Spectra Of Exoplanets Research Articles

The atmospheres of rocky exoplanets

Context. Little is known about the interaction between atmospheres and crusts of exoplanets so far, but future space missions and ground-based instruments are expected to detect molecular features in the spectra of hot rocky exoplanets. Aims. We aim to understand the composition of the gas in an exoplanet atmosphere which is in equilibrium with a planetary crust. Methods. The molecular composition of the gas above a surface made of a mixture of solid and liquid materials was determined by assuming phase equilibrium for given pressure, temperature, and element abundances. We study total element abundances that represent different parts of the Earth’s crust (continental crust, bulk silicate Earth, mid oceanic ridge basalt), CI chondrites and abundances measured in polluted white dwarfs. Results. For temperatures between ~600 and ~3500 K, the near-crust atmospheres of all considered total element abundances are mainly composed of H2O, CO2, and SO2 and in some cases of O2 and H2. For temperatures ≲500 K, only N2-rich or CH4-rich atmospheres remain. For ≳3500 K, the atmospheric gas is mainly composed of atoms (O, Na, Mg, and Fe), metal oxides (SiO, NaO, MgO, CaO, AlO, and FeO), and some metal hydroxides (KOH and NaOH). The inclusion of phyllosilicates as potential condensed species is crucial for lower temperatures, as they can remove water from the gas phase below about 700 K and inhibit the presence of liquid water. Conclusions. Measurements of the atmospheric composition could, in principle, characterise the rock composition of exoplanet crusts. H2O, O2 and CH4 are natural products from the outgassing of different kinds of rocks that had time to equilibrate. These are discussed as biomarkers, but they do emerge naturally as a result of the thermodynamic interaction between the crust and atmosphere. Only the simultaneous detection of all three molecules might be a sufficient biosignature, as it is inconsistent with chemical equilibrium.

How surfaces shape the climate of habitable exoplanets

ABSTRACT Large ground- and space-based telescopes will be able to observe Earth-like planets in the near future. We explore how different planetary surfaces can strongly influence the climate, atmospheric composition, and remotely detectable spectra of terrestrial rocky exoplanets in the habitable zone depending on the host star’s incident irradiation spectrum for a range of Sun-like host stars from F0V to K7V. We update a well-tested 1D climate-photochemistry model to explore the changes of a planetary environment for different surfaces for different host stars. Our results show that using a wavelength-dependent surface albedo is critical for modelling potentially habitable rocky exoplanets.

Analyzing Atmospheric Temperature Profiles and Spectra of M Dwarf Rocky Planets

Abstract The James Webb Space Telescope (JWST) will make it possible to comprehensively measure the thermal emission spectra of rocky exoplanets orbiting M dwarfs and thus characterize their atmospheres. In preparation for this opportunity, we present model atmospheres for three M-dwarf planets particularly amenable to secondary eclipse spectroscopy—TRAPPIST-1b, GJ 1132b, and LHS 3844b. Using three limiting cases of candidate atmospheric compositions (pure H2O, pure CO2, and solar abundances) we calculate temperature–pressure profiles and emission spectra in radiative-convective equilibrium, including the effects of a solid surface. We find that the atmospheric radiative transfer is significantly influenced by the cool M-star irradiation; H2O and CO2 absorption bands in the near-infrared are strong enough to absorb a sizeable fraction of the incoming stellar light at low pressures, which leads to temperature inversions in the upper atmosphere. The non-gray band structure of gaseous opacities in the infrared is hereby an important factor. Opacity windows are muted at higher atmospheric temperatures, so we expect temperature inversions to be common only for sufficiently cool planets. We also find that pure CO2 atmospheres exhibit lower overall temperatures and stronger reflection spectra compared to models of the other compositions. We estimate that for GJ 1132b and LHS 3844b we should be able to distinguish between different atmospheric compositions with JWST. The emission lines from the predicted temperature inversions are currently hard to measure, but high-resolution spectroscopy with future extremely large telescopes may be able to detect them.

