Single Femtosecond Laser Pulse Research Articles

Coherent diffractive imaging of lipid vesicles and synaptic vesicles by femtosecond x-ray FEL pulses.

The structure of biological vesicles, in particular synaptic vesicles (SVs), as well as synthetic lipid model systems, in particular small unilamellar lipid vesicles (LVs) has been subject of abiding interest. Given the small size of both LVs and SVs (R≈20 nm), high spatial resolution is required to identify the distribution of lipids and protein constituents. Cryogenic electron microscopy studies of synaptic vesicles have revealed the outer and inner layer of proteins around the lipid bilayer. However, the samples have to be cryogenically fixed for this technique and throughput is limited. Another standard technique for structural characterization is solution small angle x-ray scattering (SAXS), which enables the measurement of vesicles in a quasi-physiological environment combined with a high spatial resolution. However, due to the average over an extremely large ensemble, SAXS yields information only about the average structure (size and electron density profile). The distribution function of structural parameters is not accessible, and many structural details are lost or screened by polydispersity, as well as by powder averaging. To overcome these limitations, we now have performed coherent diffractive imaging experiments on single vesicles using single femtosecond x-ray free electron laser (XFEL) pulses. For these measurements, single vesicles surrounded by a thin buffer layer are delivered into a nano-focused XFEL beam by an aerosol injector. By the ‘diffract-before-destroy’ principle, the individual vesicles can be probed without radiation damage. This approach leads to the measurement of thousands of diffraction patterns that can now be analyzed and reconstructed. The (preliminary) results of this analysis will be presented.

Structural dynamics of water in a supersonic shockwave

We explore the pressure evolution and structural dynamics of transient phase transitions in a microfluidic water jet after laser-induced dielectric breakdown. To this end, we use a combined approach of near-field holography with single femtosecond x-ray free-electron laser pulses and x-ray diffraction. During cavitation and jet breakup, we observe shock wave emission along the jet. The formation of the shockwave is accompanied by pronounced changes in the structure factor of water as an evidence by a shift in the water diffraction peak. This indicates a transition to a high density liquid structure induced by the transient pressure increase.

Raman Study of the Diamond to Graphite Transition Induced by the Single Femtosecond Laser Pulse on the (111) Face.

The use of the ultrafast pulse is the current trend in laser processing many materials, including diamonds. Recently, the orientation of the irradiated crystal face was shown to play a crucial role in the diamond to graphite transition process. Here, we develop this approach and explore the nanostructure of the sp2 phase, and the structural perfection of the graphite produced. The single pulse of the third harmonic of a Ti:sapphire laser (100 fs, 266 nm) was used to study the process of producing highly oriented graphite (HOG) layers on the (111) surface of a diamond monocrystal. The laser fluence dependence on ablated crater depth was analyzed, and three different regimes of laser-induced diamond graphitization are discussed, namely: nonablative graphitization, customary ablative graphitization, and bulk graphitization. The structure of the graphitized material was investigated by confocal Raman spectroscopy. A clear correlation was found between laser ablation regimes and sp2 phase structure. The main types of structural defects that disrupt the HOG formation both at low and high laser fluencies were determined by Raman spectroscopy. The patterns revealed give optimal laser fluence for the production of perfect graphite spots on the diamond surface.

Nanoscale morphology and thermal properties of low insertion loss fiber Bragg gratings produced using the phase mask technique and a single femtosecond laser pulse.

Fiber Bragg gratings with a very low insertion loss are inscribed using the phase mask technique and a single infrared (800 nm) femtosecond laser pulse. The morphology of the resultant light-induced structural changes in the Ge-doped silica fiber (SMF-28) is analyzed using scanning electron microscopy. The electron microscopy images reveal that each Bragg grating period incorporates an elongated micropore embedded in a region of homogeneous material modification. The Bragg wavelength drift and reflectivity of fiber Bragg gratings produced with single pulses having the same energy but different duration (80 fs and 350 fs) are monitored for 1000 hours in the course of isothermal annealing at 1000°C. The annealing data demonstrate that both the isothermal Bragg wavelength drift and the decrease in the reflectivity of the fiber Bragg gratings under test are statistically slower for the 350 fs inscription pulses.

