Site U1313 Research Articles

Bifurcation of mantle plumes by interaction with stagnant slabs in the mantle transition zone: Evidence from late Cenozoic basalts within Southeast Asia

Mantle plumes can encounter stagnant slabs in the mantle transition zone (MTZ) during their ascent from the lower mantle to Earth’s surface. However, the interactions between stagnant slabs and mantle plumes remain poorly understood. This study presents new data on the spatial thermal−lithological−chemical heterogeneity in the mantle over a vast area of Southeast Asia that reflects the variable influence of a late Cenozoic mantle plume. Site U1433 of International Ocean Discovery Program (IODP) Expedition 349 in the southwest sub-basin of the South China Sea (SCS) is located near the center of this seismically imaged mantle upwelling. This area also contains mid-ocean ridge basalt (MORB) derived from a peridotite-dominated and normal temperature mantle source with a depleted Nd-Hf and enriched 207Pb/206Pb isotopic composition. In contrast, MORB from Site U1431 of IODP Expedition 349 within the eastern sub-basin of the SCS and other intraplate basalts from the Hainan-Leizhou area, the eastern Indochina block, and elsewhere in the SCS are dominantly sourced from higher temperature pyroxenite-enriched mantle material that records mantle plume activity. These observations are in contrast with previous models involving a single plume rising from the lower mantle beneath the SCS that then tilted toward Hainan Island, China. Instead, it is likely that the observations from this region are indicative of plume-stagnant slab interaction. The shallow upper mantle beneath Site U1433 has not been influenced by a mantle plume as the presence of stagnant slabs within the MTZ prevented further upwelling of the plume. In contrast, a mantle plume passed through the weaker MTZ within the eastern sub-basin and circum-SCS areas, allowing plume-related magmatism to occur. The bifurcation of a deep-rooted mantle plume by stagnant slabs in the MTZ produced a cluster of small mantle upwellings that ascended to shallow depths, consistent with new multiscale global tomographic data for Southeast Asia.

Planktonic foraminifera response to orbital and millennial-scale climate variability at the southern Iberian Margin (IODP Site U1385) during Marine Isotope Stages 20 and 19

The orbital configuration of Marine Isotope Stage (MIS) 19 provides a good analogue to our present interglacial, and it is marked by millennial-scale climate variability. To evaluate how orbital and millennial-scale climate changes interact during this interglacial we have conducted a high-resolution study of planktonic foraminifera assemblages at International Ocean Discovery Program (IODP) Site U1385, SW Iberian Margin, encompassing late MIS 20 and MIS 19. Estimates of sea surface temperature (SST), using transfer-functions, are compared with geochemical, XRF elemental data, biomarker and pollen records from the same site. These results are then compared with SST and ice-rafted debris records from North Atlantic IODP Site U1314 to reconstruct basin-wide palaeoceanographic conditions. During MIS 20, the large size of the ice sheets imparted a strong cooling in the subpolar gyre whereas the Iberian Margin remained under the influence of the subtropical gyre with the development of a high meridional thermal gradient in the North Atlantic. During MIS 20 terminal stadial (794–789 ka) and MIS 19b-a stadial events, the meltwater discharges related to the instability of ice sheets affected both the North Atlantic and the Iberian Margin leading to a weaker thermal gradient. Our data indicate that Termination IX (TIX, ∼795–788 ka) was punctuated by short-term warming/cooling phases in the ocean coupled with warming/cooling events on land. A short-term cooling episode, recognized in the ocean and on land, occurred on Termination IX and preceded the beginning of MIS 19c. During MIS 19c, the planktonic foraminifera SST indicates warm and almost stable conditions in the sea decoupling the cool and dry millennial-scale events on land inferred by pollen assemblages. Starting from 780 ka towards MIS 18, the planktonic foraminifera assemblages and SSTs indicate a cooling trend along the Iberian Margin related to a progressive southward migration of the polar front.

The source of Pleistocene carbonate below the CCD in the central basin of South China Sea: Evidences from coccolith and geochemistry