HyDRA-H: Simultaneous Hybrid Retrieval of Exoplanetary Emission Spectra

Abstract High-resolution Doppler spectroscopy has been used to detect several chemical species in exoplanetary atmospheres. Such detections have traditionally relied on cross correlation of observed spectra against spectral model templates, an approach that is successful for detecting chemical species but not optimized for constraining abundances. Recent work has explored ways to perform atmospheric retrievals on high-resolution spectra (HRS) and combine them with retrievals routinely performed for low-resolution spectra (LRS) by developing a mapping from the cross-correlation function to a likelihood metric. We build upon previous studies and report HyDRA-H, a hybrid retrieval code for simultaneous analysis of low- and high- resolution thermal emission spectra of exoplanets in a fully Bayesian approach. We demonstrate HyDRA-H on the hot Jupiter HD 209458b as a case study. We validate our HRS retrieval capability by confirming previous results and report a simultaneous hybrid retrieval using both HRS and LRS data. The LRS data span the HST WFC3 (1.1–1.7 μm) and Spitzer photometry (IRAC 3.6–8 μm) bands, while the HRS data were obtained with CRIRES on VLT at 2.3 μm. The constraints on the composition and temperature profiles for the hybrid retrieval are more stringent than retrievals with either LRS or HRS data sets individually. We retrieve abundances of and , and C/O = , consistent with previous works. We constrain the photospheric temperature to be K, consistent with the equilibrium temperature. Our results demonstrate the significant advantages of hybrid retrievals by combining strengths of both HRS and LRS observations, which probe complementary aspects of exoplanetary atmospheres.

On physical interpretations of the reference transit radius of gas-giant exoplanets

ABSTRACT Two theoretical quandaries involving transmission spectra of gas-giant exoplanets are elucidated. When computing the transit radius as a function of wavelength, one needs to specify a reference transit radius corresponding to a reference pressure. Mathematically, the reference transit radius is a constant of integration that originates from evaluating an integral for the transit depth. Physically, its interpretation has been debated in the literature. Jordán & Espinoza suggested that the optical depth is discontinuous across, and infinite below, the reference transit radius. Bétrémieux & Swain interpreted the spherical surface located at the reference transit radius to represent the boundary associated with an opaque cloud deck. It is demonstrated that continuous functions for the optical depth may be found. The optical depth below and at the reference transit radius need not take on special or divergent values. In the limit of a spatially uniform grey cloud with constant opacity, the transit chord with optical depth of the order of unity mimics the presence of a ‘cloud top’. While the surface located at the reference pressure may mimic the presence of grey clouds, it is more natural to include the effects of these clouds as part of the opacity function because the cloud opacity may be computed from first principles. It is unclear how this mimicry extends to non-grey clouds comprising small particles.

Towards the analysis of JWST exoplanet spectra: the effective temperature in the context of direct imaging

ABSTRACT The current sparse wavelength range coverage of exoplanet direct imaging observations, and the fact that models are defined using a finite wavelength range, lead both to uncertainties on effective temperature determination. We study these effects using blackbodies and atmospheric models and we detail how to infer this parameter. Through highlighting the key wavelength coverage that allows for a more accurate representation of the effective temperature, our analysis can be used to mitigate or manage extra uncertainties being added in the analysis from the models. We find that the wavelength range coverage will soon no longer be a problem. An effective temperature computed by integrating the spectroscopic observations of the James Webb Space Telescope will give uncertainties similar to, or better than, the current state–of–the–art, which is to fit models to data. Accurately calculating the effective temperature will help to improve current modelling approaches. Obtaining an independent and precise estimation of this crucial parameter will help the benchmarking process to identify the best practice to model exoplanet atmospheres.

