Solution Of Gd Research Articles

Achieving enhanced thermal conductivity and mechanical properties in Mg-Zn-Gd-Zr alloys via regulation microstructure characteristics

It is well known that the microstructure of metallic materials determines the mechanical properties. However, the effect of microstructure on thermal conductivity lacks an accurate quantitative description of this relationship. In this work, the mechanism of variation in mechanical and thermal conductivities with microstructure was revealed by the characterization of cast, heat-treated, and extruded Mg-xZn-yGd-0.6Zr (wt%) alloys: ZV66, ZV62, and ZV26. The contributions of solution atoms, second phases, grain size, and dislocations to the yield strength and thermal conductivity were quantitatively calculated, and their effects on the plasticity and work-hardening behavior were qualitatively analyzed. The results show that hot extrusion promotes the precipitation of nanoprecipitates, such as MgZn2, Mg4Zn7, and Mg5Gd, resulting in the reduction of Zn and Gd solute atoms and the introduction of high-density dislocations and grain boundaries. The extruded ZV66 alloy exhibits excellent mechanical properties and thermal conductivity (a tensile yield strength of 232 MPa, an elongation of 22 %, and a thermal conductivity of 127.6 W/(m·k)); these values are better than those reported for similar products. The achievement of high strength and thermal conductivity is attributed to the precipitation of solute atoms to improve thermal conductivity in addition to grain boundary strengthening and work-hardening strengthening to improve strength. These findings provide new insights into achieving excellent strength–thermal conductivity property amalgamations in magnesium alloys by tailoring their microstructure.

A green and facile direct ink writing technique for preparation calibration standards in laser ablation inductively coupled plasma mass spectrometry analysis

BackgroundLaser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) is a powerful tool for microanalysis of solid materials. Nevertheless, one limitation of the method is the lack of well-characterized homogeneous reference materials (RMs), such as BaF2 crystal and BaCO3 ceramics samples, making direct quantification difficult. This work presents a novel Direct Ink Writing (DIW) method to produce RMs for microanalysis. The Mg, Cr, Fe, Co, Ni, Cu, Y, Mo, Pr, Gd, Dy, Ho, Er, Tm, Yb, and Lu solutions were gravimetrically doped into BaCO3 by mixing with the dispersant and then cured with DIW techniques. (94) ResultsBaCO3 powder was combined with a dopant analyte to produce a printable slurry, aided by the use of a dispersant and cellulose. The resulting mixture was then printed using DIW equipment. The retention rates of the doped elements were investigated by internal and external standard method, and the results showed that they were completely dispersed in the solid material. After further optimization, it was found that there was no significant heterogeneity among the printed samples. LA-ICP-MS was used to analyze printed samples, to evaluate micro-scale homogeneity. The mass concentration of the doped element was determined by ICP-MS, verify its move closer to nominal value. Compared with the traditional reference materials preparation methods, the DIW technology greatly increased the sample homogeneity and the accuracy of the desired concentration. (132) SignificanceAs far as we know, there are few reports on the application of DIW method to prepare calibration standards. In brief, it is proved that the proposed method of preparing calibration standard by DIW technique to quantify analytes is valid and robust. This procedure provides great potential for LA-ICP-MS in-situ analysis in the field of well-prepared products, such as ceramic and crystal samples.(63)

Toxicity of REEs, Th, and U: A Biodisponibility, Cytotoxicity, and Bioaccumulation Assessment in Marine Sediment.

