Specific Mass Loss Research Articles

A low-temperature preparation strategy of SiC/ZrB2-CrSi2-Si/SiC multilayer oxidation-resistant coating for C/C composites: Process, kinetics and mechanism research

In this work, a strategy of preparing multilayer SiC/ZrB2-CrSi2-Si/SiC coating at low-temperature by combining chemical vapor deposition (CVD), brush-sintering and preoxidation was proposed for C/C composites. The coated C/C composites could maintain stable and long-term oxidation resistance at 1473–1673 K, and the specific mass loss was only 8.05 mg∙cm−2 after 1673 K/340 h oxidation. The coupling mechanism of the preparation process on the microstructure and performance, the kinetics process of oxidation behavior and the protection/failure mechanism of the coating were analyzed. Furthermore, the importance of organosilicon (SiCxOy) in the process of self-healing and oxidation resistance was enlightened.

Elevated temperature thermal properties of advanced materials used in LSF systems

SUMMARYLightweight cold‐formed steel (CFS) construction solutions are increasingly adopted in low and mid‐rise buildings. Many different materials are used to construct CFS wall systems, without a full understanding of their thermal properties. For many of these materials, only ambient temperature thermal properties are available from their manufacturers. This creates difficulty in classifying the materials for use at elevated temperatures. In this study, a series of elevated temperature thermal property tests to measure specific heat, thermal conductivity, and mass loss was conducted for a range building materials from wallboards, insulation, and phase‐change materials (PCMs), used in Australia and several other countries. Simultaneous Thermal Analyser and Laser Flash Apparatus were used to determine the elevated temperature thermal properties of the selected materials, gypsum plasterboard, PCM incorporated gypsum plasterboard, magnesium sulphate board, fibre cement board, cellulose insulation, vacuum insulation panel, microencapsulated paraffin PCM, and bio‐based PCM. Their elevated temperature thermal properties are presented in this article, which also includes analyses of their chemical composition and associated chemical reactions at elevated temperatures. These results can be used in the selection of suitable energy‐efficient and fire‐resistive materials, and in heat transfer modeling to identify wall configurations with increased fire resistance and energy efficiency.

Corrosion of cast iron sections of gas-collecting bells of EcoSoderberg electrolyser

The article presents results of the research of high-temperature gas corrosion of sections of EcoSoderberg electrolyzers’ gas-collecting bells (GSB) made of high-strength VCh50 cast iron with spherical graphite. The gravimetric method was used to study the specific mass losses of the sections due to corrosion. The microstructure of cast iron, structure, chemical and phase composition of corrosion products were studied using optical, electron microscopy and electron microprobe analysis. It was established that the specific weight loss of the sections during operation reaches 0.36 – 0.46 g/(cm2·month). Corrosion of cast iron sections of EcoSoderberg electrolyzers’ GSB is characterized by high unevenness by area. There are cases of decommissioning sections due to local through “burnouts” with a weight loss of 19 – 24 kg. With relatively uniform corrosion, the maximum allowable weight loss of the sections is 25 – 30 kg. To make predictive estimates based on experimental data, dependence of the sections’ mass loss on the operating time was obtained. It was found that the corrosion products of the sections consist of iron oxides and alloying elements of cast iron. Most samples are characterized by increased content of C, S, F, K, Al, and Na. Corrosion products have a pronounced layered structure and contain a large number of defects in the form of pores and cracks. The layers differ in chemical, phase composition, and macrostructure. All the studied samples are characterized by cyclic alternation of relatively dense layers of iron oxides Fe2O3 and Fe3O4 and more porous layers between them. The layers are characterized by increased content of C and F. Sulfur is evenly distributed over the thickness of corrosion products. The studied samples of corrosion products have high defectiveness, friability, large number of pores, cracks, discontinuities, and low adhesion to the surface of cast iron. This is due to the presence of phases and compounds with different coefficients of thermal expansion. The mechanism of corrosion products layers formation was established and scientifically proved.

Simulation of steel rod atmospheric corrosion by alternate immersion in salt solution

Corroded B235 reinforcing steel rods, which were exposed to an open air environment for 25 years, with a certain specific mass loss, were studied. Test pieces were prepared from them by lathe machining. The test pieces were subjected to accelerated corrosion through an alternate immersion in NaCl solution. The same specific mass loss as on the initial corroded rods was achieved for 52 days. Further the test pieces were cleaned, observed, photographed and tensile tested. The cleaned surfaces and the stress-strain curves of the test pieces were compared with results, obtained from the initial corroded rods. It was found out about the tested steel rods that alternate immersion in salt solution for 52 days is a good simulation of twenty-five-year atmospheric corrosion.