Remote sensing of exoplanetary atmospheres with ground-based high-resolution near-infrared spectroscopy

Context. Thanks to the advances in modern instrumentation we have learned about many exoplanets that span a wide range of masses and composition. Studying their atmospheres provides insight into planetary origin, evolution, dynamics, and habitability. Present and future observing facilities will address these important topics in great detail by using more precise observations, high-resolution spectroscopy, and improved analysis methods. Aims. We investigate the feasibility of retrieving the vertical temperature distribution and molecular number densities from expected exoplanet spectra in the near-infrared. We use the test case of the CRIRES+ instrument at the Very Large Telescope which will operate in the near-infrared between 1 and 5 μm and resolving powers of R = 100 000 and R = 50 000. We also determine the optimal wavelength coverage and observational strategies for increasing accuracy in the retrievals. Methods. We used the optimal estimation approach to retrieve the atmospheric parameters from the simulated emission observations of the hot Jupiter HD 189733b. The radiative transfer forward model is calculated using a public version of the τ-REx software package. Results. Our simulations show that we can retrieve accurate temperature distribution in a very wide range of atmospheric pressures between 1 bar and 10−6 bar depending on the chosen spectral region. Retrieving molecular mixing ratios is very challenging, but a simultaneous observations in two separate infrared regions around 1.6 and 2.3 μm helps to obtain accurate estimates; the exoplanetary spectra must be of relatively high signal-to-noise ratio S∕N ≥ 10, while the temperature can already be derived accurately with the lowest value that we considered in this study (S∕N = 5). Conclusions. The results of our study suggest that high-resolution near-infrared spectroscopy is a powerful tool for studying exoplanet atmospheres because numerous lines of different molecules can be analyzed simultaneously. Instruments similar to CRIRES+ will provide data for detailed retrieval and will provide new important constraints on the atmospheric chemistry and physics.

Helium Absorption at 1083 nm from Extended Exoplanet Atmospheres: Dependence on Stellar Radiation

Strong absorption signatures in the helium line at 1083 nm have recently been detected in transmission spectra of several close-in exoplanets. This absorption line originates from neutral helium atoms in an excited, metastable 2$^3$S state. The population of helium atoms in this excited state is governed by the spectral shape and intensity of the incident stellar radiation field. We investigate what kind of stellar environments are most favorable for populating the metastable helium state in extended planetary atmospheres. Our results suggest that planets orbiting at close separations from late-type stars, particularly K stars, are the most promising candidates for transit absorption signals at 1083 nm. This result is supported by observations, as all four exoplanets with currently reported helium detections orbit K-type stars. In general, conditions for exciting helium atoms become more favorable at closer orbital separations, and around stars with higher levels of extreme-ultraviolet (EUV) flux, which ionizes the helium ground state, and lower levels of mid-ultraviolet (mid-UV) flux, which ionizes the helium metastable state.

Aggregate Hazes in Exoplanet Atmospheres

Abstract Photochemical hazes have frequently been used to interpret exoplanet transmission spectra that show an upward slope toward shorter wavelengths and weak molecular features. While previous studies have only considered spherical haze particles, photochemical hazes composed of hydrocarbon aggregate particles are common throughout the solar system. We use an aerosol microphysics model to investigate the effect of aggregate photochemical haze particles on the transmission spectra of warm exoplanets. We find that the wavelength dependence of the optical depth of aggregate particle hazes is flatter than for spheres because aggregates grow to larger radii. Consequently, while spherical haze opacity displays a scattering slope toward shorter wavelengths, aggregate haze opacity can be gray in the optical and near-infrared, similar to those assumed for condensate cloud decks. We further find that haze opacity increases with increasing production rate, decreasing eddy diffusivity, and increasing monomer size, although the magnitude of the latter effect is dependent on production rate and the atmospheric pressure levels probed. We generate synthetic exoplanet transmission spectra to investigate the effect of these hazes on spectral features. For high haze opacity cases, aggregate hazes lead to flat, nearly featureless spectra, while spherical hazes produce sloped spectra with clear spectral features at long wavelengths. Finally, we generate synthetic transmission spectra of GJ 1214b for aggregate and spherical hazes and compare them to space-based observations. We find that aggregate hazes can reproduce the data significantly better than spherical hazes, assuming a production rate that is limited by delivery of methane to the upper atmosphere.

