Silicone Matrices Research Articles

Dynamics of resonant magnetoelectric effect in a magnetoactive elastomer based cantilever: Magnetic field induced orientation transition and giant frequency tuning

Magnetoelectric (ME) effects in composite heterostructures containing mechanically coupled ferromagnetic and piezoelectric layers enable the mutual transformation of magnetic and electric fields and form the basis for the development of magnetic field sensors, actuators and energy harvesters. Promising materials for such composite structures are magnetoactive elastomers (MAE), which are silicone matrices with ferromagnetic particles uniformly distributed within them. The strong dependence of MAE properties on magnetic fields and their low rigidity enable contactless control of ME effects characteristics within such structures. In this work we have experimentally investigated the dynamics of resonant ME effects in a structure consisting of a MAE layer with carbonyl iron particles and a layer of polyvinylidene fluoride piezopolymer in a cantilever geometry. For the structure magnetized in a plane along the axis, the frequency tuning of the bending oscillations reached 360 % at the fields up to 2 kOe, and the maximum ME conversion coefficient was 1.74 V/(Oe·cm). For the structure magnetized perpendicular to the plane, an orientation transition was observed, which manifested itself as a jump-like bending of the structure to the angle up to ∼850 at magnetic field above the critical value. The frequency tuning by the magnetic field reached 185 %, and the maximum ME conversion coefficient was 135 V/(Oe·cm). A model has been developed that qualitatively describes the dynamics of ME effect in composite cantilever structures with a MAE layer for different orientations of the applied magnetic field.

Posterior composite resin restorations combined with stamping technique for increasing vertical dimension: a case report

This clinician's report addressed the crucial consideration of occlusion functionality in aesthetic and oral rehabilitation treatments, highlighting the need to restore the lost vertical dimension. The objective of the study was to evaluate the relevance of recovering the occlusal vertical dimension in aesthetic and rehabilitative treatments, and to determine the viability of composite resin restorations combined with the stamping technique as a restorative option. A comprehensive approach supported by accurate diagnosis and the application of a functional and aesthetic wax-up was proposed. The study focused on the use of posterior composite resin restorations with the stamping technique as a viable restorative alternative. The development and reliability of composite resins and their adhesive systems were highlighted, highlighting their key characteristics. The results obtained demonstrated notable longevity in the restorations, supporting a conservative approach that replicates anatomical details with precision using transparent silicone matrices. Additionally, the benefits of this technique in terms of time and cost efficiency were explored. In summary, this clinical case highlights the importance of implementing an appropriate treatment plan supported by solid clinical evidence. The use of posterior composite resin restorations with the stamping technique to raise the vertical dimension is revealed not only as an effective alternative in aesthetic terms, but also as a long-term sustainable option

The Impact of Liquid Components on Alteration of the Adhesion of Polyacrylate and Silicone Patches.

Polyacrylates and polysiloxanes are polymers used in pressure-sensitive adhesive (PSA) patches. Liquid additives are co-solvents of the active substances or permeation enhancers, and their compatibility with the polymeric matrix and the effect on adhesive properties should be considered. The patches were prepared from commercial polyacrylates (three types of Duro-Tak®) and siloxanes (Bio-PSA® and Soft Skin Adhesive®). Propylene glycol, polyoxyethylene glycol, isopropyl myristate, triacetin, triethyl citrate and silicone oil were added (10% w/w). Formulations were evaluated microscopically and with a texture analyzer in terms of in vitro adhesiveness and hardness. Only silicone oil was compatible with the silicone matrices. The best compatibility of acrylic PSA was observed with triethyl citrate; one out of three Duro-Tak matrices was incompatible with every additive. In all compositions, the adhesiveness was impaired by the liquid additives. A significant drop in adhesiveness was noted after immersion of the patches in buffer and drying. The probe tack test was considered as the most useful for evaluation of the effect of the liquid additive on adhesiveness, but the results obtained with a spherical and cylindrical probe were contradictory. The structural changes caused by the additives were also demonstrated by a 90° peel test, considered as complementary to the tack test.

Exploring Lipoic Acid-Mediated Dynamic Bottlebrush Elastomers as a New Platform for the Design of High-Performance Thermally Conductive Materials.

