This paper presents an experimental characterization of the prebreakdown phenomena in liquid/solid interfaces. The characterization is devoted to the 2nd mode positive streamers initiated and propagated along interfaces of mineral-oil and solids with different chemical composition and physical properties. Polymers of low density polyethylene (LDPE), polyethylene terephthalate (PET), polytetrafluoroethylene (PTFE) polyvinylidene fluoride (PVDF) and papers made of kraft paper and a kraft fibril paper (made from cellulosic micro and nano fibrils), lignin-free paper and paper with high lignin content (referred to as k107 kraft paper) are used as the solid to study their influence on the streamer inception and propagation. The streamers are initiated at the interface by applying steps of voltage to a point-plane electrode arrangement with a solid (dielectric barrier) into the gap. The solid is placed diagonal to the oil gap and near to the point electrode. Shadowgraphs, charge and light intensity recordings are obtained during the inception and propagation of the streamers. Thus, estimations of the streamer length, velocity, current and average charge, are also presented. A time delay has been observed before the initiation of the streamer. This delay is probably correlated to the initiation process and formation of the gaseous phase of the streamer near to the interface. The threshold propagation voltage of the 2nd mode streamers at mineral-oil/solid interfaces is shown to be independent of the interface. However, the inception voltage is highly influenced by the interface. Additionally, the observed characteristics of streamers propagation (e.g. current, length, velocity, etc) along the tested interfaces cannot be fully explained by a capacitive coupling effect (permittivity mismatch). This open a discussion for the possibility that properties of the solid such as chemical composition, wettability and surface roughness can influence the streamer propagation.
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