Surface solar radiation (SSR) and its components are important parameters in studies of land, hydrology and the atmosphere. However, the SSR of ECMWF Reanalysis 5 (ERA5) rather than observations is often used in related research fields due to the sparse and uneven spatial distribution of observations. Therefore, understanding the deviation from observations and the attribution is essential for the appropriate use of reanalysis SSR. Based on station observations in China for 2014–2020, this study evaluates the ERA5 SSR products including global radiation (Rs), direct radiation (Rdir) and diffuse radiation (Rdif) under various PM2.5 concentrations to explore the influence of aerosols on ERA5 radiation. Overall, Rs from ERA5 has higher accuracy than Rdir and Rdif. The ERA5 product generally overestimates (underestimates) Rdir (Rdif), and this overestimate (underestimate) increases with the intensification of particle pollution. Under the influence of biomass burning (BB) events, the Rdir (Rdif) of ERA5 exhibits overestimation (underestimation) similar to that under the heaviest particle pollution. In terms of the time series, the deviations of Rdir and Rdif from ERA5 in 1999–2020 still vary with the local aerosol optical depth (AOD). The diurnal variation in Rdir (Rdif) from ERA5 also shows larger deviations under air pollution conditions than under clean conditions, especially at the hours around noon. Furthermore, the misrepresentation of aerosols also causes large deviations in the Rdif/Rdir of ERA5 from observations, especially at stations in eastern China. Similar changes in the deviation of ERA5 radiation from observations with increasing aerosol loading are found under both all sky and clear sky conditions. The high association with aerosol pollution found here indicates that ERA5 SSR products should be used with caution in the presence of atmospheric particle pollution.
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