The development of high-performance thermally conductive interface materials is the key to unlocking the serious bottleneck of modern microelectronic technology through enhanced heat dispersion. Existing methods that utilize silicone composites rely either on loading large doses of randomly distributed thermal conductive fillers or on filling prealigned thermal conductive scaffolds with liquid silicone precursors. Both approaches suffer from several limitations in terms of physical traits and processability. We describe an alternative approach in which malleable silicone matrices, based on the dynamic cyclic disulfide nature cross-linker (α-lipoic acid), are readily prepared using ring-opening polymerization. The mechanical properties of the resultant dynamic silicone matrix are readily tunable. Stress-dependent depolymerization of the disulfide network demonstrates the ability to reprocess the silicone elastomer matrix, which allows for the fabrication of highly efficient thermal conductive composites with a 3D interconnecting, thermally conductive network (3D-graphite/MxBy composites) via in situ methods. Applications of the composites as thermal dispersion interface materials are demonstrated by LEDs and CPUs, suggesting great potential in advanced electronics.

Electric Current as an Alternative Method for Surface Treatment of Acid-Sensitive Ceramics

Objectives: The aim of this study was to evaluate the silane application with electric current as an alternative method for surface treatment of acid-sensitive ceramic. Materials and Methods: IPS E.max Press ceramic discs applied with silane, associated or not with hydrofluoric acid, electric current and storage time in water were divided in the groups (n=10) AE+CF (Acid etching + electric current free); AE+CA (Acid etching + electric current); AF+CF (Acid etching free + electric current free); AF+CA (Acid free + electric current); AE+CF +T (Acid etching + electric current free + thermal cycling); AE+CA+T (Acid etching + electric current + thermal cycling); AF+CF+T (Acid free + electric current free + thermal cycling) and AF+CA-T (Acid etching free + electric current + thermal cycling. In the conditioned groups, 10% hydrofluoric acid was applied for 20s. The silane was applied with microbrush in the AE+CF-T, AE+CA-T, AF+CF-T and AE+CA-T groups and in the other groups it was replaced by a metal tip conductor of electric current. Cylindrical silicone matrices with three holes (12 mm in diameter and 1mm thick) were placed on the ceramic. The resin cement RelyX U200 was inserted into the holes of the matrix, subjected to a static load of 250mg for 2min and photoactivated for 20s. After removing the matrix, the sample with resin cement cylinder adhered to the ceramic was stored in an oven at 37 ºC for 24h. The 24-h samples and those thermocycled with 10,000 cycles in vats with water at temperatures of 5±1 ºC and 55±1 ºC were submitted to microshear resistance test, fracture analysis, SEM analysis and contact angle. Data were submitted to one-way ANOVA and Tukey’s test (α=0.05). Results: At 24h, AE+CA showed the highest value in bond resistance and AF+CF at the lowest, both different from AE+CF while AF+CA was intermediate. After thermocycling, with higher values AE+CA+T and AE+CF-T were similar, as well as AF+CF+T and AF+CA+T with lower values. AE+CF+T and AE+CA+T differed statistically from AF+CF+T and AF+CA+T. Adhesive failure was predominant in all groups with or without thermocycling. At 24h, there was cohesive failures in mixed resin cement in the AE+CA and AF+CF. After thermocycling, there were mixed failures in the AE+CA+T and cohesive failures in resin cement for the AE+CF+T and AF+CA+T. The greater contact angle vas observed in the AE+CF. Conclusions: The association of hydrofluoric acid etching, application of silane with electric current and storage times promoted different values of bond strength, types of failures and contact angles in samples of resin cement bonded to acid-sensitive ceramics. Clinical Relevance: The application of silane with an electric current is a promising method to improve the adhesive bond between resin cement and ceramics, especially when associated with hydrofluoric acid etching.

Silicone matrices for controlled dexamethasone release: toward a better understanding of the underlying mass transport mechanisms.

