Steel 1Cr18Ni9Ti Research Articles

Properties of cold-deformed powder materials 12Cr18Ni10Ti AND AlSi10Mg obtained by selective laser melting

The article considers a combined technology which mixes selective laser melting (SLM) and longitudinal rolling of powder materials 12Cr18Ni10Ti and AlSi10Mg. The objective of the work is to experimentally establish the regularities of pressure treatment on the mechanical characteristics of the obtained SLM materials, namely on hardness and bending strength. A literature review was prepared, based on the information from which a batch of test samples were made from powders of stainless steel 12Cr18Ni10Ti and aluminum alloy AlSi10Mg. Pressure treatment of the resulting samples was performed using longitudinal rolling technology. The assessment of the high-altitude deformation of the 12Cr18Ni10Ti alloy samples was carried out using true (logarithmic) high-altitude deformation. The morphology of the raw materials was studied using an electron microscope. The mechanical properties of the materials were assessed by HRB hardness and bending strength. The results of radial compression tests on annular samples manufactured under similar technological parameters were analyzed additionally. Based on the results of the analysis, the dependence between stress and deformation was established, where for AlSi10Mg there is a smooth shape change under load, and for 12Cr18Ni10Ti there is a critical stress, at which an increase in deformation dynamics is observed. Scanning electron microscopy of the fractures of the AlSi10Mg material showed a more homogeneous structure of the rolled sample compared to the sample in the initial state, which is evidence of the positive effect of pressure treatment (within certain limits) on the density of the AlSi10Mg material obtained by the SLM method. Based on the results of the researches, a hypothesis about the interdependence of high-altitude deformation and hardness of the cold-deformed material 12Cr18Ni10Ti obtained by SLM was formulated and confirmed by the results of experiments. The bending strength limit of the AlSi10Mg powder material was established and the maximum bending loads for the 12Cr18Ni10Ti alloy was fixed. The dependences between stress and deformation of materials under radial compression and bending are shown. It has been found that longitudinal rolling of 12X18H10T powder material helps to reduce the resistance to bending force, but at the same time the hardness and elastic properties increase.

Applying the Hollomon-Jaffe parameter to predict changes in mechanical properties of irradiated austenitic chromium-nickel steels during isothermal exposure

<abstract> <p>The Hollomon-Jaffe parameter is widely used in metallurgy and materials science to characterize the behavior and predict the various metals' physical-mechanical properties under different temperature and time modes. The possibility of predicting changes in the mechanical properties of structural steels due to thermal influences has been studied. The paper presents the results of a study of the mechanical properties of the materials of the core components of the BN-350 reactor facility (RF) made of austenite chromium-nickel steel 12Cr18Ni10Ti (a spent fuel assembly's jacket) and 09Cr16Ni15M3Nb (an intro-channel displacer). The samples were studied both before and after radiation annealing. Annealing of steel samples at 550 ℃ reduced the yield strength and significantly restored the plasticity and ability of the material to strain hardening. The efficiency of post-radiation annealing of the materials increases with annealing temperature and leads to a transition to the reduction process. It was established that medium of high temperature annealing during heat treatment does not lead to significant changes in the mechanical properties of irradiated materials. The microstructure studied using a scanning electron microscope reasonably correlates with the results of mechanical tests. The possibility of using the Hollomon-Jaffe parameter to predict the properties of austenite chromium-nickel steel, which received damaging doses in the range from 12 to 59 dpa, was shown for the first time. Thus, for the first time, the unique coefficient (<italic>C</italic>) of the Holloman-Jaffe parameter for irradiated materials of chromium-nickel steel was experimentally determined, and dependencies characterizing the change in hardness of chromium-nickel steel on temperature and duration of post-radiation thermal exposure were established.</p> </abstract>

INFLUENCE OF PARAMETERS OF OPERATING CONDITIONS OF SELECTIVE LASER MELTING ON SPALL FRACTURE KINETICS OF 12Cr18Ni10Ti STEEL

