75µg/mL) than normal cells (IC50 = 210µg/mL). Flow cytometry analysis of TiO2@Gln-TSC treated and control cells showed that the population of apoptotic cells considerably increased from 2.8 to 27.3% after treatment with the NPs. Moreover, 34.1% of the TiO2@Gln-TSC treated cells were mainly arrested at the sub-G1 phase of the cell cycle, which was significantly greater than control cells (8.4%). The Hoechst staining assay showed considerable nuclear damage, including chromatin fragmentation and the appearance of apoptotic bodies. This work introduced TiO2@Gln-TSC NPs as a promising anticancer compound that could combat liver cancer cells through apoptosis induction.

Design of hydrophobic polyurethane–magnetite iron oxide-titanium dioxide nanocomposites for oil-water separation

Efficacious oil-water separation has become a global challenge owing to regular oil spillage accidents and escalating industrial oily wastewater. In this study, we synthesized titanium dioxide and magnetite iron oxide nanoparticles to use as a precursor for the production of the nanocomposites. Hydrophobic nanocomposites were fabricated using polyurethane, hematite and magnetite iron oxide nanoparticles, and titanium dioxide nanoparticles through a sol-gel process. The formation of the obtained nanocomposites was confirmed by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) analyses. In addition, the thermogravimetric and differential thermogravimetric (TGA/DTG) and BET surface area results exhibited enhanced thermal stability of the optimized nanocomposite which displayed mesoporous type materials feature with high porosity. Furthermore, the obtained outcomes demonstrated that the distribution of nanoparticles into a polymer matrix had a significant impact on enhancing superhydrophobicity and the separation efficiency against sunflower oil. Seeing the water contact angle of the nanocomposite-coated filter paper was about 157° compared to 0° for the uncoated filter paper and endowed separation efficiency of almost 90% for 5 consecutive cycles. Thereby, these nanocomposites could be an ideal candidate for self-cleaning surfaces and oil-polluted water purification.

Synthesis, characterization and antifungal potential of titanium dioxide nanoparticles against fungal disease (Ustilago tritici) of wheat (Triticum aestivum L.)

Nanoparticles (NPs) preparation using a green as well as environmentally acceptable processes has achieved a lot of attention in recent decade. The current study compared the synthesis of titania (TiO2) nanoparticles synthesized from leaf extracts of two plant species (Trianthema portulacastrum, Chenopodium quinoa) and traditional approach by chemical preparation. The effects of no calcination on the physical characteristics of TiO2 NPs as well as their antifungal effects were examined and compared with the already reported calcinated TiO2 NPs. The produced TiO2 NPs were evaluated using high-tech techniques such as X-ray diffraction (XRD), scanning electron microscope, energy dispersive spectroscopy (EDX), and elemental mapping. TiO2 NPs prepared by sol-gel technique (T1) and prepared from extractions from leaves of T. portulacastrum (T2), and C. quinoa (T3) were either calcinated or non calcinated and tested against fungal disease (Ustilago tritici) of wheat for antifungal efficacy. The -peak (2θ) at 25.3 was confirmed by XRD to be connected with the anatase (101) form in both cases but before calcination, NPs were lacking the rutile and brookite peaks. The results showed that all types of TiO2 NPs examined had good antifungal activity against U. tritici, but those made from C. quinoa plant extract have good antifungal activity against disease. TiO2 NPs which are produced by the green methods (T2, T3) have the highest antifungal activity (58%, 57% respectively), while minimal activity (19%) was recorded when NPs were synthesized using the sol-gel method (T1) with 25 μl/mL. Non calcinated TiO2 NPs have less antifungal potential than calcined TiO2 NPs. It can be concluded that calcination may be preferred for efficient antifungal activity when using titania nanoparticles. The green technology may be used on a larger scale with less damaging TiO2 NP production and can be utilized against fungal disease on wheat crop to reduce crop losses worldwide.

