Settleable Particulate Matter Research Articles

The impact of settleable atmospheric particulate on the energy metabolism, biochemical processes, and behavior of a sentinel mangrove crab

We use the sentinel mangrove crab, Minuca rapax, as a model to investigate the effects of metallic settleable particulate matter (SePM) on wetland. Multiple levels of energetic responses, including (i) metabolic rate and energy budget, (ii) oxidative stress, and (iii) behavioral response by righting time, were assessed as well as the metal and metalloid content in crabs exposed to 0, 0.1 and 1 g.L−1 of SePM, under emerged and submerged conditions over five days, simulating the rigors of the intertidal habitat. Al, Fe, Mn, Cr, and Y exhibited a concentration-dependent increase. Metal concentrations were higher in submerged crabs due to the continuous ingestion of SePM and direct exposure through gills. Exposure concentration up to 1 g.L−1 decreased metabolic rate and enzymatic activities, reduced assimilation efficiency and energy for maintenance, and induces a slower response to righting time, probably by metal effects on nervous system and energy deficits. In conclusion, SePM exposure affects the redox status and physiology of M. rapax depending on he submersion regime and SePM concentration. The disruption to the energy budget and the lethargic behavior in M. rapax exposed to SePM implies potential ecological alterations in the mangrove ecosystem with unknown consequences for the local population.

Oxidative stress and neurotoxicity induced by exposure to settleable atmospheric particulate matter in bullfrog tadpoles, Aquarana catesbeiana, (Shaw, 1802)

Bullfrog tadpoles, Aquarana catesbeiana, were exposed to settleable particulate matter (SePM), (1 g L−1, 96 h) and their organs were collected for analysis of metal/metalloid, oxidative stress and neurotoxicity in liver, muscle, kidney and brain. The SePM water of the exposed groups contained 18 of the 28 metals/metalloids detected in ambient particulate matter (APM). Fe56 and Al were those that presented the highest concentrations, Cr, Mn, Pb and Cu increased from 10 to 20 times and Ti, V, Sr, Rb, Cd, Sn and Ni increased from 1 to 3 times compared to the control. Bioaccumulation of metals/metalloids in the exposure water varied significantly between organs, with the muscle and liver showing the highest concentrations of metals, followed by the brain. Lipoperoxidation and malondialdehyde increased only in muscle, while carbonyl proteins increased only in the liver and brain. Regarding nitric oxide synthase, there was an increase in the liver and brain in the group exposed to SePM. Catalase activity decreased in the liver and muscle, while the activity of glutathione peroxidase, increased in the liver and kidney and decreased in muscle. Glutathione S-transferase, which is mainly responsible for detoxification, increased in the liver and decreased in muscle and the kidney. Cholinesterase activity increased only in the muscle. The results indicate oxidative stress, due to oxidation catalyzed by metals, components of SePM. Thus, the results contribute to the understanding that SePM has a deleterious effect on the aquatic environment, negatively affecting bullfrog tadpoles, in different ways and levels in relation to the analyzed organs.

Toxic, genotoxic, mutagenic, and bioaccumulative effects of metal mixture from settleable particulate matter on American bullfrog tadpoles (Lithobates catesbeianus)

Amphibians are more susceptible to environmental stressors than other vertebrates due to their semipermeable skin and physiological adaptations to living in very specific microhabitats. Therefore, the aim of the present study was to investigate the effects of a metal mixture from settleable particulate matter (SePM) released from metallurgical industries on Lithobates catesbeianus tadpoles. Endpoints analyzed included metal bioconcentration, morphological (biometrical indices), hematological parameters (hemoglobin and blood cell count), and erythrocyte DNA damage (genotoxicity and mutagenicity). American bullfrog tadpoles (Gosner's stage 25) were kept under control condition (no contaminant addition) or exposed to a sub-lethal and environmentally relevant concentration (1 g.L−1) of SePM for 96 h. Tadpoles exposed to SePM exhibited elevated whole blood levels of Fe56, AL, Sn, Pb, Zn, Cr, Cu, Ti, Rb, V, Ce, La, Ag, As. SePM-exposed tadpoles showed a significant decrease in condition factor (12%) and increases in hepatosomatic index (25%), hemoglobin concentration (17%), and total leukocytes (82%), thrombocytes (90%), and monocytes (78%) abundance. In addition, exposed tadpoles showed higher MN and ENAs (340 and 140%, respectively) frequencies, and erythrocyte DNA damage with approximately 1.2- to 1.8-fold increases in comet parameters. Taken together, these results suggest that the multimetal mixture found in SePM is potentially genotoxic and mutagenic to L. catesbeianus tadpoles, induces stress associated with hematological changes, and negatively affects growth. Although such contamination occurs at sublethal levels, regulatory standards are needed to control the emission of SePM and protect amphibian populations.