Three-dimensional Circulation Driving Chemical Disequilibrium in WASP-43b

Abstract Spectral features in the observed spectra of exoplanets depend on the composition of their atmospheres. A good knowledge of the main atmospheric processes that drive the chemical distribution is therefore essential to interpret exoplanetary spectra. An atmosphere reaches chemical equilibrium if the rates of the forward and backward chemical reactions converge to the same value. However, there are atmospheric processes, such as atmospheric transport, that destabilize this equilibrium. In this work we study the changes in composition driven by a 3D wind field in WASP-43b using our Global Circulation Model, THOR. Our model uses validated temperature- and pressure-dependent chemical timescales that allow us to explore the disequilibrium chemistry of CO, CO2, H2O, and CH4. In WASP-43b the formation of the equatorial jet has an important impact on the chemical distribution of the different species across the atmosphere. At low latitudes the chemistry is longitudinally quenched, except for CO2 at solar abundances. The polar vortexes have a distinct chemical distribution since these are regions with lower temperature and atmospheric mixing. Vertical and latitudinal mixing have a secondary impact on the chemical transport. We determine graphically the effect of disequilibrium on the observed emission spectra. Our results do not show any significant differences in the emission spectra between the equilibrium and disequilibrium solutions for C/O = 0.5. However, if C/O is increased to 2.0, differences in the spectra due to the disequilibrium chemistry of CH4 become non-negligible. In some spectral ranges the emission spectra can have more than 15% departure from the equilibrium solution.

Space-based infrared interferometry to study exoplanetary atmospheres

The quest for other habitable worlds and the search for life among them are major goals of modern astronomy. One way to make progress towards these goals is to obtain high-quality spectra of a large number of exoplanets over a broad range of wavelengths. While concepts currently investigated in the United States are focused on visible/NIR wavelengths, where the planets are probed in reflected light, a compelling alternative to characterize planetary atmospheres is the mid-infrared waveband (5-20~$\mu$m). Indeed, mid-infrared observations provide key information on the presence of an atmosphere, the surface conditions (e.g., temperature, pressure, habitability), and the atmospheric composition in important species such as H$_2$O, CO$_2$, O$_3$, CH$_4$, and N$_2$O. This information is essential to investigate the potential habitability of exoplanets and to make progress towards the search for life in the universe. Obtaining high-quality mid-infrared spectra of exoplanets from the ground is however extremely challenging due to the overwhelming brightness and turbulence of Earth's atmosphere. In this paper, we present a concept of space-based mid-infrared interferometer that can tackle this observing challenge and discuss the main technological developments required to launch such a sophisticated instrument.

Revisiting the potassium feature of WASP-31b at high resolution

The analysis and interpretation of exoplanet spectra from time-series observations remains a significant challenge to our current understanding of exoplanet atmospheres, due to the complexities in understanding instrumental systematics. Previous observations of the hot Jupiter WASP-31b using transmission spectroscopy at low-resolution have presented conflicting results. Hubble Space Telescope (HST) observations detected a strong potassium feature at high significance (4.2\sigma), which subsequent ground-based spectro-photometry with the Very Large Telescope (VLT) failed to reproduce. Here, we present high-resolution observations (R>80,000) of WASP-31b with the UVES spectrograph, in an effort to resolve this discrepancy. We perform a comprehensive search for potassium using differential transit light curves, and integration over the planet's radial velocity. Our observations do not detect K absorption at the level previously reported with HST, consistent with the VLT observations. We measure a differential light curve depth $\Delta F = 0.00031 \pm 0.00036$ using 40\AA\ bins centred on the planet's K feature, and set an upper limit on the core line depth of $\Delta F \leq 0.007$ (3\sigma) at a few times the resolution limit ($\approx0.24\AA$). These results demonstrate that there are still significant limitations to our understanding of instrumental systematics even with our most stable space-based instrumentation, and that care must be taken when extracting narrow band signatures from low-resolution data. Confirming exoplanet features using alternative instruments and methodologies should be a priority, and confronting the limitations of systematics is essential to our future understanding of exoplanet atmospheres.

