Stress Creep Research Articles

Thermal Oxidative Aging Effect on Chemo-Rheological and Morphological Evolution of Crumb Rubber Modified Asphalt Binders with Wax-Based Warm Mix Additives

Wax-based warm mix additives can decrease the viscosity and improve the workability of crumb rubber (CR)-modified asphalt, but the mechanism of influence on the aging performance of CR-modified asphalt is not clear. To investigate the thermal aging behavior and mechanism of wax-based warm mix CR-modified asphalt, polyethylene wax (PEW) and polyamide wax (PAW) were mixed to prepare warm mix CR-modified asphalt. The effect of thermal aging on the rheological and mechanical properties was characterized by a basic property test, frequency sweep test, and multiple stress creep recovery test. The chemical composition changes during aging were then analyzed by Fourier transform infrared spectroscopy and gel permeation chromatography. Finally, the phase morphology during thermal aging was observed by fluorescence microscopy. The results showed that compared with the degradation of CR, the oxidative aging of the asphalt binder played a dominant role in the process. Not only did PEW and PAW attach to the asphalt surface in the form of crystallization to prevent its reaction with oxygen but they also promoted the dissolution of CR, and released polymerization chains, thereby enhancing the antiaging properties of CR-modified asphalt. Furthermore, the antiaging of PAW/CR-modified asphalt was better than that of PEW/CR-modified asphalt, because the amide group of PAW reacted with CR-modified asphalt to form a polymer structure.

Yield stress anomaly and creep of single crystal Ni-base superalloys – Role of particle size

In the present work we subject the single crystal Ni-base superalloy ERBO1 (CMSX 4 type) to constant strain rate (CSR) and creep testing at temperatures between 1023 and 1223 K. Three material states are considered which have similar particle volume fractions >60% but differ in γ′-particle sizes (material states S, M and L of particle sizes: 240, 390 and 540 nm). In constant strain rate testing, a yield stress anomaly is observed for all three material states, with a yield stress maximum at 1073 K. This increase of strength with increasing temperature is not observed during creep testing at significantly lower deformation rates in this low temperature high stress creep regime, where different elementary deformation mechanisms govern CSR and creep behavior. In contrast, in the low stress high temperature creep regime, stress/strain rate data pairs from CSR creep tests both show decreasing strength with increasing temperature. It is found that in both types of tests the material state M shows the highest strength (highest yield stress and lowest creep rate). This can be rationalized based on a scenario where both, γ-channel and γ′-particle dislocation activities are important. Diffraction contrast transmission electron microscopy is used to study the relevant elementary deformation processes. Details of dislocation arrangements are discussed with a special focus on the role of Kear Wilsdorf (KW) locks, γ′-particle shearing by superlattice stacking faults (extrinsic and intrinsic) and dislocation climb.

Particle gradation effects on creep characteristics and the underlying mechanism in calcareous sand

Calcareous sand, a foundation material of marine origin, is an indispensable component in marine construction and has found extensive applications in building foundations and airport runways. The complex nature of the marine environment and the unique characteristics of calcareous sand present significant challenges for ensuring the stability and durability of engineering structures. To address these challenges, multistage loading triaxial creep tests were conducted on calcareous sands with different particle gradations to analyze their creep characteristics and underlying mechanisms. The result shows that the amount of ultimate axial creep strain is positively correlated with deviatoric stress but negatively correlated with the coefficient of uniformity (Cu). The creep process demonstrates a significant creep structure effect, characterized by creep rate lag and creep failure lag. The volumetric creep strain-time relationship at different creep stress ratios can be classified into three types. When the creep stress ratio is less than the stress ratio at the dilative point, the sample is first compacted followed by dilatancy; when the creep stress ratio is equal to the stress ratio at the dilative point, only compaction is obtained; as the creep stress ratio becomes larger than the stress ratio at the dilative point, pure dilatancy is found. The particle crushing modes and creep mechanisms of calcareous sand are also examined through meso-observations. It is found that the particle crushing modes can be categorized into three distinct types: grinding, angular breakage, and whole particle breakage. The particle gradation not only impacts the primary particle crushing mode but also governs the movement of particles and fragments, thereby influencing the occurrence of creep deformation. Specifically, a smaller Cu value corresponds to a higher fragmentation rate of the specimen, an increased number of overall crushing and angular fractures, a larger space for fragment migration after crushing, and eventually a greater creep deformation. Finally, a modified Burgers model is proposed based on the test results, which can effectively capture the creep deformation in the presence of creep structure effects and creep failure stages.