Early Loss of Fat Mass During Chemoradiotherapy Predicts Overall Survival in Locally Advanced Squamous Cell Carcinoma of the Lung, but Not in Locally Advanced Squamous Cell Carcinoma of the Head and Neck.

Background: Cancer cachexia is highly prevalent in advanced non-small cell lung cancer (NSCLC) and locally advanced head and neck squamous cell carcinoma (LAHNSCC), and compromises treatment tolerance and overall survival (OS). NSCLC and LAHNSCC patients share similar risk factors, and receive comparable anti-cancer treatment regimens. The aim of this study was to determine the predictive value of body composition assessed by bioelectrical impedance analysis (BIA) and handgrip strength (HGS) (baseline and early changes during therapy) on OS in NSCLC and LAHNSCC patients treated with platinum-based chemoradiotherapy (CRT) or cetuximab-based bioradiotherapy (BRT). To elucidate potential underlying determinants of early changes in body composition and HGS, specific (fat and fat free) mass loss patterns of squamous NSCLC (sNSCLC) were compared to human papilloma virus negative (HPV–) LAHNSCC patients treated with CRT.Methods: Between 2013 and 2016, BIA and HGS were performed at baseline and after 3 weeks of CRT/BRT in LAHNSCC and NSCLC patients treated with curative intent.Results: Two hundred thirty-three patients were included for baseline measurements. Fat free mass index (FFMI) and HGS<10th percentile of reference values at baseline were both prognostic for poor OS in NSCLC and LAHNSCC [HR 1.64 [95%CI 1.13–2.39], p = 0.01 and HR 2.30 [95%CI 1.33–3.97], p = 0.003, respectively], independent of Charlson Comorbidity Index, cancer site, and gross tumor volume. Early fat mass (FM) loss during CRT was predictive for poor OS in sNSCLC (n = 64) [HR 3.80 [95%CI 1.79–8.06] p ≤ 0.001] but not in HPV– LAHNSCC (n = 61). In patients with significant weight loss (>2%) in the first 3 weeks of CRT (sNSCLC n = 24, HPV– LAHNSCC n = 23), the FM change was −1.4 ± 14.5% and −8.7 ± 9.0% in sNSCLC and HPV– LAHNSCC patients, respectively (p < 0.05). Fat fee mass change was −5.6 ± 6.3% and −4.0 ± 4.3% for sNSCLC and HPV– LAHNSCC, respectively (p = 0.31).Conclusion: FFMI and HGS<10th percentile at baseline are independent prognostic factors for poor OS in NSCLC and LAHNSCC patients treated with CRT/BRT. The specific composition of mass loss during first 3 weeks of CRT significantly differs between sNSCLC and HPV– LAHNSCC patients. Early FM loss was prognostic in sNSCLC only.

Effect of Environmental Conditions on the Dehydration and Performance of Fire-Protective Gels

During wildfire events fire-protective gels can be used as a line of defense to protect structures. The effectiveness of freshly applied gels in delaying ignition and flame growth on structures has been well established. However, in a real-world scenario there is a period between the application of the gel and the arrival of a spot fire or the fire-front. During this period, the gels are often exposed to extreme conditions consisting of high winds and low relative humidity. The effect of these weathering conditions on the performance of fire-protective gels is still poorly understood. This study examined the dehydration and performance of fire-protective gels following a range of weathering conditions. Two commercially available gels were applied to a 100-mm by 100-mm T1-11 plywood sample and then artificially weathered in an environmental chamber, with controlled temperature, relative humidity, and wind. The remaining mass of the gels was measured at selected intervals to determine the relationship between mass loss and dehydration related to weathering. A second series of tests was conducted on weathered T1-11 samples at specific mass loss states as well as on freshly applied gels using a 50 kW/m2 heat flux exposure utilizing a cone calorimeter. Results indicated that they dehydrated to the point where, after 3 h, fire performance was no better than the uncoated wood samples and the gels could facilitate ignition. This timeline suggests that gels should only be applied by first responders and homeowners should focus on evacuation related activities.

