Surface Topographical Features Research Articles

Kinematic behaviour of a large earthflow defined by surface displacement monitoring, DEM differencing, and ERT imaging

Large earthflow-type landslides are destructive mass movement phenomena with highly unpredictable behaviour. Knowledge of earthflow kinematics is essential for understanding the mechanisms that control its movements. The present paper characterises the kinematic behaviour of a large earthflow near the village of Ľubietová in Central Slovakia over a period of 35years following its most recent reactivation in 1977. For this purpose, multi-temporal spatial data acquired by point-based in-situ monitoring and optical remote sensing methods have been used. Quantitative data analyses including strain modelling and DEM differencing techniques have enabled us to: (i) calculate the annual landslide movement rates; (ii) detect the trend of surface displacements; (iii) characterise spatial variability of movement rates; (iv) measure changes in the surface topography on a decadal scale; and (v) define areas with distinct kinematic behaviour. The results also integrate the qualitative characteristics of surface topography, in particular the distribution of surface structures as defined by a high-resolution DEM, and the landslide subsurface structure, as revealed by 2D resistivity imaging. Then, the ground surface kinematics of the landslide is evaluated with respect to the specific conditions encountered in the study area including slope morphology, landslide subsurface structure, and local geological and hydrometeorological conditions. Finally, the broader implications of the presented research are discussed with particular focus on the role that strain-related structures play in landslide kinematic behaviour.

Single-Sheeted Double Many-Body Expansion Potential Energy Surface for Ground-State ClO2

A global single-sheeted double many-body expansion potential energy surface is reported for the ground electronic state of ClO2. The potential energy surface is obtained by fitting 3200 energy points that map all atom-diatom dissociation channels as well as all relevant stationary points, including the well-known OClO and ClOO structures. The ab initio calculations are obtained at the multireference configuration interaction level of theory, employing the cc-pVXZ (X = D, T) Dunning basis sets, and then extrapolated to the complete basis set limit with the generalized uniform singlet- and triplet-pair protocol. The topographical features of the novel global potential energy surface are examined in detail.

Influence of surface topography on the human epithelial cell response to micropatterned substrates with convex and concave architectures.

BackgroundUnderstanding the fundamental mechanisms underlying the cellular response to topographical surface features will extend our knowledge regarding the regulation of cell functions. Analyzing the cellular response to different topographical features, over multiple temporal and spatial scales, is central to understanding and guiding several biological functions. We used micropatterned substrates with convex and concave architectures to evaluate the behaviors of human epithelial cells on these substrates.ResultsPillar and pit substrates caused heterogeneous spatial growth and distribution, with differences in cell density, over 48 h. Regional densities and distribution were significantly increased at pillar sidewalls, and at pit sidewalls and bottoms compared with those on flat unpatterned areas. Time-lapse observations revealed that different mechanisms of cell migration were dependent upon pillar and pit features. Cells on pillar substrate migrated towards the sidewall, whereas cells on pit substrate tended to move towards the sidewalls and bottom. Cytoskeletal staining of F-actin and vinculin showed that this migration can be attributed to difference in spatial reorganization of actin cytoskeleton, and the formation of focal adhesions at various points on the at the convex and concave corners of pillar and pit substrates. Cells cultured on the pillar substrate had stress fibers with extended filopodia and immature focal contacts at the sidewalls and convex corners, similar to those on the flat unpatterned substrate. Cells at the sidewalls and concave corners of pit substrate had more contractile stress fibers and stable focal contacts compared with cells on the pillar substrate. We also found that the substrate structures affect cell-cell contact formation via E-cadherin, and that this was associated with reorganization of the actin cytoskeleton at the sidewall, and at the convex and concave corners of the substrate.ConclusionMigration is an important factor affecting spatial growth and distribution. Heterogeneity at various locations was caused by different migratory behaviors at the convex and concave corners of pillar and pit substrates. We propose that this investigation is a valuable method for understanding cell phenotypes and the heterogeneity during spatial growth and distribution of epithelial cells during culture.

