Supercritical State Research Articles

CO2 transport in supercritical state: Nikiski, Alaska pipeline study

AbstractCarbon dioxide (CO2) in the supercritical state, being denser yet less viscous, is suitable for long‐distance transportation. Despite this well‐known principle, implementing an operational scheme with appropriate inlet pressure and mass flow rate for supercritical CO2 (srCO2) transportation is challenging due to the complex interplay among state variables, fluid properties, pipeline dimensions and materials, and the intricate boundary and ambient conditions surrounding the pipeline. This paper utilizes PIPESIM software to conduct a feasibility study of srCO2 transportation over a 10‐mile‐long model pipeline in the Cook Inlet region of Alaska, USA. The study aims to understand the limitations of operational parameters and develop a scheme for selecting feasible parameters for srCO2 transportation. Considering geographic location, elevation profiles, and ambient conditions, the simulations calculated pressure and temperature profiles, erosion kinetics, and fluid states for various conditions derived from a combinatorial set of pipeline diameters ranging from 11 to 16 in, inlet pressures between 1,400 and 1,900 psia, and mass flow rates from 10 to 275 lbm/s, with an inlet temperature of 200 °F. The major findings indicate that larger pressure losses are expected in smaller pipelines that are well‐insulated and/or operated at lower inlet pressures. Turbulent flow is more likely to occur in smaller pipelines and at higher mass flow rates, potentially altering the state of the transported fluid. The parametric modeling results provide a scenario‐driven approach to determining a feasible range of mass flow rates, pipeline inner diameters, and inlet pressures for srCO2 transportation. © 2024 Society of Chemical Industry and John Wiley & Sons, Ltd.

ANALYSIS OF THE INNER SURFACE OF A SUPERCRITICAL WATER CONVECTION LOOP AFTER AN ELECTRON IRRADIATION SESSION

Supercritical water (SCW) can be an effective cooler for nuclear reactors. All sorts of research on the subject of SCW are very important, especially bearing in mind that SCW is a non-polar solvent, while subcritical water is a polar solvent. Irradiation leads to an increase in corrosion and migration of some metals into the volume of the SCW. The transition from the supercritical state to the normal state and inversely contributes to the synthesis of substances in the SCW. On the inner surface of the convection loop, a film of corrosion products is formed, which are minerals that can protect the metal from corrosion.

Mineralization reaction between CO2 and coal ash produced from underground coal gasification: Implication for in situ carbon sequestration

Underground coal gasification (UCG) represents a promising clean and low-carbon energy technology, which could create a suitable cavity for in situ carbon sequestration by mineralization reaction between CO2 and coal ash produced from UCG. This may assist in achieving a net-zero carbon emission goal for UCG projects. To determine the carbonation efficiency and mineralization potential of CO2 mineral sequestration in abandoned UCG cavity, coal ash produced from the gasification of three different low-rank coal samples was used in this study. A comparative experiment was conducted using a group of high-calcium fly ash from a coal-fired power plant. All mineralization reaction experiments were performed in a high-temperature and high-pressure reactor, with CO2 pressures ranging from 2 to 8 MPa and temperatures ranging from 40 to 80°C. These conditions were selected to simulate the sequestration conditions in the UCG cavity. Real-time monitoring of CO2 pressure in the reactor was used to assess the impact of solid-to-water ratio, temperature, and pressure on the CO2 mineralization. X-ray diffraction and scanning electron microscopy were employed to identify the presence of newly formed carbonate minerals associated with mineralization reaction. The results indicated that the coal ash produced by gasification pretreatment at 900°C contains a substantial quantity of alkaline-earth oxides, such as calcium oxide (CaO), with a relative mass fraction reaching 25.9%. It provided an adequate supply of alkali metal ions for the mineralization reaction, which exhibited comparable efficacy in mineralizing CO2 to that observed in high-calcium fly ash. Without stirring, at lower solid-to-water ratio, the maximum amount of CO2 consumed through mineralization was increased by up to 74.12%. Carbonation efficiency decreased with rising temperatures below 70°C due to the limited dissolution of CO2 in water, it increased with elevated pressure but decreased in the supercritical state, potentially attributable to the dissolution of carbonate minerals in a supercritical CO2 environment. The process of mineralization reaction between CO2 and coal ash aligned well with the Surface Coverage Model (R2 values ranging from 0.92 to 0.99). A preliminary estimation based on Chinese coal reserves revealed that the potential of CO2 sequestration capacity in UCG cavities by mineralization ranging from 29 to 102 Gt, an additional 517 Gt CO2 may be stored when filled with fly ash. This paper provides theoretical bases for predicting the maximum carbonation efficiency under high-pressure and high-temperature conditions in UCG cavities, and research directions for achieving a net-zero carbon emission goal for UCG projects.