A Design of Transesterification Vitrimers with Variable Fractions of Network Defects and the Creep Characteristics

AbstractVitrimer materials have attained great interest owing to their sustainable functions and distinctive physical properties. Compared with conventional cross‐linked materials, the thermoplastic‐like nature, such as the stress relaxation and creep at high temperatures, is outstanding, which is owing to the activation of the bond exchange in the cross‐linked network. The activation temperature of the bond exchange, so‐called topology freezing temperature (Tv), are treated as the important material parameters, and non‐isothermal (i.e., temperature‐ramp) creep test is one of the method to determine the Tv. This study investigates effects of network defects, that is, the breaking point of network connectivity, on the creep and Tv. The transesterification vitrimer samples with varying fraction of the network defects are designed using thiol‐epoxy click reaction, where the overall fraction of the bond exchange units, that is, the ester bond and hydroxyl group, is kept constant. Non‐isothermal creep tests are conducted with varying temperature‐ramp rate and applied stress levels, and the difference of Tv and creep behaviors at T > Tv are discussed in terms of network strand diffusion during bond exchange and chain elongation under stress.

Experimental Study on the Accelerating Creep of Rock Under Dry and Wet Conditions Based on a New Test Method

Creep tests under constant stress are among the most important tests for investigating the time-dependent behavior of rock. In previous studies, creep tests were conducted under various loading and environmental conditions; however, it was very difficult to demonstrate accelerating creep at failure at stresses less than 50% of strength in conventional creep tests. In this study, a new test method is proposed that combines an alternating loading-rate test and a creep test in the post-failure region. The accelerating creep as well as the loading-rate dependence of strength were successfully obtained simultaneously from a single specimen. This test method was applied to three rock types under dry and wet conditions. The results of Sanjome andesite under both dry and wet conditions, Kimachi sandstone under dry conditions, and Tage tuff under dry conditions showed a similar relationship between creep strain, creep strain rate, and residual time (i.e., creep lifetime minus elapsed time), from high to low creep stress levels, and a close relationship between accelerating creep and the loading-rate dependence of strength. Further, the mechanism responsible for the time dependence was found not to change significantly from high to low stress levels. In contrast, different results were obtained when high and low creep stress levels were compared in Kimachi sandstone and Tage tuff under wet conditions. The larger increase in creep strain with increasing creep strain rate at lower creep stress levels was related to the shape of the stress–strain curve in the post-failure region.

Evaluation of the laboratory aging of field-blended crumb rubber modified binder

Field-blending approach is widely employed by the industry to introduce crumb rubber into asphalt binder. Rubber-modified binder provides satisfactory performance and benefits the environment by consuming recycled rubber manufactured from scrap tires. This work investigated the aging mechanism and post-aging performance of rubber-modified binders using laboratory aging protocols. Four rubber-modified binders containing two rubber contents (5 and 10 percent) and two particle sizes (passing 1.18 mm and 2.36 mm, respectively) were evaluated in this study. After multiple laboratory aging protocols, chemical components in aged binders were measured with Fourier transform infrared spectroscopy. Chemical analysis revealed that rubber-modified binders accumulated fewer oxidative aging products (carbonyl and sulfoxide components) than their unmodified base binder after long-term aging. Increasing rubber content and particle size increased the complex shear modulus while decreasing the phase angle of the binder. Binder viscosities were back-calculated from complex moduli and phase angles. A linear correlation between logarithmic viscosity and carbonyl area index exists for the long-term aged rubber-modified binders. This linearity can be used to predict the age-hardening of rubber-modified binders. These binders were also tested in dynamic shear rheometer to determine performance grades. Multiple stress creep recovery tests evaluated the rutting resistance of short-term aged binders. Bending beam rheometer was used to evaluate the low-temperature cracking resistance of long-term aged binders. These test results showed that rubber-modified binders provided better rutting and cracking resistance than their base binder. Statistical analysis indicated that carbonyl components correlated to the binder performance at various aging statuses.