In this work, bioaccessibility tests for rare earth elements (REEs), Th, and U in marine sediment were carried out, in addition to complementary tests for cytotoxicity and bioaccumulation for the elements La, Ce, Eu, and Gd. The evaluation of human health risk through dermal absorption and oral ingestion was performed using the hazard quotient (HQ). According to the gastric digestion simulation (SBET), it was observed that the elements Ce and Nd exhibited higher absorption capacities in the human body (> 2µgg-1). La and Sc presented intermediate concentrations (close to 1µgg-1), while the remaining elements displayed concentrations below 0.5µgg-1. In the gastrointestinal digestion extraction stage (PBET), all the elements maintained a similar absorption capacity to that observed in SBET, except for the absorption of Y which increased. The results of the bioaccumulation test conducted with fibroblast cells (L929) indicated that La and Eu had a 25% probability of intracellular accumulation. The cell viability test, with exposure to a standard REEs, Th, and U solution in 2% v v-1 HNO3 medium (until 100μgmL-1) and an aqueous solution of La2O3, Gd(NO3)3, Ce(NO3)3, and Eu2O3 (until 1000μgmL-1), did not demonstrate cytotoxic effects on fibroblast cells. Considering the ingestion hazard quotient (HQing) and dermal hazard quotient (HQderm) obtained, it was suggested that there is no significant risk of non-carcinogenic effects (< 1). However, they had higher HQing values compared to HQderm, indicating that REEs pose more significant risk to human health through oral ingestion absorption than dermal absorption.

Exploring solute behavior and texture selection in magnesium alloys at the atomistic level

This study advances our understanding of how chemical binding and solute distribution impact grain boundary segregation behavior and subsequent annealing texture modification in lean Mg-X-Zn alloys (X = RE or Ca). Notably, differences in Ca and Gd solute behavior at grain boundaries were revealed, where Ca exhibited stronger binding to vacancy sites than Gd, resulting in elevated Ca segregation and an RD-TD-type texture. The introduction of Zn showed significant synergistic effects on solute clustering, with Gd-Zn pairs forming more favorably than Ca-Zn pairs, leading to a strong synergy between Zn and Gd. This promoted their co-segregation and high concentration at the grain boundary, generating a unique TD-spread texture. In contrast, weaker binding in Ca-Zn pairs did not affect Ca segregation but influenced Zn segregation, which underscores the importance of solute binding behavior in alloy design concepts. Additionally, the combined atomic-scale experiments and ab initio predictions provide strong evidence that selective texture development in Mg alloys is tied to heterogeneous solute-boundary interactions, where the sensitivity of the binding energy to volumetric strain affects solute segregation at grain boundaries, resulting in varying grain boundary mobilities and specific texture component growth. It also emphasizes that solute behavior in clustering and segregation is influenced not only by atomic size but also by chemical binding strength with vacancies or co-added Zn.

Gd2O3–Carbon Nanoflakes (CNFs) as Contrast Agents for Photon-Counting Computed Tomography (PCCT)

2–3 nm Gd2O3 nanoparticles deposited on carbon nanoflakes were prepared. These are new contrast agents for photon-counting computed tomography based on detectors allowing counting of separate photons. Contrast agents of the Gd2O3@C core–shell structure were prepared by graphitization of the surface of these particles. The Gd2O3 and Gd2O3@C nanoparticles obtained, aqueous solution of Gd(NO3)3·6H2O, and a dispersion of 300–500 nm Gd2O3 particles in gelatin were studied by photon-counting computed tomography. At equal gadolinium concentrations, the highest X-ray absorption was noted for Gd(NO3)3·6H2O and Gd2O3, which is associated with higher density of these samples. Carbon in the contrast agents does not affect the absorption. An algorithm was developed for semiquantitative determination of gadolinium by photon-counting computed tomography.

Effect of dilute atom Gd on critical resolved shear stress and anisotropic deformation mechanism of Mg-Gd alloy

Formability and ductility of Mg alloy are highly dependent on its mechanical anisotropy and are mainly dominated by the anisotropic deformations of basal slip, tension twining and non-basal slips. This work is engaged to measuring critical resolved shear stress (CRSS) for basal slip, twin nucleation/growth and pyramidal slip of a Mg-1 wt% Gd alloy by micropillar compressions. The effects of rare earth (RE) element, Gd, on the CRSS and the deformation mechanisms are discussed, and the mechanical anisotropy is determined. The results suggest that Gd atom is capable of balancing the anisotropy ratio of hard mode to soft mode, by triggering significant strengthening in basal slip of Mg alloy. The strengthening effect is related to the misfit-volume induced fluctuations in solute concentrations and the wavy solutes/dislocation interaction energies when Gd is added. As a result, Gd solute is advantageous to reduce the mechanical anisotropy, thus benefits to formability and ductility of Mg alloys. The presented results can provide a framework to understand basically the physical origin of mechanical anisotropy and formability of Mg-RE alloys and can be guidelines to design high ductility Mg alloys for next-generation lunar exploration.