Investigating mass balance of Parvati glacier in Himalaya using satellite imagery based model

Accurate assessment of glacier mass loss is essential for understanding the glacier sensitivity to climate change and the ramifications of glacier retreat or surge. The glacier melt affects the runoff and water availability, on which the drinking and irrigation water supplies and generation of hydroelectric energy depend upon. The excessive glacial retreat may cause flood, glacial lake outburst flood, avalanches and sea level rise which are likely to affect the lives and livelihood of the people and damage the infrastructure. Here, we present a remote sensing based modeling framework to improve the understanding of accumulation and ablation processes and to quantify the glacier mass balance using multispectral satellite imageries, as several glacierized regions of the world are still poorly monitored because the field measurements for continuous monitoring on a large scale or in a complex harsh terrain are costly, time consuming and difficult. The developed modeling framework has been applied to the Parvati glacier in the western Himalaya to investigate glaciological processes and estimate the surface mass loss using 19 years of satellite images from 1998 to 2016. It spreads over 425.318 km2 and more than 50% of the area is accumulation area. The study shows that the Parvati glacier is not in equilibrium and its behavioural response changes year to year characterized with high rate of mass loss. The value of accumulation area ratio varies between 0.33 and 0.70 with an average value of 0.55, indicating a negative mass loss. The mean specific mass loss is − 0.49 ± 0.11 m w.e. and the total mass loss is 3.95 Gt., indicating strong influence of climate change and effect on river flows and water availability.

Investigation on Tribological and mechanical behaviour of AA6082—Graphene based composites with Ti particles

In the recent years, high strength and low weight materials are being preferred in automobile sectors for fabricating high-speed rotating shafts and machineries. For satisfying dynamic requirements, Aluminium Metal Matrix Composites can be used. In this paper, an attempt has been made to fabricate AA 6082—graphene based Aluminium Matrix Composites reinforced with Titanium (Ti) particles. The effect of increase weight percentage of Graphene and Ti reinforcement on the mechanical characteristics was evaluated. Using tensile tests and surface micro hardness measurements, the fluctuations in mechanical aspects were measured. Tribological characteristics of the Aluminium Matrix Composites were found using pin on disc tribo wear meter, using Silver (Ag) nanoparticles incorporated Jatropha oil as bio-lubricant. Microstructural variations were evaluated by using FESEM which indicated surface tear offs, surface ploughing, demarcations, micro pits, grooves, demarcations, micro cuts and micro tears on the surfaces. The effect of Ag Nano particle addition on Jatropha oil was observed with the fluctuations in Coefficient of friction, specific wear rate and wear mass loss. On increase in reinforcement percentage of G and Ti, specific wear rate was found to decrease and coefficient of friction decreased till 3% by weight reinforcement and beyond 3%, it increased. The surface chemistry modifications were identified using XRD. It was observed that AA6082 Aluminium Matrix Composites reinforced with 3% G and 3% Ti exhibited better mechanical and tribological properties when used with 1% Ag Nanoparticles incorporated Jatropha oil as lubricant.

Unusual Cu–Co/GO Composite with Special High Organic Content Synthesized by an in Situ Self-Assembly Approach: Pyrolysis and Catalytic Decomposition on Energetic Materials

An interesting Cu-Co/GO composite with special high organic content was accidentally fabricated for the first time via a one-pot solvothermal method in the mixed solvent of isopropanol and glycerol. The Cu-Co/GO composite was calcined separately in three different atmospheres (air, nitrogen, and argon) and further investigated by a series of characterization techniques. The results indicate that the spinel phase nano-CuCo2O4 composite, nanometal oxides (CuO and CoO), and nanometal mixture of Cu and Co were unexpectedly formed after calcination in air, N2, and Ar atmospheres, respectively, and the possible reaction mechanism was discussed. The specific mass losses of the Cu-Co/GO composite calcined in air, N2, and Ar atmospheres were 28.14 %, 21.68 %, and 23.76 %, respectively. The catalytic decomposition performances of the as-prepared samples for cyclotrimethylenetrinitramine (RDX) and the mixture of nitrocellulose (NC) and RDX (NC + RDX) were investigated and compared via DSC method, and the results demonstrate that Cu-Co/GO composites obviously decrease the thermal decomposition temperature of RDX from 242.3 to 236.5 (before calcination), 238.6 (air), 235.8 (N2), and 228.6 °C (Ar), respectively. Cu-Co/GO(Ar) composite exhibits the best catalytic decomposition performance among all samples, which makes the decomposition temperature of RDX and NC + RDX decrease by 13.7 and 4.9 °C and the apparent activation energy of decomposition for RDX decrease by 110.1 kJ/mol. The enhanced catalytic performance of Cu-Co/GO(Ar) composite could be attributed to the smaller particle size, better crystallinity, and specific well-dispersed metal atoms, whereas the Cu-Co/GO(air) composite after air calcination presents a bad catalytic performance due to the removal of GO.