Carbonate dissolution and deposition in the deep ocean is a critical component of carbon cycle, but detailed pictures of carbonate dynamics below the Carbonate Compensation Depth (CCD) remains poorly understood. In this study, we present a ∼ 420 thousand years record of carbonate content below CCD in IODP Site U1433 at 4.4 km water depth in the South China Sea (SCS). Instead of carbonate-free sediment, we observed that the carbonate content in this deep site could reach as high as 40%. The dissolution-resistant biogenic carbonate, coccoliths, and stable isotope ratio of bulk carbonate were analyzed to trace the carbonate sources. The coccolith assemblage in IODP Site U1433 shows an unrealistic feature of high productivity, which indicates a lateral transport of coccoliths from the northern SCS to the central basin. Coccoliths' contribution to total carbonate was on average 30% and could be as high as ∼80%. Their contribution to carbonate increased at the expense of the dissolution of other biogenic carbonate, such as foraminifera, and decreased with the dilution of other terrestrial carbonate particles. According to the thickness of coccoliths, significant dissolution of coccoliths only happened when the carbonate content dropped below 3%. Marbles from Taiwan, with negative oxygen isotope ratios, and early diagenetic carbonates from carbonate platform nearby, with both negative carbon and oxygen isotope ratios, could be the other important sources besides the marine biogenic carbonate. With help of numerical simulations, we estimated that the lateral transport by turbidity currents could contribute up to 70–90% of the deep-sea sediment in the central basin of SCS. These new findings enrich our knowledge of the carbon fluxes from continental margins to the deep ocean as a key part of the carbon cycle.

Hydroclimatic conditions and sediment provenance in the northeastern Arabian Sea since the late Miocene: insights from geochemical and environmental magnetic records at IODP Site U1457 of the Laxmi Basin

AbstractPalaeo-monsoon and palaeoclimate conditions over Southeast Asia are a matter of debate despite notable studies on the continental and oceanic sedimentary record. The present study investigates the environmental magnetic and geochemical records preserved in the deep marine sediments of the northeastern (NE) Arabian Sea to elucidate the erosion history of the western Himalayas and its link with the prevailing hydroclimatic conditions since the late Miocene. For this, the sediment core retrieved during International Ocean Discovery Program (IODP) Expedition 355 at Site U1457 in the NE Arabian Sea has been explored. The results reveal that the hydroclimatic conditions were predominantly arid during the late Miocene, except for humid intervals from 6.1 Ma to 5.6 Ma. Humid climate conditions in the Indus River Basin returned during the mid-Pliocene and continued to the Pleistocene with an intense chemical weathering regime from 1.9 Ma to 1.2 Ma. The dominant sediment source to the NE Arabian Sea at Site U1457 during the late Miocene and the Pliocene was the Indus River, while during the Pleistocene, mixed sediments brought by the Indus River and the Peninsular Indian rivers were observed. The sediment contribution from a chemically less altered mafic source (the Deccan basalts) increased between 1.2 Ma and 0.2 Ma, possibly linked to a weak Indian Summer Monsoon. The summer monsoon wind strength and associated shift in the Inter-Tropical Convergence Zone (ITCZ) influenced the dominant sediment provenance at Site U1457 of the Laxmi Basin.

THE DISTRIBUTION RANGE OF CALCAREOUS NANNOFOSSIL SPECIES <em>RETICULOFENESTRA PSEUDOUMBILICUS</em> IN THE MIOCENE: AN EXAMPLE OF ECOLOGICAL INFLUENCE ON EVOLUTIONARY DEVELOPMENT

Reticulofenestra pseudoumbilicus is a Neogene calcareous nannofossil species whose highest stratigraphic occurrence (Top) is a reliable biohorizon in the Pliocene, calibrated at 3.82 Ma. The species is present in the stratigraphic record from at least the Middle Miocene, within an interval around the biohorizon Top Sphenolithus heteromorphus, calibrated at 13.53 Ma, but its lower distribution range is not precisely delineated. The study of nannofossil assemblages in sediment cores from Integrated Ocean Drilling Program IODP Site U1338 (eastern equatorial Pacific) indicates a lower stratigraphic position for the evolutionary emergence (Base) of R. pseudoumbilicus, detected in the Early Miocene with an estimated age of 16.46 Ma. This age results from a new astronomically tuned chronology, which dates the deepest sediments at Site U1338 to 16.67 Ma. Base R. pseudoumbilicus is followed above by a temporary disappearance of the taxon until a re-entrance after ~3 Myr. This lengthened stratigraphic range has been confirmed by data from other locations at low and mid-latitudes in the Atlantic. The distribution range of R. pseudoumbilicus, lasting ~13 Myr during the Neogene, is thus characterized by a variable pattern of repeated occurrences and disappearances. Comparison to benthic foraminifera δ18O and δ13C records suggests a control by global climatic/environmental conditions on these events, particularly by temperature variations. The recurrent presence of R. pseudoumbilicus at stratigraphically different intervals could represent an example of iterative evolution, expressed as repeated speciation events that are in part influenced by complex external factors related to the dynamic climate and environmental evolution during the Miocene.