Electrical detection and current control of all-optical magnetization switching in GdFeCo ferrimagnetic alloy thin film

We experimentally demonstrated electrical detection of all-optical magnetization switching (AOS) induced by a single femtosecond laser pulse irradiation by measuring alternate rapid changes in anomalous Hall voltage and magneto-optic image pulse by pulse in a Hall-cross shape ferrimagnetic GdFeCo alloy thin film. We also demonstrated that the amplitude of the change in anomalous Hall voltage depended on the position of the AOS-created magnetic domain on the Hall cross. Furthermore, the AOS-created magnetic domains were stable against subsequent current applications in the Hall cross circuit, whereas reversed magnetic domains were not created when the laser pulse was irradiated with a high current. We found that the cooperative effect among magnetism, light, and electric current was assumed to have effects on the absence of the AOS. Combining the AOS phenomenon and electrical measurement/control techniques can realize ultrafast, deterministic, and distinguishable applications.

Enhancing all-optical switching of magnetization by He ion irradiation

All-optical switching (AOS) of magnetization by a single femtosecond laser pulse in Co/Gd based synthetic ferrimagnets is the fastest magnetization switching process. On the other hand, He ion irradiation has become a promising tool for interface engineering of spintronic material platforms, giving rise to significant modification of magnetic properties. In this paper, we explore the use of He ion irradiation to enhance single pulse AOS of Co/Gd bilayer-based synthetic ferrimagnets. The intermixing of the constituent magnetic layers by He ion irradiation was both numerically simulated and experimentally verified. We theoretically modeled the effects of intermixing on AOS using the layered microscopic 3-temperature model and found that AOS is enhanced significantly by breaking the pristine Co/Gd interface through intermixing. Following this notion, we studied the threshold fluence of AOS as a function of He ion irradiation fluence. We found that the AOS threshold fluence can be reduced by almost 30%. Our study reveals the control of AOS by He ion irradiation, which opens up an industrially compatible approach for local AOS engineering.

Bridging atomistic spin dynamics methods and phenomenological models of single-pulse ultrafast switching in ferrimagnets

We bridge an essential knowledge gap on the understanding of all-optical ultrafast switching in ferrimagnets, namely, the connection between atomistic spin dynamics methods and macroscopic phenomenological models. All-optical switching of the magnetization occurs after the application of a single femtosecond laser pulse to specific ferrimagnetic compounds. This strong excitation puts the involved degrees of freedom, electrons, lattice, and spins out-of-equilibrium between each other. Atomistic spin models have quantitatively described all-optical switching in a wide range of experimental conditions, while having failed to provide a simple picture of the switching process. Phenomenological models are able to qualitatively describe the dynamics of the switching process. However, a unified theoretical framework is missing that describes the element-specific spin dynamics as atomistic spin models with the simplicity of phenomenology. Here, we bridge this gap and present an element-specific macrospin dynamical model which fully agrees with atomistic spin dynamics simulations and symmetry considerations of the phenomenological models.

Quasi-periodic micro-lens array via laser-assisted wet etching

A close-packed micro-lens array (MLA) is widely used not only in novel optical systems but also in various engineering fields, such as semiconductors and display devices. In this paper, we present a simple and efficient method for fabricating MLAs on a glass substrate via laser ablation with a single femtosecond laser pulse and chemical wet etching in a hydrofluoric acid solution. The shapes of concave micro-lenses were optimized for laser pulse energy and etching time, and ∼70 000 micro-lenses with 15 µm diameter were formed. The shape of the micro-lens varies significantly with respect to the etching time in accordance with an initial ablated area (or laser energy), which is a key feature in fabricating micro-lenses of several tens of μm. Using the glass MLA as a mold, a polydimethylsiloxane convex-plano lens array was replicated, and the performance of the optical imaging and beam integrator was then examined.

