Split Application Research Articles

Immobilization of Prussian Blue Nanoparticles Onto Au‐Modified ZnIn2S4 Photoanode for Efficient Photoelectrochemical Water Splitting

AbstractZnIn2S4 has been regarded as a promising photoanode material for photoelectrochemical (PEC) water splitting. However, its severe charge recombination and low carrier transport efficiency limit practical applications in PEC water splitting. A novel ZnIn2S4/Au/PB photoanode was prepared by using the in‐situ photodeposition of Au nanoparticles and electrodeposition of Prussian blue (PB) nanoparticles onto ZnIn2S4 nanosheets. The photocurrent density of the prepared ternary photoanode reached 0.42 mA/cm2 at 1.23 VRHE, which is 6 times higher than pure ZnIn2S4. The introduction of Au nanoparticles remarkably improved the efficiency of carrier transport and separation. Additionally, the application of PB onto ZnIn2S4 resulted in an extended spectrum of light absorption. The incident photon‐to‐current efficiency (IPCE) value recorded was 24.6 % at 350 nm. This improvement can be attributed to the formation of a Z‐type heterojunction.

Alternating wet and dry irrigation cycles enhance the nitrogen “cache” function of duckweed in a rice-duckweed system

In continuously-flooded paddies, the small, fast-growing aquatic plant duckweed (Lemna minor L.) considered to compete with rice for nitrogen, thereby having a negative impact on early rice growth. While duckweed overpopulation was known can be effectively overcome through field water management, the influence of such management on the N fate and its use efficiency in rice-duckweed systems is poorly documented. Accordingly, a three-year (2020–2022) field experiment was conducted to examine the combined impact on rice yield, as well as N loss and utilization, of two water management approaches (flood irrigation, FI vs. alternate wetting and drying irrigation, AWD), factorially combined with two rice production systems (rice-duckweed, +D, vs. duckweed-free rice, -D). In AWD+D fields, the density of duckweed generally remained below 250 g m−2 (about 85 % coverage), whereas in FI+D fields it reached 100 % coverage (300 g m−2) within 5 days after transplanting, with individual duckweeds overlapping one another. Following AWD irrigation, duckweed performed as a nitrogen “cache,” akin to a split fertilizer application, with the first of several splits occurring at the rice crop's early tillering stage. Within the first 2 days of a specific wet-dry cycle, duckweed can store 0.5–1.5 g N m−2, and then, within a further 3 days, release 0.3–1.0 g N m−2. In contrast, in FI+D paddies, this caching function occurred once under mid-season drainage, with further N being stored in the duckweeds during the remaining rice production season. As a result, at harvest the 0–0.10 m soil layer's N level increased significantly (p<0.05) in both FI+D (8.5–16.8 %) and AWD+D (14.9–20.8 %) compared to FI-D and AWD-D, respectively. Due to the coverage and storage-release function of duckweed, apparent N loss decreased in rice-duckweed system by 1.4–12.5 % in the FI field and 22.1–31.3 % in the AWD field compared to their respective duckweed-free systems. In FI fields, except for a 10 % relative reduction in nitrogen recovery efficiency (NRE) in 2020, duckweed didn't significantly affect rice yield or NRE. The yield reduction (3.5–6.7 %) and the NRE increase (0.8–7.4 %) under AWD-D (vs. FI-D) was, in the presence of duckweed, compensated for and overrun, resulting in a greater yield (5.3–6.7 %) and NRE (5.4–28.9 %) in the AWD+D vs. AWD-D field. When duckweed was present, AWD irrigation improved the by-path nitrogen cycling through duckweed, making the AWD+D system more beneficial for rice cultivation and the agroecosystem's environment health. The AWD+D system offers a promising measure for building an efficient and sustainable rice-duckweed agroecosystem.