Rock physics characteristics of marine sediments in the South China sea: The link between the geological factors and elastic properties

Understanding the geological factors behind the physical and elastic properties of marine sediments and unconsolidated rock is essential for the interpretation of geophysical measurements, hazard assessment, and ocean engineering applications. Core and well logging data from the six drilling sites of the Ocean Drilling Program/International Ocean Discovery Program (ODP/IODP) were used to analyze the rock physical characteristics in the South China sea. The depositional environment plays a significant role in affecting the physical properties of marine sediments. The sediments deposited under shallow water conditions show a higher velocity than the basin, slope, and deeper shelf carbonate deposits. Moreover, the non-depositional hiatus along the Oligocene-Miocene boundary displays a notable control on the variation of rock physical properties. It is found that the lithofacies and physical compaction remarkably influence the elastic characteristics of P-impedance and Vp/Vs ratio. The calcareous-rich sediment and ooze have very low P-impedance and high Vp/Vs ratio, whereas the siltstone and coarse sand present high P-impedance and low Vp/Vs ratio characteristics. With the enhancement of the consolidation degree, the Vp/Vs ratio significantly decreases from 6 to less than 2, suggesting that the shear wave velocity is highly sensitive to physical compactions. The basalt at site U1431 is considerably lower in its P-wave velocity than that at the site of U1433, which is probably caused by the intense fracturing occurring at the site of U1431 associated with different tectonic environments. We establish the link between geological factors and elastic characteristics of marine sediments of SCS, laying the foundation for characterizing depositional environments, lithofacies, and compaction degrees using geophysical measurements.

Paleomagnetic secular variation and revised chronostratigraphy of Bering sea (IODP Ex. 323) deep-sea sediments (MIS 1–4)

This study develops composite full-vector paleomagnetic secular variation (PSV) records from IODP Ex. 323 Sites U1339, U1343, U1344, and U1345 in the Bering Sea (51°N-60°N). These PSV records cover the last 71 ka (Marine Isotope Stages (MIS) 1–4). This is the first time that long PSV records have been recovered from such high latitudes. The records have been dated by oxygen isotope records and paleointensity correlations. The records have an age uncertainty of ∼1000 years. The paleomagnetic data come from shipboard paleomagnetic studies of deep-sea sediments with sediment accumulation rates of 20–40 cm/ky. The sample interval is 5 cm, with a time resolution of ±120–200 years. We have identified 66 correlatable inclination features and 59 declination features in all four sites. The relative paleointensity has been estimated by normalizing the natural remanence (after 20 mT af demagnetization) by magnetic susceptibility. This normalization process is strongly biased by environmental variability and so our relative paleointensity records are limited to correlating variability among the four sites. We can identify 8 key, dated paleointensity highs/lows in our composite records. There are two magnetic field excursions recorded reproducibly at these four sites – the Laschamp Excursion (∼41 ka) and the Norwegian-Greenland Sea Excursion (∼61 ka). Both occur quickly, in 1000 years or less, are associated with the lowest paleointensities, and show no significant evidence for pre- or post-excursion anomalous PSV. Both of these are Class I excursions. There are no excursional directions associated with the time interval of the Mono Lake Excursion (∼34 ka). We have carried out a statistical study using our PSV records to assess 3ky and 9ky average variability over the last 71 ky after removing all excursional directions. The averaged inclinations and declinations have correlatable variability, mostly on ∼104 yr time scales. We see significant variation in averaged angular dispersion that appears to be bimodal. Most time is spent with low angular dispersion (∼10°–12°) with shorter time intervals with significantly higher angular dispersion (∼24–30°). This study suggests that excursions, high angular dispersion, and low paleointensities occur together. This may define a distinctive low-intensity (or low-energy) state to the geomagnetic field.

Coccolithophore paleoproductivity since the Last Glacial Maximum in the Atlantic Ocean: Relationship with calcification and preservation variability

Paleoproductivity, calcification and preservation patterns are presented from calcareous nannoplankton paleo-assemblages records covering the last ∼25 kyr retrieved from Integrated Ocean Drilling Program Sites U1385 (37°34.285′N; 10°7.562′W) and U1313 (41°0.0′N; 32°57.4′W), located respectively along the Western Iberian Margin and in the North Atlantic Ocean. The main aim of the study is to provide paleoceanographic and paleoclimatic analyses together with an investigation of changes in coccolithophore calcification processes occurring in response to climate variability from the Last Glacial Maximum up to the Holocene. Coccolithophore calcification was investigated by comparing variations in coccolith thickness and total coccolith calcite; at the same time dissolution/preservation indices were used to better understand the response of coccolithophores to changes in environmental parameters.In general, the increasing CO2 recorded during the last 25 kyr has a negative effect on calcification, resulting in a reduction of the different species size-normalized thicknesses at both sites. However, differences between the responses at the two latitudes studied are identified, in particular during the Heinrich Stadials; in contrast, during both Younger Dryas and Holocene intervals, the different size-normalized species thicknesses show consistent patterns at the two sites. During the Last Glacial Maximum the influence of subtropical waters due to Azores Current recirculation leads to a moderate productivity, initially at Site U1385 and later at Site U1313. At the same time, temperature influences the calcification at both sites. At Site U1385, the temperature is the main parameter affecting the paleoproductivity during Heinrich Stadial events; in addition, during Heinrich Stadial 1 alone, it also affects the calcification. At Site U1313 the calcification processes during Heinrich Stadial events are apparently hampered by an increasing water turbidity, caused by icebergs acting as ice rafted debris transporters, which affects light filtration in the water column. Light availability is an important calcification-influencing factor. At Site U1313 during Heinrich Stadial 1 and at the Last Glacial Maximum inception, dissolution, a consequence of increased CO2 solubility in the colder ice-age ocean, has a negative influence on calcification. Furthermore, at Site U1313, in contrast to Site U1385, the continually increasing CO2 concentration recorded during the Bølling-Allerød hampers both calcification and preservation.