Accelerating and decelerating effects of Gd content and peak-aging treatment on the grain growth of magnesium

This short communication concerns the dependence of thermal stability of fine grains in Mg alloy on the Gd content. The enhanced thermal stability via increasing Gd content can be reflected by the SRX mechanism and corresponding boundary migration ability. In the low Gd-alloyed Mg, continuous SRX dominates the annealing process via dislocation re-arrangement. The grain boundaries composed by dislocations can easily migrate, since the uniform Gd solute distribution provides limited delaying effect. In the high Gd-alloyed Mg, discontinuous SRX dominates the annealing process via consuming dislocations for grain nucleation. The grain boundaries can hardly migrate due to the strong delaying effect provided by the Gd-segregation along grain boundaries. But unexpectedly, peak-aging can deteriorate the decelerated effect of high Gd-alloying owing to the absent Gd-segregation. Consequently, an accelerated grain growth rate is attained, even faster than that in the low Gd-alloyed Mg.

(Digital Presentation) GDC/YSZ Bilayer Electrolyte Fabrication by In-situ Hydrothermal Growth

GDC (gadolinia-doped ceria) can be used as barrier layer between the high-performance LSCF (La0.6Sr0.4Co0.2Fe0.8O3-δ) cathode and YSZ (8% mol yttria stabilized zirconia) electrolyte, to prevent chemical incompatibility and elements diffusion. However, the GDC layer is difficult to achieve as high density as the YSZ electrolyte, especially under low sintering temperatures. While, increase sintering temperature over ~1200 ℃ could induce the formation of (Ce,Zr)O2 solid solution.In this work, we report a highly dense bilayer GDC/YSZ electrolyte prepared at low sintering temperature. Specifically, the as-sintered anode supported SOFC half-cell with already-dense YSZ electrolyte was immersed in solution of Gd(NO3)3·6H2O and Ce(NO3)3·6H2O, followed by a hydrothermal treatment at 180 ℃ (accounts for steam pressure of ~1 MPa) for 36 h. This yielded a dense GDC layer growth on YSZ electrolyte with thickness of ~200 nm. Then, the cells were sintered at 1100, 1150 and 1200 ℃, respectively. Afterwards, the hydrothermal treatment was repeated once, to grow an additional GDC layer. This post-grown GDC was then co-sintered with the screen printed LSCF cathode at 1075 ℃.Results show that, the GDC/YSZ bilayer electrolyte is successfully fabricated under low sintering temperature below 1200 ℃, with overall GDC layer as thick as ~540 nm and ultra-high density as the YSZ electrolyte. The single cell with 1200 ℃ sintered GDC, named as GDC-1200, shows the best output performance, i.e. maximum power density of ~0.96 W/cm2 at 780 ℃. Moreover, the cell runs stably at 720 ℃ for 300 hours, showing decent durability.Fig. 1 (a) j-V-P curves of bilayer electrolyte SOFCs with varied GDC sintering temperature; (b) operation voltage versus time for GDC-1200 cell under constant current mode; (c) SEM images and (d) EDS mapping of single cell (GDC-1200) fracture Figure 1

Effect of Y and Gd solutes on grain refinement of the as-extruded Mg-Gd(-Y)-Zn-Mn alloys