Femtosecond Laser Fabrication and Ultrafast Dynamics Study on FTO Film

Transparent conductive oxides (TCO) are widely used in optoelectronic devices due to their high visible light transmittance and high electrical conductivity. Fabricating micro-nano structures on TCO films with femtosecond lasers can further enhance their optoelectronic properties. However, most of the existing researches on femtosecond laser processing of TCO films focus on materials such as indium tin oxide (ITO) and ZnO, and the research on fluorine-doped tin oxide (FTO) is still insufficient. In this paper, the ablation rules of FTO film irradiated by femtosecond laser is studied in detail. When the fluence is reduced to 1/e2 of the peak value as the radius of the laser spot, the ablation threshold measured by epitaxy method is 1.27 J/cm2. The experiment explores the ablation morphology of FTO film irradiated by single femtosecond laser pulse. When the laser fluence is 2.8-8.3 J/cm2, a bowl-shaped micro-crater is ablated, and when the laser fluence is 9.6-23.4 J/cm2, a secondary crater with a vertical inner wall and a flat bottom generates in the center of the ablated bowl-shaped crater. The pump-probe technique was used to study the ultrafast dynamics of the femtosecond laser interaction with FTO film, and we found that the phase explosion was responsible for the bowl-shaped crater formation.

Investigation of structural transformation and residual stress under single femtosecond laser pulse irradiation of 4H–SiC

Silicon carbide (SiC) is an attractive semiconductor material for devices that operate under extreme conditions. However, its high hardness and chemical stability hinder micromachining. Femtosecond laser has been proposed extensively as an effective micromachining tool for SiC. However, the fundamental mechanisms of laser-material interaction during femtosecond laser irradiation process remain elusive. This paper presents a comprehensive study of the structural transformation and residual stress induced by irradiating a 4H–SiC target with a single-pulse femtosecond laser. The energy dependence of the structural characteristics at the spot center and the spatial distribution across the laser spot were determined using optical microscopy and micro-Raman spectroscopy. The effect of the laser fluence on the residual stress was discussed. The obtained results showed that no structural changes occurred at low energy, whereas bond breaking occurred among crystalline SiC (c-SiC) at high energy. A central disk with no structural transformation and no residual stress was formed for the fluence of 22.2 J/cm 2 , owing to phase explosion-induced spluttering. Meanwhile, an inhomogeneous distribution of the structural transformation was generated from the spot centre to the edge. Based on this, threshold fluences for modification and structural transformation were proposed and calculated. The fundamental mechanisms for different laser-fluence regimes are discussed, and some suggestions for improving the surface quality are put forward. This study provides deep insights into the laser-material interaction mechanisms and is beneficial for optimising the utilisation of femtosecond laser for 4H–SiC micromachining. • Structural characteristics and residual stress at the spot centre depend on laser energy. • Spatial distribution of structural transformation from the spot centre to the edge is inhomogeneous. • Threshold fluences for modification and structural transformation are proposed and calculated. • The fundamental mechanisms of laser-material interaction for different laser-fluence regimes are analysed. • The residual stress in central disk region vanishes for the laser fluence of 22.2 J/cm 2 , owing to explosive boiling.

High-speed microgroove processing of glass by expanding the high-temperature region formed by transient and selective laser absorption.

Microgroove processing of glass is important in many fields, however, it is difficult to achieve the processing with a high speed. In this study, we developed a novel method for the high-speed microgroove processing of glass using two types of lasers, namely a femtosecond laser and a near-infrared continuous-wave (CW) laser. A single femtosecond laser pulse was initially focused on the surface of the material, enabling the area to absorb the CW laser, which is otherwise not absorbed by the glass. The CW laser was then scanned along the material surface, expanding the machined hole to form a groove. The resulting grooves, with a width of approximately 10 µm and depths of up to 350 µm, can be machined with a scanning speed of up to 200 mm/s, 25 times faster than conventional methods. This method exhibits the potential to improve the industrial application of fast laser microprocessing of glass.

Femtosecond laser induced amorphization of quantum dots and application in three‐dimensional optical data storage

AbstractThe information burst in modern society poses new challenges to information preservation technology, both in storage efficiency, capacity, and security. Multi‐dimensional optical data storage based on the femtosecond laser direct writing technique is a promising way to face these challenges. Herein, a new optical storage method based on femtosecond laser‐induced local darkening of CdSe quantum dots doped glass is reported. Photoluminescence image and spectrum indicate that highly luminescent well‐crystallized CdSe quantum dots can be amorphized by a single femtosecond laser pulse and reconstructed by thermal treatment, resulting in reversible luminescence modulation, in which the luminous efficacy of CdSe quantum dots in glass matrix was well recovered after each cycle of writing and erasing. Complicated patterns written inside the glass and multi‐layer information are also successfully inscribed and well demonstrated. Data bit could be written by just one 380 fs single pulse with pulse energy as low as 100 nJ. The present work provides a potential way for three‐dimensional optical information storage and data encryption with low power consumption, fast writing speed, large capacity, and high security.