The results are presented with regard to experimental studies of dynamic strength characteristics of samples made of 12Cr18Ni10Ti steel powder. They were obtained through selective laser melting with various parameters of a technological process at shock-wave compression up to pressures of ~7 GPa. Critical parameters of a process, in addition to powder characteristics, include laser operating conditions: a laser spot diameter, laser power, a laser beam scanning velocity, as well as a powder layer thickness, protective atmosphere, etc. It has been demonstrated that an increase in the scan laser power and a decrease in a powder layer thickness bring about a decrease in a number of internal defects in initial structures of samples. The results are given, which compare strength characteristics of these steels with properties of steel produced by a traditional technique of hot rolling. Shock-wave experiments were carried out using a light gas gun-type facility, which makes it possible to accelerate flat impactors to speeds of ~700 m/s; internal wave processes in samples were reproduced when recording a rate of movement of the sample's free surface via a PDV laser interferometer; a degree of spall fracture was determined by the help of a metallographic analysis of samples recovered in tests. It has been showed that steel samples made through a selective laser melting technique have high spall strength and a lower degree of damage compared to hot-rolled steel under the same conditions of high-speed shock loading. According to the results of the metallographic studies, the presence of internal defects in initial structures of samples associated with a choice of operating conditions of a manufacturing process does not affect a degree of their spall damage. At the same time, a wave pattern of shock wave propagation differs significantly for samples with and without defects.

Corrosion Resistance of Fe-Cr-Al Intermetallic Coatings Obtained by Aluminizing

The growing interest in intermetallic and metal–intermetallic materials and coatings is based on the number of favorable properties they possess, primarily mechanical. However, the lack of data on their corrosion resistance has largely limited their scope of application. In this study, the corrosion destruction mechanisms of coatings formed on substrates made of AISI 321 steel and Aluchrom W (fechralloy) were investigated. The coatings were created by alloying in an aluminum melt followed by diffusion annealing to form the ultimate intermetallic structure. Corrosion resistance was studied under cyclic exposure to a humid marine atmosphere simulator and potentiostatic tests in an aqueous NaCl solution. Corrosion destruction parameters were determined, and mechanisms for each type of coating were revealed. The conducted studies allowed us to determine the electrochemical parameters of the corrosion destruction process and its mechanisms. It was shown that the corrosion rates during potentiostating for coatings on substrates Cr15Al5 and 12Cr18Ni10Ti differed by almost twofold. Two different mechanisms of corrosion are proposed. The first is associated with the formation of Al2O3 and MgO oxide films, which at the initial stage protect only local areas of the coating surface on Cr15Al5. The second is determined by the diffusion of titanium atoms during annealing to the coating surface on a 12Cr18Ni10Ti steel substrate with the formation of TiC carbide at the grain boundaries.

PROTECTIVE METAL COATINGS MADE OF MOLYBDENUM ON STEEL 12Cr18Ni10Ti FOR FLUORIDE MELTS. OBTAINING, CERTIFICATION, EFFICIENCY

The successful use of molten alkali metal fluorides as an electrolyte for high-temperature devices requires the development of such reactor materials that have high corrosion resistance in melts with compositions characteristic of liquid-salt mixing reactors. This is one of the most important unresolved problems. One of the effective ways to reduce corrosion losses is to create a layer on the surface of the material that protects the metal from the corrosive effects of the environment. In this paper, molybdenum insulating coatings on steel 12Kh18Ni10Ti obtained in molten salts of various compositions and by various methods are considered as protective layers. Experiments were carried out on the electrodeposition of molybdenum coatings on structural materials based on iron (steel 12Cr18Ni10Ti). The coatings obtained by the electrochemical method are inhomogeneous and easily exfoliating. The thickness of molybdenum coatings obtained from molten salts is 8.15 and 20.34 μm on steel in FLiNaK and LiCl–KCl melt, respectively. Corrosion tests have shown the inefficiency of the molybdenum coating obtained from both chloride and fluoride melts. The corrosion rate of 12Cr18Ni10Ti steel in FLiNaK/FLiNaK + 5% CeF3 melts at 650°C and a holding time of 100 hours decreases in the following row: 12Cr18Ni10Ti + Mo (0.75/0.77 mm/year) 12Cr18Ni10Ti (0.45/0.50 mm/year).

INVESTIGATION OF RESISTANCE TO PITTING CORROSION OF STRUCTURAL MATERIALS OF THE BN-350 REACTOR

The article is devoted to the study of the resistance of structural materials of the BN-350 reactor to pitting corrosion in an aqueous medium containing chlorine ions in the presence of organic corrosion inhibitors. The results of accelerated testing of samples of austenitic steels 12Cr18Ni10Ti, 08Cr16Ni11Mo3Ti and Cr13Mo2NbVB (EP-450) ferrite-martensitic steel for pitting corrosion in a 10% aqueous solution of iron three-chloride hexahydrate without an inhibitor and in the presence of various concentrations of corrosion inhibitor are presented. The effect of heat treatment on the pitting resistance of structural steels is studied and the role of carbide precipitates of MC and M23C6 types in pitting defects formation is discussed.