Stellar contributions to the line profiles of high-resolution transmission spectra of exoplanets

Context. In-depth studies of exoplanetary atmospheres are starting to become reality. In order to unveil their properties in detail, we need spectra with a higher signal-to-noise ratio (S/N) and also more sophisticated analysis methods. Aims. With high-resolution spectrographs, we can not only detect the sodium feature in the atmosphere of exoplanets, but also characterize it by studying its line profile. After finding a clearly w-shaped sodium line profile in the transmission spectrum of HD 189733b, we investigated the possible sources of contamination given by the star and tried to correct for these spurious deformations. Methods. By analyzing the single transmission spectra of HD 189733b in the wavelength space, we show that the main sodium signal that causes the absorption in the transmission spectrum is centered on the stellar rest frame. We concentrate on two main stellar effects that contaminate the exoplanetary transmission spectrum: center-to-limb variations (CLVs) and stellar rotation. We show the effects on the line profile: while we correct for the CLV using simulated theoretical stellar spectra, we provide a new method, based directly on observational data, to correct for the Rossiter–McLaughlin contribution to the line profile of the retrieved transmission spectrum. Results. We apply the corrections to the spectra of HD 189733b. Our analysis shows line profiles of the Na D lines in the transmission spectrum that are narrower than reported previously. The correction of the sodium D2 line, which is deeper than the D1 line, is probably still incomplete since the planetary radius is larger at this wavelength. A careful detrending from spurious stellar effects followed by an inspection in the velocity space is mandatory when studying the line profile of atmospheric features in the high-resolution transmission spectrum of exoplanets. Since the line profile is used to retrieve atmospheric properties, the resulting atmospheric parameters could be incorrectly estimated when the stellar contamination is not corrected for. Data with higher S/N coupled with improved atmospheric models will allow us to adapt the magnitude of the corrections of stellar effects in an iterative way.

Microphysics of KCl and ZnS Clouds on GJ 1214 b

Abstract Clouds in the atmospheres of exoplanets confound characterization efforts by reducing, eliminating, and distorting the spectral signatures of molecular abundances. As such, interpretations of exoplanet spectra strongly depend on the choice of cloud model, many of which are highly simplified and lack predictive power. In this work, we use a cloud model that incorporates microphysical processes to simulate potassium chloride (KCl) and zinc sulfide (ZnS) clouds in the atmosphere of the super-Earth GJ 1214 b and how they vary as a function of the strength of vertical mixing and the atmospheric metallicity. Microphysical processes control the size and spatial distribution of cloud particles, allowing for the computation of more physical cloud distributions than simpler models. We find that the mass and opacity of KCl clouds increase with mixing strength and metallicity, with the particle size and spatial distribution defined by nucleation, condensation, evaporation, and transport timescales. ZnS clouds cannot form without the presence of condensation nuclei, while heterogeneous nucleation of ZnS on KCl reduces particle sizes compared to pure KCl cases. In order to explain the flat transmission spectrum of GJ 1214 b with homogeneously nucleated KCl clouds, the atmospheric metallicity must be at least 1000× solar, and the eddy diffusivity must be at least 1010 cm2 s−1. We predict that James Webb Space Telescope observations of GJ 1214 b may reveal the presence of methane, carbon monoxide, and water, allowing for constraints to be placed on atmospheric metallicity and C/O ratio.

Exoplanet Biosignatures: Understanding Oxygen as a Biosignature in the Context of Its Environment.