AFM in mode Peak Force applied to the study of un-worn contact lenses

Contact lenses (CLs) are of common use and the biocompatibility, topography and mechanical properties of the used materials are of major importance. The objective of this contribution is to apply the AFM in mode Peak Force to obtain surface topography and mechanical characteristics of un-worn CLs of different materials. One material of hydrogel, two of siloxane-hydrogel and one of rigid gas-permeable were used in the study. The results obtained with different materials have been compared, at a nanoscopic level, and the conclusions are diverse. There is no significant influence of the two environments used to measure the characteristics of the CLs, either water or saline solution. The pHEMA hydrogel CL (Polymacon of Soflens) shows the highest values of roughness, adhesion and elastic modulus. The siloxane-hydrogel CL named Asmofilcon A of PremiO presents the lowest values of mean roughness (Ra), root-mean-square roughness (RMS or Rq), adhesion (Adh) and elastic modulus (Ym), meanwhile the siloxane-hydrogel CL named Lotrafilcon B of Air Optix presents the lowest value of skewness (Rsk) and the rigid gas-permeable CL, named RXD, presents the lowest values of kurtosis (Rku) and maximum roughness (Rmax).

Osteoclast resorption of beta-tricalcium phosphate controlled by surface architecture

A resorbable bone graft substitute should mimic native bone in its capacity to support bone formation and be remodeled by osteoclasts (OCl) or other multinucleated cells such as foreign body giant cells (FBGC). We hypothesize that by changing the scale of surface architecture of beta-tricalcium phosphate (TCP), cellular resorption can be influenced. CD14+ monocyte precursors were isolated from human peripheral blood (n = 4 independent donors) and differentiated into OCl or FBGC on the surface of TCP discs comprising either submicron- or micron-scale surface topographical features (TCPs and TCPb, respectively). On submicrostructured TCPs, OCl survived, fused, differentiated, and extensively resorbed the substrate; however, on microstructured TCPb, OCl survival, TRAP activation, and fusion were attenuated. Importantly, no resorption was observed on microstructured TCPb. By confocal microscopy, OCl formed on TCPs contained numerous actin rings allowing for resorption, but not on TCPb. In comparison, FBGC could not resorb either TCP material, suggesting that osteoclast-specific machinery is necessary to resorb TCP. By tuning surface architecture, it appears possible to control osteoclast resorption of calcium phosphate. This approach presents a useful strategy in the design of resorbable bone graft substitutes.

Correlation between surface morphology and defect structure of heteroepitaxial diamond grown on off‐axis substrates

The topographic surface features that develop during chemical vapour deposition of heteroepitaxial diamond on off‐axis Ir/YSZ/Si(001) and their implications on the incorporation and modification of 0D and 1D defects have been studied. After growth with nitrogen in the gas phase, the surface has split into alternating stripes of opposite inclination. The terrace regions are tilted towards the crystallographic [001] axis, while the risers are tilted in the opposite direction. AFM measurements on the macroscopic terraces reveal a microscopic substructure consisting of terraces and risers on a smaller length scale. Cross‐section SEM images display inclined dark and bright striations. In photoluminescence maps, the stripes ending at risers show a higher NV and SiV emission intensity thus indicating a stronger defect incorporation of colour centres. Relative growth rates on terrace and riser areas have been evaluated. In high resolution Raman measurements, the cross‐section maps display bands of high line width embedded in a background of lower line width. Conversion of these data into dislocation density maps reveals local variations by one order of magnitude. The tilt angle of the threading dislocation bundles is attributed to an interaction induced by the lateral step flow on the off‐axis growth surface.Scheme of the investigated diamond samples.

Influence of Te doping on the dielectric and optical properties of InBi crystals grown by directional freezing

Stoichiometric pure and tellurium (Te) doped indium bismuthide (InBi) were grown using the directional freezing technique in a fabricated furnace. The X-ray diffraction profiles identified the crystallinity and phase composition. The surface topographical features were observed by scanning electron microscopy and atomic force microscopy. The energy dispersive analysis by X-rays was performed to identify the atomic proportion of elements. Studies on the temperature dependence of dielectric constant (ɛ), loss tangent (tanδ), and AC conductivity (σac) reveal the existence of a ferroelectric phase transition in the doped material at 403 K. When InBi is doped with tellurium (4.04 at%), a band gap of 0.20 eV can be achieved, and this is confirmed using Fourier transform infrared studies. The results thus show the conversion of semimetallic InBi to a semiconductor with the optical properties suitable for use in infrared detectors.

