ABSTRACTThe majority of the water on Earth roughly 97% is contaminated or salty, only 3% is fresh water, and only 1% of pure water is easily available for human use. In rural areas and remote locations suffering from pure drinking water scarcity.Water purification techniques are generally dependent on electricity, which relies on coal and gas plants, these poses a risk to the environment and society. Solar desalination is being recognized as the most practical way to deal with the scarcity of pure drinking water in all aspects of sustainable development. This paper describes the creation of a single slope solar still (SSSS) using opaque and crystal‐clear toughened glass with a thickness of 6 mm as a cover and also another setup of a single slope phase change material (PCM)‐based solar still (MSSSS). In this paper, a flat plate solar collector coupled with water heater is used to enhance the productivity of still. In this study, an experimental model has been developed to experimentally analyze exercise productivity performance of SSSS and MSSSS of MMIT Kushinagar, India on April 10, 2023 to April 15, 2023. Combination of stearic acid, lauric acid, and paraffin wax combined with CuO (nanoadditive) is used to enhance the solar still productivity. Also, basin temperature for different PCM's such as paraffin wax, lauric acid, and stearic acid are compared. Different combinations of PCM's and nanoadditives are compared to find the better productivity. It is observed that maximum output is obtained at 3:00 p.m. afternoon on experimental setup. Paraffin wax, stearic acid, and lauric acid still increases productivity by 38.8%, 20.3%, and 30.5%, respectively, when compared to simple solar still. On experimentation of various combinations, it is found that the use of PCM paraffin wax and nanoadditives CuO gives 55% better productivity compared to other combinations. This innovative system is suitable and ideal for desalinating water in isolated and rural locations with low traffic and limited demand.