Implementing a soil ammonium N fertilizer management for synchronizing potato N demands

Potatoes, as a high-nitrogen (N)-demand crop, are strongly influenced by both the quantity and form of N supply. Previous studies have demonstrated that applying nitrate N prior to tuber formation and ammonium N post-tuber formation can substantially enhance potato yields and improve N fertilizer use efficiency. However, the ammonium N introduced into the soil undergoes nitrification, creating challenges in aligning the N supply form with the needs of potatoes. This study explored novel N regulation strategies aimed at augmenting potato yields and improving N fertilizer use efficiency. Two field experiments were conducted from 2020 to 2022. Experiment 1 involved four N gradients, namely no N, 150 kg N ha−1, 300 kg N ha−1, and 450 kg N ha−1. Soil samples were collected regularly to determine the transformation patterns of soil ammonium N during potato growth. Experiment 2 included three N management practices: farmer practice (Con), "nitrate followed by ammonium" with nitrification inhibitor (N–NI), and optimization (the soil ammonium N transformation-based split application of N fertilizer, Opt). The potato yield and N fertilizer use efficiency were compared to assess the performance of the optimized strategy. The results showed that 90 % of the ammonium N transformed 20 days after the basal dressing of N. When N fertilizer was applied as top dressing during the tuber formation and bulking stages, more than 90 % of ammonium N was transformed after 10 days. The optimized strategy resulted in a 20 % increase in potato yield, a 20 % increase in N fertilizer partial factor productivity, and a 12–20 % reduction in residual inorganic N in the 0–60 cm soil layer. This suggests that ammonium N applied as base fertilizer exhibits a relatively slow transformation rate, while applying ammonium N as top dressing during the tuber formation and bulking stages accelerates the transformation rate. The split application of ammonium N based on soil ammonium N transformation patterns can improve the alignment between the N supply form with the specific demands of potatoes.

Оптимизиране на калиевото торене при ранно и средноранно производство на домати за устойчиви добиви и икономическа рентабилност

Split potassium fertilization is emerging as an effective technique for the prolonged assimilation of significant amounts of accessible potassium during the vegetation, with the aim of establishing a positive potassium balance in the soil and achieving increased yields of quality produce. The aim of this study was to determine the economic efficiency of the partitioning and split application of potassium doses in the cultivation of tomatoes, both in the early and mid-early production. The results showed that tomato plants demonstrate improved potassium utilization through split application, resulting in increased yields and total production revenues. Split fertilization alternatives proved to be economically viable, with N24Р12К8+8+8 approach being particularly beneficial in early tomato production. This study underlines the importance of optimizing fertilization practices in agriculture, highlighting the potential to increase economic efficiency and profitability for farmers and to ensure the sustainable use of soil resources.

Solution-processed Sb2O3: A promising electrode material for high-performance supercapacitors and electrocatalysts

Easy accessibility, wide range of redox states, affordable cost, and simple synthesis methods of metal oxides have gained a significant interest in the domains of electrochemical supercapacitors and electrocatalysts. The successive ionic layer adsorption and reaction (SILAR) chemical synthesis approach has been introduced to preparing nanocrystalline antimony oxide (Sb2O3) for both energy storage and water splitting applications. The Sb2O3 electrode demonstrates a remarkable specific capacitance of 3011 F/g at a current density of 2 A/g in a 1 M solution of potassium hydroxide (KOH). The current design of the Sb2O3//Bi2O3 (bismuth oxide) asymmetric electrochemical supercapacitor device has endowed a specific capacitance of 391 F/g, a maximum energy density of 78.2 Wh/Kg at a power density of 1000 W/Kg, and an outstanding capacitance retention of 77 % even after 5000 redox cycles. The Sb2O3 electrode demonstrates outstanding performance in the oxygen evolution process at a current density of 10 mA cm2, with an overpotential of 206 mV. The Sb2O3 as an electrocatalyst also exhibits exceptional results in the hydrogen evolution reaction with an overpotential of 124 mV/dec. Both of these electrochemical processes are distinguished by the evolution of oxygen which is capable of facilitating the process of water splitting to obtain clean energy for day by day growing population.

Long‐term 4R nitrogen management in dryland wheat–fallow systems

AbstractSeveral short‐term studies have investigated 4R (right source, rate, time, and place) N management for dryland wheat (Triticum aestivum L.) production and profitability, but few long‐term studies exist in the United States or abroad. This study evaluated long‐term impacts of several aspects of 4R N management on dryland hard red wheat yield, protein, and return to N. Experiments were conducted at Nephi and Blue Creek, UT, during 1995–2007. Fourteen N treatments evaluated performance of starter fertilizer, fall applications of anhydrous ammonia (AA) with and without nitrapyrin (AA‐Nitrapyrin and AA, respectively), and several split applications in the fall and spring. Across years, winter wheat required N to increase yield, protein, and returns at both sites. Applying 56 kg N ha−1 as AA in the fall usually produced the best return to N compared to other N treatments. Starter N (6 kg N ha−1) at fall planting rarely increased yield, protein, or returns at either site. Across both sites, nitrapyrin increased mean annual yield by 0.6 Mg ha−1 and mean return to N by $150 ha−1. Spring application of N was rarely required and only increased yield in 13% of the years. Results indicate that nitrapryin is often needed with fall AA applications to optimize yield and returns and that starter N or extra N in the spring are rarely economical in dryland wheat in Utah and possibly the greater Intermountain West. Further, N rate had the most influence among 4Rs on wheat production and should be the focus of future efforts to improve 4R stewardship.