Dexamethasone-loaded silicone matrices offer an interesting potential as innovative drug delivery systems, e.g. for the treatment of inner ear diseases or for pacemakers. Generally, very long drug release periods are targeted: several years/decades. This renders the development and optimization of novel drug products cumbersome: experimental feedback on the impact of the device design is obtained very slowly. A better understanding of the underlying mass transport mechanisms can help facilitating research in this field. A variety of silicone films were prepared in this study, loaded with amorphous or crystalline dexamethasone. Different polymorphic drug forms were investigated, the film thickness was altered and the drug optionally partially/completely exchanged by much more water-soluble dexamethasone 'phosphate'. Drug release studies in artificial perilymph, scanning electron microscopy, optical microscopy, differential scanning calorimetry, X-ray diffraction and Raman imaging were used to elucidate the physical states of the drugs and polymer, and of the systems' structure as well as dynamic changes thereof upon exposure to the release medium. Dexamethasone particles were initially homogeneously distributed throughout the systems. The hydrophobicity of the matrix former very much limits the amounts of water penetrating into the system, resulting in only partial drug dissolution. The mobile drug molecules diffuse out into the surrounding environment, due to concentration gradients. Interestingly, Raman imaging revealed that even very thin silicone layers (<20 µm) can effectively trap the drug for prolonged periods of time. The physical state of the drug (amorphous, crystalline) did not affect the resulting drug release kinetics to a noteworthy extent.

Accuracy of Direct Composite Veneers via Injectable Resin Composite and Silicone Matrices in Comparison to Diagnostic Wax-Up.

Purpose: To evaluate the discrepancy between the diagnostic wax-up and the resulting direct veneers using different matrices. Materials and method: A total of 48 identical misaligned models, 12 wax-up models and one ‘every other tooth’ wax-up model were 3D printed. Group 1: Transparent silicone matrices with holes for the injection of the flowable composite. Group 2: The same procedure as group 1, but the first three teeth were restored using the matrix constructed from the ‘every other tooth’ wax-up model. Group 3: Transparent silicone matrices cut for each tooth and preheated resin composite. Group 4: The same procedure as group 3, but the loaded matrix was placed first in the clear plastic tray, which was used for the matrix’s fabrication. Group 5: Wax-up models (control group). Scans from the veneers were superimposed with the scans from the wax-up and compared using the Patient Monitoring software. Measurements were made at the incisal, middle and cervical third. Kruskal-Wallis test and Dunn post-hoc test (p < 0.05) were used to analyze the results. Results: No statistically significant differences were found between groups 1 and 2 and the control. Group 3 was different from the control in the incisal and middle third, and group 4 was different in the cervical third. Conclusions: (1) Use of one or two matrices and the injection of flowable composite were accurate techniques. (2) Use of a matrix for each tooth combined with a pre-heated composite was the most inaccurate technique, but the use of the clear tray in combination with the matrix improved the accuracy.

Plant Growth Monitoring: Design, Fabrication, and Feasibility Assessment of Wearable Sensors Based on Fiber Bragg Gratings

Global climate change and exponential population growth pose a challenge to agricultural outputs. In this scenario, novel techniques have been proposed to improve plant growth and increase crop yields. Wearable sensors are emerging as promising tools for the non-invasive monitoring of plant physiological and microclimate parameters. Features of plant wearables, such as easy anchorage to different organs, compliance with natural surfaces, high flexibility, and biocompatibility, allow for the detection of growth without impacting the plant functions. This work proposed two wearable sensors based on fiber Bragg gratings (FBGs) within silicone matrices. The use of FBGs is motivated by their high sensitivity, multiplexing capacities, and chemical inertia. Firstly, we focused on the design and the fabrication of two plant wearables with different matrix shapes tailored to specific plant organs (i.e., tobacco stem and melon fruit). Then, we described the sensors' metrological properties to investigate the sensitivity to strain and the influence of environmental factors, such as temperature and humidity, on the sensors' performance. Finally, we performed experimental tests to preliminary assess the capability of the proposed sensors to monitor dimensional changes of plants in both laboratory and open field settings. The promising results will foster key actions to improve the use of this innovative technology in smart agriculture applications for increasing crop products quality, agricultural efficiency, and profits.