Development of dynamic shear-rheology-based method to improve evaluation of swelling degree of recycled crumb rubber in asphalt rubber

Inappropriate disposal of substantial scrap tires has become an unavoidable and imminent environmental concern. Asphalt rubber (AR) facilitates the value-added recycling of scrap tires into eco-friendly and durable pavement, showcasing immense potential for pollution alleviation and resource conservation. In preparing AR, the swelling effect of rubber plays a dominant role in the gel-like network formation and performance enhancement of the modified asphalt. Accordingly, it is crucial to accurately evaluate the rubber swelling degree for guiding AR preparation and mixture design. Existing research mainly relies on measuring the volume of expanded rubber particles to assess the rubber swelling degree, which requires sophisticated instruments or a cumbersome process of extracting the crumb rubber. In this study, a method was proposed to conveniently evaluate the swelling degree of crumb rubber based on the dynamic shear rheological indicators. Firstly, the base asphalt was mixed with crumb rubber at different levels of time to prepare AR binders with varying swelling degrees. The mechanical properties (i.e., elastic recovery) and physical properties (i.e., volume expansion) were measured and analyzed to investigate the impacts of swelling time on AR properties. Secondly, the rheological properties of AR with different swelling degrees were measured via temperature sweep (TS) test, multiple stress creep recovery (MSCR) test, and linear amplitude sweep (LAS) test. Thirdly, the particle effect (PE) and interaction effect (IE) values were calculated, and the swelling degrees were determined based on the variations of PE values. Relationships between swelling degrees and PE-related indicators were established to facilitate the development of the new evaluation method. Finally, the swelling degrees evaluated by the newly developed method were compared with volume expansion to validate its reliability. The results from different rheology tests were also used to verify the feasibility of the proposed method, and the prediction of swelling degree against the swelling time was established. The findings of this research provide references for evaluating the swelling degree of crumb rubber conveniently and accurately.

Long-term mechanical properties of sludge-cured lightweight soil under the superimposed effects of drying-wetting and freezing-thawing

ABSTRACT Sludge-cured lightweight soils have unique advantages in roadbed treatment due to their properties such as low density and high strength. Its long-term mechanical law based on the superposition of drying-wetting and freezing-thawing (D-W-F-T) is studied through creep experiment. The test results show that: with the increase of the number of D-W-F-T, the deformation of the soil gradually increases, and the deformation tends to be stable when it reaches a certain number of times; the stress-strain isochronous curves are obviously nonlinear in general; The long-term strength increases with the increase of density and confining pressure, and decreases with the increase of the number of D-W-F-T; by comparing the isochronous stress-strain curve cluster method and the steady state creep rate vs. The comparative analysis suggests that the steady state creep rate versus stress level curve method be used to determine the long term strength.

Homogenization effects by Co additions to high temperature and low stress creep performance of a 4th-generation Ni-based single crystal superalloys

The important factors limiting the fourth-generation Ni-based single-crystal superalloys (Ni-SXs) are the increases in cost and density. A cheaper and lighter potential alternative element of Ru, Co's comprehensive effects were studied. The effects of Co and inhomogeneity between dendrite core (DC) and interdendritic region (ID) on creep performance at 1100 °C and 137 MPa in a 4th generation Ni-SXs were systematically investigated. The results show that the Ni-SXs with 9 wt% Co has the longest creep lifetime. Co additions alleviate the overall element segregations between DC and ID, especially Re, Cr, and W. And reverse partitioning behavior of Co also changes the partitioning ratio of elements between γ and γ′ phases, resulting in the inhibition of TCP phases precipitation for most creep time to avoid excessive consumption of solid solution strengthening elements and local stress concentration. The decrease of the lattice constant of γ reduces lattice misfit between γ and γ′ with the addition of Co, leading to the enlargement of dislocation network spacing and less resistance for movement or shearing of dislocation. The decrease of γ′ solvus temperature with Co addition promotes the dissolution of γ′ at high working temperature, resulting in severe topological inversion of γ/γ′ microstructures at ID. In addition, the main creep cracks of all Ni-SXs appear at ID, so the inhomogeneity between DC and ID is concerned.