Studying the Influence of Surface Topography on Bacterial Adhesion using Spatially Organized Microtopographic Surface Patterns

The influence of surface topography on bacterial adhesion has been investigated using a range of spatially organized microtopographic surface patterns generated on polydimethylsiloxane (PDMS) and three unrelated bacterial strains. The results presented indicate that bacterial cells actively choose their position to settle, differentiating upper and lower areas in all the surface patterns evaluated. Such selective adhesion depends on the cells' size and shape relative to the dimensions of the surface topographical features and surface hydrophobicity/hydrophilicity. Moreover, it was found that all the topographies investigated provoke a significant reduction in bacterial adhesion (30-45%) relative to the smooth control samples regardless of surface hydrophobicity/hydrophilicity. This remarkable finding constitutes a general phenomenon, occurring in both Gram-positive and Gram-negative cells with spherical or rod shape, dictated by only surface topography. Collectively, the results presented in this study demonstrate that spatially organized microtopographic surface patterns represent a promising approach to controlling/inhibiting bacterial adhesion and biofilm formation.

Heat-induced coarsening of layer-by-layer assembled mixed Au and Pd nanoparticles.

This article shows the coarsening behavior of nanoparticle multilayers during heat treatments which produce larger metallic nanostructures with varying shapes and sizes on glass slides. Nanoparticle multilayer films are initially constructed via the layer-by-layer self-assembly of small and monodispersed gold and/or palladium nanoparticles with different compositions (gold only, palladium only, or both gold and palladium) and assembly orders (compounding layers of gold layers over palladium layers or vice versa). Upon heating the slides at 600°C, the surface nanoparticles undergo coalescence becoming larger nanostructured metallic films. UV-Vis results show a clear reliance of the layering sequence on the optical properties of these metal films, which demonstrates an importance of the outmost (top) layers in each nanoparticle multilayer films. Topographic surface features show that the heat treatments of nanoparticle multilayer films result in the nucleation of nanoparticles and the formation of metallic cluster structures. The results confirm that different composition and layering sequence of nanoparticle multilayer films clearly affect the coalescence behavior of nanoparticles during heat treatments.

Propagation of vertical and horizontal source data errors into a TIN with linear interpolation

Digital elevation models (DEMs) have been widely used for a range of applications and form the basis of many GIS-related tasks. An essential aspect of a DEM is its accuracy, which depends on a variety of factors, such as source data quality, interpolation methods, data sampling density and the surface topographical characteristics. In recent years, point measurements acquired directly from land surveying such as differential global positioning system and light detection and ranging have become increasingly popular. These topographical data points can be used as the source data for the creation of DEMs at a local or regional scale. The errors in point measurements can be estimated in some cases. The focus of this article is on how the errors in the source data propagate into DEMs. The interpolation method considered is a triangulated irregular network (TIN) with linear interpolation. Both horizontal and vertical errors in source data points are considered in this study. An analytical method is derived for the error propagation into any particular point of interest within a TIN model. The solution is validated using Monte Carlo simulations and survey data obtained from a terrestrial laser scanner.

Holographic volume displacement calculations via multiwavelength digital holography

In this work multiwavelength digital holography is applied to calculate the volume displacement of various topographic surface features. To accurately measure the volume displacement of macroscopic features, long synthetic wavelengths up to several millimeters are generated using tunable IR laser sources. Practical methods of implementation are considered, including geometric effects of both Michelson and Mach-Zehnder recording configurations and error due to wavelength selection.