The first appearance of Glacial North Atlantic Intermediate Water (GNAIW) during the Mid-Pleistocene transition

The Mid-Pleistocene Transition (MPT) is arguably the most prominent shift in the Earth's climate system during the entire Pleistocene. It is characterized by a shift from a ∼ 40 kyr to a ∼ 100 kyr glacial cyclicity, going in hand with considerable growth of glacial continental ice-sheets. In search for potential drivers of these changes in the cryosphere, a slow-down of deep ocean circulation has been proposed as an important factor that might have reduced the atmospheric pCO2 level and thus created boundary conditions favourable for pertaining large ice-sheets. Additionally, as argued for the Last Glacial Maximum, enhanced production of intermediate waters might enhance intermediate to deep oceanic stratification and thus suppress CO2 release from the deep ocean and thereby reduce atmospheric greenhouse gas concentrations. To investigate potential changes in the North Atlantic intermediate water-mass configuration across the MPT we utilize δ18O and δ13C records obtained on the deep thermocline-dwelling foraminifera Globorotalia crassaformis from mid-latitude International Ocean Discovery Program (IODP) Site U1313. In conjunction with benthic and planktic δ18O and δ13C data from reference sites for Labrador Sea Water (IODP Site U1305) and intermediate water formation in the north-eastern North Atlantic (Ocean Drilling Program Site 982) our data show that major changes in the production and dispersal of intermediate water masses took place across the MPT. In particular, we note a shoaling of glacial intermediate waters commencing with Marine Isotope Stage (MIS) 22, which we interpret as the first occurrence of Glacial North Atlantic Intermediate Water, a prominent constituent of Late Pleistocene glacial water masses in the Atlantic Ocean. We further infer that the amount and vertical position of the warm and saline Mediterranean Outflow Water (MOW) had a major impact on the spatial configuration of North Atlantic intermediate water masses during the MPT, due to its capacity to modulate subsurface heat transport and isopycnal configuration. Our new findings thus provide evidence for a so far underestimated role of intermediate water circulation in shaping oceanic and potentially atmospheric changes during the MPT.

Timing of Tectonic and Magmatic Events in the Philippine Sea Plate Since 50 Ma From High‐Resolution Magnetostratigraphy of IODP Site U1438

The Philippine Sea Plate in the West Pacific is a unique natural laboratory to study subduction dynamics and the evolution of upper plate magmatism following subduction initiation. To investigate these processes, International Ocean Discovery Program Expedition 351 recovered at Site U1438, located in a rear-arc position, a complete sedimentary sequence from recent age to the early Eocene and the top of the underlying volcanic basement. The recovered cores offered the opportunity to study for the first time and in unprecedented detail the styles, products, and timing of the volcanic events that marked the emplacement, growth, and demise of the Kyushu-Palau volcanic arc following the inception of the Izu-Bonin-Mariana subduction. Here, we report a magnetostratigraphy for Site U1438 based on ∼60,000 remanence directions isolated from 1,063 archive half core sections and 429 discrete specimens. We identified 142 magnetic reversals and correlated 115 of them with the geomagnetic polarity timescale. When combined with additional biostratigraphic and geochronological constraints, our magnetostratigraphy allowed construction of a high-resolution age model for Site U1438 and the determination of changes in sedimentation rates. We show that following subduction initiation at 52–50 Ma and the emplacement of basalts in the rear-arc at 48.7 Ma, a diffuse volcanism in the rear-arc (48.4–45.6 Ma) preceded the true emplacement of the Kyushu-Palau arc at 40.2 Ma, which then grew through four compositionally distinct eruptive phases until 28.8 Ma. Subsequent rollback of the Pacific slab triggered rifting of the arc (28.8–24.3 Ma) and ultimately back-arc spreading in the Shikoku and Parece Vela basins.