Experimental research on mechanical, material, and metallurgical properties of Inconel 600: Application in elevated temperature environment

Experimental research on mechanical, material, and metallurgical properties of Inconel 600: Application in elevated temperature environment

The effect of eco-friendly functionalised acid sludge on thermo-rheological characteristics of bituminous composites

Used engine oil recycling produces acid sludge as a by-product of the acid-clay treatment. It is classified as hazardous waste material. This paper introduces a novel material named PS (powdery sludge) by functionalising the acid sludge. PS was used in a dry method to replace fine aggregates of the asphalt mixture. The effect of adding PS was investigated on the rheological behaviour of asphalt mastics by using dynamic shear rheometer for performing frequency sweep and multiple stress creep and recovery tests, bending beam rheometer, differential scanning calorimetry, and Fourier transforms infrared spectroscopy tests. Adding PS makes the mastic softer at low temperatures and stiffer at high temperatures, causing it up to 5 and 1.38 times more resistant to rutting and fatigue, respectively. Also, PS reduces temperature sensitivity, aging potential, and moisture sensitivity. Therefore, using PS as a replacement for siliceous aggregates in cold, moderate, and tropical regions is recommended.

Room temperature tensile creep behavior of Mg-6Zn-0.4Mn-0.3Al-0.2Ca (wt%) alloy containing icosahedral quasicrystals

The poor creep resistance at room temperature is the critical issue limiting magnesium (Mg) alloys to be structural components in engineering fields. In this study, we designed a novel Mg-6Zn-0.4Mn-0.3Al-0.2Ca (ZMAX6000) alloy, which had superior creep properties at room temperature, and the steady creep rate of ZMAX6000 (2.52×10−9 s−1) alloy was one order of magnitude lower than that of pure Mg (5.0×10−8 s−1) and AZ31 alloy (1.5×10−8 s−1), when the creep stress is equivalent to the 0.8 yield stress (YS). The ZMAX6000 alloy featured icosahedral quasicrystal phases (I-phases) distributed at almost all triangular grain boundaries. The room temperature creep threshold stress (σ0) and stress exponent (n) for the I-phase enhanced ZMAX6000 alloy were σ0 = 209 MPa and n = 4.9, respectively. I-phases can act as barriers to grain boundary sliding, and the high-density nanoscale second phases inside the grains can impede the dislocation slip. Consequently, the ZMAX6000 alloy exhibits excellent creep properties at room temperature. The cross-slip consisting of basal < a > dislocation and prismatic < a > dislocation, as well as the pyramidal <c + a> slip are the main creep mechanisms of the ZMAX6000 alloy at room temperature.

Study on the hot corrosion-creep failure mechanism of Ni-based single crystal superalloy considering the stress dependence

The accelerated creep failure of Ni-based single crystal superalloy by hot corrosion is confirmed by creep tests at 900 °C/550 MPa–400MPa in air and salt environments. The analysis of creep curve, microstructure and fracture type shows that there are obvious differences in hot corrosion-creep behavior under high, middle and low creep stress conditions, indicating that there is the stress dependence between the influence of hot corrosion on the creep properties of the alloy. Hot corrosion accelerates creep failure of Ni-based single crystal superalloy by decreasing the deformation resistance, reducing the effective stress area, and affecting the creep fracture mode.