Reinforcement of structural, thermal and electrical properties and antibacterial activity of PVA/SA blend filled with hybrid nanoparticles (Ag and TiO2 NPs): Nanodielectric for energy storage and food packaging industries‏

In this work, silver nanoparticles (Ag NPs) were prepared using a plant extract which is a cost-effective and environmentally friendly method. The sol-gel method was used to synthesize titanium dioxide nanoparticles (TiO2 NPs). A solid polymer nanocomposite samples have been prepared via the well-known solution cast way. The present samples were examined using various analytical measurements. The XRD patterns showed a decrease in the degree of crystallinity of the PVA/SA blend due to the addition of the hybrid nanoparticles (Ag and TiO2 NPs). It was evident by the ATR-FTIR measurement that there is an interaction between the functional groups of the polymeric matrix and the hybrid nanoparticles. XPS confirmed that Ag NPs were loaded onto the surfaces of the PVA/SA/TiO2 organic-inorganic nanocomposite samples. The TGA curves of the doped samples showed an improvement in their thermal stability compared to the pure sample. From the AC conductivity and electrical modulus, the dynamic ions activity and the kind of relaxation process of the nanocomposites samples were examined. The highest conductivity was log −6.066 S/cm for the polymeric sample doped with 1.60% Ag@TiO2 NPs, as showed by the AC conductivity measurement. A wide dispersion is observed in the dielectric constant spectra at low frequency. It was also evident from the data that the antibacterial activity of the pristine PVA/SA matrix was growing due to the inclusion of the hybrid nanoparticles to the polymeric matrix. Therefore, the obtained results indicate the applicability of these samples and their potential for use in the semiconductor industry, portable electrochemical batteries and energy storage industry, due to the remarkable improvement in the structural, thermal and electrical properties. Also, the good antibacterial activity of these films provides new samples as effective biomaterials and has the potential to be used in the food packaging industry.

Green Synthesized Titanium Dioxide Nanoparticle from Aloe Vera Extract as a Promising Candidate for Radiosensitization Applications

Green Synthesized Titanium Dioxide Nanoparticle from Aloe Vera Extract as a Promising Candidate for Radiosensitization Applications

Immunomodulatory and antioxidant effect of green synthesized titanium dioxide nanoparticles on pregnant female albino rats and their fetuses.

Titanium dioxide nanoparticles (TiO2 NPs) are one of the various nanoparticles that have been increasingly commonly used in vital sectors. This study was aimed at evaluating the effects of prenatal exposure to the chemical TiO2 NPs (CHTiO2 NPs) and green-synthesized TiO2 NPs (GTiO2 NPs) on immunological and oxidative status as well as lungs and spleen. Fifty pregnant female albino rats were divided into five groups of ten rats each: control, CHTiO2 NPs-treated groups orally received 100 and 300mg/kg CHTiO2 NPs, and GTiO2 NPs-treated groups received 100 and 300mg/kg GTiO2 NPs, respectively, daily for 14days. The serum level of proinflammatory cytokines IL-6, oxidative stress markers (MDA and NO), and antioxidant biomarkers (SOD and GSH-PX) were assayed. Spleen and lungs were collected from pregnant rats and fetuses for histopathological examinations. The results showed a significant increase in IL-6 levels in treated groups. In the CHTiO2 NPs-treated groups, there was a significant increase in MDA activity and a significant decrease in GSH-Px and SOD activities, revealing its oxidative effect, while GSH-Px and SOD activities significantly increased in the 300 GTiO2 NPs-treated group, confirming the antioxidant effect of green-synthesized TiO2 NPs. Histopathological findings of the spleen and lungs of the CHTiO2 NPs-treated group revealed severe congestion and thickening of the blood vessels, while those of the GTiO2 NPs-treated group revealed mild tissue alterations. It could be deduced that green synthesized titanium dioxide nanoparticles have immunomodulatory and antioxidant effects on pregnant female albino rats and their fetuses, with an ameliorated impact on the spleen and lung compared to chemical titanium dioxide nanoparticles.