High resolution benthic foraminiferal δ18O and δ13C records at ODP site 807 over the past 5 Ma, Ontong Java Plateau: Evolution of North Pacific ventilation, Pliocene to Holocene

The western equatorial Pacific is pivotal to precisely understand the global climate change and its evolution over geological time. However, continuous paleoceanographic records with high time resolution and accurate age model over the last 5 Myr are few in this important ocean region. Here, we present a high time resolution (2–3 kyr) benthic foraminiferal δ 18 O and δ 13 C record from Ocean Drilling Program Site 807 on Ontong Java Plateau in the western equatorial Pacific and establish an accurate age model for the past 5.025 Myr. Comparison of the benthic δ 13 C records from the west and east equatorial Pacific, and the North and South Pacific indicates that water aging effects have dominated since the Pliocene. From 4.0 Ma to 2.7 Ma, a rapid decrease in benthic δ 13 C gradients (Δδ 13 C W-E ) between the west (Hole 807A) and east (ODP Site 849 and IODP Site U1338) equatorial Pacific potentially resulted from strong ventilation in the North Pacific during the warm Pliocene. The subsequent gentle decrease in benthic δ 13 C gradients might indicate stratification in the North Pacific and reduction of biogenic flux with the intensification of the Northern Hemisphere Glaciation (NHG) at 2.7 Ma. Both the Δδ 18 O W-E and Δδ 13 C W-E are strongly paced by 405 ka long eccentricity cycles and 41 kyr obliquity cycle, revealing the complex interplay of both high and low latitude climatic processes on deep Pacific circulation changes. • Continuous 5 Myr long high time resolution benthic foraminiferal δ 18 O and δ 13 C records in the western equatorial Pacific. • West-east equatorial Pacific δ 13 C gradient indicates the evolution of the Pacific deep ocean circulation over the past 5 Myr. • 405-kyr eccentricity cycle modulates the Pacific deep ocean circulation changes.

Formation of calcium chloride brines in volcaniclastic-rich sediments

The Amami-Sankaku Basin, located in the Philippine Sea, records approximately 50 million years of sediment accumulation and diagenesis of volcanic ash derived from the Kyushu-Palau and Kyushu-Ryukyu arcs. Analyses of porewater and sediment samples from the 1461-m core recovered at IODP Expedition 351, Site U1438, included major and trace elements, strontium radiogenic isotope ratio (87Sr/86Sr), and taxonomic identification of archaeal classes and bacterial orders. Sediment X-ray diffraction and thin section analyses show that smectite, zeolites and chlorite are the main authigenic minerals. A multicomponent solute diffusion and reaction numerical model was developed to simulate the long-term diagenesis that took place in this sedimentary sequence and to account for the transition to a calcium chloride brine at about 670 mbsf. Numerical results indicate that 45% of the initial amount of volcanic ash has been dissolved at 750 mbsf. At this depth, 13% of the initial water (H2O) in the pore space is estimated to have been transferred to the solid phase by the formation of zeolites, which accounts for an increase in porewater chloride concentration. In contrast, dissolution of anorthite and volcanic ash combined with sodium uptake by zeolites accounts for the predominance of calcium in the brine. In the upper 160 m of the sedimentary column, the electrochemical migration of solutes causes chloride to move in the opposite direction of the concentration gradient, i.e., uphill diffusion, sustaining downward diffusion of seawater chloride into the sediments.

Climate and sea level forcing of terrigenous sediments input to the eastern Arabian Sea since the last glacial period

Analyses of mass accumulation rate (MAR), laser grain-size, clay mineralogy, and SrNd isotopic compositions of <2 μm and < 63 μm grain-size fractions have been applied to sediments from the International Ocean Discovery Program (IODP) Site U1456, which span the last 31 ka, in order to constrain (i) past changes in the relative proportions of the fine-grained detrital sediments derived from the Indus River and the Deccan Traps and the dynamics of sediment transport to the Laxmi Basin and (ii) past changes in Indian monsoon rainfall and latitudinal migration of Intertropical Convergence Zone since the last glacial period. Sr and Nd isotopes results combined with clay mineral assemblages suggest that clay-sized sediments at IODP Site U1456 derive mainly from the Indus River (70–90%), followed by a minor contribution from rivers draining the volcanic province of the Deccan Traps (10–30%). During the Last Glacial Maximum, clay mineralogy was dominated by illite and chlorite primarily derived from the highlands of the Indus River basin. The combination of lower temperatures and lower monsoonal rainfall during glacial times led to a reduction of smectite formation rates in the floodplains, while glacial erosion accelerated in the Himalayan and Tibetan highlands leading to the release of large quantities of illite and chlorite minerals into the Arabian Sea. In addition, glacial low sea-level stands allowed a connection between river mouths and the heads of deep-sea channels favoring the southward transfer of sediments to IODP Site U1456 by turbidity currents. Each maximum of the summer insolation curve, associated with a northward shift of the ITCZ and an intensification of summer monsoon rainfall (from 31 to 25 ka BP and from 12 to 8 cal ka BP), was associated with enhanced rainfall in the Indus floodplain which in turn led to an increase in the physical erosion and weathering of plain soils, which were rich in pedogenic minerals (such as smectite), and/or a higher production rate of smectite in the soils of the Indus floodplain. A compilation of three Nd isotopic composition records obtained at sites located on a N-S latitudinal transect in the eastern Arabian Sea have allowed us to establish the impact of sea level variations and latitudinal migration of the ITCZ over time on the sedimentation of the eastern Arabian Sea.