Microstructural response of coal fracture surface induced by ScCO2 injection measured with AFM

Fractures in coal serve as the principal channels for the migration of coalbed methane (CBM). The microscopic traits of coal fracture surface are of significance for evaluating reservoir permeability and directly influence the outcome of CO2 storage and displacement. To comprehend the impact of CO2 on the coal fracture surface, the alterations in the coal fracture surface before and after CO2 injection are investigated vis atomic force microscopy. As CO2 gradually transforms into a supercritical state, the fracture density and aperture on the coal fracture surface gradually escalate. The mean pore size and porosity of the coal fracture surfaces rose from 5.45 nm to 6.55 nm and from 4.66% to 6.85%, respectively. The proportion of micropores (<2 nm) gradually diminished. The proportions of mesopores (2∼50 nm) and macropores (>50 nm) proportions gradually. Swelling, extraction and mineral dissolution are the predominant reasons for the alteration in the pore structure of the coal fracture surface. CO2 injection modifies the roughness and fractal characteristics of the coal fracture surface. The mean roughness Ra dropped from 6.54 nm to 4.03 nm, and the fractal dimension Ds declined from 2.45 to 2.28. With the fixed scanning range, the injection of CO2 has been shown to reduce the roughness of coal fracture surface and lower their fractal dimension, thereby has a positive influencing permeability enhancement. Therefore, in CO2-ECBM engineering, it is essential not only to analyse the physical properties of the target reservoir, but also to conduct a comprehensive evaluation of permeability with a suitably defined area of the reservoir.

Comprehensive Assessment of Deep-Water Vessel Implosion Mechanisms: OceanGate's Titan Submersible Failure Sequence Explained

This study outlines the physical mechanisms involved in a submersible implosion and analyzes the loss of the Titan submersible (‘sub’) that occurred on 18 June 2023 during a mission to visit the wreck of the Titanic. Titan’s collapse mechanisms at the moment of implosion are described in detail and outer hull fracturing rate, subsequent implosion rate, accompanying heat release and other key processes are quantified. Plausible causes of the hull’s leak leading up to critical loss of the sub's hermetic closure are reviewed using test results made publicly available by the U.S. Marine Board of Investigation. Their data indicated that the bond interfaces between the individual layers of the carbon fiber hull (Hull V2) were critically compromised due to manufacturing defects, voids, porosity, and inadequate adhesive integrity, resulting in significant delamination. Analysis of data from the real-time hull health monitoring system, revealed acoustic anomalies and strain shifts, pointing toward increasing structural fatigue, which went unaddressed prior to the fatal dive. The implosion process can be characterized by an instantaneous collapse of the air volume within the hull under extreme external pressure: even the tiniest leak would lead to destruction of the vessel's structural integrity. The destruction was the more devastating, because it was accompanied by a secondary explosion due to the heat exchange between the collapsing air volume and the ambient sea water. While the collapsing air was phase-changed into a supercritical state, the generated heat caused the adjacent seawater to evaporate and expand. Hull pieces fragmented by the initial implosion were strewn around during the secondary explosion phase, which ceased rapidly as the steam condensed back into seawater once again. The Titan incident underscores the urgent need for improved design standards, rigorous quality control in manufacturing, and enhanced real-time monitoring to prevent similar failures of future deep-sea exploration vehicles.

Molecular dynamics analysis of the crossover phenomenon in supercritical carbon dioxide

Supercritical carbon dioxide (SCO2) finds widespread applications but its complex phase behavior near and beyond the critical point remains unclear. In this work, extensive focus has been invested in the thermodynamic transitions of SCO2 from a microscopic perspective. It is revealed that both the radial distribution function and structure factor exhibit apparent crossover phenomena as temperature changes. Remarkably, our findings demonstrate an unprecedented agreement between the predicted crossover points using different functions and the experimental Frenkel Line (FL), with a deviation of merely 5.6%. By applying the same method, the FL crossover region is successfully predicted and extended up to an impressive pressure of 200 MPa. Notably, this prediction is a valuable guide in narrowing down the temperature range for further experimental tests. Concurrently, a correlation between the coordination number and the FL is discovered. Overall, our research provides compelling evidence supporting the FL as thermodynamic transitions between the gas-like and liquid-like regions and presents a novel and reliable approach for identifying the FL, which offers valuable theoretical insights into the phase behavior in the supercritical state.