Teff grass increases summer forage availability in the Rolling Plains of Texas

AbstractTeff [Eragrostis tef (Zucc.) Trotter] grass has gained popularity in the United States as an emergency summer forage for livestock due to its drought tolerance and rapid growth habit. An alternative forage would benefit Texas Rolling Plains growers due to the summer forage shortage caused by drought conditions. However, among the teff research conducted in the United States, there is great variability in the forage yields and nutritive values depending on the amount of nitrogen and available water. The objective of the study was to evaluate forage productivity and nutritive value of teff in the Texas Rolling Plains under irrigated and dryland conditions with two nitrogen rates and application timings. Nitrogen fertilizer treatments included single applications of either 50 or 100 lb a−1 applied at planting and a split application of either 50 or 100 lb a−1 applied both at planting and after the first harvest. No differences were observed among nitrogen rates and application methods in the irrigated trial (5286 lb a−1). The split application of 100 lb a−1 produced the greatest total yield in the dryland trial (3096 lb a−1) with no yield advantage of 100 lb N a−1 over 50 lb N a−1 at the first cutting. Forage nutritive values were similar to the warm‐season forage species utilized in the region. This study showed that teff can be an alternative forage species in the region. Future research will include planting dates, nitrogen application timing, cutting height, and the interaction of these factors on yield and nutritive values of teff.

Growth and yield variability of wheat as effected by split application of potassium and nitrogen

Growth and yield variability of wheat as effected by split application of potassium and nitrogen

The Quality of Winter Wheat Grain by Different Sowing Strategies and Nitrogen Fertilizer Rates: A Case Study in Northeastern Poland

The present study was undertaken to determine the effect of different sowing strategies and spring nitrogen (N) fertilizer rates on the technological quality of winter wheat (Triticum aestivum L.) grain in terms of its milling quality, protein complex quality, and enzyme activity (falling number). Winter wheat grain for laboratory analyses was produced in a small-area field experiment conducted between 2018 and 2021 in the AES in Bałcyny (53°35′46.4″ N, 19°51′19.5″ E, NE Poland). The experimental variables were (i) sowing date (early: 6 September 2018, 5 September 2019, and 3 September 2020; delayed by 14 days: 17–20 September; and delayed by 28 days: 1–4 October), (ii) sowing density (200, 300, and 400 live grains m−2), and (iii) split application of N fertilizer in spring (40 + 100, 70 + 70, and 100 + 40 kg ha−1) at BBCH stages 22–25 and 30–31, respectively. A sowing delay of 14 and 28 days increased the bulk density (by 1 and 1.5 percent points (%p), respectively), vitreousness (by 3 and 6%p, respectively), and total protein content of grain (by 1% an 2%, respectively). A sowing delay of 14 days increased grain hardness (by 5%), the flour extraction rate (by 1.4%p), and the falling number (by 3%) while also decreasing grain uniformity (by 1.9%p). In turn, a sowing delay of 28 days increased the wet gluten content of grain (+0.5–0.6%p) and improved the quality of the protein complex in the Zeleny sedimentation test (+1.5%). An increase in sowing density from 200 to 300 live grains m−2 led to a decrease in grain uniformity (by 2.6%p), the total protein content (by 1.5%), and the wet gluten content of grain (by 0.7%p). A further increase in sowing density decreased grain vitreousness (by 1.4%p). The grain of winter wheat fertilized with 40 and 100 kg N ha−1 in BBCH stages 22–25 and 30–31, respectively, was characterized by the highest hardness (64.7), vitreousness (93%), flour extraction rate (73.9%), total protein content (134 g kg−1 DM), wet gluten content (36%), and Zeleny sedimentation index (69 mL).