Mg alloys exhibit high Hall-Petch coefficients, so obtaining refined grains in wrought alloys is important for their high performance. This study explored the roles of Y and Gd solutes on grain refinement of the Mg-(1.25–2.5)Gd-(0–1.25)Y-0.5Zn-0.4Mn(at%) extruded alloys, and the mechanical properties were tested. Microstructural analyses show that incomplete dynamic recrystallization (DRX) occurred after hot extrusion of Mg-Gd(-Y)-Zn-Mn alloys and DRX behaviors varied with Y and Gd contents. The addition of Y or an increase in Y/Gd atomic ratio (by partially substituting Gd with Y) resulted in a reduction of the average DRXed grain size, while adding Gd (or Y) or decreasing the Y/Gd atomic ratio facilitated DRX nucleation. Mechanical properties demonstrate that the joint alloying of two RE elements, Y and Gd, enhanced the experimented alloys’ strength surpassing the effect of using Gd alone. The Mg-2.5Gd-0.75Y-0.5Zn-0.4Mn(at%) extruded alloy displayed the optimal mechanical characteristics having a 402 MPa ultimate tensile strength, a 345 MPa yield strength, and 5.2% moderate ductility.

Effect of Gd solutes on the micromechanical response of twinning and detwinning in Mg

An investigation of the effect of solutes on the migration of a single {101¯2} Gd decorated twin boundary in a Mg-4wt.% Gd binary alloy in terms of the corresponding stress-strain response and the defect structure in the wake of (de)twinning was undertaken in this work. The results were benchmarked against those of a pure Mg sample that was tested under same conditions. We established that the critical stresses for both twinning and detwinning increased by 29% and 10%, respectively, due to the addition of Gd. We showed that the latter is mediated by the pinning effect of Gd atoms that decorated the pre-existing twin boundaries in the alloy. Conversely, a 68% decrease in the detwinning stress was recorded in pure Mg. We attributed the decrease to the nucleation-free nature of detwinning along with the absence of solutes atoms at the pre-existing twin boundaries. Unlike previous investigations, the work does not just highlight how twinning and detwinning affects the concurrent slip activity in pure Mg and Mg alloys, it establishes a direct link between these activities and the magnitude of the observed mechanical response.

Anomalous Ferromagnetic Phase in the Gd1−xErxB4 Series: Crystal Growth, Thermal, and Magnetic Properties

Rare-earth tetraborides RB4 are of great interest due to the occurrence of geometric magnetic frustration and corresponding unusual magnetic properties. While the Gd3+ spins in GdB4 align along the ab plane, Er3+ spins in the isomorphic ErB4 are confined to the c–axis. The magnetization in the latter exhibits a plateau at the midpoint of the saturation magnetization. Therefore, solid solutions of (Gd, Er)B4 provide an excellent playground for exploring the intricate magnetic behavior in these compounds. Single crystals of Gd1−xErxB4 (x = 0, 0.2, and 0.4) were grown in aluminum flux. X-ray diffraction scans revealed single-phase materials, and a drop in the unit cell volume with increasing Er content, suggesting the partial substitution of Er at the Gd sites. Heat capacity measurements indicated a systematic decrease of the Néel temperature (TN) with increasing Er content. The effective magnetic moment determined from the magnetization measurement agreed with the calculated free ion values for Gd3+ and Er3+, providing further evidence for the successful substitution of Er for Gd. The partial substitution resulted in an anomalous ferromagnetic phase below TN, exhibiting significant anisotropy, predominantly along the c-axis. This intriguing behavior merits further studies of the magnetism in the Gd1−xErxB4 borides.

First Demonstration of Compton Camera Used for X-Ray Fluorescence Imaging.