Constraints of barium isotopes on recycling of ancient oceanic crust in the mantle of the South China Sea

As surface reservoirs (e.g. sediments and altered oceanic crust) have extremely high barium (Ba) concentrations and distinctive Ba isotope compositions compared to the mantle, Ba isotopes have the potential to trace crustal recycling in the mantle. The sediment components and fluids derived from altered oceanic crust in arc lavas and continental basalts have been identified using Ba isotopes, while the geochemical behavior of Ba in subducted oceanic crust remains enigmatic. A series of volcanic breccia that temporally evolved from carbonated silicate clasts to alkali basalts in the South China Sea (SCS) drilled by the Integrated Ocean Discovery Program (IODP) Site U1431 was suggested to originate from the mantle source contaminated by recycled oceanic crust. To understand the potential of using Ba stable isotopes to trace recycled oceanic crust in the mantle, we report high-precision Ba isotope compositions of these samples, together with alkali basalts from adjacent Hainan Island to constrain the Ba isotope characteristics of the Hainan mantle plume. The carbonated silicate clasts and alkali basalts from the SCS display extremely high Ba concentrations and are thus insensitive to magma evolution during ascent through the thin lithospheric mantle and proper to trace crustal materials in their mantle source using Ba isotopes. These samples have variable Ba isotope compositions ranging from δ138/134Ba = −0.10 to +0.05‰, implying local mantle isotopic heterogeneity underlying the SCS. The Ba isotope characteristics of some samples, which are much lighter than those of the mantle-derived carbonatites and global mid-ocean ridge basalts (MORBs), in conjunction with trace element ratios and radiogenic isotope compositions, reflect significant incorporation of recycled carbonated oceanic crust after subduction-related dehydration. The rising of the Hainan mantle plume offers the most reasonable interpretation of the entrainment of the recycled oceanic crust in the carbonated silicate magmatism beneath the SCS. Alkali basalts from Hainan Island display Ba isotope characteristics slightly heavier than the SCS carbonated silicate clasts and alkali basalts. It implies that the Hainan mantle plume underlying Hainan Island contains less recycled-oceanic-crust components than that underneath the SCS. This study highlights Ba isotopes as effective tracers of recycled oceanic crust in the mantle.

Unusual δ26Mg values in oceanic crust basalts from the South China Sea

Abstract Whether or not oceanic crust basalts are affected by plate subduction is a hot topic of debate. The South China Sea is one of the largest marginal basins in the western Pacific Ocean and has been surrounded by subduction of the Pacific plate and Indian plate, yet, to date, no study has clearly shown evidence of subduction in the geochemistry of volcanism in the basin due to a lack of sampling of igneous crust basalts on the seafloor. The International Ocean Discovery Program Expedition 349 cored seafloor basalts near the fossil spreading ridges of the eastern (Site U1431) and southwestern (Site U1433 and U1434) subbasins in the South China Sea. The recovered basalt samples indicated a pyroxenite-bearing peridotite mantle source. Here, we report Mg isotopic data from 14 of these oceanic crust basalt samples. The δ26Mg values of most basalts from the three drill holes were higher (up to −0.10‰) than that of the average mantle (−0.25‰). The lack of correlations of δ26Mg with geochemical indices of magmatic processes (e.g., MgO, CaO/Al2O3, La/Sm, Nb/Zr) suggests that crystal fractionation and partial melting had insignificant effects on the Mg isotopic compositions of the South China Sea basalts. Thus, the variations in Mg isotopes were inherited from their mantle sources. Considering the highly varied Ce/Pb ratios and elevated 87Sr/86Sr values but mantle-like 143Nd/144Nd values, we propose that the varied δ26Mg values were likely caused by metasomatism of subduction-released fluids. The coupling of Mg and Sr-Fe isotopes provides robust evidence that the high-δ26Mg values of the South China Sea basalts resulted from mixing among pyroxenite-bearing peridotite mantle, the nearby Hainan plume materials, and subducting serpentinite-released fluids. Therefore, these Mg isotopes suggest that the mantle source of the South China Sea basalts was influenced by subducted materials, providing further evidence of the initial expansion, formation, and evolution of the South China Sea during plate subduction.

