A description is given of the synthesis of PA by the anionic polymerization of caprolactam in the presence of new macromolecular polyfunctional activators that promote a three-dimensional structure. PA of this type have a cross-linked structure (gel-fraction in cresol amounts to 100 wt%). The size of the inter-node fragment of the network has been determined as 9850-18500. The PA synthesized are distinguished by a high value of specific impact strength (12–34 kJ/m 2 in the Izod test) and are characterized by the existence of hyperelasticity in the temperature range 220–300°C.
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