X-ray fluorescence computed tomography (XFCT) is a promising approach used for obtaining the distribution of high-Z elements in the target object. The characteristic energy of X-ray fluorescence (XRF) photons makes XFCT have higher sensitivity and contrast ratio. Conventional XFCT systems usually require mechanical collimators, which leads to a huge loss of incident photons and reduce photon collection efficiency. The Compton camera is an imaging modality that uses electronic collimation to obtain the incident direction of the photons, which brings advantages in the detection area and X-ray photon collection efficiency. Compton cameras can also achieve three-dimensional (3D) imaging with one or several views of scanning without rotation. Therefore, it is a good idea to realize XRF imaging by using Compton cameras, which may provide more potential applications and imaging possibilities, such as handheld XRF imaging or image-guided interventional operation. In this work, we demonstrate the first Compton camera platform which is used for XRF imaging. The proposed X-ray fluorescence Compton camera (XFCC) mainly consists of a conventional X-ray tube (150kVp) and a Timepix3 photon-counting detector (PCD). A PMMA phantom with insertions containing different concentrations of 4%, 6%, 8%, and 10% (weight/volume) Gd solution is scanned by a fan-beam X-ray. Besides, a Compton camera-based X-ray fluorescence imaging reconstruction method (CCFIRM) is developed to solve specific problems in XFCC reconstruction. The reconstruction images and the quantitative analyses of the contrast-to-noise ratio (CNR) are presented. The results indicate that the detectability limit of the proposed XFCC platform is 3.5139 wt.% (CNR =4 ).

The Performance of the Two-Seeded GdBCO Superconductor Bulk with the Buffer by the Modified TSMG Method.

The multiseeding technique is a method to grow large-sized REBa2Cu3O7-δ (REBCO, where RE is a rare earth element) high temperature superconducting bulks. However, due to the existence of grain boundaries between seed crystals, the superconducting properties of bulks are not always better than those of single grain bulks. In order to improve the superconducting properties caused by grain boundaries, we introduced buffer layers with a diameter of 6 mm in the growth of GdBCO bulks. Using the modified top-seeded melt texture growth method (TSMG), that is, YBa2Cu3O7-δ (Y123) as the liquid phase source, two GdBCO superconducting bulks with buffer layers with a diameter of 25 mm and a thickness of 12 mm were successfully prepared. The seed crystal arrangement of two GdBCO bulks with a distance of 12 mm were (100/100) and (110/110), respectively. The trapped field of the GdBCO superconductor bulks exhibited two peaks. The maximum peaks of superconductor bulk SA (100/100) were 0.30 T and 0.23 T, and the maximum peaks of superconductor bulk SB (110/110) were 0.35 T and 0.29 T. The critical transition temperature remained between 94 K and 96 K, with superior superconducting properties. The maximum JC, self-field of SA appeared in specimen b5, which was 4.5 × 104 A/cm2. Compared with SA, the JC value of SB had obvious advantages in a low magnetic field, medium magnetic field and high magnetic field. The maximum JC, self-field value appeared in specimen b2, which was 4.65 × 104 A/cm2. At the same time, it showed an obvious second peak effect, which was attributed to Gd/Ba substitution. Liquid phase source Y123 increased the concentration of the Gd solute dissolved from Gd211 particles, reduced the size of Gd211 particles and optimized JC. For SA and SB under the joint action of the buffer and the Y123 liquid source, except for the contribution of Gd211 particles to be the magnetic flux pinning center with the improvement of JC, the pores also played a positive role in improving the local JC. More residual melts and impurity phases were observed in SA than in SB, which had a negative impact on the superconducting properties. Thus, SB exhibited a better trapped field and JC.

Microstructural characterisation and mechanical properties of the cast Gd-containing Mg−8Mg2Si in situ composites

Cast Mg–8 wt% Mg2Si in situ composites containing 0, 0.5, 1, 2 and 3 wt% Gd were studied for their microstructure and high-temperature behaviour. Mechanical properties of the composites were investigated in the temperature range 25–250°C. Gd addition resulted in the modification of the primary Mg2Si particles, reduction of their average size and volume fraction, and formation of new Mg3Si2Gd2 and Mg5SiGd intermetallic phases and solid solution of Gd in the Mg matrix. The composite with 1% Gd addition showed the highest strength due to the presence of finer Mg2Si particles with polygonal morphology. Higher Gd contents decreased the strength, due to the coarsening of the Mg2Si particles, caused by the over-modification effect of Gd.