A quaternary nanocomposite as an efficient counter electrode for Pt-free Dye-sensitized solar cells (DSSC)

Solar Cells are one of the most promising energy conversion sources available. But most solar cells use conventional Pt as a counter electrode (CE) which is very costly, scarce and corrosive in liquid medium. So, an alternative novel quaternary nanocomposite of rGO Reduced graphene oxide (rGO)/ Manganese dioxide (MnO2)/ Nickel oxide (NiO)/Copper oxide (CuO) (RMNCu) was employed under varied photoanodes like hydrothermally synthesized Titanium dioxide (TiO2), Zinc oxide (ZnO) and TiO2/ZnO with N-719 as dye matrix over Fluorine-doped Tin Oxide (FTO) substrate. The fabricated Dye-Sensitised Solar Cell (DSSCs) were examined under functional, optical and photovoltaic studies. It was found that the prepared DSSC with RMNCu as CE had a Power Conversion Efficiencies (PCE) of 93.31% of Pt-CE in the same ambience. The uplifted conversion efficiency promotes RMNCu as a promising candidate for counter electrodes for DSSC.

The Effect of Titanium Oxyfluoride Morphology on Photocatalytic Activity of Fluorine-Doped Titanium(IV) Oxide

Titanium oxyfluoride (TiOF2) is a metastable product that can be obtained in a fluorine-rich environment. This material can also be a valuable precursor in the synthesis of titanium(IV) oxide (TiO2). However, the effect of TiOF2 morphology on the physicochemical properties of TiO2 has not been studied so far. In this work, single-phase TiOF2 was prepared by a solvothermal method. The as-synthesized samples exhibited a variety of morphologies, including different shapes and crystallite sizes. These materials were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) combined with energy-dispersive X-ray spectroscopy (EDS), surface area measurements, thermal gravimetric analysis (TGA) and UV–vis diffuse reflectance spectroscopy (DR/UV–vis). Furthermore, TiOF2 samples were used as precursors in the synthesis of fluorine-doped titanium(IV) oxide and applied in photocatalytic phenol degradation under UV-vis light. The experiments showed that the crystallite size of the precursor, as well as the number of fluoride ions used in the synthesis, were the predominant factors that affected the photocatalytic activity of the final photocatalyst.

Anthracene removal potential of green synthesized titanium dioxide nanoparticles (TiO2-NPs) and Alcaligenes faecalis HP8 from contaminated soil

Anthracene biodegradation potential has been studied in liquid culture and soil microcosm environment by employing green synthesized TiO2 nanoparticles (NPs) and Alcaligenes faecalis HP8. The bacterium was isolated from crude oil contaminated soil, while TiO2 nanoparticles were synthesized using Paenibacillus sp. HD1PAH and Cyperus brevifolius which have PAHs remediation abilities. The dual application of TiO2 nanoparticles and Alcaligenes faecalis HP8 decreases anthracene concentration up to 21.3% in liquid at the end of 7 days and 37.9% in the soil treatments after completion of 30 days. Besides, the GC-MS analysis revealed production of five metabolites including 1,2-anthracenedihydrodiol; 6,7-benzocoumarin; 3-hydroxy-2-naphthoic acid; salicylic acid and 9,10-anthraquinone at different time interval of the treatments. Anthracene degradation pathway confirms the breakdown of three ring anthracene to one ring salicylic acid. Additionally, soil dehydrogenase, urease, alkaline phosphatase, catalase and amylase activities increased up to 4.09 folds, 8.6 folds, 4.4 folds, 3.6 folds and 2.1 folds respectively after the combined treatments of TiO2 nanoparticles and Alcaligenes faecalis HP8. The bacterial biomass and residual anthracene concentration were found to be negatively correlated. Finally, the study brings into light a novel anthracene biodegradation pathway and provides a new dimension in nano assisted bacterial remediation.