An integrated dynamic modeling workflow for acid gas and CO2 geologic storage screening in saline aquifers with faults: A case study in Western Canada

This study investigates the feasibility of storing the acid gas produced from the oil and gas facilities in Southern Saskatchewan into the Basal Sand aquifer using a coupled wellbore-aquifer-compositional reservoir model. The simulations investigate the pressure change around the fault in proximity of the primary storage location incorporating the influence of reservoir permeability, fault transmissibility, and wellbore configuration, on the factors critical to safe and efficient storage, such as plume migration, pressure changes, and CO2 storage capacity. A compositional fluid model created using an equation of state was integrated into the reservoir model. Simultaneous incorporation of fault transmissibility, phase solubility, water salinity, temporal in-situ hysteresis and structural trapping, and in-situ compositional tracking of individual gas components is considered as the main novelty of this work. The main challenge of the study was the lack of available data to characterize the aquifer. To this end, a comprehensive workflow of reservoir studies and modeling was applied to reduce the uncertainties and evaluate the site selection. The Basal sand scoping models reveal that the aquifer is expected to handle the required disposal volume given its extent. The injected acid gas plume migrates laterally and preferentially towards the northwest, away from the fault, owing to the aquifer's geological structure. CO2 remains entirely in the supercritical state, offering storage advantages due to its lower volume. The reservoir permeability significantly impacts the pressure patterns with lower permeability formations triggering higher wellhead injection pressures. Substantial pressure increases around the sealing fault can be observed. Pressure changes of 110 kPa (16 psi) to over 400 kPa (58 psi) were observed at the fault segment after 20 years of continuous gas injection for the expected range of reservoir properties. Mitigation strategies to minimize the increase in fault pressure entail relocating the injection site away from the fault or utilizing a horizontal well trajectory and using an observation well near the fault for monitoring any pressure buildup and slippage.

Transient microstructural behavior of methanol/n-heptane droplets under supercritical conditions

Supercritical fluids exist widely in nature and have enduringly attracted scientific and industrial interest. In power systems like liquid rocket engines, fluids undergo the trans-critical process transferred from the subcritical state to the supercritical state, and the phase change process exhibits different features distinguished from subcritical evaporation. In this work, we conducted a series of molecular dynamics studies on the behavior of methanol (MeOH), n-heptane (C7), and binary C7/MeOH droplets under supercritical nitrogen environments. The emphasis is on clarifying the transient characteristics and physical origins of the trans-critical evolution of droplets. During the trans-critical process, droplets are found to experience an unstable period without a spherical shape, where the droplet diameter no longer decreases, violating the traditional d2-law rule. The occurrence of nonspherical droplets is related to the microstructural behavior of trans-critical droplets. Two types of microscopic structures within the droplet are identified: large-scale thermally induced clusters for long-chain C7 and hydrogen-bond connected network-like structures for MeOH, which contains hydroxyl (–OH) groups. Based on these findings, the mechanism behind the evolution of trans-critical droplets is illustrated. Finally, we determine the boundary of ambient conditions in the form of dimensionless expressions Tr−1=a(pr−1)−b, which dictate whether droplets can maintain a spherical shape during the trans-critical process.

Analysis of Carbon Dioxide Injectivity and Dynamic Storage Capacity in Shale Reservoirs

Abstract Carbon dioxide could be stored in unconventional shale reservoirs in supercritical state due to available pore volume, infrastructure, and injectivity. However, there is a lack of knowledge about the injectivity and storage capacity in shale reservoirs. In this manuscript, a two-dimensional dual-porosity, dual-permeability model was built to investigate CO2 injectivity and dynamic storage capacity spatially and temporally. Parametric studies are conducted to evaluate the effect of matrix permeability, fracture conductivity, fracture half length, operating conditions, and near-wellbore connectivity on storage factors. Systematic and comprehensive numerical experiments are carried out using random sampling to generate a probability distribution of CO2 storage factors and replacement ratio. Results showed the parameters with most impact to least impact on injectivity and storage factor: matrix permeability, near-wellbore connectivity, bottomhole pressure, fracture half length, and fracture conductivity. The methodology in this study provides a foundation to examine how CO2 storage factors change spatially and temporally in and outside the SRV. The new understanding can be applied to optimize field development, well spacing, and infill drilling to increase economic storage.