Multi-level biological responses of Daphnia magna exposed to settleable atmospheric particulate matter from metallurgical industries

Metallurgical industries are a continuous source of air pollution due to the amount of settleable particulate matter (SePM) they release. This SePM is a complex mixture formed by metallic nanoparticles and metals, which reach terrestrial and aquatic ecosystems and can be a significant source of contamination. The aim of this study was to evaluate the adverse effects of SePM at different levels of biological organization in order to estimate its ecological impacts on aquatic ecosystems. For this purpose, the crustacean Daphnia magna was exposed to different concentrations of SePM (0.01, 0.1, 1, 5, 10 g/L) using a multi-level response approach. The endpoints studied were: avoidance throughout 24 h in a non-forced exposure system, reproduction (total number of neonates per female after 21 days of exposure), acetylcholinesterase activity (AChE) after 48 h, and finally, the feeding rates during a short-term exposure (48 h) and a long-term exposure (21 day + 48 h). There was a negative effect of SePM on all responses measured at high concentrations. The avoidance was concentration-dependent and represented 88 % and 100 % at the two highest concentrations. The AChE activity was significantly inhibited at 5 and 10 g/L. The total number of neonates increased from 1 g/L of SePM and the first brood occurred earlier as of 5 g/L compared to control. The post-exposure feeding rates were lower during long-term exposure at the highest concentration. Chemical analyses were performed to characterize the metals present in this SePM, but this study did not report any direct relationship with toxicity, due to the chemical heterogeneity of the particles. The emission of compounds caused by anthropogenic activity may have significant ecological consequences, so it is important to consider these possible effects on aquatic biota generated by the mixture of metals present in SePM originated from metallurgical activities. Environmental and sectorial regulations are needed to prevent contamination and ecological disturbances.

Metalliferous atmospheric settleable particulate matter action on the fat snook fish (Centropomus parallelus): Metal bioaccumulation, antioxidant responses and histological changes in gills, hepatopancreas and kidneys.

Metallic smoke released by steel industries is constitute by a mixture of fine and gross particles containing metals, including the emerging ones, which sedimentation contaminates soil and aquatic ecosystems and put in risk the resident biota. This study determined the metal/metalloids in the atmospheric settleable particulate matter (SePM, particles >10 μm) from a metallurgical industrial area and evaluated metal bioconcentration, antioxidant responses, oxidative stress, and the histopathology in the gills, hepatopancreas and kidneys of fat snook fish (Centropomus parallelus) exposed to different concentrations of SePM (0.0, 0.01, 0.1 and 1.0 g L−1), for 96 h. From the 27 metals (Al, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, As, Se, Rb, Sr, Y, Zr, Nb, Mo, Ag, Cd, Sn, Ba, La, Ce, W, Hg, Pb, Bi) analyzed, 18 were quantified in SePM and dissolved in seawater. Metal bioconcentrations differed among organs; Fe and Zn were the metals most bioconcentrated in all organs, Fe was higher in hepatopancreas and Zn > Fe > Sr > Al was higher in kidneys. The activity of superoxide dismutase (SOD) decreased in the gills; SOD, catalase (CAT) decreased, and glutathione peroxidase (GPx) increased in hepatopancreas and, CAT, glutathione-S-transferase (GST) and the level of glutathione (GSH) increased in kidneys. The unchanged levels of lipid peroxidation and oxidized protein in any organ indicate that the antioxidant responses were efficient to avoid oxidative stress. Organ lesion indices were higher in the gills > kidneys > hepatopancreas, being higher in fish exposed to 0.01 g L−1 SePM. All changes indicate a tissue-specific metal/metalloids bioconcentration, antioxidant and morphological responses that all together compromise fish health. Regulatory normative are needed to control the emission of these metalliferous PM to preserve the environment and biota.