Response of chickpea's yield and yield components to double inoculation with mycorrhiza and rhizobium under split application of nitrogen

AbstractThe utilization of advantageous microorganisms as a biofertilizer has gained significant importance in the agricultural industry due to their potential contribution to food safety and the sustainable cultivation of crops. To evaluate the effect of nitrogen (N) fertilizer and co‐inoculation with arbuscular mycorrhiza and rhizobium on the yield and yield component of chickpea (Cicer arietinum L.), a 2‐year field experiment was conducted in 2020–2021 at the Agricultural Research Station of Ferdowsi University of Mashhad, Iran. The experiment was designed as a randomized block trial in factorial design with three replicates. The treatments included two levels of inoculation (noninoculated and inoculated with rhizobium and mycorrhiza) and application of different levels of N fertilizer (0, 25, or 50 kg ha−1) at three growth stages (sowing, flowering, pod filling) as follows; F0 (0,0,0), F1 (25,0,0), F2 (25,25,0), F3 (25,25,25), F4 (50,0,0), F5 (50,50,0) and F6 (50,50,50), respectively. The results showed that seed inoculation and split N fertilization significantly increased yield and yield components in chickpea (Cicer arietinum L.). Seed inoculation showed the highest values for all traits studied compared to the noninoculated treatments. Moreover, among the fertilizer treatments, the highest values for plant height (41.8 cm), number of branches (9.1), number of grains per plant (17.8) and 100‐grain weight (30.4 g) from F6 through the F3 treatment, were statistically similar. The results show that the effect of inoculation is more significant when a lower amount of N fertilizer is applied. Due to the health and environmental problems associated with chemical fertilizers, double inoculation and split application of N fertilizers at lower doses can be recommended.

Grain protein and amino acid dynamics in sorghum with in‐season split‐nitrogen application

AbstractBackground and ObjectivesField experiments were conducted to assess the influence of in‐season split application of nitrogen (N) on grain protein, protein digestibility, and amino acid dynamics in grain sorghum, in three different environments. Treatments included a zero N check and eight treatments with varying N application timings and amounts.FindingsThe five high N treatments had significantly greater grain protein content than all the lower N treatments. As the total protein increased, the kafirin portion of the protein increased, whereas the albumin‐globulin levels decreased. Nitrogen treatment had a significant effect on 13 of the 18 amino acids. High N applications significantly increased amino acids on a protein basis including alanine, glutamic acid, leucine, proline, and phenylalanine.ConclusionsTreatment N92 with N applied at 92 kg N ha−1 as split application at three different growth stages including planting, panicle initiation, and booting emerged as the optimum N treatment for increasing protein and amino acid concentration in grain sorghum.Significance and NoveltyThe ideal N application approach identified can be used to screen a wide range of sorghum hybrids under varying levels of irrigation and the same N treatments can be adopted by producers to enhance grain protein in sorghum.

Self-supported iron-doped nickel oxide multifunctional electrodes for highly efficient energy storage and overall water-splitting uses

Caused by complex synthesis processes, slow diffusion rates, and the formation of undesired nanostructures, it is tedious to produce a high-quality nickel oxide (NiO) electrodes for potential energy storage and water splitting applications. This paper introduces a novel chemical technique for producing self-supported iron-doped NiO electrodes having a high concentration of oxygen vacancies by utilizing different iron-based salts i.e. iron nitrate, iron chloride, iron ammonium sulfate, iron fumarate, and iron sulfate salts. After examining physical properties, the electrochemical energy storage and water splitting measurements were performed where iron nitrate precursor-mediated self-supporting Fe-NiO electrode confirms the optimum performance. Specifically, it exhibits a specific capacitance (SC) of 3302.5 Fg−1 at a current density of 5 Ag−1. The as-fabricated Fe-NiO-A//Bi2O3 asymmetric supercapacitor has a broad voltage range of 1.5 V, a remarkable volumetric-energy-density of 98.2 W hkg−1 at a power density of 900 Wkg−1, and a long-lasting cycling life with 92.6 % capacity retention after 5000 cycles at a current density of 15 Ag−1. A bifunctional Fe-NiO//Fe-NiO electrocatalyst demonstrates a current density of 10 mA cm−2 and remarkable long-term durability of 75 h without any degradation while operating at an ultra-low cell voltage of only 1.51 V, specifying importance of self-supported Fe-doped NiO electrodes for electrochemical energy storage and water splitting applications.