The influence of gadolinium concentration on the twin propagation rate in magnesium alloys

Ultra-high-speed camera (UHSC) imaging was used for the study of the influence of gadolinium (Gd) content on the longitudinal growth of twins in Mg-Gd binary alloys. The results clearly indicate that the twin propagation rate is of the order of 101 m/s and slows down with increasing Gd concentration. Concurrent molecular dynamics (MD) simulations reveal that the presence of Gd atoms enhances the formation of stacking faults (SFs), which hinder twin propagation as effectively as twin boundary pinning by Gd solutes. As a result, the twin tip exhibits intermittent motion at the microscopic level.

Creep Behavior of Squeeze-Cast Mg–15Gd Alloy

The creep behavior of a binary Mg-15 wt.% Gd alloy was investigated over the temperature range from 523 K to 743 K, i.e., in both the single-phase region (the hexagonal close-packed solid solution of Gd in Mg) and the two-phase region (the solid solution plus Mg5Gd precipitates). The alloy was prepared by the squeeze casting technique. In the higher temperature range, at 723 and 743 K, the specimens were solution treated by in situ annealing prior to testing. At the temperature of 673 K and below, the alloy was tested in the cast state. In the higher temperature range, the behavior was interpreted in terms of the viscous glide, where the dislocation motion was constrained by the presence of solute atmospheres. The dislocation motion was controlled by the rate of the cross slip from the basal to the prismatic planes. At the temperatures of 623 K and 673 K, the creep behavior was rationalized by introducing the threshold stress concept. At the temperatures of 523 K and 573 K, the stresses required to achieve experimentally measurable creep rates were such that dislocations broke away from the atmospheres of foreign atoms. Comparison with a series of magnesium alloys prepared by squeeze casting and creep-tested by the same technique showed that gadolinium can be a favorable creep-resistance enhancing element.

Full-field in vivo imaging of nanoparticles using benchtop cone-beam XFCT system with pixelated photon counting detector

Objective. X-ray fluorescence computed tomography (XFCT) is a promising noninvasive technique for in vivo imaging of high-Z elements (e.g. gadolinium (Gd) or gold (Au)). In this study we upgraded our experimental XFCT system using a flat panel photon counting detector with redesigned pinhole collimation in order to achieve 3D XFCT images during one scan. Approach. Aiming at the characteristics of pinhole-collimated cone-beam XFCT imaging, a new scatter correction algorithm was proposed to estimate the normalized spectrum of scatter background based on K–N formula and realize correction by a weighted least squares method. Then, images were quantitatively reconstructed by a maximum likelihood iterative algorithm with the attenuation correction. Main results. The potential on full-field in vivo XFCT imaging of this new system was investigated. An imaging experiment of a PMMA phantom with the diameter of 35 mm was carried out for quantitative evaluation of the system performance. Results show that 2 mg ml−1 Gd solutions can be successfully reconstructed with a 45 min cone-beam XFCT scan. In vivo XFCT imaging experiments of mice with injection of Gd nanoparticles (GdNPs) were also performed and demonstrated in this paper. A mouse was injected through the tail vein with 20 mg ml−1 NaGdF4 solution and then anesthetized with isoflurane during the cone-beam XFCT scan. Significance. The distribution of the GdNPs inside the mouse can be well reconstructed so that the deposition of NPs in vivo can be clearly observed, which indicates the feasibility of the proposed system for full-field XFCT of small animals and further potential in relevant in vivo research.

Role of strain rate in phase stability and deformation mechanism of non-equiatomic Fe38-xMn30Co15Cr15Ni2Gdx high-entropy alloy

