We present two new classes of quasi-exactly solvable periodic potentials. It is shown that their solutions are given in terms of a known special function. When the parameters in the two periodic potentials satisfy a certain condition, some of the Bloch waves and associated energies can be found exactly and in closed form at either the center or the edge of the first Brillouin zone. Two fundamental sets of solutions have been constructed to calculate all the Bloch waves and energy bands.
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