Investigating the synergistic effects of NbCo-oxide composite electrodes in supercapacitor and water splitting applications via hydrothermal synthesis

A self-supported, binderless NbCo-oxide composite electrode was synthesized directly on a nickel foam (NF) substrate through a simple one-step hydrothermal process and utilized for energy storage and conversion applications. The optimized NbCo-oxide electrode displayed impressive energy storage capabilities, boasting an areal capacitance of 10.1 F/cm2 (equivalent to 9.10C/cm2), an energy density of 0.57 mWh/cm2, and a power density of 6.75 mW/cm2 at a 15 mA/cm2 current density. Furthermore, this electrode exhibited notable bifunctional activity, with low overpotentials of 217 mV for the hydrogen evolution reaction (HER) and 250 mV for the oxygen evolution reaction (OER) at a 10 mA/cm2 current density. The distinctive morphology, featuring rectangular blocks and plate-like microstructures, provided numerous exposed electro-active sites, facilitating efficient charge transfer, and enhancing overall electrochemical performance. The sturdy self-supporting structure on the NF substrate ensures remarkable stability, highlighting NbCo-composite materials' potential for energy storage and conversion.

Temporal Synchronization of Nitrogen and Sulfur Fertilization: Impacts on Nutrient Uptake, Use Efficiency, Productivity, and Relationships with Other Micronutrients in Soybean

Nitrogen (N) and sulfur (S) are essential nutrient elements, and their deficiency affects crop growth, productivity, and nutrient uptake due to their multifaceted role in plant metabolism, which has been well documented. Therefore, agricultural management strategies that can overcome these deficiencies are the need of the hour. In this context, a study was undertaken with the objective to assess the impacts of N and S applications, either basally or through split application (12.5, 25 and 50 kg ha−1), on the nutrient uptake, productivity, use efficiency, and micronutrient content status in soybean seeds, and also the change in soil nutrient zinc (Zn) and iron (Fe) content at different critical stages of soybean crop growth. The field trial was conducted utilizing a randomized complete-block design, and comprised fourteen treatments with varying N and S quantities. N and S were applied through basal and split applications in different combinations. The salient findings indicated that the highest seed, straw yield, N, and S uptake were obtained with the application of N25+25, S25+25, and did not significantly vary with N25+25, S12.5+12.5, N50, and N25+S50. The highest N use efficiency was recorded with the application of N25+S50, and S use efficiency with the application of N25+25, S25+25. The split application of N and S as N25+25, S25+25 significantly increased soil Zn and Fe content at R2 and R5 stages of soybean crop growth, as well as seed Zn and Fe uptake. It can be concluded that the basal and split application of N and S at the rate of 25 kg ha−1 can improve soybean productivity through increased mobilization and assimilation by plants. The findings indicated that applying N and S separately, with 25 kg ha−1 each basally and at the R2 stage resulted in the highest nutrient uptake, and seed and straw yields. The nutrient use efficiencies, along with Zn and Fe uptake by seeds, exhibited noticeable improvements with this split application approach compared to the control. Furthermore, the soil Zn and Fe contents also experienced enhancements due to the split application of both Nand S fertilizers. These results underscore the potential benefits of temporally adopting optimized fertilizer application strategies to maximize agricultural productivity while ensuring efficient nutrient utilization and soil health maintenance. Further research and field trials could provide deeper insights into the long-term impacts and scalability of this approach across different crop varieties and environmental conditions.

Self‐Supported Fe‐Based Nanostructured Electrocatalysts for Water Splitting and Selective Oxidation Reactions: Past, Present, and Future

AbstractElectrochemical water splitting plays a vital role in facilitating the transition towards a sustainable energy future by enabling renewable hydrogen (H2) production, energy storage, and emission‐free transportation. Developing earth‐abundant electrocatalysts with outstanding overall water‐splitting performance, excellent catalytic activity, and robust long‐term stability is highly important in the practical application of water electrolysis. Self‐supported electrocatalysts have emerged as the most appealing candidate for practical H2 production due to their increased active site loading, rapid mass and charge transfer, and strong interaction with the underneath conducting support. Additionally, these electrocatalysts also provide enhanced reaction kinetics and stability. Here, a comprehensive review of recent progress in developing self‐supported Fe‐based electrocatalysts for water splitting and selective oxidation reactions is presented with examples of oxyhydroxides, layered double hydroxides, oxides, chalcogenides, phosphides, nitrides, and other Fe‐containing electrocatalysts. A comprehensive historical development in the synthesis of self‐supported Fe‐based electrocatalysts is provided, with an emphasis on the various deposition methods and the choice of self‐supported conducting substrates considering large‐scale commercial applications. An overview of mechanistic understanding and approaches for enhanced H2 production are also presented. Finally, the challenges and opportunities associated with developing Fe‐based electrocatalysts for practical applications in water splitting and alternative oxidation reactions are discussed.