CORROSION BEHAVIOR OF 12Cr18Ni10Ti STEEL IN LiCl–KCl MELT CONTAINING ADDITIVES OF <i>f</i>-ELEMENT CHLORIDES

When reprocessing spent nuclear fuel, it is supposed to use LiCl–KCl melt (0.49:0.51) in an inert atmosphere, all metal materials in this salt melt are extremely susceptible to corrosion, besides, during the processing of spent fuel, both the liquid (melt) and the gas phase are saturated with decay products that can act as additional oxidizing agents, increasing the aggressiveness of the environment. The pyrochemical technology of SNF includes operations such as soft chlorination, electrofining and metallization, implying the presence in the melt of compounds of chlorides of rare earth metals lanthanum, cerium and neodymium, as well as uranium(III, IV) chlorides. In this work, the corrosion behavior of 12CR18NI10TI steel in LiCl–KCl melt containing NdCl3, CeCl3, LaCl3, UCl3 and UCl4 additives up to 2 wt % was investigated. Corrosion tests lasting 100 hours were performed at a temperature of 500°C in an inert argon atmosphere. It was found that the presence of REM chlorides significantly reduces the degradation of the steel under study. The addition of (REM)Cl3 leads to the formation of a compound (REM) on the surface of the samples OCl, the thickness and continuity of which increases in the following row: LaCl3 NdCl3 CeCl3. The formation of such a compound leads to the inhibition of the corrosion process of steel 12CR18NI10TI due to salt passivation of the surface. The addition of UF4 to the melt causes significant corrosion of 12CR18NI10TI intercrystalline steel. The introduction of UF3 into the melt leads to a decrease in the corrosion rate, which is associated with the predominant interaction of trivalent uranium chloride with dissolved molecular oxygen contained in the melt, and the formation of a non-stoichiometric compound with the crystal chemical formula U3O7 on the surface of samples according to microrentgenospectral analysis.

КОРРОЗИЯ КОНСТРУКЦИОННЫХ МАТЕРИАЛОВ В РАСПЛАВЛЕННЫХ ФТОРИДАХ ЩЕЛОЧНЫХ МЕТАЛЛОВ

Corrosion processes of candidate materials for MSR were investigated: nickel-chromium-molybdenum alloys of the "Hastelloy" type: C-2000, CrNi65 and steel 12Cr18Ni10Ti, nickel-chromium (Ni80Cr20), nickel-titanium (NITINOL), nickel-copper (Monel 404) in a melt based on LiF–NaF–KF with compositions characteristic of MSR at a temperature of 550 °C. The weight and depth indicators of corrosion of materials are determined.

Влияние фрикционной обработки и жидкостной цементации на сопротивление общей коррозии хромоникелевых аустенитных сталей

Currently, to increase the hardness, strength and wear resistance of thermally non-hardenable austenitic chromium-nickel steels, such methods as frictional treatment with a sliding indenter and liquid carburizing have been used. However, along with an effective increase in mechanical characteristics, the application of these types of treatment may be accompanied by a decrease in the corrosion resistance of austenitic steels. Therefore, it is reasonable to study the influence of frictional treatment and liquid carburizing on the general corrosion resistance of Cr–Ni austenitic steels. In this work, the surface microhardness of the 12Cr18Ni10Ti and AISI 321 steels was determined using the recovered indentation method after electropolishing, mechanical grinding, frictional treatment, and liquid carburizing at a temperature of 780 °C. Using scanning electron microscopy and optical profilometry, the authors studied steel surfaces subjected to the specified types of treatment and determined their roughness. The corrosion resistance of steel was studied by testing for general corrosion using the gravimetric method. When testing for general corrosion, it was found that hardening (up to 710 HV 0.025) frictional treatment leads to an increase in the corrosion rate of the 12Cr18Ni10Ti austenitic steel compared to the electropolished state (from km=0.35 g/(m2·h) to km=0.53–0.54 g/(m2·h)). The corrosion rate of the ground steel is km=0.58 g/(m2∙h), while mechanical grinding does not provide a significant increase in the microhardness of the steel under study (from 220 to 240 HV 0.025). It is shown that the corrosion behavior of 12Cr18Ni10Ti steel subjected to various types of treatment is determined by the following factors: the presence/absence of strain-induced α'-martensite in the structure, the quality of the formed surface and, apparently, the dispersion of the formed structure. Liquid carburizing of the AISI 321 austenitic steel leads simultaneously to an increase in its microhardness to 890 HV 0.025 and a certain increase in corrosion resistance compared to fine mechanical grinding. This is related to the fact that carbon embedding atoms stabilize the electronic structure of iron (austenite and martensite), thereby increasing its corrosion resistance.