Multi-year monitoring of atmospheric dust fall as a sink for lead in an agro-industrial and petrochemical city of Argentina. Geo-accumulation and ecological risk assessment.

A multi-year monitoring data set of potentially harmful elements (PHEs), which are present in the chemical composition of atmospheric settleable particulate matter (SPM) in the urban, industrial and port areas in Bahía Blanca, was studied in order to assess potential ecological risk. The selected PHEs were metal elements of local and regional environmental importance (Cd, Cr, Cu, Ni, Pb, and Zn). Seventeen sampling campaigns were carried out between April 2013 and September 2019. After the microwave-assisted acid digestion of samples, the total contents of the PHEs were determined by ICP-OES. The annual dry deposition rate, the indexes associated with the potential ecological risk (RI) and the degree of geo-accumulation (Igeo) of each PHE were calculated. The results indicated that: (a) there are 3 groups (I, II, III) of PHEs with differentiated concentration levels, ranked I (Pb > Zn > Cu) > II (Cr ≈ Ni) > III (Cd) (p < 0.01) in all the studied areas; (b) the median of the total deposition rate was 1mgcm-2. month-1 with a significant relative contribution of Pb; (c) a considerable increase in geo-accumulation of Pb indicated that SPM was functioning as a sink for Pb, and also reflected a significant progressive increase in the potential ecological risk in all sites (p < 0.01); and (d) there were chemometrically identified potential sources of Pb, Cu and Zn emissions that would be associated mainly to the resuspension of dust from geogenic, industrial and urban origin, and to a lesser extent, to other gaseous emissions of the industrial sector. This work highlights three major aspects of environmental assessment: (a) the value of continuous monitoring as an important tool to detect long-term trends; (b) the importance of the role of dust fall as a useful environmental indicator of lead geo-accumulation; and (c) the great utility of geo-accumulation and potential ecological risk indices as rapid quantitative assessment tools of environmental pollution.

Impact of COVID-19 restrictions on the dry deposition fraction of settleable particulate matter at three industrial urban/suburban locations in northern Spain

Ninety 24-h samples of the dry deposition fraction of settleable particulate matter (DSPM) were collected at one suburban industrial site (‘EMA’) and two urban industrial sites (‘Lauredal’ and ‘Laboratory’) in the western area of Gijón (North of Spain) from December 2019 to June 2020. The levels registered point to an environmental issue that should receive close attention from environmental authorities. Before lockdown restrictions due to COVID-19 were established, all samples collected at the EMA site exceeded 300 mg·m−2·d−1 (the Spanish limit value until 2002). Large amounts of DSPM were also registered at the Lauredal and Laboratory sites, maximum levels reaching 1039.2 and 672.7 mg·m−2·d−1, respectively. Seven metals were analysed in DSPM samples: Al, Ca, Fe, K, Mg, Mn and Na. Fe reached the highest values: 2473.4, 463.4 and 293.3 mg·m−2·d−1 (EMA, Lauredal and Laboratory sites, respectively). This study quantifies the reductions in the DSPM levels registered (on average, 97.2, 73.5 and 90.5% at the EMA, Lauredal and Laboratory sites, respectively) during the lockdown, which involved the restriction of population mobility and industrial activity. The influence of wind speed and its direction were also assessed to better understand the role of these restrictions in the observed reductions. The concentrations of all the metals in the DSPM were reduced by more than 75%, on average, except for K at the Laboratory and Lauredal sites. These decreases were much higher than those found by other authors for smaller fractions of the atmospheric particulate matter (PM10, PM2.5). The findings of the present study highlight the importance of DSPM in highly industrialized urban/suburban locations and indicate the direction that legal measures might take, given the influence of anthropogenic emissions.