An Agronomic Efficiency Analysis of Winter Wheat at Different Sowing Strategies and Nitrogen Fertilizer Rates: A Case Study in Northeastern Poland

This study was undertaken to examine the influence of the sowing date, sowing density, and split spring application of nitrogen (N) fertilizer on plant density, tillering, yield components, and grain yields of winter wheat (Triticum aestivum L.) grown in northeastern Poland between 2018 and 2021. The experiment had a split-plot design with three sowing dates (early (3–6 September), delayed by 14 days, and delayed by 28 days), three sowing densities (200, 300, and 400 live grains m−2), and three split spring N rates (40 + 100, 70 + 70, and 100 + 40 kg ha−1 applied in BBCH stages 22–25 and 30–31, respectively). The number of spikes m−2 increased by 11% on average when winter wheat was sown with a delay of 14 days (17–20 September) and 28 days (1–4 October). The number of spikes m−2 was highest when winter wheat was sown at 300 and 400 live grains m−2. The application of 100 + 40 kg N ha−1 (BBCH 22–25 and 30–31, respectively) increased the number of spikes m−2. An increase in sowing density from 200 to 300 to 400 live grains m−2 decreased the number of grains spike−1 by 5% and 7%, respectively. Thousand grain weight (TGW) increased by 1% and 2% when sowing was delayed by 14 (17–20 September) and 28 days (1–4 October), respectively. In northeastern Poland, grain yields peaked when winter wheat was sown between 17 September and 4 October (10.52–10.58 Mg ha−1). In late-sown winter wheat, grain yields increased due to a higher number of spikes m−2 and higher grain weight. The highest sowing density (400 live grains m−2) induced a greater increase in grain yields than the lowest sowing density (200 live grains m−2) (10.25 vs.10.02 Mg ha−1). In winter wheat sown at a density of 400 live grains m−2, the increase in grain yields resulted in a higher number of spikes m−2. Grain yields peaked in response to 100 kg N ha−1 applied in BBCH stages 22–25 and 40 kg N ha−1 applied in BBCH stages 30–31 (this split N rate increased the number of spikes m−2). In turn, the highest straw yield (6.23 Mg ha−1) was obtained when the second split of N fertilizer was applied in BBCH stages 30–31 (40 + 100 kg N ha−1). Straw yields decreased significantly (by 6%) when winter wheat was sown late (early October). Delayed sowing (mid-September and early October) increased the harvest index (HI) of winter wheat by 5–7%. Split spring N application influenced grain and straw yields, but it had no effect on the HI of winter wheat.

Modified NiFe2O4-Supported Graphene Oxide for Effective Urea Electrochemical Oxidation and Water Splitting Applications.

The production of green hydrogen using water electrolysis is widely regarded as one of the most promising technologies. On the other hand, the oxygen evolution reaction (OER) is thermodynamically unfavorable and needs significant overpotential to proceed at a sufficient rate. Here, we outline important structural and chemical factors that affect how well a representative nickel ferrite-modified graphene oxide electrocatalyst performs in efficient water splitting applications. The activities of the modified pristine and graphene oxide-supported nickel ferrite were thoroughly characterized in terms of their structural, morphological, and electrochemical properties. This research shows that the NiFe2O4@GO electrode has an impact on both the urea oxidation reaction (UOR) and water splitting applications. NiFe2O4@GO was observed to have a current density of 26.6 mA cm-2 in 1.0 M urea and 1.0 M KOH at a scan rate of 20 mV s-1. The Tafel slope provided for UOR was 39 mV dec-1, whereas the GC/NiFe2O4@GO electrode reached a current of 10 mA cm-2 at potentials of +1.5 and -0.21 V (vs. RHE) for the OER and hydrogen evolution reaction (HER), respectively. Furthermore, charge transfer resistances were estimated for OER and HER as 133 and 347 Ω cm2, respectively.