Development of protective MMC coating on TZM alloy for high temperature oxidation resistance by LPCS

TZM is an important Mo based alloy for high temperature applications, however, oxide structures formed in an air atmosphere at high temperatures restrict its commercial applications. In this study, TZM alloys were coated with Ni-Zn-Al2O3 by low pressure cold spray (LPCS) in order to improve the high temperature oxidation behaviour. The effects on the microstructure, oxidation, and tribological properties of the MMC protective coating were examined. According to microstructural examinations, the LPCS solid-state coating had a wave-like lamellar structure due to an interlocking mechanism and consisted of ceramic alumina particles embedded in a Ni and Zn metal matrix. The EDS and XRD results showed that phase changes or oxidation were not formed in the LPCS coating due to the solid state deposition mechanism and low process temperature. The oxidation test results showed that the specific mass losses of the TZM alloy were sharply increased at high temperature due to the deformation of the oxygen in the molybdenum matrix. The Ni-Zn-Al2O3 MMC coating prevented oxidation on the TZM alloy at 600–1000 °C due to the reaction of the oxygen with the Ni and Zn elements generating a NiO and ZnO protective film layer on the coating surface. Dry sliding tests of the MMC coating were performed at different test loads for determination of the tribological performance. Although MMC coatings showed similar friction behaviour at different test loads, the wear rate in the 4 N test load was about 1.2 times higher than the 2 N loading.

Corrosion decomposition and mechanical behaviors of As‐cast Mg–xZn–Zr alloys

AbstractDeveloping new‐type alloy materials with excellent decomposition properties and mechanical behaviors is a thorny issue for preparing fracturing balls in oil exploitation. As‐cast Mg–xZn–Zr alloys designed by regulating Zn contents have been fabricated in this study. Compressive strength and immersion corrosion test have been investigated to assess their feasibility as decomposition materials. Scanning electron microscopy and X‐ray diffract meter have also been used to characterize surface morphologies and phase structures for determining their decomposition mechanism. Results show that matrix phases and secondary phases with discontinuous reticular features form on the alloys. They also achieve excellent mechanical properties to ensure stability and pressure‐maintaining capacity in the decomposition process in chloride environment. Meanwhile, with Zn content and immersion time increasing, galvanic corrosion effect strengthens leading to accelerated specific mass loss rates of the alloys. Rapid corrosion decomposition of the alloys mainly attributes to anodic dissolution of matrix phases, exfoliation of microparticles, and poor resistance of corrosion products to the decomposition process. This study provides positive insight into the preparation of new‐type Mg alloys for guaranteeing fast decomposition of fracturing balls and also ensuring their compressive strength stability.

TiO2 Immobilized on Fibrous Clay as Strategies to Photocatalytic Activity

Abstract TiO2 immobilized in Sepiolite (TiO2/Sep) was successfully prepared by the sol-gel technique, with titanium isopropoxide as the precursor for the formation of TiO2 in the anatase phase calcined at 400 °C. The prepared samples were characterized by X-ray diffraction, Fourier Transform Infrared spectroscopy, Scanning Electron Microscopy coupled to energy dispersive spectroscopy, and thermogravimetric analysis. The results showed that TiO2/Sep structure was identified in all characterizations, showing the specific peaks, bands, mass loss, and morphology after the impregnation process. Photocatalytic experiments were performed under UV irradiation with various photocatalyst concentrations and pH effects in the reaction. The prepared samples presented 72% photocatalytic efficiency for eosin (EA) dye discoloration after 150 min under UV light. This efficiency was attributed to the radicals generated from the TiO2 and the high specific surface area, showing that TiO2/Sep is promising candidate in the degradation of organic pollutants.

Effect of Graphite and Bronze Fillers on PTFE Tribological Behavior: A Commercial Materials Evaluation

This work presents a tribological evaluation of the influence of graphite and bronze fillers in two commercial composites in a dry sliding pin-on-disc test at the same contact severity ( parameter) and four testing conditions (varying both normal force and sliding velocity). Both fillers, in comparison to pure PTFE, significantly affected the coefficient of friction (COF) and the mass loss. The sliding distance required to reach steady-state for COF was statistically equal for all three materials. The COF experienced a relevant influence of both normal force and sliding velocity. The graphite filler acted as a solid lubricant and exhibited reductions in COF (∼27% on average) and in mass loss (∼4.2 times lower on average). The bronze filler, on the other hand, had a COF increase of up to 5% for conditions with lower normal force but showed a significant reduction on the specific mass loss (∼5.3 times lower on average). Due to its higher thermal conductivity, the composite filled with graphite presented lower tribosystem temperatures in thermography evaluations. Good agreement of the temperature data was found considering a model that proposes the rate of heat generated by friction. With respect to wear of the composites, evidence of adhesion (transfer films to the counterface) and abrasive (microploughing and microcutting) wear mechanisms was found, in addition to the identification of preferential wear.