Preparation and pipeline transport of CO2 as a hydrate slurry – Modelling and techno-economic analysis

CO2 transportation as a hydrate slurry is modelled in Aspen Plus, including the slurry preparation and the pipeline transport. Due to the lack of built-in models for the hydrate formation, mass and energy balances were developed and implemented using a User-block function. NRTL-RK global property method was used, given the accuracy in predicting the CO2 solubility in water under incipient hydrate formation conditions and the dissolution heat of CO2 in water. The conventional process of transporting CO2 in a supercritical state was also modelled to benchmark the hydrate-based technology. The hydrate-based process is safer than the conventional process as it requires lower operating pressures, but the estimated costs are higher due to the need for refrigeration and larger pipeline diameters for transportation. The addition of thermodynamic promoters, that moderate the hydrate formation conditions, the integration of cold streams with other processes, and valuing the water transported with CO2, will enhance the economic attractiveness of the hydrate-based process.

Xenon fluid state model and evaluation of working medium in satellite electric propulsion system

Xenon, the working medium of satellite electric propulsion system, is easy to enter the supercritical state, and does not follow the ideal gas equation of state in filling and in-orbit application. The error of fluid state and parameter evaluation of xenon is large. In view of this difficulty, the working fluid state test system and test method of xenon were established. The saturation vapor pressure, gas phase PVT and supercritical PVT characteristics of xenon were tested. A new saturation vapor pressure equation of xenon was established. The relative deviation between the saturated vapor pressure test results and the NIST equation is less than 0.2 %. The Helmholtz equation established on the basis of xenon experimental data has a high accuracy, and the deviation from the experimental data is less than 0.5 % within 273 K–358 K. In 358 K–373 K, the deviation from the test data is better than 0.05 %, and the second dimension coefficient is used to prove the accuracy and reliability of the model, which provides a state model for satellite xenon filling and in-orbit application.

Corrosion at Top-of-the-Line in High Pressure and Dense CO2 Environments

This study presents unique data on top-of-the-line corrosion (TLC) occurring in high-pressure environments where CO2 was in the gaseous, liquid, or supercritical state. While CO2 is traditionally in a gaseous phase, this form of degradation is referred to as TLC. In this study, similar phenomena with different mechanisms were observed in liquid CO2 and supercritical states all of which are referred to as TLC due to the location of specimens and ease of comprehension. Experiments were conducted to investigate the effect of CO2 partial pressure (ranging from 20 bar to 100 bar) with temperatures (30°C to 50°C) relating to different water condensation rates (0.001 mL/m2/s to 0.1 mL/m2/s). Uniform and localized TLC rates increased with a higher water condensation rate and surface temperature. As long as CO2 remained gaseous, its partial pressure (pCO2) showed a negligible influence on both uniform and localized TLC rates. At the highest gaseous CO2 content tested, the formation of a protective iron carbonate (FeCO3) layer decreased the TLC rate, with this effect being more pronounced at lower water condensation rates. The risk of localized corrosion for specimens exposed to this environment at high and medium water condensation rates remained an issue. In the dense phase CO2 environment, the difference in temperature between the bulk environment and the specimen’s surface caused a similar phenomenon to water condensation, termed water drop-out, which resulted in corrosion. The rate of water drop-out could not be measured experimentally or estimated theoretically but is a complex function of temperature, pCO2, and CO2 physical state. The interplay between high pCO2 and low pH of the dropped-out water led to elevated uniform and localized corrosion rates. The depth of localized corrosion, at the high and medium water drop-out conditions, reached its maximum at the surface temperature of ca. 45°C. At a lower surface temperature of ca. 25°C and a higher surface temperature of ca. 65°C, the maximum penetration rate was decreased due to slower kinetics of reactions and the formation of a more protective FeCO3 layer, respectively. The results presented in this study highlight the significant difference between corrosion rates, especially in the form of localized damage, in gaseous and dense-phase CO2 environments.

