The study of lithium isotopic (δ7Li) signatures in sedimentary deposits has become a powerful tool to infer past silicate weathering regimes, thus informing our knowledge of the geological carbon cycle and paleoclimate evolution. Sediments from Qinghai Lake, the largest saltwater lake in China (4625 km2), offer an unparalleled archive for investigating the climatic history of the Qinghai-Tibet Plateau. However, prior to leveraging the δ7Li proxy in this context, it is imperative to unravel the mechanisms of lithium (Li) isotope fractionation and elemental cycling within the lake's aqueous and sedimentary systems. In this study, we collected and analyzed samples of Qinghai Lake's water, sediments, and recharge waters (rivers, groundwater, and rainfall) to investigate the processes controlling the δ7Li value recorded in Qinghai Lake sediments.Our data reveal subtle variances in Qinghai Lake water Li concentration ([Li]), ranging from 652 to 873 ng/g, suggesting interactions with iron oxides or suspended matter. The δ7Li signature, however, exhibits remarkable uniformity across the lake at 32.1‰ (±0.4‰). Near the estuary of the Buha River, there is a swift homogenization of [Li] and δ7Li, stabilizing within just 3 km of the inflow. Lake sediments exhibit δ7Li values ranging from 1.5‰ to 6.6‰, exceeding those of the upper continental crust (∼0‰ ± 4‰), yet approximately 30‰ lower than those in lake waters. This significant discrepancy between the δ7Li of lake water and sediments is likely due to the preferential incorporation of 6Li over 7Li during the neoformation of clay minerals.Lithium mass balance modeling for Qinghai Lake, incorporating inputs from river and groundwater (∼46.5 t/a with δ7Li ∼18.3‰) and outputs via clay mineral uptake (∼44 t/a with δ7Li ∼5.1‰), indicates that the lake's Li system is currently out of steady state. The model predicts a gradual rise in the lake's Li inventory, estimated to achieve steady state within 1.2 ka and the δ7Li value of lake water will increase until reaching ∼45‰ assuming constant climate conditions.
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