A creep/recovery model of dry fiber fabric during compaction considering temperature and in‐plane tension

AbstractIn the manufacturing of fiber‐reinforced composite materials, the preforming stage of dry fiber fabric entails compaction operations carried out under constant pressure, a specific preforming temperature, and in‐plane tension. Throughout this process, permanent deformation and creep/recovery behavior are observed in the fabric, correlating with factors such as time, sustained pressure, temperature, and in‐plane tension. Effective control of fiber volume fraction and material composition necessitates a thorough comprehension of these phenomena as well as the capacity to predict them with accuracy. To solve this, a viscoelastic‐plastic model was put forth, which provides an account of the viscous effects on the fabric during its stages of compression and recovery. The proposed model incorporates changed Burgers units to manage time‐dependent deformations and plastic units to address permanent deformations. Through the application of a single set of parameters, the model precisely and comprehensively characterizes through‐thickness creep/recovery behavior of preformed dry fiber fabrics under varying conditions, including creep stress, temperature, and in‐plane tension. To enhance the practical utility of the model, an application has been developed and validated against experimental data conducted under diverse test conditions. The results demonstrate consistency between experimental curves and model‐predicted curves across various compression scenarios.Highlights A viscoelastic‐plastic model was proposed with a single parameter set. Stress, temperature, and in‐plane tension all exacerbated creep/recovery. Model captures temp. and time‐related creep/recovery with in‐plane tension. The model has been transformed into a practical application tool.

Characteristics of negative creep aging and its microstructure-oriented tensile behavior

UNS S17400 steel was creep-aged under a constant stress of 300 MPa at 480 °C and 600 °C for 1, 3, and 5 h, and its microstructural phase evolution was investigated. During the initial creep aging at 480 °C for 15 min, negative creep strain occurred because of the stress-assisted precipitation, which resulted in Cu-rich precipitates impeding the movement of dislocations. By contrast, the sample creep-aged at 600 °C had a typical creep-strain curve comprising a primary creep stage and secondary steady-state stage. The creep stress accelerated the growth of Cu-rich precipitates and austenite γ phase reversion, which were clearly observed in samples creep-aged at 600 °C. The reverted γ phase formed due to the stress-assisted aging at 480 °C for 3 h, as well as at 600 °C due to the elevated temperature aging. The samples with the longer creep aging times decreased in tensile yield strength but increased in strain hardening rate. Strain hardening after strain softening was observed in the sample creep-aged at 600 °C for 5 h, which had the highest strain hardening rate. Strain hardening was attributed to the dislocations becoming entangled with nanoscale Cu-rich precipitates, the formation of microtwins, and the presence of deformation-induced martensite.

Investigation on creep behavior and microstructural features of an additively manufactured Ti2AlNb alloy upon isothermal deformation at elevated temperature

In this work, we investigated the creep behavior of a SLM-printed Ti2AlNb alloy and systematically examined the corresponding microstructural features using multi-scale characterization methods. A single β-phase matrix is produced in the alloy due to the extremely fast solidification process. A new O phase transformation is triggered by the applied external stress following the crystallographic relation of (101) B2//(001) O, compared with the aged counterpart in which only the conventional β-to-O phase transformation with a (110) B2//(020) O relation occurs. This phase transformation contributes to improving the creep resistance of printed specimen test applied with creep stress of 150 MPa at 923 K, suggesting a final steady strain rate of ∼5 × 10–8/s. This work further elucidates the mechanisms of the microstructural evolution of SLM-printed Ti2AlNb-based alloys on creep and offers valuable insights for the future development of high creep-resistance alloys.

Investigation into Stress Relaxation and Creep Rate of C47200 Copper Alloy

Copper alloys have high thermal conductivity, relatively high mechanical strength, and toughness over a wide range of temperature; hence they are highly sorted for complex structural applications that required extreme heat flux under load. Creep of materials is classically associated with time-dependent plasticity under a constant stress/load at an elevated temperature, often greater than the absolute melting temperature. This research is aimed to study the evaluation of stress and creep rate in copper, identifying the mechanisms at which copper can easily be exposed to stress and creep deformations in structures. A 12 mm diameter copper rod with the composition of 52.05 % CuO and 30.26 % SnO2 was procured locally. Samples from the procured rod were heat treated to 650°C for 30 minutes and cooled in the still air as well as inside the furnace. Creep test was carried out at 760uC with a constant load corresponding to an initial stress (between 1.5 MPa and 350 MPa) and stress relation was carried out on a 98 kN capacity stress relaxation frame (from 350 MPa to 300 MPa). Rockwell hardness test and metallographic analysis (at 200 mm) were also conducted on the heat treated and unheated control samples. It was established that heat treatment reduced the hardness property of stress relaxed copper, accelerated the stress relaxation process up to 60 %, speed up both primary creep rate and the tertiary creep rate as well altered the linear creep pattern and behaviour.