Nano and Microscale Topographies for the Prevention of Bacterial Surface Fouling

Bacterial surface fouling is problematic for a wide range of applications and industries, including, but not limited to medical devices (implants, replacement joints, stents, pacemakers), municipal infrastructure (pipes, wastewater treatment), food production (food processing surfaces, processing equipment), and transportation (ship hulls, aircraft fuel tanks). One method to combat bacterial biofouling is to modify the topographical structure of the surface in question, thereby limiting the ability of individual cells to attach to the surface, colonize, and form biofilms. Multiple research groups have demonstrated that micro and nanoscale topographies significantly reduce bacterial biofouling, for both individual cells and bacterial biofilms. Antifouling strategies that utilize engineered topographical surface features with well-defined dimensions and shapes have demonstrated a greater degree of controllable inhibition over initial cell attachment, in comparison to undefined, texturized, or porous surfaces. This review article will explore the various approaches and techniques used by researches, including work from our own group, and the underlying physical properties of these highly structured, engineered micro/nanoscale topographies that significantly impact bacterial surface attachment.

Accurate ab initio-based DMBE potential energy surface for HLi2(X 2A′) via scaling of the external correlation

A globally accurate potential energy surface is reported for the electronic ground-state HLi2 by fitting ab initio energies to double many-body expansion formalism. The total 3726 ab initio energies used to map the HLi2 potential energy surface are calculated using the multi-reference configuration interaction method, with their dynamical correlation being semiempirically corrected by the double many-body expansion-scaled external correlation method. The current potential energy surface generates an excellent fit of the ab initio energies, showing a small root-mean squared derivation of 0.636 kcal mol-1. The topographical features of the HLi2 potential energy surface are examined in detail, which concludes that the H + Li2(X 1 Σ g ) → Li + LiH(X 1 Σ) reaction is essentially barrierless and the exothermicity is calculated to be 33.668 kcal mol-1, thus corroborates the available experimental and theoretical results.

Enamel Deproteinization After Acid Etching - Is It Worth The Effort?

Objectives: This study was undertaken to observe the topographical features of enamel surface deproteinized with 5.25% sodium hypochlorite(NaOCl) after phosphoric acid (H3PO4) etching using Scanning Electron Microscope (SEM) analysis and also the effect of enamel deproteinization after acid etching on the shear bond strength (SBS) of AdperTM Single Bond 2 adhesive and FiltekTM Z- 350 XT composite resin. Study Design: SEM Observation: 10 enamel blocks of 1mm2 from 10 human sound permanent molar teeth were obtained and treated with 37% H3PO4 gel for 15 seconds followed by treatment with 5.25% NaOCl for 60 seconds. All the 10 samples were subjected to SEM analysis and 5 microphotographs of each sample were obtained at 500X magnification and evaluated for the occurrence of Type I – II etching pattern in percentage (%) using Auto – CAD 2007 software. SBS Evaluation: A 5X4 mm window of the enamel surface was etched with 37% H3PO4 gel for 15 seconds, washed with distilled water and air dried. The etched enamel surface was then treated with 5.25% NaOCl for 60 seconds, washed with distilled water and air dried. A single coat of Adper™ Single Bond 2 adhesive was applied and photo polymerized for 20 seconds and Filtek™ Z- 350 XT composite resin block of length 5mm, width 4mm and height 5mm respectively was built and photo polymerized in increments for 20 seconds each. The shear bond strength of all the 20 test samples (permanent molar teeth) were measured (in MPa) on Instron Mechanical Testing Machine. Results: The mean value of Type I – II etching pattern of all the test samples was observed to be 40.68 + 26.38 % and the mean SBS value for all the test samples was observed to be 17.35 + 7.25 MPa. Conclusions: No significant enhancive effect of enamel deproteinization after acid etching with respect to the occurrence of Type I-II etching patterns as well as on the SBS of adhesive resin and composite resin complex to the enamel surface was observed in this study. The use of 37% phosphoric acid alone for 15 seconds still remains the best method for pretreatment of the enamel.