Effect of tin content on TiO2-supported platinum-tin bimetallic catalysts for low temperature CO oxidation reaction

Removal of carbon monoxide (CO) is a significant issue in fuel processing for the production of hydrogen. Bimetallic platinum-tin catalysts are well-known as efficient catalysts for oxidation process due to their synergistic bi-functional mechanism, their ability to dissociate molecular oxygen at low temperature, and their capacity to adsorb both atomic oxygen and CO. In this study, we synthesized titanium dioxide supported platinum-tin bimetallic catalysts for low temperature CO oxidation process with different amount of tin. Titanium dioxide provided oxygen to active sites due to its abundant oxygen vacancies and prevented metal sintering of active platinum nanoparticles. We confirmed that our titanium dioxide supported platinum-tin bimetallic catalysts showed excellent performance for low temperature CO oxidation. Moreover, the amount of tin on titanium dioxide affected the adsorption behaviors of CO and O2, resulting in the difference in catalytic activity of Pt based catalysts.

Green synthesis of TiO2 nanospheres from isolated Aspergillus eucalypticola SLF1 and its multifunctionality in nanobioremediation of C. I. Reactive Blue 194 with antimicrobial and antioxidant activity

For synthesis of titanium dioxide (TiO2) nanoparticles (NPs), Green methods have been proven to be more efficient than several physiochemical methods. This article presents a non-toxic, ecofriendly, cost-effective and a facile route of green synthesis of TiO2 NPs by an isolated fungus Aspergillus eucalypticola SLF1, which exhibits excellent photocatalytic, antimicrobial and antioxidant activity without structural modification done by physicochemical methods. The TiO2 NPs are characterized by UV–Visible spectroscopy, XRD, FTIR, FE-SEM, DLS, TEM, BET, Raman spectroscopy and PL. The mesoporous, anatase phase, with a band gap 3.49 eV observed by BET, XRD. UV–Visible spectral analysis displayed sunlight driven photocatalytic performance against C. I. Reactive Blue 194 by advanced oxidation process. Decolourization and 99.70% degradation within 30 min exhibited pseudo first order kinetic with reaction rate constant 0.1935 min−1 by linear method. These findings are superior physicochemical methods. Ecofriendly degradation was confirmed by UV–Vis. HPLC and LCMS etc and phytotoxic studies.

Characterization and Biological Studies of Synthesized Titanium Dioxide Nanoparticles from Leaf Extract of Juniperus phoenicea (L.) Growing in Taif Region, Saudi Arabia

Green synthesis of metal nanoparticles in nanosized form has acquired great interest in the area of nanomedicine as an environmentally friendly and cost-effective alternative compared to other chemical and physical methods. This study deals with the eco-friendly green synthesis of titanium dioxide nanoparticles (TiO2 NPs) utilizing Juniperus phoenicea leaf extract and their characterization. The biosynthesis of TiO2 NPs was completed in 3 h and confirmed by UV-Vis spectroscopy, a strong band at 205.4 nm distinctly revealed the formation of NPs. Transmissions electron microscopy (TEM) analysis showed the synthesized TiO2 NPs are spherical in shape, with a diameter in a range of 10–30 nm. The XRD major peak at 27.1° congruent with the (110) lattice plane of tetragonal rutile TiO2 phase. Dynamic light scattering (DLS) analysis revealed synthesized TiO2 NPs average particle size (hydrodynamic diameter) of (74.8 ± 0.649) nm. Fourier transmission infrared (FTIR) revealed the bioactive components present in the leaf extract, which act as reducing and capping agents. The antimicrobial efficacy of synthesized TiO2NPs against, Staphylococcus aureus, and Bacillus subtilis (Gram-positive), Escherichia coli and Klebsiella pneumoniae (Gram-negative), Yeast strain (Saccharomyces cerevisiae) and fungi (Aspergillus niger, and Penicillium digitatum) assayed by a disc diffusion method. TiO2NPs inhibited all tested strains by mean inhibition zone (MIZ), which ranged from the lowest 15.7 ± 0.45 mm against K. pneumoniae to the highest 30.3 ± 0.25 against Aspergillus niger. The lowest minimum inhibitory concentration (MIC) and bactericidal (MBC) values were 20 μL/mL and 40 μL/mL of TiO2NPs were observed against Asp. niger. Moreover, it showed significant inhibitory activity against human ovarian adenocarcinoma cells with IC50 = 50.13 ± 1.65 µg/mL. The findings concluded that biosynthesized TiO2 NPs using Juniperus phoenicea leaf extract can be used in medicine as curative agents according to their in vitro antibacterial, antifungal, and cytotoxic activities.