We describe how environmental context can help determine whether oxygen (O2) detected in extrasolar planetary observations is more likely to have a biological source. Here we provide an in-depth, interdisciplinary example of O2 biosignature identification and observation, which serves as the prototype for the development of a general framework for biosignature assessment. Photosynthetically generated O2 is a potentially strong biosignature, and at high abundance, it was originally thought to be an unambiguous indicator for life. However, as a biosignature, O2 faces two major challenges: (1) it was only present at high abundance for a relatively short period of Earth's history and (2) we now know of several potential planetary mechanisms that can generate abundant O2 without life being present. Consequently, our ability to interpret both the presence and absence of O2 in an exoplanetary spectrum relies on understanding the environmental context. Here we examine the coevolution of life with the early Earth's environment to identify how the interplay of sources and sinks may have suppressed O2 release into the atmosphere for several billion years, producing a false negative for biologically generated O2. These studies suggest that planetary characteristics that may enhance false negatives should be considered when selecting targets for biosignature searches. We review the most recent knowledge of false positives for O2, planetary processes that may generate abundant atmospheric O2 without a biosphere. We provide examples of how future photometric, spectroscopic, and time-dependent observations of O2 and other aspects of the planetary environment can be used to rule out false positives and thereby increase our confidence that any observed O2 is indeed a biosignature. These insights will guide and inform the development of future exoplanet characterization missions. Key Words: Biosignatures—Oxygenic photosynthesis—Exoplanets—Planetary atmospheres. Astrobiology 18, 630–662.

A Self-consistent Cloud Model for Brown Dwarfs and Young Giant Exoplanets: Comparison with Photometric and Spectroscopic Observations

Abstract We developed a simple, physical, and self-consistent cloud model for brown dwarfs and young giant exoplanets. We compared different parametrizations for the cloud particle size, by fixing either particle radii or the mixing efficiency (parameter f sed), or by estimating particle radii from simple microphysics. The cloud scheme with simple microphysics appears to be the best parametrization by successfully reproducing the observed photometry and spectra of brown dwarfs and young giant exoplanets. In particular, it reproduces the L–T transition, due to the condensation of silicate and iron clouds below the visible/near-IR photosphere. It also reproduces the reddening observed for low-gravity objects, due to an increase of cloud optical depth for low gravity. In addition, we found that the cloud greenhouse effect shifts chemical equilibrium, increasing the abundances of species stable at high temperature. This effect should significantly contribute to the strong variation of methane abundance at the L–T transition and to the methane depletion observed on young exoplanets. Finally, we predict the existence of a continuum of brown dwarfs and exoplanets for absolute J magnitude = 15–18 and color = 0–3, due to the evolution of the L–T transition with gravity. This self-consistent model therefore provides a general framework to understand the effects of clouds and appears well-suited for atmospheric retrievals.

Transmission spectroscopy with the ACE-FTS infrared spectral atlas of Earth: A model validation and feasibility study

Infrared solar occultation measurements are well established for remote sensing of Earth’s atmosphere, and the corresponding primary transit spectroscopy has turned out to be valuable for characterization of extrasolar planets. Our objective is an assessment of the detectability of molecular signatures in Earth’s transit spectra.To this end, we take a limb sequence of representative cloud-free transmission spectra recorded by the space-borne ACE-FTS Earth observation mission (Hughes et al., ACE infrared spectral atlases of the Earth’s atmosphere, JQSRT 2014) and combine these spectra to the effective height of the atmosphere. These data are compared to spectra modeled with an atmospheric radiative transfer line-by-line infrared code to study the impact of individual molecules, spectral resolution, the choice of auxiliary data, and numerical approximations. Moreover, the study serves as a validation of our infrared radiative transfer code.The largest impact is due to water, carbon dioxide, ozone, methane, nitrous oxide, nitrogen, nitric acid, oxygen, and some chlorofluorocarbons (CFC11 and CFC12). The effect of further molecules considered in the modeling is either marginal or absent. The best matching model has a mean residuum of 0.4 km and a maximum difference of 2 km to the measured effective height. For a quantitative estimate of visibility and detectability we consider the maximum change of the residual spectrum, the relative change of the residual norm, the additional transit depth, and signal-to-noise ratios for a JWST setup. In conclusion, our study provides a list of molecules that are relevant for modeling transmission spectra of Earth-like exoplanets and discusses the feasibility of retrieval.