Geophysical analysis of transverse ridges and internal structure at Lone Peak Rock Glacier, Big Sky, Montana, USA

AbstractRock glaciers are periglacial alpine landforms that are found in many locations worldwide. Whereas well-developed models of deformation are established for traditional alpine glaciers, rock glacier deformation is poorly understood. Geophysical data from Lone Peak Rock Glacier (LPRG), southwest Montana, USA, are paired with lidar bare-earth 1 m digital elevation model (DEM) analysis to explore potential genetic relationships between internal composition, structure and regularly spaced arcuate transverse ridges expressed at the rock glacier surface. The internal composition of LPRG is heterogeneous, with frozen debris and clean ice overlain by an unconsolidated talus mantle. Upslope-dipping, clearly distinguished reflectors in the ground-penetrating radar (GPR) longitudinal survey at LPRG correspond to transverse ridges. The spacing and slope of individual features at the surface and in the subsurface were measured and compared and are found to be similar. The structures observed at LPRG and other rock glaciers are similar to structures detected in glaciotectonically altered sediment, ice-cored moraines and other rock glacier settings. This finding suggests that transverse ridges on rock glaciers may be used as geomorphic indicators of internal deformation. This study contributes to the body of research on the application of GPR to rock glaciers, and is the first to directly pair and analyze individual surface topographic features with internal structures.

Pattern Transfer of Sub-micrometre-scaled Structures into Solid Copper by Laser Embossing

Abstract Laser embossing allows the micron and submicron patterning of metal substrates that is of great interest in a wide range of applications. This replication process enables low-cost patterning of metallic materials by non-thermal, high-speed forming which is driven by laser-induced shock waves. In this study the surface topography characteristics as well as the material structure at laser embossing of sub-micrometre gratings into solid copper is presented. The topography of the laser-embossed copper pattern is analysed with atomic force microscopy (AFM) in comparison to the master surface. The height of the embossed structures and the replicated pattern fidelity increases up to a laser fluence of F∼10 J/cm 2 . For higher laser fluences the height of the embossed structures saturates at 75% of the master pattern height and the shape is adequate to the master. Structural modifications in the copper mono crystals after the laser embossing process were investigated with transmission electron microscopy (TEM) and electron backscatter diffraction (EBSD). Almost no modifications were detected. The residual stress after laser embossing of 32 MPa(F = 30 J/cm 2 ) has only a limited influence on the surface pattern formation.

Effect of thermal-resistant polymeric coatings on thermomechanical and topographical properties of glass fiber

Thermal-resistant coatings, based on polysilazane and polysiloxane polymers, were applied onto the glass fiber rovings with the dip-coating method. The coated glass fibers were characterized by performing different experiments to evaluate the effect of coatings on thermomechanical and topographical properties of glass fiber. The effect of temperature on the mechanical properties of the coated rovings were studied and compared with the uncoated rovings. Thermogravimetric analysis was carried out to investigate the thermal stability of coated samples. Scanning electron microscopy and energy-dispersive X-ray analyses were performed to evaluate the surface topographical characteristics of the glass fiber rovings. These analyses showed the changes in surface morphological properties due to modification of glass fiber by coating treatment. The results of tensile testing indicated that thermal-resistant coatings enhanced up to 60% tensile strength and 20% stiffness of uncoated glass fiber roving. Thermomechanical study up to 500℃ revealed that polysiloxane coating on glass fiber showed better performance than polysilazane polymeric coating.

EFFECTS OF FLOW PATH DEPTH ON EMITTER CLOGGING AND SURFACE TOPOGRAPHICAL CHARACTERISTICS OF BIOFILMS

ABSTRACTThe depth of the flow path of a drip irrigation emitter can affect the anti‐clogging ability of a drip irrigation system by changing the flow velocity distribution and material transportation process. In order to evaluate these effects, in this paper a drip irrigation experiment using reclaimed water was performed, and four types of emitters with four flow path depths were chosen for the experiment. The dynamic outflow changes of the emitters were tested with constant intervals and the surface topographical characteristics of biofilms at the inlets and outlets of emitters and the inner lateral walls were tested with the 3D‐WLSI (3D white‐light scanning interferometer). Thus, the effect of flow path depth on emitter clogging was analysed. The results showed that emitter clogging with different degrees in the 204 hrs was observed. The discharge ratio variation (Dra) and coefficient of uniformity (CU) of emitters all slightly decreased with fluctuant changes. Moreover, clogged emitters were more likely to occur at the end part of the lateral, which revealed obvious difference among emitters with different flow path depths. The average thickness (Sd) and relative average thickness (RSd) of biofilms increased with deeper flow path, while surface topographical characteristics of biofilms varied from smooth to rough. On the other hand, the average thickness and relative thickness of the biofilms at different positions of the lateral represented the order as: Sd head < Sd middle < Sd end and RSd head < RSd middle < RSd end. This was because the flow velocity decreased from the head to the end part of the lateral. Higher flow velocity resulted in limited nutrient supply and slower microbial metabolism, as well as higher turbulence intensity and hydraulic shear stress, which led to the easier detachment of biofilms. In contrast, the lower flow velocity and turbulence could result in the accumulation of biofilms and more serious clogging in the end part. Moreover, the average biofilm thickness at the emitter inlet closest to the end part of the lateral could be selected as a suitable site for monitoring emitter clogging and biofilm growth characteristics. On the other hand, the appropriate range of flow path depths for drip irrigation emitters using reclaimed water was 0.70–0.75 mm, which will provide the reference for exploring the emitter clogging mechanism of reclaimed water drip irrigation and developing efficient clogging control strategies. Copyright © 2013 John Wiley & Sons, Ltd.