Health risk assessment of potentially toxic elements in the dry deposition fraction of settleable particulate matter in urban and suburban locations in the city of Gijón, Spain

This study investigates the human health risk of Al, As, Fe, Mn, Ni, Pb, Sb and Sr in the dry deposition fraction of settleable particulate matter (DSPM). Sixty samples were collected at an industrial suburban site (‘EMA’) and a waterfront urban site (‘Naval’) in Gijón, a coastal city in northern Spain. Up to 4898.4 mg m−2 d−1 were measured at the station closer to industrial activity. The levels of the eight elements were greater at this site. Fe and Al were the major constituents, comprising up to 50% of DSPM.The human health risk posed by DSPM was assessed using a U.S.EPA methodology. The level of exposure to the metals/metalloids in this atmospheric pollutant was studied via ingestion, inhalation, and dermal contact. The results showed that ingestion was the main exposure pathway for the residents at the two locations, followed by dermal contact and inhalation. For adults, the non-carcinogenic hazard indexes and the carcinogenic risk levels of the eight elements were within the acceptable levels (1 and 10−5, respectively). Nevertheless, in the case of children, the non-carcinogenic hazard indexes of Fe and Pb as well as the carcinogenic risk level of As via ingestion were higher than those thresholds.Despite its importance, little research has focused on assessing the human risk posed by metals/metalloids in DSPM. Although there are uncertainties regarding the exposure factors and toxicity values, the outcomes of this study provide useful knowledge for regulatory authorities to establish appropriate mitigation measures to reduce DSPM emissions in urban and suburban environments.

Settleable matter in a highly industrialized area: Chemistry and health risk assessment

Settleable particulate matter (SPM) was collected at two sampling points within an urban area highly affected by nearby industrial activities. Total deposition values up to 386 mg ·m−2·d−1 were registered, the majority of samples exceeding the limit value established in the legislation in force in Spain until 2002 (300 mg·m−2·d−1). Dry deposition values showed high variability (8.6–830.3 mg·m−2·d−1).Forty-one metals and metalloids were analysed in the dry fraction of SPM, the main being Fe and Ca (maximums: 304.4 and 68.6 mg·m−2·d−1, respectively), followed by Al, Mg, Na, K, Mn, Ti, P and Zn. Trace elements like As and Pb reached up to 7.3 and 76.3 μg· m−2·d−1, respectively. Strong correlations (r > 0.90, p-value < 0.05) between Fe and other elements (Ca, Mn and Pb) were found at both sampling sites. Scanning electron microscopy confirmed the presence of these particles rich in Fe and Ca, in addition to other components, whose morphologies pointed out to anthropogenic sources. These results combined with meteorology data suggest a common industrial source contributing to the levels of these metals.Furthermore, a human health risk study was carried out to assess the potential carcinogenic and non-carcinogenic risks of exposure to thirteen elements in these particles (Al, As, Cd, Co, Cu, Mn, Mo, Ni, Pb, Sb, Sr, V and Zn). The highest levels of risk seemed to be associated with the presence of As, Pb and Sb.

Atmospheric particulate matter from an industrial area as a source of metal nanoparticle contamination in aquatic ecosystems

Air pollution legislation and control worldwide is based on the size of particulate matter (PM) to evaluate the effects on environmental and human health, in which the small diameter particles are considered more dangerous than larger sizes. This study investigates the composition, stability, size and dispersion of atmospheric settleable particulate matter (SePM) in an aqueous system. We aimed to interrogate the changes in the physical properties and characteristics that can contribute to increased metal uptake by aquatic biota. Samples collected in an area influenced by the steel and iron industry were separated into 8 fractions (425 to ≤10 μm) and analysed physically and chemically. Results from ICP-MS and X-ray showed that the PM composition was mainly hematite with 80% of Fe, followed by Al, Mn and Ti. Among 27 elements analysed we found 19 metals, showing emerging metallic contaminants such as Y, Zr, Sn, La, Ba and Bi. Scanning electron microscopy (SEM) showed that SePM fractions are formed by an agglomeration of nanoparticles. Furthermore, dynamic light scattering (DLS), zeta potential and nanoparticle tracking analysis (NTA) demonstrated that SPM were dissociated in water, forming nanoparticles smaller than 200 nm, which can also contribute to water pollution. This study highlights that SePM contamination may be substantially higher than expected under that allowed in atmospheric regulatory frameworks, thereby extending their negative effect to water bodies upon settling, which is an underexplored area of our knowledge. We therefore provide important insights for future investigations on safety regulations involving SePM in the environment, indicating the need to revise the role of SePM, not solely associated with air pollution but also considering their deleterious effects on water resources.