Strength and creep characteristics of methane hydrate-bearing clayey silts of the South China Sea

Natural gas hydrates are abundantly detected in the clayey-silty deposits of the South China Sea (SCS). The long-term hydrate extraction process may trigger creep deformation and failure of the clayey-silty reservoir. Hence, it is essential to evaluate the creep properties of the clayey-silty hydrate reservoir for safe production. Current research mainly focused on rapid failure, while neglecting time-dependent creep deformation of the clayey-silty hydrate reservoir. In this study, a number of triaxial shear and creep experiments were carried out on methane hydrate-bearing clayey silts (HBCSs) in the SCS in order to investigate their strength and creep deformation characteristics. The results indicated that: (1) the increase of effective stress enhances the shear strength and deformation, and the presence of hydrates enhances the shear strength while reducing the deformation; (2) the creep strain and strain rate increase as the creep stress ratio and effective stress rise; (3) the accelerated creep stage only occurs at higher effective stress in HBCSs and not in hydrate-free clayey silts (HFCSs), and the creep strain and strain rate of the HBCSs are lower than those of the HFCSs. The experimental data will contribute to the construction and verification of creep constitutive models for HBCSs in the SCS.

Expansion and creep of concrete with expansive agents at variable temperature

Extensive research has shown that expansive agents can reduce engineering cracks of concrete, while temperature and creep significantly affect the ability of the expansive agent to compensate shrinkage of concrete. In order to study the expansion and creep of concrete mixed with expansive agents under variable temperature, Series of parameters of concrete mixed with MgO expansive agent (MEA) and CaO-calcium sulfoaluminate expansive agent (CEA) were tested by temperature stress testing machine (TSTM), and the elastic modulus, expansion and creep were calculated according to the maturity theory. The results showed that CEA had a larger free expansion but smaller constrained expansion compared to MEA, and the expansion energy of CEA almost completely released within 36 h of the temperature-rise stage. MEA had a smaller compressive stress creep in the temperature-rise stage and larger tensile stress creep in the cooling stage, which was beneficial to resistance to cracking. The proposed expansion kinetics model showed a remarkable level of consistency with the test results and held significant importance in guiding the application of MEA in practical engineering.

Effect of pH on primary and secondary crack propagation in sandstone under constant stress (creep) loading

Time-dependent, chemically assisted crack propagation behavior in rocks is fundamental to understanding the long-term stability of civil engineering structures. In this study, we investigated the propagation of primary and secondary cracks in macrofractured sandstone in distilled water (pH = 5.6) and in an aqueous solution of hydrochloric acid (HClaq, pH = 1.82) using digital image correlation (DIC), comparing the results to those from experiments performed in air. Results show that for the macrofracture angles γ = 0 and 90°, the nucleation position r of the primary crack is not affected by pH, and always occurs at the fracture tip (r = 0) and fracture center (r = 1), respectively. For γ = 30, 45, and 60°, r increases quasi-linearly with the increase of γ in semi-log plots, and an increase in pH moves the primary crack away from the fracture tip. For a given γ, an increase in pH produces an increase in the kink angle k1 of the secondary crack. The influence of pH on secondary crack propagation is most pronounced at high γ values. As the pH increases, the location of the secondary cracks gradually turns counterclockwise with a decreasing swing range, from 37° at pH 1.82–35° at pH 5.6. The secondary crack is inclined at a maximum of 30° and 32° to the maximum principal stress direction at pH 1.82 and pH 5.6, respectively. Right-lateral shear secondary cracks with well-developed tensile tail fractures are more prevalent in higher pH environments. The comparison with dry experiments indicates that distilled water is more aggressive than HClaq. The significant loss of calcium ions in distilled water and the reduction of large pore volume fraction in HClaq are considered the main reasons for the deterioration of the pH effect.