Long term behavior of dexamethasone-loaded cochlear implants: In vitro & in vivo

The aim of this study was to better understand the long term behavior of silicone-based cochlear implants loaded with dexamethasone: in vitro as well as in vivo (gerbils). This type of local controlled drug delivery systems offers an interesting potential for the treatment of hearing loss. Because very long release periods are targeted (several years/decades), product optimization is highly challenging. Up to now, only little is known on the long term behavior of these systems, including their drug release patterns as well as potential swelling or shrinking upon exposure to aqueous media or living tissue. Different types of cylindrical, cochlear implants were prepared by injection molding, varying their dimensions (being suitable for use in humans or gerbils) and initial drug loading (0, 1 or 10%). Dexamethasone release was monitored in vitro upon exposure to artificial perilymph at 37 °C for >3 years. Optical microscopy, X-ray diffraction and Raman imaging were used to characterize the implants before and after exposure to the release medium in vitro, as well as after 2 years implantation in gerbils. Importantly, in all cases dexamethasone release was reliably controlled during the observation periods. Diffusional mass transport and limited drug solubility effects within the silicone matrices seem to play a major role. Initially, the dexamethasone is homogeneously distributed throughout the polymeric matrices in the form of tiny crystals. Upon exposure to aqueous media or living tissue, limited amounts of water penetrate into the implant, dissolve the drug, which subsequently diffuses out. Surface-near regions are depleted first, resulting in an increase in the apparent drug diffusivity with time. No evidence for noteworthy implant swelling or shrinkage was observed in vitro, nor in vivo. A simplified mathematical model can be used to facilitate drug product optimization, allowing the prediction of the resulting drug release rates during decades as a function of the implant's design.

Influence of Fit-checking Material and Cleaning Protocols on the Bond Strength of Lithium Disilicate Glass-ceramics.

To evaluate the bond strength of a resin luting agent to a lithium disilicate glass-ceramic after the use of different fit-checking materials and cleaning protocols. Two hundred and forty-two (242) ceramic specimens were etched with 5% hydrofluoric acid for 20 seconds and distributed into 22 groups (n=10), in total. Four (4) groups were created based on fit-checking material and that had no following cleaning protocol: no fit-checking material used (control group); articulating paper; articulating spray; and fit-checker liquid. For each fit-checking material (3), 6 cleaning protocols were tested creating an additional 18 groups (n=10): air/water spray; 70% alcohol (ethanol); acetone; 35% phosphoric acid; 5% hydrofluoric acid; and a commercially available cleaning paste (Ivoclean, Ivoclar Vivadent). Silane and bonding resin were applied to all ceramic surfaces. Resin luting agent cylinders (1 mm in diameter) were created using silicone matrices, light-cured, and specimens were stored in deionized water at 37°C for 24 hours. Microshear bond strength test (μSBS) was performed on a universal testing machine (DL 500, EMIC) at a crosshead speed of 1 mm/min until failure. Results were statistically analyzed using ANOVA and Tukey's test (α=0.05). Articulating paper and fit-checker liquid, when not properly removed, negatively affected the bond strength (p<0.05). None of the tested cleaning protocols were effective for articulating paper (p<0.05). There was no significant difference in bond strength after the cleaning protocols between articulating spray and fit-checker liquid when compared to the control group (no contamination) (p>0.05). The cleaning protocols tested can effectively restore the bond strength of resin luting agents to lithium disilicate ceramics that were exposed to articulating spray or fit-checker liquid. The use of articulating paper is not recommended for fit-checking indirect lithium disilicate restorations.

Development of a Silicone-Based Polymer Matrix as a Suitable Transdermal Therapeutic System for Diallyl Disulfide.

There is an unmet need for novel therapeutic tools relieving chronic pain. Hydrogen sulfide (H2S) is highly involved in pain processes; however, the development of ideal matrices for sulfide donor compounds remains a great pharmaceutical challenge. We aimed to establish a suitable transdermal therapeutic system (TTS) using the H2S donor diallyl disulfide (DADS) as a model compound. After the preparation of DADS, its solubility was investigated in different liquid excipients (propylene glycol, polyethylene glycol, silicone oil) and its membrane diffusivity was assessed in silicone matrices of different compositions. Drug-releasing properties of DADS-containing patches with different silicone oil contents were determined with Franz and flow-through cells. We found a correlation between the liquid excipient content of the patch and the diffusion rate of DADS. DADS showed the best solubility in dimethyl silicone oil, and the diffusion constant was proportional to the amount of oil above the 3 m/m% threshold value. The 8-day-old patch showed a significantly lower, but better-regulated, drug release over time than the 4-day-old one. In conclusion, the silicone-based polymer matrix developed in this study is suitable for stable storage and optimal release of DADS, providing a good basis for a TTS applied in chronic pain.