Sedimentation rate of settleable particulate matter in Santiago city, Chile

AbstractSettleable particulate matter (SPM) is an atmospheric pollutant harmful to human health and the environment in high concentrations. Despite this fact, no up‐to‐date information on SPM levels exists for the capital of Chile, Santiago (7 million inhabitants). To address this knowledge gap, SPM sedimentation rates, including soluble and insoluble components, were measured at three different urban sites from July to November of 2016. We compare the measurements with ambient and meteorological information, as well as urban typology settings.Our results indicate SPM deposition rates between 2.5 and 3.9 g/(m2·30 days). Only one site exceeded the national limit of 4.5 g/(m2·30 days), but we found an increasing trend in all three sites. SPM and its insoluble sedimentation rates increased during warm and dry months and presented significant correlations with meteorological parameters. The highest sedimentation rates were measured at the location with the least permeable surfaces and the lowest green spaces, while the lowest sedimentation rates were found in the sites with abundant green spaces and permeable soil. No significant differences were detected in the soluble components.Our results suggest that SPM levels in Santiago are close to the national limit and may increase with climate change and urban expansion.

Size distribution and elemental composition of vent particles from abused prismatic Ni-rich automotive lithium-ion batteries

Abstract The lithium-ion battery (LIB) jet is often accompanied by particulate matter (PM) (e.g. spark) during vent and combustion caused by thermal runaway. These hot PM could ignite the combustible vent gases, and the settleable matter may promote water and soil pollution. The aim of this study is to reveal the statistical size distribution and elemental composition of the settleable PM released by LIBs after thermal runaway. A fully charged commercial 50 Ah Li(Ni0.6Mn0.2Co0.2)O2 cell was triggered by heating in a sealed chamber. These PM were divided into 4 samples using sieves. The sizes were analyzed and the elements were detected. The results show that these PM account for 11.20% of the cell mass. Nearly 45% of particles by mass were found to have a size less than 0.85 mm, with the median size being approximately 198 um. The main elements are carbon, nickel, cobalt, etc. The content of metallic elements is approximately 40%. The emissions also contain potentially toxic elements, including aluminum, lithium, fluorine, etc. The element species in different samples are similar, but their contents differ. The size distribution provides a basis for the design of the particle filter pore, and elemental composition reveals the pollution of LIB emissions.

Mineralogical and Chemical Characterization of Settleable Dustfall in Sulaimani City, Kurdistan Region, Iraq

Airborne particulate matter has now become an important global environmental issue because of its many diverse effects on overall health and environmental degradation. Because of its unique complexity, solutions to this problem are challenging. The main objectives of this study were to assess the mineralogical composition and selected chemical properties of atmospheric settleable particulate materials from 15 locations in Sulaimani City, Kurdistan Region, Iraq, sampled between August 2009 and March 2010. In addition, representative samples from a heavy dust storm that affected the region on February 22, 2010, were collected from 3 locations within the city. Organic carbon, total carbonate (CaCO3 equivalent), and total free iron contents, along with pH, were determined in all samples. Mineralogical analysis of the collected samples was performed by x-ray diffraction. Carbonates made up the largest fraction of the identified minerals and were predominantly in an active form. The following abundant minerals occurred in all the studied dust samples in decreasing amounts: calcite, clay minerals, quartz, feldspar, and dolomite. The clay fraction was composed (in descending order of abundance) of palygorskite, illite, muscovite, chlorite, and smectite. Samples from the dust storm event contained gypsum minerals that were not present in the other samples and had the highest percentage of dolomite of all samples, indicating that settleable particulate matter from the meteorological dust storm had a different source than local dust.