Fracture Evolution during CO2 Fracturing in Unconventional Formations: A Simulation Study Using the Phase Field Method

With the introduction of China’s “dual carbon” goals, CO2 is increasingly valued as a resource and is being utilized in unconventional oil and gas development. Its application in fracturing operations shows promising prospects, enabling efficient extraction of oil and gas while facilitating carbon sequestration. The process of reservoir stimulation using CO2 fracturing is complex, involving coupled phenomena such as temperature variations, fluid behavior, and rock mechanics. Currently, numerous scholars have conducted fracturing experiments to explore the mechanisms of supercritical CO2 (SC-CO2)-induced fractures in relatively deep formations. However, there is relatively limited numerical simulation research on the coupling processes involved in CO2 fracturing. Some simulation studies have simplified reservoir and operational parameters, indicating a need for further exploration into the multi-field coupling mechanisms of CO2 fracturing. In this study, a coupled thermo-hydro-mechanical fracturing model considering the CO2 properties and heat transfer characteristics was developed using the phase field method. The multi-field coupling characteristics of hydraulic fracturing with water and SC-CO2 are compared, and the effects of different geological parameters (such as in situ stress) and engineering parameters (such as the injection rate) on fracturing performance in tight reservoirs were investigated. The simulation results validate the conclusion that CO2, especially in its supercritical state, effectively reduces reservoir breakdown pressures and induces relatively complex fractures compared with water fracturing. During CO2 injection, heat transfer between the fluid and rock creates a thermal transition zone near the wellbore, beyond which the reservoir temperature remains relatively unchanged. Larger temperature differentials between the injected CO2 fluid and the formation result in more complicated fracture patterns due to thermal stress effects. With a CO2 injection, the displacement field of the formation deviated asymmetrically and changed abruptly when the fracture formed. As the in situ stress difference increased, the morphology of the SC-CO2-induced fractures tended to become simpler, and conversely, the fracture presented a complicated distribution. Furthermore, with an increasing injection rate of CO2, the fractures exhibited a greater width and extended over longer distances, which are more conducive to reservoir volumetric enhancement. The findings of this study validate the authenticity of previous experimental results, and it analyzed fracture evolution through the multi-field coupling process of CO2 fracturing, thereby enhancing theoretical understanding and laying a foundational basis for the application of this technology.

Repetitive shock waves generated by a single long pulse underwater arc discharge

The electrohydraulic effect induced by underwater arc discharge is an efficient way to generate controllable, high-intensity shock waves. However, the development process of underwater arc discharge involves the complex coupling of plasma arc, gas bubble, and liquid medium, of which the evolution mechanism is not well understood. In this paper, the underwater arc discharge process at a millisecond pulse (&amp;gt;50 ms) was investigated by high-speed shadow imaging and colorimetric temperature measurement, and a simulation model of bubble pulsation was proposed to quantitatively estimate the state variation and energy transfer of the gas bubble. The results indicate that the whole arc discharge process can be categorized into three successive stages: short-period oscillation, long-period oscillation, and quasi-steady state. The vapor inside the bubble can reach a supercritical state (827 K and 140 MPa) at the minimum bubble radius. The simulation shows that the light radiation absorption and the heat conduct loss through metal electrodes are the two dominant factors influencing the pulsation of the bubble, and further analysis indicates that the dynamic evolution of the arc determines the bubble pulsation mode. Our findings demonstrate why and how repetitive electrohydraulic shock waves can be generated by a single long pulse underwater arc discharge, providing a low-cost way of shock wave generator based on an AC/DC high-voltage power source.

Decomposition behavior of supercritical ethylene under ultra-high temperature and ultra-high pressure

The gas-phase raw materials in many industrial scenarios currently exist in the reactor in a supercritical state. Unlike gas phase molecules, the supercritical molecules usually exhibited dynamic motion patterns in the system, which made them more susceptible to decomposition. Previous researches mainly focused on low-temperature and low-pressure systems, and few research on decomposition behavior of supercritical molecules under ultra-high temperature and ultra-high pressure were studied. This study focused on the decomposition behavior of supercritical ethylene under ultra-high temperature and ultra-high pressure, the effect of triggering conditions on supercritical ethylene decomposition was investigated. In addition, the temperature and pressure change curves during ethylene decomposition were analyzed to obtain evolution time nodes to determine energy accumulation in supercritical states. Moreover, the gas product distribution and derived explosive carbon were characterized for better evaluating the consequences of supercritical ethylene decomposition. This article aimed to provide theoretical basis and data guidance for energy utilization and conversion in ethylene supercritical systems.