Laser alloying with Mn + Cr3C2 and Mn + NiCr-C for improved wear and corrosion resistance of stainless steel

In-situ formed high Mn steel reinforced by carbides was fabricated by laser surface alloying with Mn + Cr3C2 and Mn + NiCr-C powders to improve the wear and corrosion behavior of 1Cr18Ni9Ti steel. Microstructure, phases, element distribution, microhardness, wear and corrosion behavior of the laser alloyed layers were investigated. Results indicated that high Mn steel matrix composites with austenite dendrites, eutectics and pine-needle shaped colonies were formed by laser surface alloying. Furthermore, there are lots of large block primary Cr7C3 in the layer alloyed with Mn + Cr3C2. An improvement in average microhardness in the matrix of both alloyed layers was achieved. The layer alloyed with Mn + NiCr-C showed the best wear and corrosion resistance, which is closely related to microstructure uniformity, Cr distribution, formed phases, type and content of carbides, microhardness and toughness of the alloyed layers.

High-Temperature Passivation of the Surface of Candidate Materials for MSR by Adding Oxygen Ions to FLiNaK Salt.

The problem of tailoring the structural materials for MSR is solved by continuously overcoming the shortcomings of widely used materials and finding new ones. The materials commonly used in engineering may not be applicable for MSR due to their high corrosivity. Experiments were carried out to determine the corrosion rate of stainless steel 12Cr18Ni10Ti with different concentrations of oxide ions (by adding lithium oxide to the melt in the concentration range from 0 to 0.8 wt.%) in a FLiNaK melt. The formation of a protective oxygen-containing layer with a thickness of 1 micron has been realized. The corrosion rate decreases by an order of magnitude at the concentration of oxygen anions in the melt, in the range from 0.2 to 0.4% by weight, which may indicate high-temperature passivation of the material due to modification of the composition of the fluoride melt and reduction in its corrosion activity. In addition, the corrosion type of stainless steel in fluoride melts changes from the intercrystalline and pitting that is usually harmful to reactor material structure to total corrosion when lithium oxide is added. This is due to the “healing” of individual corrosion defects formed on the surface of the studied material by oxygen-containing compounds.

Влияние степени деформации в условиях низких температур на превращения и свойства метастабильных аустенитных сталей

Introduction. For reliable operation of low-temperature equipment, it is necessary to use materials capable of ensuring operability in a wide temperature range under conditions of alternating loads, exposure to corrosive media, etc. Most often, in such cases, metastable austenitic steels (MAS) of various alloying systems are used. Despite sufficient experience in the use of such materials, not enough information is collected on the behavior of such materials at low temperatures, including phase-structural transformations, the features of such transformations in different temperature zones, including when a load is applied, both static and dynamic. The subject of the study in this work is selected MAS 10Cr14NMn20 and 10Cr14Mn14Ni4Ti grades. The purpose of the study is to evaluate the performance of industrially used metastable austenitic steels for its possible use instead of steel 12Cr18Ni10Ti. Research methodology. The phase composition of the samples was studied on a DRON-3.0 X-ray diffractometer. Mechanical tests were carried out in the temperature range from +20 to -196 °C. Static uniaxial tensile tests were carried out on a R-20 tensile testing machine; cylindrical specimens with threaded heads were prepared according to GOST 11150–75, as well as samples with a circumferential notches. Dynamic bending tests were carried out on a pendulum impact tester, using samples according to GOST 9454–78. Results and Discussion. Based on the data obtained, it is found that an increase in the strain rate at low temperatures contributes to a decrease in the number of martensitic phases in the steels under study. It is found that the hardenability during elastic-plastic deformation decreases and completely disappears at the temperature of the material transition to a brittle state. It is shown that an increase in the rate of low-temperature deformation of samples prevents the development of phase martensitic transformations in steels. The results obtained can be recommended for use in the selection of materials for the manufacture of equipment operating at temperatures down to -196 °C. Conclusions. It is shown that the obtained values of the characteristics of mechanical properties make it possible to recommend the studied MAS as a substitute for steel 12Cr18Ni10Ti, down to a temperature of -196 °C.