A new methodology to derive settleable particulate matter guidelines to assist policy-makers on reducing public nuisance

Air quality standards for settleable particulate matter (SPM) are found in many countries around the world. As well known, annoyance caused by SPM can be considered a community problem even if only a small proportion of the population is bothered at rather infrequent occasions. Many authors have shown that SPM cause soiling in residential and urban environments and degradation of materials (eg, objects and surface painting) that can impair the use and enjoyment of property and alter the normal activities of society. In this context, this paper has as main contribution to propose a guidance to establish air quality standards for annoyance caused by SPM in metropolitan industrial areas. To attain this objective, a new methodology is proposed which is based on the nonlinear correlation between the perceived annoyance (qualitative variable) and particles deposition rate (quantitative variable). Since the response variable is binary (annoyed and not annoyed), the logistic regression model is used to estimate the probability of people being annoyed at different levels of particles deposition rate and to compute the odds ratio function which gives, under a specific level of particles deposition rate, the estimated expected value of the population perceived annoyance. The proposed methodology is verified in a data set measured in the metropolitan area of Great Vitória, Espirito Santo, Brazil. As a general conclusion, the estimated probability function of perceived annoyance as a function of SPM has shown that 17% of inhabitants report annoyance to very low particles deposition levels of 5 g/(m2∙30 days). In addition, for an increasing of 1 g/(m2∙30 days) of SPM, the smallest estimated odds ratio of perceived annoyance by a factor of 1.5, implying that the probability of occurrence is almost 2 times as large as the probability of no occurrence of annoyance.

Source apportionment of settleable particles in an impacted urban and industrialized region in Brazil

Settleable particulate matter (SPM), especially coarser particles with diameters greater than 10μm, has been found culprit of high deposition rates in cities affected by hinterland industrial activities. This is the case of Metropolitan Region of Vitoria (MRV), Espirito Santo, Brazil where industrial facilities are located within the urban sprawl and building constructions are intense. Frequent population complaints to the environmental protection agency (IEMA) throughout the years have triggered monitoring campaigns to determine SPM deposition rates and source apportionment. Eight different locations were monitored throughout the MRV, and SPM was quantified and chemically characterized. Sources profiles were defined either by using US EPA SPECIATE data or by experimental analysis. Atmospheric fallout in the MRV ranged between 2 and 20g/(m2 30-day), with only one monitoring station ranging from 6-10g/(m2 30-day). EC, OC, Fe, Al, and Si were found the main constituents of dry deposition in the region. Source apportionment by the chemical mass balance (CMB) model determined that steel and iron ore pelletizing industries were the main contributor to one of the eight locations whereas resuspension, civil construction, and vehicular sources were also very important contributors to the other stations. Quarries and soil were also considered expressive SPM sources, but at the city periphery. CMB model could differentiate contributions from six industrial source groups: thermoelectric; iron ore, pellet, and pellet furnaces; coal coke and coke oven; sintering, blast furnace, and basic oxygen furnace; and soil, resuspension, and vehicles. However, the CMB model was unable to differentiate between iron ore and pellet stockpiles which are present in both steel and iron ore pelletizing industries. Further characterization of source and SPM might be necessary to aid local authorities in decision-making regarding these two industrial sources.

A Case Study for the Assessment of Settleable and Suspended Particulate Material in Sand and Gravel Industry

Natural aggregates, represent the main source of construction aggregates in Turkey and throughout the world. The processing of sand and gravel industry is one of the mineral products industries and generally lead the formation of sudden and intense particulate emissions. In this study, the results of the air quality measurements which were followed throughout one year in Istanbul Anatolian Side Sand Cooperative (IASSC) are summarized and the measuring methods are explained briefly. IASSC is a sand and gravel sales cooperative which was established near the residential area in Istanbul. For this reason, air quality measurement results are of great importance in terms of public health. The purpose of this air quality monitoring study is to determine the compliance with regulations taking into account potential impacts on human health and the environment. The suspended particulate matter and the settleable particulate matter parameters were monitored. At the end of the observation period, it is determined that, the average values for both of the parameters from the plant are compatible with the standards, but because of the results of especially settleable particulate matter parameter were under close proximity to the limits, some recommendations were made for increasing the air quality in the plant.