Slit Beam Shaping for Femtosecond Laser Point-by-Point Inscription of Highly Localized Fiber Bragg Grating

We propose and experimentally demonstrate a slit beam shaping method for femtosecond laser Point-by-Point (PbP) inscription of highly localized Fiber Bragg Gratings (FBGs). The influence of slit width on the shape and area of Refractive Index Modulation Region (RIMR) induced by a single femtosecond laser pulse was investigated. The shape of RIMR can be changed from a spot to a line with an enlarged RIMR, and hence enhances the coupling strength of core mode and cladding modes. The RIMRs were precisely assembled along the fiber core, producing highly localized FBGs with a spectral comb of pronounced Cladding Mode Resonances (CMRs) intensity of more than 30 dB, a wide wavelength span of 240 nm and a low insertion loss of 0.3 dB. Note that the total processing time for fabricating such a highly localized FBG only requires ∼3.7 s. Subsequently, by including tilted angle on the slit, highly localized tilted FBGs were fabricated and these FBGs show adjustable envelope on the CMRs. Moreover, we investigated the surrounding Refractive Index (RI) response and thermal characteristics of the fabricated highly localized FBGs, which exhibit a sensitivity of 510.87 nm/RIU in a wide RI measurement range and excellent high temperature resistance at 1000°C. Therefore, such highly localized FBGs could potentially be used for multi-parameter sensing in many extreme environments.

Classical Molecular Dynamics Simulations of Surface Modifications Triggered by a Femtosecond Laser Pulse

This work is devoted to classical molecular dynamics simulations of surface modifications (craters) drilled by single femtosecond laser pulses in silicon and diamond, materials relevant for numerous industrial applications. We propose a methodology paving the way towards a significant decrease in the simulation computational costs, which could also enable a precise estimation of the craters’ size and shape.

On/Off Ultra‐Short Spin Current for Single Pulse Magnetization Reversal in a Magnetic Memory Using VO2 Phase Transition

AbstractUltrafast magnetization reversal of magnetic thin films induced by one single femtosecond laser light pulse, without any applied magnetic nor electrical field, known as all‐optical switching has become one of the most attractive technologies for prospective ultrafast and low‐energy magnetic devices. A single femtosecond laser pulse switching of a ferromagnet in specific spin valves, driven by electron pulse originating from ultrafast demagnetization of a ferrimagnetic layer, has been recently demonstrated. This opens the way to ultrafast and energy‐efficient writing for magnetic memory. Here, a new functionality is presented through introducing a thin VO2 into the specific spin valve, where a switchable ultra‐short polarized electron pulse by thermally triggering the phase transition of VO2 to dynamically control the switching of the ferromagnet is experimentally achieved. It is demonstrated that the generated ultra‐short electron pulse can be free to pass through the VO2 in its metallic state while it is blocked in its insulating state. Additionally, the change on electrical and optical properties of VO2 during the phase transition leads to various possible magnetic states. On/off ultra‐short spin current controlled by phase transition paves the way to address specific ultra‐fast spintronic devices in large array devices.

Patterning the surface structure of transparent hard-brittle material β-Ga2O3 by ultrashort pulse laser