Long eccentricity forcing Asian dust input into the northwestern Pacific during the early Pleistocene

Asian dust deposition in the northwestern Pacific is generally linked to high-latitude paleoclimate evolution during the Quaternary. However, whether low-latitude tropical Pacific processes, such as El Niño-Southern Oscillation (ENSO), influence Asian dust input into the northwestern Pacific remains uncertain. Here, we present clear periodic variations in potassium content (K (wt%)) and gamma-ray attenuation (GRA) bulk density, which are closely linked to the variations in Asian dust, in a sediment core recovered at Site U1438 in the Amami Sankaku Basin (ASB), northwestern Philippine Sea. Based on the shipboard age-depth model, we tuned the GRA to the mass accumulation rate curve on the Chinese Loess Plateau and the 8-kyr-lagged obliquity curve, and established the astronomical timescale. The K (wt%) content and GRA were higher during glacials and lower during interglacials, as driven by the variability in the Northern Hemisphere ice sheet (NHIS) during the Quaternary. In addition, strong long eccentricity 405-kyr cycles were observed in the dust records (K (wt%) content and GRA) during the early Pleistocene. The 405-kyr filter results showed that increased (decreased) Asian dust corresponded to the La Niña-like (El Niño-like) state, suggesting that Asian dust input into the northwestern Pacific was modulated by ENSO on 405-kyr cycles in the early Pleistocene. Our study illustrated the possible link between long eccentricity 405-kyr cycles in the Asian interior and low-latitude forcing, including potential modulation by ENSO. • K (wt%) and GRA from Site U1438 are related to input of Asian dust. • Dust signals were used to reconstruct the orbital chronological model. • Dust signals have clear 405-kyr cycles during the early Pleistocene. • Long eccentricity forcing Asian dust input into the northwestern Pacific.

Geochemistry of mantle source during the initial expansion and its implications for the opening of the South China Sea

The South China Sea (SCS) is the largest extensional basin in the western Pacific. Due to the lack of sampling appropriate seafloor rocks, few studies focused on magma evolution in the initial expansion of the SCS, which limits the understanding of the tecto-magmatic evolution of the SCS. Here, we analyzed whole-rock Sr-Nd-Pb-Hf isotopic compositions as well as major and trace element concentrations of basalts recovered from the International Ocean Discovery Program (IODP) Expedition 367 Site U1500B in the northern margin of the SCS, which represents the early-stage formed oceanic crust. Combining with published oceanic crust basalts (e.g., IODP Expedition 349 Site U1431 in the eastern sub-basin, Sites U1433 and U1434 in the southwestern sub-basin) formed in the late spreading, the mantle nature and its evolution during the expansion of the SCS were evaluated. Although Sr-Nd-Pb-Hf isotope compositions of these basalts from the SCS suggest an Indian-type mid-ocean ridge basalts (MORB) mantle, the northern margin basalts from Site U1500B show moderate Pb isotopic compositions between those from the eastern and southwestern sub-basin, suggesting a heterogeneous mantle source beneath the SCS. Modeling calculations based on Sr-Nd-Pb-Hf isotopic compositions show that different amounts of lower continental crust and Hainan plume can account for the heterogeneity of such Indian-type MORB mantle in the SCS. The difference in the involved enriched components in the mantle source might be related to the periodic expansion of the SCS. Based on the geochemical imprints of Hainan plume on the SCS basalts that formed in the initial and late spreading stage, we propose that Hainan plume has a great effect in triggering the opening of the SCS.

Eocene relative paleointensity of the geomagnetic field from Integrated Ocean Drilling Program Site U1403 and U1408 sediments in the northwest Atlantic

Published relative paleointensity (RPI) records older than ∼3Ma are extremely limited in time and space. To develop a more robust understanding of RPI variations, we have conducted rock magnetic and paleomagnetic measurements on Eocene marine sediments recovered at Integrated Ocean Drilling Program (IODP) Sites U1403 and U1408 in the northwest Atlantic. A series of rock magnetic measurements indicate that the main remanence carrier is single domain biogenic magnetite. Paleomagnetic measurements yielded RPI records for Chrons C18–C21 and C22n, which correlates to ∼38.4–49.6Ma. The record is compromised in a few short intervals by inhomogeneous rock magnetic properties. RPI minima always occur at chron boundaries and RPI fluctuates between highs and lows within each chron. This record is the first to show that these characteristics persist at least since the onset of Chron C22n at ∼49.3Ma. We conclude that these are intrinsic and fundamental features of the geomagnetic field regardless of the polarity reversal rate. We produce a stacked RPI curve for Chron 18, named PIS-C18, on the basis of the RPI records obtained in this study and those from IODP Sites U1331 and U1332 in the equatorial Pacific that are matched by visual inspection. The PIS-C18 RPI of the stack is generally high with no prominent lows during Chron C18n.2n, whereas it is not as high and has several prominent lows almost equivalent to the RPI minima at the chron boundaries during Chrons C18n.1n and C18r. A histogram of RPI during Chron 18 is slightly skewed to the right, and the ratio of the standard deviation to the mean paleointensity is 0.38. These characteristics are similar to a histogram of the RPI stack for the last 1.5 million years. We interpret this to imply that character of the geodynamo for 104–106 years timescales has been unchanged since the Eocene.