Surface Layer Damage of Silicon Wafers Sliced by Wire Saw Process

Wire saw process is widely used in the machining of hard and brittle materials with low surface damage and high efficiency. Cutting of silicon wafers in integrated circuit (IC), semiconductor and photovoltaic solar industries is also generally using wire saw process. However, the surface layer damage induced by wire saw process will seriously decrease the wafer quality and increase the process time and production costs of the post grinding and polishing. The surface layer qualities of the silicon wafers sawed by the different wire saw processes was investigated in this paper. The characteristics of surface roughness, surface topography and subsurface damage of silicon wafers sliced by the fixed abrasive and the loose abrasive wire sawing respectively were compared and the corresponding reasons were analyzed.

Climatic versus halokinetic control on sedimentation in a dryland fluvial succession

AbstractFluvial systems and their preserved stratigraphic expression as the fill of evolving basins are controlled by multiple factors, which can vary both spatially and temporally, including prevailing climate, sediment provenance, localized changes in the rates of creation and infill of accommodation in response to subsidence, and diversion by surface topographic features. In basins that develop in response to halokinesis, mobilized salt tends to be displaced by sediment loading to create a series of rapidly subsiding mini‐basins, each separated by growing salt walls. The style and pattern of fluvial sedimentation governs the rate at which accommodation becomes filled, whereas the rate of growth of basin‐bounding salt walls governs whether an emergent surface topography will develop that has the potential to divert and modify fluvial drainage pathways and thereby dictate the resultant fluvial stratigraphic architecture. Discerning the relative roles played by halokinesis and other factors, such as climate‐driven variations in the rate and style of sediment supply, is far from straightforward. Diverse stratigraphic architectures present in temporally equivalent, neighbouring salt‐walled mini‐basins demonstrate the effectiveness of topographically elevated salt walls as agents that partition and guide fluvial pathways, and thereby control the loci of accumulation of fluvial successions in evolving mini‐basins: drainage pathways can be focused into a single mini‐basin to preserve a sand‐prone fill style, whilst leaving adjoining basins relatively sand‐starved. By contrast, over the evolutionary history of a suite of salt‐walled mini‐basins, region‐wide changes in fluvial style can be shown to have been driven by changes in palaeoclimate and sediment‐delivery style. The Triassic Moenkopi Formation of the south‐western USA represents the preserved expression of a dryland fluvial system that accumulated across a broad, low‐relief alluvial plain, in a regressive continental to paralic setting. Within south‐eastern Utah, the Moenkopi Formation accumulated in a series of actively subsiding salt‐walled mini‐basins, ongoing evolution of which exerted a significant control on the style of drainage and resultant pattern of stratigraphic accumulation. Drainage pathways developed axial (parallel) to salt walls, resulting in compartmentalized accumulation of strata whereby neighbouring mini‐basins record significant variations in sedimentary style at the same stratigraphic level. Despite the complexities created by halokinetic controls, the signature of climate‐driven sediment delivery can be deciphered from the preserved succession by comparison with the stratigraphic expression of part of the system that accumulated beyond the influence of halokinesis, and this approach can be used to demonstrate regional variations in climate‐controlled styles of sediment delivery.