In Situ Volumetric Filtration Physical Model to Separate Particulate Matter from Stormwater

AbstractIn the last several decades there has been a proliferation of structural best management practices (BMPs) for particulate matter (PM) sequestration. However, effective separation and continued retention of PM without washout throughout loading periods in which there is no maintenance remains challenging. In this study the physical modeling (in situ testing) of a volumetric clarifying filter (VCF) for separation and retention of PM was conducted for an urban source area (∼500 m2) in north central Florida loaded by rainfall runoff. This paper examines the event-based response of a VCF unit for 25 events (384 mm of rainfall, 117 m3 of runoff over 13 months with no maintenance), differentiating the role of volumetric sedimentation (2.3 m3 tank) and depth filtration (106 m2 of cartridge surface area). Manual sampling was conducted with a PM mass balance over the monitoring campaign. Suspended sediment concentration (SSC), suspended and settleable PM fractions, and turbidity were measured. PM was fu...

Dustfall Associated with Dust Storms in the Al-Ahsa Oasis of Saudi Arabia

Dustfall is a major threat to agricultural and industrial infrastructures, as well as to other aspects of livelihood. Dustfall associated to a severe dust storm that hit the Al-Ahsa Oasis of Saudi Arabia during 12-13 March 2014 is discussed in this paper. The storm caused widespread and heavy dust deposition. A dramatic decrease in the visibility coincided with the storm, and the average dust concentrations recorded during a peak 10-hour period were 6772, 5862.4 and 451.1 μg/m3 for total suspended particles (TSP), particulate matter smaller than or equal to 10 μm (PM10) and those smaller than or equal to 2.5 μm (PM2.5), respectively. The lowest visibility was 200 m, and the wind speed increased to 17.5 m/s from the north. The average daily dust deposited in the study area during the event was 12.84 (SD = 1.2) g/(m2?d). The dust samples comprised insoluble dust (48.5%) and soluble dust (51.5%). Based on the Munsell color system, the final color description of the falling dust was 10 YR/6/3. A microphotograph of the dustfall (settleable particulate matter) captured by a stereo dissection microscope shows that the dust particles had various colors and sizes, and they contained fibers and vegetative debris).

Sobre el sentido y alcance del artículo 291 del Código Penal

This paper studies the meaning and scope of Article 291 of the Chilean Criminal Code. It pays particular attention to the applicability of that criminal offense to the emission of particulate matter (fine dust and settleable particulate matter) by copper crusher plants, which usually is deposited on the land adjacent to such plants due to the action of wind on the geography of the place. In this regard, a detailed study of the meaning and scope of the provision is carried out and it is concluded that the aforementioned facts do not fit the Article 291, and therefore, do not constitute an offence. Environmental offence – Chilean criminal law – pollution

Distribution and disinfection of bacterial loadings associated with particulate matter fractions transported in urban wet weather flows

Urban runoff is a resource for reuse water. However, runoff transports indicator and pathogenic organisms which are mobilized from sources of fecal contamination. These organisms are entrained with particulate matter (PM) that can serve as a mobile substrate for these organisms. Within a framework of additional treatment for reuse of treated runoff which requires the management of PM inventories in unit operations and drainage systems there is a need to characterize organism distributions on PM and the disinfection potential thereof. This study quantifies total coliform, Escherichia coli, fecal streptococcus, and enterococcus generated from 25 runoff events. With the ubiquity and hetero-dispersivity of PM in urban runoff this study examines organism distributions for suspended, settleable and sediment PM fractions differentiated based on PM size and transport functionality. Hypochlorite is applied in batch to elaborate inactivation of PM-associated organisms for each PM fraction. Results indicate that urban runoff bacterial loadings of indicator organisms exceed U.S. wastewater reuse, recreational contact, and Australian runoff reuse criteria as comparative metrics. All monitored events exceeded the Australian runoff reuse criteria for E. coli in non-potable residential and unrestricted access systems. In PM-differentiated events, bacteriological mobilization primarily occurred in the suspended PM fraction. However, sediment PM shielded PM-associated coliforms at all hypochlorite doses, whereas suspended and settleable PM fractions provide less shielding resulting in higher inactivation by hypochlorite.