Impact of nano-oxides and injected gas on swelling and hardening of 18Cr10NiTi stainless steel during ion irradiation

The radiation performance of 18Cr10NiTi-ODS steel with the addition of Y2O3-ZrO2 nano-oxides was compared with that of non-ODS 18Cr10NiTi austenitic steel in terms of radiation-induced hardening and cavity swelling. TEM observations were performed to evaluate the effect of grain refinement and nano-sized oxide precipitates on microstructural changes and radiation tolerance in specimens exposed to 1.8 MeV Cr3+ or 1.4 MeV Ar+ irradiations over a wide range of temperatures. Formation of homogenously distributed voids was observed in both alloys upon Cr3+ irradiation but the ODS steel exhibited a considerably broader temperature range of void formation and lower overall swelling. Cavity formation in steels irradiated with Ar+ showed a strong dependence on Ar/dpa ratio. Argon addition was found to enhance the nucleation of cavities, which act as point defects sinks that reduce void swelling. The largest swelling resistance was observed in the ODS steel due to the combined effect of mechanical alloying and Ar gas co-injection. The hardening behavior was investigated in both non-irradiated and Ar+ irradiated samples at room temperature and elevated temperatures by means of nano-indentation. Along with the strengthening effect of radiation-induced dislocations, gas-filled nano-cavities strongly contribute to the hardening of irradiated alloys with a tendency to increase the barrier strength of nano-cavities with decreasing cavity size. The ODS variant was found to be somewhat less susceptible to radiation hardening compared to non-ODS 18Cr10NiTi steel.

Effect of Heat Treatment on Structure of Austenitic Steels Fabricated by Laser Synthesis

In this work, the evolution of the microstructure, phase composition and crystal structure of 3D products before and after heat treatment, obtained from the original steel 12Cr18Ni10Ti by various metallurgical methods of melting, was studied. The obtained 3D steel samples were subjected to heat treatment, then structural changes were investigated by metallography, X-ray phase (XRD) and X-ray structure (XRD) analyzes. The analysis showed that heat treatment did not increase the grain size of austenite in additive steels, but could lead to an increase in the proportion of ferrite.

Investigation of the microstructure of the base and weld metal of steel Fe–0.08C–18Cr–10Ni–Ti after low-temperature irradiation in the BOR-60 reactor in the range of damage doses from 40 to 101 displacements per atom

The microstructures of irradiated samples of Fe–0.08C–18Cr–10Ni–Ti steel were studied by transmission electron microscopy (TEM). Specimens of the base metal (BM) and the weld metal (WM) were irradiated in the BOR-60 reactor at temperatures from 330 to 350°C to doses of 43 dpa (BM) and 40 dpa (WM), 96 dpa (BM) and 101 dpa (WM). New data on the quantitative microstructural characteristics of dislocation loops, titanium carbonitrides, fine G-phase, and voids in irradiated specimens in the range of damage doses from 40 to 101 dpa were obtained during the studies of specimens of the base metal and the weld metal.

Corrosion Behavior of Candidate Functional Materials for Molten Salts Reactors in LiF–NaF–KF Containing Actinide Fluoride Imitators

Molten fluorides of alkali metals are considered a technological medium for molten salt reactors (MSRs). However, these media are known to be extremely corrosive. The successful implementation of high-temperature technological devices using molten alkali metal fluorides requires the selection of such structural materials that have high corrosion resistance in melts with compositional characteristic of MSRs. In this research, the corrosion behavior of 12Cr18Ni10Ti steel, the alloy Ni60Cr20Mo15, and the alloy Monel 404 (Ni50Cu50) was investigated in the LiF–NaF–KF eutectic melt, containing additions of CeF3 and NdF3 from 0 to 5 wt.% as imitator fluorides of actinides in an inert argon atmosphere at 550 °C for 100 h. Gravimetry, energy-dispersive X-ray (EDX) microanalysis of surfaces and cross-section of samples, and ICP-MS were used to establish the corrosion behavior of the investigated alloys. Corrosion resistance of the studied materials was found to decrease in a row from Monel 404 > Hastelloy C2000 > 12Cr18Ni10Ti. The addition of cerium fluoride into the melt resulted in the additional etching of the alloy surface. The addition of neodymium fluoride resulted in the formation of the point/inter-crystalline corrosion damages in the sample bulk. The samples of steel 12Cr18Ni10Ti were subjected to local cracking corrosion. The austenitic nickel-based alloys suffered specific local corrosion with formation of subsurface voids. Excellent corrosion resistance of the Monel alloy under the test conditions was found.