Microscopic and Spectroscopic Imaging and Thermal Analysis of Acrylates, Silicones and Active Pharmaceutical Ingredients in Adhesive Transdermal Patches.

Dermal or transdermal patches are increasingly becoming a noteworthy alternative as carriers for active pharmaceutical ingredients (APIs), which makes their detailed physicochemical evaluation essential for pharmaceutical development. This paper demonstrates mid-infrared (FTIR) and Raman spectroscopy with complementary microscopic methods (SEM, optical and confocal Raman microscopy) and differential scanning calorimetry (DSC) as tools for the identification of the state of model API (testosterone TST, cytisine CYT or indomethacin IND) in selected adhesive matrices. Among the employed spectroscopic techniques, FTIR and Raman may be used not only as standard methods for API identification in the matrix, but also as a means of distinguishing commercially available polymeric materials of a similar chemical structures. A novel approach for the preparation of adhesive polymers for the FTIR analysis was introduced. In silicone matrices, all three APIs were suspended, whereas in the case of the acrylic PSA, Raman microscopy confirmed that only IND was dissolved in all three acrylic matrices, and the dissolved fraction of the CYT differed depending on the matrix type. Moreover, the recrystallization of TST was observed in one of the acrylates. Interestingly, a DSC analysis of the acrylic patches did not confirm the presence of the API even if the microscopic images showed suspended particles.

Three-dimensional digital evaluation of thickness accuracy of mock-ups fabricated by silicone matrices: An in vitro study.

Although mock-ups have been widely used in dental esthetic rehabilitation, their accuracy has not been quantitatively evaluated, and the methods of fabricating mock-ups are various. This in vitro study investigated the thickness accuracy of mock-ups fabricated with different silicone matrices. Mock-ups of maxillary anterior teeth were respectively fabricated by 72 silicone matrices that were equally divided into four groups (n=18 for each group) according to two variables of the silicone matrices: labial margin position (equigingival or cover labial gingiva for 1-2 mm) and palatal notches (with or without notches on the palatal side of silicone matrices). The thickness accuracy of the mock-ups was analyzed using 3D scanning and 3D deviation analysis techniques compared with diagnostic waxing. The thickness change ratios of the mock-ups were compared using a two-way analysis of variance (ANOVA). One-way ANOVA and Kruskal-Wallis tests were used to compare differences in thickness change ratios between different teeth in each group. The thickness accuracy of the mock-ups was significantly affected by the labial margin position and the palatal notches of the silicone matrices, respectively, in the labial area and the incisal area. The most accurate mock-ups were made using silicone matrices with equigingival labial margins and palatal notches. The thickness accuracy of the mock-ups was also inconsistent on different teeth. The mock-ups fabricated by silicone matrices were thicker than the diagnostic waxing. The application of silicone matrices to equigingival labial margins and palatal notches was beneficial to the thickness accuracy of mock-ups.

Stretchable reflective coating for soft optical waveguides and sensors

Soft robots must embody mechanosensing capabilities to merge with and act in the environment. Stretchable waveguides are making a mark in soft mechanical sensing since they are built from pristine elastomers. Therefore, they are insensitive to electromagnetic fields and weakly affect the deformations of the robot. However, issues in light-shielding, signal decoupling, and core-cladding interfaces are still open challenges. In this work, titanium oxide particles (TiO2) are dispersed in silicone elastomers to develop a soft optical shield coating. Results show that the added particles do not harden the matrix and reduce light transmission. Almost full NIR shielding is achieved by adding 1.0 vol% of TiO2 in 150 μm thick films. These properties make the proposed shielding coating an excellent candidate for soft mechanosensing. An open-access tool is developed to design soft optical devices by programming light transmittance at desired wavelengths by tuning, both, TiO2 concentration and film thickness. Finally, two proof-of-concepts are demonstrated, a soft waveguide and a soft strain sensor, by integrating the developed material to shield a transparent PDMS resin and a semi-transparent Ecoflex00-10 matrix, respectively. The soft waveguide can stretch up to 40% with very low optical loss, while the optical strain sensor can detect strain up to 90%. In both cases, bending, folding, and indentation of the devices have a significantly low impact on light transmission. These results can pave the way to design new optical transmission devices and sensors that exploit light reflection and that allow for discriminating different types of mechanical stimuli in soft robots.