Oxidation behavior of plasma-sprayed MoSi2-Yb2O3 composite coating at 1700 °C

Rare earths with unique electronic structure and properties have incomparable advantages for modifying the comprehensive performance of silicide materials. In this study, MoSi2-based composite coatings with different rare-earth Yb2O3 contents were prepared using supersonic atmospheric plasma spraying, and their microstructural features and oxidation behavior at 1700 °C were investigated systematically. Results showed that the sprayed MoSi2-Yb2O3 composite coating possessed the dense structure without visible defects and tightly adhered to the SiC transition layer. During oxidation at 1700 °C, all the samples exhibited an explicit linear oxidation mode, in which the MoSi2-10 wt%Yb2O3 coating qualified the optimal oxidation resistance with the lowest specific mass loss relative to other coatings. It was natural to consider that the Yb2O3 dopant changed the microstructural aspects of the formed oxide scale upon oxidation, and then affecting the oxidation behavior of the applied coating. Moderate doping of Yb2O3 stabilized the Si–O covalent bonds in SiO2 network, leading to the enhanced viscosity of oxide glass scale, thereby delaying the effective delivery of oxygen molecules as well as the oxidation degradation of the coating.

Oxidation kinetics of supersonic atmospheric plasma spraying ytterbium oxide doped molybdenum silicide coating

Rare earth oxides usually play an active role in modifying the microstructure and oxidation resistance of silicide coatings, but its modification mechanism has not yet been clarified. In this work, molybdenum silicide (MoSi2) coating with different contents of ytterbium oxide (Yb2O3) was fabricated using supersonic atmospheric plasma spraying, and its microstructural evolution and oxidation behavior were investigated. Experimental results shown that the morphological characteristics of produced SiO2-rich glass scale varied with the doping of Yb2O3, which noticeably affected the oxidation resistance of sprayed MoSi2-Yb2O3 coatings. All coated specimens exhibited a parabolic oxidation behavior, wherein the MoSi2-10 wt%Yb2O3 coating possessed the smallest parabolic constant and the lowest specific mass loss with 100 h oxidation at 1500 °C due to the absence of SiC-depleted region and the formation of continuous multicomponent compound scale. Given this, Yb2O3 additive with proper concentration not only guaranteed the sufficient filling of open spaces in SiO2 network by Yb3+ cations, but also strengthened the Si–O bonds to increasing the viscosity of SiO2 glass, thereby delaying the effective delivery of reactive oxygen species inwardly.

Near-Surface Plasma Formed by Dual-Pulse Laser Action at Two Wavelengths on Titanium in Air

Spectra and structures of near-surface plasma torches were studied experimentally by measuring the specific mass loss and plume luminosity caused by dual-pulse laser radiation at wavelengths 1064 and 532 nm on titanium in air as functions of the time between laser pulses and their sequence. Dependences of the laser-plasma temperature and concentration of charged particles on the paired laser pulse parameters were established at laser radiation power densities q1064 ≤ 3.1·109 and q532 ≤ 2.7·109 W/cm2 for λ = 1064 and 532 nm. The optimal conditions for recording erosion plasma spectra had the initial effect from second-harmonic radiation with a time interval between pulses of 4–5 μs; for specific mass loss, 3–6 μs. The results were important for enhancing the efficiency of laser emission spectral analysis and laser-plasma processing of materials.

Thermal Insulation Properties of Insulated Concrete

In building development, concrete is world most reliable, durable and versatile in construction materials. However, the heating and cooling system of the building is influenced by outside temperature due to extreme weather or areas condition leads to the consumption of a lot of electrical power. Thermally insulated concretes represent alternative construction materials to improve the thermal efficiency in building development. Various construction materials have different thermal insulation properties and thus, their suitability for various conditions vary. Thermal insulation properties are generally identified through specific heat, thermal conductivity, thermal diffusivity, thermal expansion, and mass loss. This paper present review the thermal insulation properties of variations insulated concrete are presently in growing demand of researchers to comfort and resolve prescribed issues related to insulated concrete in enhancing thermal insulation properties as a passive energy saving building.

