Generation, control, and detection of a non-equilibrium polarization of electron spin is the key challenge in the growing field of spintronics.1, 2 Optical orientation, in which circularly polarized photons transfer their angular momentum to electrons, is a versatile tool to prepare and investigate non-equilibrium spin polarization. In semiconductor quantum wells (QWs), this momentum transfer yields a spin-polarized electric current—a spin photocurrent—and the irradiated QW acts as a ‘spin battery’.3, 4 Because spin photocurrents occur in homogeneous, unbiased samples under uniform irradiation, the effect is very different from photovoltaic currents, which are caused by charge separation at potential barriers. These currents have been studied in various materials over a wide range of temperatures, including the technologically important room temperature. In contrast to higher-energy, inter-band excitations, the terahertz (THz) spectral range has the advantage that it involves only one kind of carrier, electrons or holes, yielding unipolar spin orientation. Two mechanisms by which THz excitation can generate a spin photocurrent have been investigated in detail: the circular photogalvanic effect (CPGE)4 and the optically induced spin-galvanic effect (SGE).5 A characteristic feature of a spin photocurrent, j, is that it reverses direction, j→ − j, when the radiation helicity is changed, for example from right-handed circular to left-handed circular, σ+ → σ−. The photocurrent is proportional to the helicity, Pcirc. 7 This dependence is illustrated in Figure 1 for p-GaAs QWs. The experimental arrangement is shown in the inset. In these low-symmetry, (113)-grown QWs, the spin photocurrent occurs for radiation at normal incidence, but in (001)-oriented samples a helicity-dependent signal is observed only at oblique incidence due to the higher symmetry. The spin photocurrent results from an asymmetric momentum distribution of photoexcited carriers, which in turn reflects Figure 1. Photocurrent, normalized to the incident power, P, of terahertz radiation, for p-GaAs quantum wells grown with (113) crystallographic orientation. The angleφ defines the helicity through Pcirc = sin 2φ. The radiation source was an NH3 molecular laser pumped by a TEA-CO2 laser emitting 100ns long pulses at 76μm at about P = 10kW peak power.
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