The electrical properties of soil at low radio-frequencies are important for engineering applications. In this work the effects of excitation frequency (42 Hz-1 MHz) as well as soil characteristics and conditions on the electrical properties of soil are experimentally investigated using remolded soil samples. Several sandy soils were tested with variable water content (dry up to saturation) using guarded two-electrode arrangements. A method is proposed based on the Nyquist plot to estimate the critical frequency above which measurements of the electrical properties of wet soil are free from electrode polarization effects. The latter result in extremely high real permittivity values, which do not correspond to the response of soil. The critical frequency is higher for smaller grain size and higher water content and varies according to a power law with soil power-frequency conductivity. The real and (effective) imaginary relative permittivity decrease with increasing frequency whereas the effective conductivity increases; this is attributed to the distributed relaxation of the interfacial polarization mechanism associated with the particulate nature of soil. The values of soil electrical properties increase with increasing water content and decreasing grain size (increasing specific surface) as a consequence of enhanced polarization and conduction phenomena. The effective imaginary permittivity varies with frequency according to a power law with an exponent approximately −1; the multiplier coefficient of this law expresses losses and has been formulated as a function of the degree of saturation and soil specific surface.