Astronomical calibration of late middle Eocene radiolarian bioevents from ODP Site 1260 (equatorial Atlantic, Leg 207) and refinement of the global tropical radiolarian biozonation

Abstract. The middle Eocene sedimentary sequence drilled at Ocean Drilling Program Site 1260 (Leg 207), Demerara Rise, western equatorial Atlantic, yielded a rich and diverse radiolarian fauna. The exceptionally expanded and complete sedimentary record of this site, as well as the existence of an orbital chronological framework, allowed us to study a number of radiolarian bioevents with a very fine temporal resolution. We compiled a well-resolved succession of 71 radiolarian bioevents (first occurrences, last occurrences, and evolutionary transitions) and provided calibrations to the geomagnetic polarity timescale and astronomical timescale. Comparison of the radiolarian successions at ODP Site 1260A with the northwestern Atlantic IODP Site U1403 and the IODP Sites U1331, U1332, and 1333, situated in eastern equatorial Pacific, allowed the demonstration of the synchroneity of primary radiolarian bioevents that underpin the middle Eocene zonal scheme. Several secondary bioevents were also found to be synchronous between the two oceans and were therefore used to define seven new subzones for the low-latitudinal middle Eocene sequences: Siphocampe ? amygdala interval subzone (RP13a), Coccolarnacium periphaenoides interval subzone (RP13b), Artostrobus quadriporus interval subzone (RP14a), Sethochytris triconiscus interval subzone (RP14b), Podocyrtis (Podocyrtopsis) apeza interval subzone (RP14c), Artobotrys biaurita interval subzone (RP15a), and Thyrsocyrtis (Pentalocorys) krooni interval subzone (RP15b). This refined radiolarian biozonation has significantly improved stratigraphic resolution and age control for the late middle Eocene interval (an average of two subzones per 1.5 million years). A substantial diachronism was also found in 20 secondary radiolarian bioevents between the two oceans. The majority of radiolarian species appear to have evolved first in the equatorial Atlantic Ocean and subsequently in the equatorial Pacific. However, the reasons for this pattern of diachroneity currently remain uncertain and would require a greater sampling coverage to be elucidated.

Palaeoredox reconstruction in the eastern Arabian Sea since the late Miocene: Insights from trace elements and stable isotopes of molybdenum (δ98/95Mo) and tungsten (δ186/184W) at IODP Site U1457 of Laxmi Basin

The present study investigates the oxygenation history of the northeastern Arabian Sea since the late Miocene using redox sensitive elemental and metal stable isotopic signatures in the deep-sea sediments. To achieve this, the sediment core samples collected at Site U1457 (67°55.80′E, 17°9.95′N, water depth 3534 m) of Laxmi Basin in the northeastern Arabian Sea during the International Ocean Discovery Program (IODP) Expedition 355 were analysed for a suite of elemental (Mo, W, U, V, Ba, Cd and P) and stable molybdenum (Mo) isotope (δ 98/95 Mo relative to NIST SRM 3134 lot No. 130418) as well as stable tungsten (W) isotope (δ 186/184 W relative to NIST SRM 3163 lot No. 080331) composition. Sedimentary δ 98/95 Mo values (−0.70‰ to +1.18‰) at IODP Site U1457 in the northeastern Arabian Sea indicated partial authigenic Mo component. In contrast, the sedimentary δ 186/184 W values (−0.02‰ to +0.21‰) were in the range similar to that of lithogenous material suggesting dominance of detrital composition. The study reveals that the water column in the eastern Arabian Sea was oxic during the late Miocene and Pliocene while oxic to suboxic condition prevailed during the Pleistocene. The study also explores that under oxic to suboxic condition with limited particle shuttling, the W isotopes do not undergo significant fractionation, and their isotope ratios reflect the detrital source signature. This study reports the first results on isotopic compositions of Mo and W in sediments of the northeastern Arabian Sea since the late Miocene to investigate the palaeoredox conditions on a million-year time scale. • First results of δ 98/95 Mo and δ 186/184 W in the late Miocene Arabian Sea sediments. • Oxic condition during late Miocene & Pliocene, and suboxic during Pleistocene. • δ 98/95 Mo values (−0.70 to +1.18‰) exhibits partial authigenic component. • δ 186/184 W values (−0.02 to +0.21‰) exhibit dominant detrital control. • Under oxic setting with limited particle shuttling, tungsten isotopes do not fractionate.