Retrieval of exoplanet emission spectra with HyDRA

Thermal emission spectra of exoplanets provide constraints on the chemical compositions, pressure-temperature (P-T) profiles, and energy transport in exoplanetary atmospheres. Accurate inferences of these properties rely on the robustness of the atmospheric retrieval methods employed. While extant retrieval codes have provided significant constraints on molecular abundances and temperature profiles in several exoplanetary atmospheres, the constraints on their deviations from thermal and chemical equilibria have yet to be fully explored. Our present work is a step in this direction. We report HyDRA, a disequilibrium retrieval framework for thermal emission spectra of exoplanetary atmospheres. The retrieval code uses the standard architecture of a parametric atmospheric model coupled with Bayesian statistical inference using the Nested Sampling algorithm. For a given dataset, the retrieved compositions and P-T profiles are used in tandem with the GENESIS self-consistent atmospheric model to constrain layer-by-layer deviations from chemical and radiative-convective equilibrium in the observable atmosphere. We demonstrate HyDRA on the Hot Jupiter WASP-43b with a high-precision emission spectrum. We retrieve an H2O mixing ratio of log(H2O) = -3.54^{+0.82}_{-0.52}, consistent with previous studies. We detect H2O and a combined CO/CO2 at 8-sigma significance. We find the dayside P-T profile to be consistent with radiative-convective equilibrium within the 1-sigma limits and with low day-night redistribution, consistent with previous studies. The derived compositions are also consistent with thermochemical equilibrium for the corresponding distribution of P-T profiles. In the era of high precision and high resolution emission spectroscopy, HyDRA provides a path to retrieve disequilibrium phenomena in exoplanetary atmospheres.

Rotational Spectral Unmixing of Exoplanets: Degeneracies between Surface Colors and Geography

Abstract Unmixing the disk-integrated spectra of exoplanets provides hints about heterogeneous surfaces that we cannot directly resolve in the foreseeable future. It is particularly important for terrestrial planets with diverse surface compositions like Earth. Although previous work on unmixing the spectra of Earth from disk-integrated multi-band light curves appeared successful, we point out a mathematical degeneracy between the surface colors and their spatial distributions. Nevertheless, useful constraints on the spectral shape of individual surface types may be obtained from the premise that albedo is everywhere between 0 and 1. We demonstrate the degeneracy and the possible constraints using both mock data based on a toy model of Earth, as well as real observations of Earth. Despite the severe degeneracy, we are still able to recover an approximate albedo spectrum for an ocean. In general, we find that surfaces are easier to identify when they cover a large fraction of the planet and when their spectra approach zero or unity in certain bands.

Search for water vapor in the high-resolution transmission spectrum of HD 189733b in the visible

Ground-based telescopes equipped with state-of-the-art spectrographs are able to obtain high-resolution transmission and emission spectra of exoplanets that probe the structure and composition of their atmospheres. Various atomic and molecular species, such as Na, CO, H2O have been already detected. Molecular species have been observed only in the near-infrared while atomic species have been observed in the visible. In particular, the detection and abundance determination of water vapor bring important constraints to the planet formation process. We search for water vapor in the atmosphere of the exoplanet HD189733b using a high-resolution transmission spectrum in the visible obtained with HARPS. We use Molecfit to correct for telluric absorption features. Then we compute the high-resolution transmission spectrum of the planet using 3 transit datasets. We finally search for water vapor absorption using a cross-correlation technique that combines the signal of 800 individual lines. Telluric features are corrected to the noise level. We place a 5-sigma upper limit of 100 ppm on the strength of the 6500 A water vapor band. The 1-sigma precision of 20 ppm on the transmission spectrum demonstrates that space-like sensitivity can be achieved from the ground. This approach opens new perspectives to detect various atomic and molecular species with future instruments such as ESPRESSO at the VLT. Extrapolating from our results, we show that only 1 transit with ESPRESSO would be sufficient to detect water vapor on HD189733b-like hot Jupiter with a cloud-free atmosphere. Upcoming near-IR spectrographs will be even more efficient and sensitive to a wider range of molecular species. Moreover, the detection of the same molecular species in different bands (e.g. visible and IR) is key to constrain the structure and composition of the atmosphere, such as the presence of Rayleigh scattering or aerosols.