Materials for optical oxygen sensing under high hydrostatic pressure

Optical oxygen sensors based on indicators immobilized into porous and nonporous matrix materials were investigated in regard to their sensing behaviour under high hydrostatic pressure. The sensors were subjected to step-wise pressure increase up to approximately 200 bar in multiple cycles using a custom-made chamber. The investigated materials are based on oxygen indicators (a platinum(II) benzoporphyrin dye and ruthenium(II) polypyridyl complexes) immobilized in microparticles: silica gels of different porosities, controlled pore glass, poly(phenylsilsesquioxane), crosslinked polystyrene, the metal-organic frameworks ZIF-8 and UiO-66. The microparticles are in turn dispersed in highly oxygen-permeable silicone and Hyflon AD matrices. Homogeneous films of dye doped polystyrene and polyurethane hydrogels as well as non-porous polystyrene nanospheres directly dispersed in water were used for comparison purposes. All the porous materials were found to be stable under elevated hydrostatic pressure. Although the actual oxygen concentration remained unchanged upon increasing pressure, the sensors demonstrated an apparent decrease of calculated oxygen concentration (between −0.02 and −0.45 mg O2 L-1 H2O per 100 bar), which was fully reversible. Furthermore, the kinetics of the pressure response of the sensors was determined in experiments with high temporal resolution. Spikes attributed to pressure-induced oxygen diffusion between sensor components were observed within the first seconds after pressurization/depressurization.

Marine Fouling Characteristics of Biocomposites in a Coral Reef Ecosystem

AbstractCoral reefs are among the most diverse ecosystems in the world. The diversity of life found in the habitats created by corals is so large that the reefs are known as the “rainforests of the sea.” Unfortunately, severe natural and anthropogenic changes such as ocean warming, acidification, coral diseases, and plastic pollution are extremely detrimental to this ecosystem. To enrich the ambient conditions of the corals and boost their growth, the potential of two biocomposites is evaluated based on biodegradable polyurethane and silicone matrices as scaffolds for the growth of oceanic organisms. Furthermore, their degradation is investigated within the coral reefs of Faafu Atoll, Republic of Maldives. The observations indicate that there are a significant number of organisms that settle and grow on these biocomposites in the Maldivian lagoon, both of an animal and photosynthetic nature. The biocomposites have the potential to become suitable scaffolds for diverse hard bottom fouling organisms. Moreover, the presence of coral larvae on the biocomposites suggests that during their biodegradation, these biocomposites can support the growth of organisms, generating a suitable environment for triggering the birth of new corals.

Dexamethasone-loaded cochlear implants: How to provide a desired “burst release”

Cochlear implants containing iridium platinum electrodes are used to transmit electrical signals into the inner ear of patients suffering from severe or profound deafness without valuable benefit from conventional hearing aids. However, their placement is invasive and can cause trauma as well as local inflammation, harming remaining hair cells or other inner ear cells. As foreign bodies, the implants also induce fibrosis, resulting in a less efficient conduction of the electrical signals and, thus, potentially decreased system performance. To overcome these obstacles, dexamethasone has recently been embedded in this type of implants: into the silicone matrices separating the metal electrodes (to avoid short circuits). It has been shown that the resulting drug release can be controlled over several years. Importantly, the dexamethasone does not only act against the immediate consequences of trauma, inflammation and fibrosis, it can also be expected to be beneficial for remaining hair cells in the long term. However, the reported amounts of drug released at “early” time points (during the first days/weeks) are relatively low and the in vivo efficacy in animal models was reported to be non-optimal. The aim of this study was to increase the initial “burst release” from the implants, adding a freely water-soluble salt of a phosphate ester of dexamethasone. The idea was to facilitate water penetration into the highly hydrophobic system and, thus, to promote drug dissolution and diffusion. This approach was efficient: Adding up to 10% dexamethasone sodium phosphate to the silicone matrices substantially increased the resulting drug release rate at early time points. This can be expected to improve drug action and implant functionality. But at elevated dexamethasone sodium phosphate loadings device swelling became important. Since the cochlea is a tiny and sensitive organ, a potential increase in implant dimensions over time must be limited. Hence, a balance has to be found between drug release and implant swelling.