Bifunctional g-GaN/Si9C15 S-scheme heterojunction for efficient photocatalytic hydrogen evolution and photodetector

S-scheme heterojunctions are commonly applied in optoelectronic devices and photocatalytic materials to achieve effective charge separation and enhance photocatalytic activity. In this study, the electronic, optical, and electrical behaviors as well as the photocatalytic water splitting performance of the g-GaN/Si9C15 S-scheme heterojunction have been researched using first-principles. The results suggest that the g-GaN/Si9C15 heterojunction is energetically, thermally, and dynamically stable. The g-GaN/Si9C15 heterojunction belongs to the S-scheme photocatalyst with the g-GaN as the oxidant and the Si9C15 as the reductant, and its band edge positions cross the standard water oxidation and reduction potentials. The g-GaN/Si9C15 heterojunction has a power conversion efficiency of 11.03 % and a large carrier mobility of 20.98 × 103 cm2 V−1 s−1. The small overpotential of 0.076 V is favorable for the occurrence of the hydrogen evolution reaction, and the oxygen evolution reaction of the g-GaN/Si9C15 heterojunction can spontaneously proceed when U = 1.23 V. The g-GaN/Si9C15 heterojunction exhibits a large solar-to-hydrogen efficiency of 25.58 %. Moreover, the g-GaN/Si9C15 heterojunction has a high photocurrent and a large extinction ratio. In conclusion, the g-GaN/Si9C15 heterojunction holds potential applications in photocatalytic water splitting and photodetector.

Evaluation of pre-plant incorporated manure and phosphorus fertilizers on alfalfa yield, nutritive value, and residual soil characteristics

Managing adequate levels of plant available P in soil is an important management practice for boosting alfalfa (Medicago sativa L.) yields and nutritive value. Although several ways of supplementing P at various stages of plant growth are in practice, pre-plant application of P through various organic and inorganic nutrient sources are largely under-investigated. Therefore, a three-year study was conducted at the New Mexico State University Rex. E. Kirksey Agricultural Science Center, Tucumcari, NM USA, to investigate the impact of manure (pre-plant applied @ 22.5 Mg ha−1vs. no manure) and inorganic P sources (00-46-00 or 11-52-00) applied to soil either in one-time bulk (336 kg P2O5 ha−1 preplant incorporated) or split applications (112 kg P2O5 ha−1 preplant incorporated with an additional 112 kg P2O5 ha−1 surface-applied annually) on the yield and nutritive value of alfalfa and residual soil characteristics. Results demonstrated that pre-plant manure application had statistically no advantage in improving the alfalfa forage yield compared to control (p > 0.05), although there was strong evidence of a consistent yield increase trend in all manure treatments. Forage nutritive value parameters such as ADF (Acid Detergent Fiber), NDF (Neutral Detergent Fiber), K, and Zn were significantly improved by manure supplementation. Manure application improved most soil quality parameters, especially the soil Nitrate-N, Olsen P, K, S, and Zn contents. Inorganic P fertilizer type or application strategy had no significant impact on alfalfa yield and nutritive value and soil characteristics. Most interactions (both two-way and three-way) among the tested treatments had no significant impact on the study parameters.

Spintronic Phenomena and Applications in Hybrid Organic–Inorganic Perovskites

AbstractThe spin degree of freedom in hybrid organic–inorganic perovskites (HOIPs) has become a rapidly growing research topic in both HOIPs and spintronics fields due to its fundamental scientific significance and tight relevance with optoelectronics. The flourishing achievements of HOIP spintronics call for a timely review to summarize the key progress and guide future developments. In this review, classical spintronic phenomena based on spin‐orbit coupling (SOC) are discussed, especially Rashba splitting and related applications such as spin‐charge conversion. Owing to the unique chirality‐spin coupling, spintronics in chiral HOIPs are particularly focused on, including chirality‐induced spin selectivity (CISS). Based on the complex band structure and carrier/exciton, spin dynamics is also widely investigated and constitutes an indispensable part of HOIP spintronics. Aside from the three main threads, other spintronic phenomena such as magneto‐optical coupling and device exploration are involved as promising opportunities. Despite the continuous breakthroughs in HOIP spintronics, more efforts are required to expand material systems, explore new physics, and optimize device configurations for enhanced performance and high integration. A deep understanding of spin behaviors in HOIPs will create a new platform beyond conventional optoelectronic and photovoltaic applications.