Excellent combination of strength and ductility makes metastable high entropy alloys (HEAs) stand out from multi-principal elements alloys. In this study, micro-alloying Gd element is effectively solid solutionized in metastable single FCC phase FeMnCoCrNi HEA system, to bring the FCC phase stability decreased that causes a pronounced FCC → HCP phase transformation during compression. In order to decouple the temperature effect from the influence of dynamic strain rate on phase transformation, a wide strain rate range is adopted from 10 −3 –10 −1 s −1 to 1000–5000 s −1 . The results show that the increased strain rate and adiabatic temperature rise both can restrain the phase transformation. Under low strain rates (10 −3 –10 −1 s −1 ), phase transformation is activated in all tested samples and gradually suppressed with the increase of strain rates, because the rate-induced shear bands inhibit the growth of the HCP phase. The reduction of strain hardening during phase transformation is related to the increase of local thermal activation volume due to disentangling of dislocations. Under dynamic strain rates (1000–5000 s −1 ), the phase transformation is completely substituted by deformation twinning due to the significant adiabatic temperature rise. The present work provides insights into the influence of strain rate on phase stability and deformation mechanism in a wide strain rate range. • Solid solution of Gd decreases the FCC phase stability bringing pronounced FCC → HCP phase transformation during quasi-state compression. • Phase transformation related dislocation dissociation enlarges the thermally activated volume causing the decrease in strain hardening rate. • Under low strain rates (10 −3 –10 −1 s −1 ), the increased strain rates activate shear bands earlier that hinder the growth of the HCP phase, it is a rate-related effect on phase transformation. • Under high strain rates (1000–5000 s −1 ), adiabatic temperature rise enhances the phase stability which is a thermo-related effect, co-works with the rate-related effect, making the phase transformation completely suppressed.

Emission characteristics of gadolinium ions in a water Cherenkov detector

Abstract To observe supernova relic neutrino events, 13 tons of gadolinium sulfate octahydrate (Gd2(SO4)3·8H2O), corresponding to 0.01% Gd solution, was dissolved in the Super-Kamiokande water Cherenkov detector in 2020. The aim is to improve the detection efficiency of neutrons from inverse β decay involving electron antineutrinos. However, Gd3+ ions can be excited by the Cherenkov light from cosmic muons, and the subsequent emission at 312 nm is a possible background (BG) source for Cherenkov signal detection. In this work, we constructed an experimental setup based on time-resolved laser-induced luminescence spectroscopy to investigate the emission characteristics of Gd3+ ions in water. The excitation laser wavelength was tuned in the range of 245–255 nm, and large resonant peaks were observed at 246.2 nm and 252.3 nm with measured emission lifetimes of around 3 ms. Good linearity was observed between Gd concentration and emission intensity for these two wavelengths, indicating that our setup is useful for remote monitoring of Gd concentration. According to the simulation results using our spectroscopic data and reference values, the Gd3+ emission BG rate from cosmic muons is expected to be 10−1 counts/μs or less, which seems small but not negligible.

Effects of deformation temperatures on microstructures, aging behaviors and mechanical properties of Mg-Gd-Er-Zr alloys fabricated by hard-plate rolling

In this investigation, a high-strength Mg-12Gd-1.0Er-0.5Zr (wt.%) alloy sheet was produced by hot extrusion (HE) and subsequent hard-plate rolling (HPR) at different temperatures. The results indicate that the microstructures of these final-rolled sheets are inhomogeneous, mainly including coarse deformed grains and dynamic recrystallized (DRXed) grains, and the volume fraction of these coarse deformed grains increases as the rolling temperature increases. Thus, more DRXed grains can be found in R-385 °C sheet, resulting in a smaller average grain size and weaker basal texture, while the biggest grains and the highest strong basal texture are present in R-450 °C sheet. Amounts of dynamic precipitation of β phases which are mainly determined by the rolling temperature are present in these sheets, and its precipitation can consume the content of Gd solutes in the matrix. As a result, the lowest number density of β phase in R-450 °C sheet is beneficial to modify the age hardening response. Thus, the R-450 °C sheet displays the best age hardening response because of a severe traditional precipitation of β' (more) and βΗ /βΜ (less) precipitates, resulting in a sharp improvement in strength, i.e. ultimate tensile strength (UTS) of ∼ 518 ± 17 MPa and yield strength (YS) of ∼ 438±18 MPa. However, the elongation (EL) of this sheet reduces greatly, and its value is ∼ 2.7 ± 0.3%. By contrasting, the EL of the peak-aging R-385 °C sheet keeps better, changing from ∼ 4.9 ± 1.2% to ∼ 4.8 ± 1.4% due to a novel dislocation-induced chain-like precipitate which is helpful to keep good balance between strength and ductility.