Effect of Synthesized Titanium Dioxide Nanofibers Weight Fraction on the Tribological Characteristics of Magnesium Nanocomposites Used in Biomedical Applications.

Biomedical applications, such as artificial implants, are very significant for the disabled due to their usage in orthopedics. Nevertheless, available materials in such applications have insufficient mechanical and tribological properties. The current study investigated the mechanical and tribological properties of a biomedical metallic material, magnesium (Mg), after incorporating titanium dioxide nanofibers (TiO2) with different loading fractions. The TiO2 nanofibers were synthesized using the electrospinning technique. The ball-milling technique was utilized to ensure the homogenous distribution of TiO2 nanofibers inside the Mg matrix. Then, samples of the mixed powder with different loading fractions of TiO2 nanofibers, 0, 1, 3, 5, and 10 wt.%, were fabricated using a high-frequency induction heat sintering technique. The physicomechanical and tribological properties of the produced Mg/TiO2 nanocomposites were evaluated experimentally. Results showed an enhancement in mechanical properties and wear resistance accompanied by an increase in the weight fraction of TiO2 nanofibers up to 5%. A finite element model was built to assess the load-carrying capacity of the Mg/TiO2 composite to estimate different contact stresses during the frictional process. The finite element results showed an agreement with the experimental results.

Green Fabrication of Titanium Dioxide Nanoparticles and their Antimcrobial and Anticancer Activities

In this study, a plant-mediated method for the synthesis of titanium dioxide (TiO2) nanoparticles is reported. Using the titanium oxide and a plant extract of medicinal herb Leucas cephalotes, the TiO2 nanoparticles were effectively synthesized. The reaction temperature was kept between 75 ºC and 80 ºC, while 1 M of TiO2 and the plant extract were being processed. The absorption peak for titanium dioxide nanoparticles in the UV-Vis spectrometer was observed at 212 and 345 nm. The typical dimension of the nanoparticles was determined to be 38.99 nm from the XRD pattern. According to the findings, titanium and oxygen were composed with high energy signals of 61.27% and 23.16%, respectively. According to FT-IR spectrum, the Ti-O bonding absorption peak is appeared at 586 cm-1. The scanning electron microscopy (SEM) was employed to confirm the spherical shape of the synthesized TiO2 nanoparticles. The green synthesized TiO2 nanoparticles could be used to treat a variety of malignancies. The MTS and MTT assays were used to assess the anticancer activity of biogenic TiO2 nanoparticles. The IC50 values were 1.89, 2.00, 1.98 and 4.00 μM, respectively, against the MCF-7, HeLa, PC-3 and A549 nanoparticles cancer cell lines. Additionally, this study has also shown that synthesized TiO2 nanoparticles are highly active against Staphylococcus aureus, Bacillus subtilis, Pseudomonas aeruginosa and Escherichia coli as well as against yeast (Candida albicans).

Photocatalytic activity of green synthesized titanium dioxide nanoparticles and wastewater remediation

Photocatalytic activity of green synthesized titanium dioxide nanoparticles and wastewater remediation

Electrochemical sensor of carboxymethyl cellulose and photocatalytic degradation of Navy Blue dye by sonochemically synthesized Titanium oxide nanoparticles