Graphene platelets versus phosphorus compounds for elastomeric composites: flame retardancy, mechanical performance and mechanisms

Polymers are widely used but their flammability remains a serious issue causing fatalities and property damage. Herein we present an investigation into the effectiveness of graphene platelets (GnPs) to simultaneously improve the flame retardancy and mechanical properties of ethylene propylene diene monomer rubber (EPDM). EPDM was melt compounded respectively with GnPs and a commercial flame retardant (ammonium polyphosphate, APP) to produce two groups of composites. Although both fillers were well dispersed in EPDM, GnPs significantly improved the mechanical properties of EPDM whilst APP compromised some of the mechanical properties particularly at high fractions. This difference was attributed to the filler particle size and interfacial bonding. Through cone calorimetry testing, 21 wt% char yield was recorded for the EPDM/GnP composite at 12.0 vol%, in comparison with 8 wt% for the EPDM/APP composite. APP was able to lower the peak heat release rate (PHRR) and specific mass loss rate (MLR), but unfortunately it decreased the ignition time and fire performance index (FPI). By contrast, GnPs has been found to increase ignition time by 29% and FPI by 62%, while still achieved the same level of reductions in PHRR and specific MLR, demonstrating clear advantages over APP. During combustion the highly thermally stable GnPs bonded with the viscous, degraded EPDM macromolecules, forming a thick solid char layer which prevented the transport of heat and smoke, contributing to its superior flame retarding performance over APP.

Fire-resistant hydrophobic nanocoated composite partition sheets

Composite partition sheets were prepared by vacuum infusion process using noncombustible glass fiber and waste nylon along with polyester matrix. The waste nylon materials obtained in the form of discarded fishing nets were reinforced in sheets with T90° orientation. They were then coated using two types of fumed silica nanopowders mixed in polyester resin. Two types of coated and corresponding bare hybrid composite samples were examined for their various properties. Appreciable values for mechanical properties were obtained for all the hybrid sheets which are more pronounced for the nanocoated sheets. Furthermore, horizontal flammability tests proved that the fumed silica-coated sheets have better flame-retardant characteristics. With constant heat flux of 50 W/m2, the specimens were investigated for the peak heat release rate (HRR) and fire reaction properties like total oxygen consumed, average specific mass loss rate, total smoke release, and average HRR which gave good results for the nanocoated sheets. Moreover, water-absorbing properties of the hybrid sheets were generally less and it was better in the case of hydrophobic fumed silica-coated samples. These low cost and less weight composite sheets were successfully developed and the results obtained were encouraging, which can be used as partition sheets in the construction of affordable buildings.

Temperature stability and thermal properties of polyurethane-polyisocyanurate foams obtained using products of citric acid condensation

Three products were obtained from the condensation of citric acid with: propane-1,2-diol with the catalyst Tyzor TPT (HDCA1), propane-1,2-diol without a catalyst (HDCA2) and ­propane-1,3-diol with the catalyst Tyzor TPT (HDCA3). We measured the viscosities (from 3972 mPa • s for HDCA1 to 27 986 mPa • s for HDCA3), densities (about 1200 g/cm3), hydroxyl values (280–427 mg KOH/g), and acid values (­23–52 mg KOH/g) of the HDCAs. The thermal resistance of the HDCAs were assessed under dynamic conditions. The temperature ranges of 5, 10, 20 and 50 % weight loss for HDCA polyols were, respectively: 174–194 °C, 230–234 °C, 263–303 °C, and 314–364 °C. The HDCAs were used in the further synthesis of rigid polyurethane-polyisocyanurate foams (PUR-PIR) and their physical qualities assessed with reference to foams produced from an industrial standard (Rokopol RF551). The authors examined the thermal properties (thermogravimetry, differential thermogravimetry and differential scanning calorimetry) of the foams, as well as the thermal stability: dimensional, volume and mass. The number of foam degradation stages was determined, as well as the speed of degradation of specific chemical bonds and percentage mass loss during all stages. We determined the temperature of the foam’s first weight loss, the extrapolating temperature of the foam’s weight loss, the temperature of the start of the foam’s rapid decomposition, and the temperature of the foam’s highest speed of weight loss, the temperatures of 5 %, 10 %, 20 % and 50 % mass loss were measured (respectively: 208–223 °C, 230–260 °C, 280–300 °C, 345–366 °C). The enthalpy related to each individual stage of foam degradation was examined using DSC (three endotherms and one exothermic peak).