HELIUM RELEASE FROM 12Cr18Ni10Ti STAINLESS STEEL AFTER IMPACT OF STEADY STATE GLOW DISCHARGE He PLASMA

The thermal desorption experiments were carried out to study the process of helium outgassing from the stainless steel 12Cr18Ni10Ti after exposure to a steady state glow discharge (GD) plasma in He atmosphere. The currentvoltage characteristics in different plasma regimes have been measured and estimation of He ions energy has been made. Measurements of He release from the stainless steel probes showed the saturation of probe surface with He after the fluencies of ~ 4 ∙ 1019 ion/cm2. The value of He outgassing strongly depends on the regime of GD plasma: pressure of work gas, discharge voltage, etc. Several maximums, including the maximum at the temperature of 100…150 °C, were registered in the He desorption curves that indicated different He atom states on the surface and in the nearest surface bulk. Physical mechanisms of such He outgassing are discussed.

Study of the low cycle fatigue of 12Cr18Ni10Ti steel based on fractal analysis and artificial intelligence approaches

The evolution of the structure and assessment of the age limit of steel 12Cr18Ni10Ti upon fatigue loading is considered using neural network modeling and approaches of fractal analysis of the microstructure. An algorithm for processing images of the microstructures has been developed to improve their quality. An indicator of the fractal dimension of the image is used as a quantitative indicator for assessing the evolution of the microstructure of the surface metal layer. A quantitative assessment of the structures at different stress amplitudes is carried out in a wide range of low temperatures using the fractal dimension index. Correlation of the fractal dimension index with the run of the sample material is shown. The appearance of the main crack was observed in the range of 0.7 - 0.8 from the number of cycles to failure, after which the crack growth rate increased. At a lower temperature, the main crack is formed later, but further loading results in a higher crack growth rate. Formation of the secondary phases in austenitic steel at a lower temperature occurred at earlier stages than that at a temperature of t = +20°C, which led to hardening of the material. An artificial neural network (ANN) has been developed and trained for assessing structural changes in metal proceeding from the fractal dimensionality of the microstructure images at different stages of fatigue loading. The developed neural network made it possible to estimate with a sufficiently high accuracy the number of cycles before damage of the sample and the residual life of the material. Thus, the developed ANN can be used to assess the current state of the material in a wide range of low temperatures.

Study of the damage to 12Cr18Ni10Ti steel samples under low cycle fatigue using methods of nondestructive control

The possibility of determining the degree of damage to flat samples in the area of low-cycle fatigue at the stage of accumulation of scattered damage before the appearance of a macroscopic crack is demonstrated. Flat samples were tested for cantilever bending at room temperature with a constant loading amplitude until a fatigue crack appeared. Austenitic steel 12Cr18Ni10Ti was used as a test material. The velocity (propagation time) of elastic waves in the material and the coercive force were measured upon testing at intervals of 500 cycles. The zone of damage development was analyzed and value of hardening (based on microhardness measurements) was determined within 15 mm of the developed crack. The analysis of the images of the alloy microstructures in the zone of the most likely crack propagation was performed following different number of cycles at the same point on the sample surface. The structural changes (γ – α transition (formation of martensite deformation)) that occur during cyclic loading, as well as nucleation and development of damage, followed by the formation of fatigue cracks, inevitably lead to changes in the elastic and magnetic properties of the material. At the initial stages of loading, we observed changes in the initial (both acoustic and magnetic) characteristics of the material, which later became stable or changed slightly. When operating time exceeded 80 % of the number of cycles before failure, a significant change in the measured parameters occurred. The obtained dependences of the acoustic and magnetic characteristics of the material provide reliable information about the current damage and can be used in estimating the residual life of the structures made of 12Cr18Ni10Ti steel.

Transformation of Chemical and Phase Composition in Al/FeAl<sub>3</sub>(Cr,Ni)/Fe<sub>2</sub>Al<sub>5</sub>(Cr,Ni) Laminated Coating at High Temperature Heating

The effect of thermal action at 1100 °C on the kinetics of phase transformations in the coating, obtained by hot-dip aluminizing of 12Cr18Ni10Ti steel, is studied. It was shown that, after 500 h of exposure, the chemical composition is leveled over the entire volume of the sample. Moreover, the predicted retention time of the heat-resistant properties of the coating at 1100 °C is about 2000 h.