Nanocrystalline titanium oxide nanoparticles (TiO2 NPs) were synthesized by using a low-cost sonochemical method. TiO2 NPs exhibited anatase phase and an average crystallite size of 40.64 ​nm, according to a powder X-ray diffraction (PXRD) investigation. SEM and TEM images revealed spherical shape, with asymmetric geometries for TiO2 NPs. The micrographs thoroughly corroborated the plate-like structure for the NPs. In order to confirm the average energy gap of TiO2 NPs, diffused reflectance spectroscopy (DRS) via Kubelka-Monk function was applied (3.66 ​eV). Navy blue dye was used to study the photocatalytic properties of NPs and discovered to be triggered at 590.9 ​nm. The photodegradation rate of NB dye decolorized up to 74.04% after 120 ​min of UV light exposure. The first order kinetics was indicated by a linear relationship between log C/Co and k. The demonstrated rates of photodecoloration for NB under UV light in the presence of scavengers AgNO3, ethanol, and ethylenediamine tetraacetic acid (EDTA), were found to be 65.50%, 61.46%, and 57.33%, respectively. Using the carbon paste electrodes and cyclic voltammetry (CV) in 0.1 ​N HCl solution, the electrochemical characteristics of the obtained sample were studied. The carboxymethyl cellulose sensor made from TiO2 NPs demonstrated a remarkable sensitivity of 0.08 A. The results showed a high recovery for lead with low% of RSD values. The TiO2 electrode is a promising electrode material for sensing applications due to its outstanding electrochemical performance.

Green synthesized TiO2 nanoparticles: Structural characterization and photoinduced antifungal activity against P. steckii

This study synthesized titanium dioxide (TiO2 ) nanoparticles (NPs) from mango leaf extract and investigated the features and antibacterial capabilities of three different. The microscopic morphological observation, scanning electron microscopy, and transmission electron microscopy results showed that all three NPs showed agglomeration phenomenon, and the TN-1 sample existed as large agglomerates, whereas the agglomeration phenomenon of TN-3 sample was improved by the modified, without large agglomerates. The biosynthetic TN-2 and TN-3 NPs were spherical and uniform in size, whereas those of the TN-3 sample was the smallest, ranging from 10 to 30nm. X-ray diffraction and Raman spectroscopy results exhibited that these were highly pure anatase NPs. The result of ultraviolet (UV)-visible-near-infrared spectral analysis showed that the TN-2 and TN-3 samples displayed higher UV absorption properties than the TN-1 samples and were highest in the modified NPs, which was more suitable for preparing chitosan-based nanocomposite material in future experiments and studies. The colony diameters of the TN-1, TN-2, and TN-3 treatment groups were 7.99, 7.80, and 6.86mm, respectively, after 120min of UV light induction at a wavelength of 365nm. Significant differences were evident between the TN-3 and the other two groups (p<0.05), indicating that the TN-3 sample more effectively inhibited Penicillium steckii than the other TiO2 NPs. PRACTICAL APPLICATION: Nanomaterials coated film preservation is widely used in fruit and vegetable preservation. In this paper, TiO2 nanomaterials will be green synthesized using mango leaf and structurally characterized, whereas antibacterial tests will be conducted against the mango fruit-specific bacterium Penicillium steckii, which will provide a theoretical basis for the storage and preservation of mango.

Potential of green synthesized titanium dioxide nanoparticles for enhancing seedling emergence, vigor and tolerance indices and DPPH free radical scavenging in two varieties of soybean under salinity stress