Femtosecond laser direct writing technology offers a powerful and advantageous tool for precise three-dimensional (3D) micro/nanofabrication of transparent hard and brittle materials. In this paper, micro-craters, micro/nano-rectangular columns, and microchannels structures with different spatial characteristics are achieved after irradiation of crystalline (100) β-Ga2O3 via an optical-fiber femtosecond laser (515/1030 nm, 285 fs, 100 kHz) with different processing parameters in air ambient. Laser scanning confocal microscope, atomic force microscopy, and Raman spectroscopy are employed to characterize the roughness and constitutive property of the surface structure under tightly focused laser conditions. The influences of different pulse numbers and different pulse energies on the morphology of the pits were investigated. Through precise control and optimization of processing parameters, the formation of cracks and chipping can be effectively avoided. Crack-free ablation holes with smooth edges were fabricated under low-energy (E = 22 nJ) single-pulse conditions. Furthermore, the effects of different laser processing parameters (single-pulse scanning interval, pulse number and scanning repetition times) on the microchannel morphology were also explored. From this work, high-precision micro-hole arrays, micro-nano rectangular column arrays, and microchannels were successfully fabricated on (100) β-Ga2O3 substrates. Due to the interaction of single-pulse femtosecond laser with β-Ga2O3 materials, this fast fabrication method of 3D submicron structures has potential applications in sensing, photonics, or electronics.

Ultrafast Modulation of the Molten Metal Surface Tension under Femtosecond Laser Irradiation

We predict ultrafast modulation of the pure molten metal surface stress fields under the irradiation of the single femtosecond laser pulse through the two-temperature model molecular-dynamics simulations. High-resolution and precision calculations are used to resolve the ultrafast laser-induced anisotropic relaxations of the pressure components on the time-scale comparable to the intrinsic liquid density relaxation time. The magnitudes of the dynamic surface tensions are found being modulated sharply within picoseconds after the irradiation, due to the development of the nanometer scale non-hydrostatic regime behind the exterior atomic layer of the liquid surfaces. The reported novel regulation mechanism of the liquid surface stress field and the dynamic surface tension hints at levitating the manipulation of liquid surfaces, such as ultrafast steering the surface directional transport and patterning.

Thermal impact on ultrafast helicity independent all-optical switching of GdxCo100-x

Ultrafast all-optical switching by single femtosecond laser pulse has recently been considered as one of the most potential technologies for the application on high-speed and energy efficient memory device. Here, to ensure such a sophisticated technology to be applicable to more complex environments, we report the dependence of all-optical switching of the ferrimagnet, GdCo, on the ambient temperature. Through heating the GdCo film up to 380 K, we demonstrate the distinct magnetic behaviours and the critical laser fluences of all-optical switching under different composition of Gd. It is found that the thermal stability for AOS will be significantly improved when there are more rare-earth elements, Gd in GdCo. This work provides a deep insight into the thermal effect on helicity independent all-optical switching and will optimize the application of ultrafast technology on the spintronic devices and magnetic memories.

Temporal-spatial characteristics of filament induced by a femtosecond laser pulse in transparent dielectrics.

The evolution mechanism of femtosecond laser-induced filaments has been widely investigated owing to its application prospects in microprocessing. However, the material dependence of the excitation, stability, and decay of filaments is not well understood despite the importance of their precise utilization. In this study, the spatiotemporal evolution of filaments induced by a single femtosecond laser pulse in sapphire and silica glass was investigated using time-resolved pump-probe shadowgraphy on femtosecond and picosecond timescales. The results revealed that the evolution was significantly different in the two typically transparent dielectrics in terms of the electronic plasma dynamics and filament lifetimes. This difference can be attributed to the self-trapped excitons (STEs) in silica glass. Furthermore, the filament dependence on pump energy and focal position was experimentally analyzed. Divergent filaments were observed when the focal position was near the surface because of the effect of the excited plasma on beam propagation. Moreover, the evolution of filament length in the two materials was discussed. This study contributes to the applications of filaments in precise processing.

Green wavelength femtosecond laser ablated copper surface

During green wavelength femtosecond laser ablation, d-band electrons are excited to become free and to participate in the absorption process. The increased electron temperature also induces the density of state shift and causes the gap between the d-band and the Fermi level to expand. The d-band electron transition effect during the laser ablation process causes nonlinear absorption, therefore, it should always be considered during simulations of laser-copper interaction.This study used a single femtosecond laser pulse with a wavelength of 515 nm and a pulse duration of 300 fs to ablate copper with fluence 0.7–63 J/cm2. The experimental results were compared with the theoretical results, where a modified Drude-critical point model was adopted to simulate the ablation depth. The modified model considered the electron transition effect and a two-temperature model that assumed both the linear and nonlinear absorption effect. Comparison of the experimental and simulated results revealed that the simulated ablation depth obtained using the nonlinear absorption model was consistent with the experimental results.