Pull-out resistance of shape memory alloy nickel-titanium ribbons embedded in silicone matrix for development of flexible composites

Active flexible composites can be developed through the coupling of silicone matrices and smart materials such as NiTi shape memory alloys (SMA). This work evaluates the mechanical behavior and adhesion of NiTi SMA ribbons embedded in a silicone matrix for the development of active flexible composites. Ribbons with cross-section of 0.15 × 0.8 mm2 were cold-rolled from superelastic NiTi wires with 0.4 mm in diameter. These ribbons were heat treated to either obtain characteristics of superelasticity (SE) or shape memory effect (SME) at room temperature. Silicone, NiTi wire, and ribbons were characterized by Differential Scanning Calorimetry (DSC), Dynamic Mechanical Analysis (DMA), and tensile tests. Adhesion between SMA ribbons and silicone matrix was evaluated with pull-out tests. The use of an adhesion promoter proved to be indispensable to ensure a good pull-out strength and shear stress at the NiTi ribbon and silicone interface. A silicone rubber cylinder with an embedded SME ribbon was built to evaluate the functionality of the NiTi ribbon in the development of flexible structures, which was demonstrated by the resistive heating and deformation of the SMA/silicone rubber composite.

Incorporation of Carbon Nanotubes in Silicone Matrices to Improve Wave Energy Converters Performance’s

The marine energies constitute a strategic sector of the renewable energies to diversify and complete the energy mix. At present, offshore wind energy and the marine turbines are the main approaches. In stages of more upstream research, demonstrators of wave energy converters (WEC) based on a hydraulic conversion have difficulty in developing because of problems of reliability. The harnessing of this field of wave energy could find a new impetus thanks to the development of concepts in break based on innovative and economically technologies: electroactive polymers (EAP). Based on the distortion of an EAP which plays the double role to get the wave energy and to convert it in electrical energy, these generators open interesting perspectives of development because they free themselves from mechanical absorber at the origin of numerous failures of the WEC.Among challenges identified for the realization of performant EAP-WEC, the availability of more successful materials to convert the mechanical energy is at the heart of the concerns. Starting from carbon nanotubes nano-object to end in a viable mechanical structure, we have developed methods and processes which will be implemented in the future technologies of the wave energy but also aim at the manufacture of a functional prototype of laboratory.Our strategy is based on the incorporation of nano/micro hybrid reinforcements of carbon nanotubes within a silicone matrix in order to realize (i) flexible conductive electrodes and (ii) to improve the properties of the active material. A parylene coating of carbon nanotubes has demonstrated to reduce percolation and thus an improvement of the dielectric strength of the active silicone matrix. Finally, mechanical – electrical conversion is undoubtedly improved by this approach as confirmed by mechanical tests, dielectric spectroscopy and dielectric strength.Acknowledgements : The authors thankfully the national French program ANR SEASEA for funding.

Silicone elastomers filled with rare earth oxides

Silicones which possess, amongst others, remarkable mechanical properties, thermal stability over a wide range of temperatures and processability, and rare earth oxides (REO), known for their unique optic, magnetic and catalytic properties can be coupled into multifunctional composite materials (S-REOs). In addition, the intrinsic hydrophobicity of REO and polysiloxanes makes them easily compatible without the need for surface treatments of the former. Thus, europium oxide (Eu2O3), gadolinium oxide (Gd2O3) and dysprosium oxide (Dy2O3) in amounts of 20 pph are incorporated as fillers into silicone matrices, followed by processing mixture as thin films and crosslinking at room temperature. The analysis of the obtained films reveals the changes induced by these fillers in the thermal, mechanical, dielectric and optical properties, as well as the hydrophobicity of the silicones. The luminescence properties of S-REO composites were investigated by fluorescence spectra and lifetime - resolved measurements with a multiemission peaks from blue to greenish register. The thermogravimetrical analysis indicates an increasing of thermal stability of the composites that contain REO, compared to pure silicone. As expected, the dielectric permittivity significantly increased due to nature of the fillers, while the dielectric loss values are relatively low for all samples, indicating a minimal conversion of electrical energy in the form of heat within bulk composites. The presence of rare earth oxides into the silicone matrix facilitates the motions of long-range charge carriers through the network resulting in higher values of conductivity of the composite films. The stress-strain measurements revealed the reinforcing effect of the rare earth metal oxides on a silicone matrix, leading to a significant increase of Young modulus. The known hydrophobicity of silicones is further enhanced by the presence of REO.