BackgroundConsidering titanium dioxide nanoparticles (TiO2 NPs) role in plant growth and especially in plant tolerance against abiotic stress, in the present work, TiO2 NPs were green synthesized using an aqueous solution of Aloe vera leaf extract as a capping agent and titanium tetrachloride as a precursor. These green synthesized TiO2 NPs were characterized using different techniques: UV spectrophotometer, scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FTIR) spectroscopy and X-ray diffraction (XRD). Results revealed that synthesized TiO2 NPs possess a tetragonal morphology with a size ranging from 10 to 25 nm. Additionally, the present work evaluated the effects of three concentrations of TiO2 NPs (0, 30 and 50 ppm) and six NaCl concentrations (0, 25, 50, 100, 150 and 200 mM) and their interactions with respect to germination parameters, vigor indices, oxidative stress and DPPH free radical scavenging of two varieties of soybean (Glycine max L. var. 22 and 35).ResultsResults demonstrated that all germination traits and vigor indices were negatively affected under all salinity levels. Also, the contents of hydrogen peroxide (H2O2) and malondialdehyde (MDA) were significantly increased by increasing the NaCl concentrations in two soybean varieties. Most interestingly, TiO2 NPs (30 ppm) mediated positive effects on germination parameters, reducing H2O2 and MDA contents by enhancing antioxidant (decreasing IC50) whereas 50 ppm showed an intermediate response under both control and saline soil conditions.ConclusionOur findings demonstrate the growth enhancement effects of TiO2 NPs application as well as its ameliorative potential in dealing with salinity.

Synthesis of titanium dioxide/reduced graphene oxide nanocomposite by ultrasound-assisted mechanical mixing method for fabricating photoanode to upgrade the performance and stability of dye-sensitized solar cell

• TiO 2 /rGO was successfully synthesized by ultrasound-asissted mechanical mixing method. • 1.0 wt.% rGO under 720-W ultrasonic power was optimal synthesis conditions. • The presence of rGO enhanced and stabilized DSSC performance. • Nano-sized TiO 2 paticles were evenly anchored on rGO sheets. • rGO could enhance the thermostability and photostability of the DSSC. Herein, titanium dioxide/reduced graphene oxide (TiO 2 /rGO – TG) nanocomposite was synthesized via the ultrasound-assisted mechanical mixing method, used for the fabrication of photoanode in dye-sensitized solar cells (DSSCs). The DSSCs performance was evaluated by current density-voltage (J-V) curves and electrochemical impedance spectroscopy (EIS), showing that the sample with 1.0 wt.% rGO under the ultrasonic power of 720 W, was an optimal material for fabricating photoanode in DSSCs, which obtained the power conversion efficiency of 6.37 %. Additionally, in the 500-hour illumination test under 300-watt metal-halide lamp and the 100-hour drying at 85 °C, DSSCs with the presence of rGO proved better stability in comparison with DSSCs fabricated from commercial TiO 2 . The characterization of TG was analyzed by ultraviolet-visible spectroscopy, Fourier-transform infrared spectroscopy, Raman spectroscopy, X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy, indicating that TiO 2 nanoparticles are uniformly distributed onto the rGO sheets with the average diameter from 20 to 70 nm.

Green synthesis of titanium dioxide nanoparticles: Development and applications

Wastewater from pharmaceutical industries contains different antibiotics and other effluents that directly affect the environment. For the degradation of antibiotics, nanotechnology is an emerging field in research that majorly focuses on molecules and atoms. Nanoparticles are fine micro-particles with more than one dimension from a size of 1–100 nm. The synthesized nanoparticles can directly be used for the process of degradation of antibiotics in wastewater. Titanium dioxide nanoparticles are majorly used among nanoparticles due to their small surface area and particle size. There are various physical, chemical and conventional (biological) methods for synthesizing titanium dioxide nanoparticles. Green synthesis is an environmentally friendly, less expensive and harmless approach, and these methods are much more efficient than any other physical-chemical means. Titanium dioxide nanoparticles are used for different purposes. In food products, these nanoparticles act as photocatalysts and are also used as a coating material in food packaging. Electrochemical biosensors are combined with titanium dioxide nanoparticles for developing nano sheet matrices. Furthermore, this review describes the usage of biological components (plants, microorganisms like fungi and bacteria) to synthesize titanium dioxide nanoparticles. The present review also focuses on applying synthesized titanium dioxide nanoparticles in various drug delivery systems and other bioactivities. • Explored green synthesis of titanium dioxide nanoparticles by various approaches. • Different types of nanoparticles along with applications are described. • Diverse characterization of synthesized nanoparticles are discussed. • Importance of biological synthesis of titanium dioxide nanoparticles are surveyed.