Experimental Study on Convection Heat Transfer of CO2 in C/SiC Composite Porous Material at Subcritical, Transcritical, and Supercritical States

Using C/SiC as the structure for transpiration cooling is prospective for new hypersonic vehicles, based on clarification of heat transfer process in porous media. But there are still gaps due to the complexity of pore structure of C/SiC, together with the effects of capillary force and strong variation of thermophysical properties for subcritical and supercritical flow. In this study, heat transfer analysis for C/SiC with CO2 as the coolant is presented by experiments. Heat transfer characteristics in typical C/SiC sample under various mass flow rates (0.003–0.018 kg/s), inlet fluid temperatures (20–40 °C) and pressures (5.9–10 MPa) are analyzed. Heat transfer and pressure drop correlations have been developed. The results show heat transfer coefficient at supercritical state behaves non-monotonic under varying flow rates caused by the combined effect of sharp increase of specific heat and the change of flow rate. The effect of pressure on heat transfer can be neglected compared to that of flow rate, while for Reynolds number (Re) >100, the pressure drop of supercritical cases are smaller than that of phase-change cases under similar Re, due to the effect of capillary force in C/SiC. This study can provide basic support for further study of transpiration cooling using C/SiC and CO2.

Stable convergence of conditional least squares estimators for supercritical continuous state and continuous time branching processes with immigration

We prove stable convergence of conditional least squares estimators of drift parameters for supercritical continuous state and continuous time branching processes with immigration based on discrete time observations.

Simulation of boost path and phase control method in supercritical CO2 pipeline commissioning process

CO2 pipeline can be applied to Enhanced Oil Recovery (EOR) projects and CO2 geological storage projects, and has high engineering application value. However, pipeline transportation of CO2 is a high-risk link in CO2 storage projects. The phase state commonly used to transport CO2 is a supercritical state with both gaseous and liquid characteristics, and there are also great challenges in the field of pipeline transportation. The existing researches have carried out a lot of exploration and application development in the heat transfer, phase change, transient and special conditions of supercritical CO2 pipeline operation.In this paper, the modeling and exploration of the commissioning process before the formal operation of the supercritical CO2 pipeline are carried out, and the boost path of the supercritical CO2 pipeline in the phase diagram under different working conditions is obtained. The model developed in this paper is based on the sensitivity analysis of the effects of variables such as ground temperature, filling pressure speed, and whether to perform pressure-stabilizing leak detection operations. The step-up path in the phase diagram of the CO2 pipeline commissioning process and the adjustment control method are obtained. And the critical temperature of each working condition that cannot avoid phase transition, thus contributing to the existing knowledge system in this field.

Thermodynamic study on the dissolution of lithium cobaltate in the cathode of spent lithium-ion batteries recovered from supercritical water

The recovery of cathode metal materials in lithium-ion batteries using supercritical water (SCW) has attracted more and more attention. To explore the separation and extraction method of LiCoO2 using SCW, the thermodynamic experiments of LiCoO2 dissolution in SCW were carried out in this paper to study the effect of essential parameters on the solubility of LiCoO2 in SCW. The results show that the solubility decreases with an increase in temperature and increases with an increase in pressure and density. The molecular dynamics were applied to simulate the dissolution process of LiCoO2 and provide a theoretical explanation for the experimental law. The solubility of LiCoO2 in SCW was also calculated using the R-HKF equation of state, and high-precision prediction results were verified using experimental data. This work will provide a reference for obtaining the solubility of cathode metal compounds of spent lithium-ion batteries in the supercritical state.

Lipidomics Study of Type 1 Diabetic Rats Using Online Phase Transition Trapping-Supercritical Fluid Extraction-Chromatography Coupled with Quadrupole Time-of-Flight Tandem Mass Spectrometry.

Chromatography-mass spectrometry-based lipidomics represents an essential tool for elucidating lipid dysfunction mechanisms and is extensively employed in investigating disease mechanisms and identifying biomarkers. However, the detection of low-abundance lipids in biological matrices, along with cumbersome operational procedures, complicates comprehensive lipidomic analyses, necessitating the development of highly sensitive, environmentally friendly, and automated methods. In this study, an online phase transition trapping-supercritical fluid extraction-chromatography-mass spectrometry (PTT-SFEC-MS/MS) method was developed and successfully applied to plasma lipidomics analysis in Type 1 diabetes (T1D) rats. The PTT strategy captured entire extracts at the column head by converting CO2 from a supercritical state to a gaseous state, thereby preventing peak spreading, enhancing peak shape for precise quantification, and boosting sensitivity without any sample loss. This method utilized only 5 μL of plasma and accomplished sample extraction, separation, and detection within 27 min. Ultimately, 77 differential lipids were identified, including glycerophospholipids, sphingolipids, and glycerolipids, in T1D rat plasma. The results indicated that the progression of the disease might be linked to alterations in glycerophospholipid and sphingolipid metabolism. Our findings demonstrated a green, highly efficient, and automated method for the lipidomics analysis of biological samples, providing a scientific foundation for understanding the pathogenesis and diagnosis of T1D.