Separate Systems Research Articles

Use of the droplet convergence effect of under-medium superlyophilic membranes in designing a system for on-demand separations of oil-in-water and water-in-oil emulsions

Separation using superwetting membranes that have discrepant interactions with water and oil, primarily those that display extreme liquid repellence, is a facile approach for oily wastewater treatment and purification of water-containing oil. However, these kinds of membranes suffer from size-sieving limitation. Owing to greater affinity toward dispersed droplets over liquid media, under-medium superlyophilic membranes have greater flexibility in the design of superwetting interfaces for oil–water separation. Herein, two membranes with completely opposite superwettabilities both in air and under oil/water media were utilized to create an integrated system for effective, on-demand separation of oil-in-water and water-in-oil emulsions. At superwetting interfaces, the under-medium superlyophilic membrane facilitates convergence of emulsion droplets while the other membrane intercepts converged droplets. As a result, the integrated membranes exhibit high purification capabilities of water and oil in surfactant-stabilized emulsions (e.g., > 99.97 % oil purification under gravity). The viscosity-dependent fluxes are > 550 L m−2h−1 when the viscosities of the liquid media are ≤ 1 mPa s. In contrast, an integrated system in which conventional in-air superhydrophilic membranes are utilized in place of the under-medium superlyophilic membranes does not efficiently separate the emulsions. The unique affinity profiles will endow under-medium superlyophilic membranes with a high potential for liquid–liquid separation.

Structure-Elasticity Relationships in Hybrid-Carrageenan Hydrogels Studied by Image Dynamic Light Scattering, Ultra-Small-Angle Light Scattering and Dynamic Rheometry.

Hybrid-carrageenan hydrogels are characterized using novel techniques based on high-resolution speckle imaging, namely image dynamic light scattering (IDLS) and ultra-small-angle light scattering (USALS). These techniques, used to probe the microscopic structure of the system in sol-gel phase separation and at different concentrations in the gel phase, give access to a better understanding of the network's topology on the basis of fractals in the dense phase. Observations of the architecture and the spatial and the size distributions of gel phase and fractal dimension were performed by USALS. The pair-distance distribution function, P(r), extracted from USALS patterns, is a new methodology of calculus for determining the network's internal size with precision. All structural features are systematically compared with a linear and non-linear rheological characterization of the gels and structure-elasticity relationships are identified in the framework of fractal colloid gels in the diffusion limit.

Hybrid use of a robotic welding system in remote laser separation of thin-sheet Al casings for the recycling of battery packs

Hybrid use of a robotic welding system in remote laser separation of thin-sheet Al casings for the recycling of battery packs

A signal detection-based confidence-similarity model of face matching.

Face matching consists of the ability to decide whether two face images (or more) belong to the same person or to different identities. Face matching is crucial for efficient face recognition and plays an important role in applied settings such as passport control and eyewitness memory. However, despite extensive research, the mechanisms that govern face-matching performance are still not well understood. Moreover, to date, many researchers hold on to the belief that match and mismatch conditions are governed by two separate systems, an assumption that likely thwarted the development of a unified model of face matching. The present study outlines a unified unequal variance confidence-similarity signal detection-based model of face-matching performance, one that facilitates the use of receiver operating characteristics (ROC) and confidence-accuracy plots to better understand the relations between match and mismatch conditions, and their relations to factors of confidence and similarity. A binomial feature-matching mechanism is developed to support this signal detection model. The model can account for the presence of both within-identities and between-identities sources of variation in face recognition and explains a myriad of face-matching phenomena, including the match-mismatch dissociation. The model is also capable of generating new predictions concerning the role of confidence and similarity and their intricate relations with accuracy. The new model was tested against six alternative competing models (some postulate discrete rather than continuous representations) in three experiments. Data analyses consisted of hierarchically nested model fitting, ROC curve analyses, and confidence-accuracy plots analyses. All of these provided substantial support in the signal detection-based confidence-similarity model. The model suggests that the accuracy of face-matching performance can be predicted by the degree of similarity/dissimilarity of the depicted faces and the level of confidence in the decision. Moreover, according to the model, confidence and similarity ratings are strongly correlated. (PsycInfo Database Record (c) 2024 APA, all rights reserved).

Scoring systems for prediction of malaria and dengue fever in non-endemic areas among travellers arriving from tropical and subtropical areas

BackgroundFever is a common symptom among travellers returning from tropical/subtropical areas to Europe, and promptly distinguishing severe illnesses from self-limiting febrile syndromes is important but can be challenging due to...

Spin‐Transfer‐Torque Magnetic Tunnel Junction Nonlinear In‐Sensor Computing Synapse for Improving the Performance of the Feedforward Neural Network

In‐sensor computing architecture has a great advantage especially in massive data sampling, transfer, and processing compared with the separated intelligent sensor systems. However, most of the in‐sensor computing device is proposed based on the traditional neural network model, where the synapse performs linear multiplication of input and weight. This approach fails to make the most use of the nonlinearity of in‐sensor computing devices. Therefore, in this article, first a modified feedforward neural network model with the nonlinear in‐sensor computing synapse (NSCS) located at the input layer is presented, and the backpropagation (BP) algorithm is modified to train the network. Then, the nonlinear characteristics of the NSCS composed of the spin‐transfer‐torque magnetic tunnel junction (STT–MTJ) devices and simple complementary metal‐oxide‐semiconductor (CMOS) circuit are analyzed. Based on the nonlinear response of STT–MTJ NSCS, the small‐scale network with NSCS synapse is experimented on the Modified National Institute of Standards and Technology dataset and compared with the traditional network of the same network size. In the simulation result, it is shown that better performance can be achieved with the STT–MTJ NSCS, including a 2–15 times improvement in convergence speed and a 2.5%–5.1% increase in accuracy.

Deep learning-based predictive classification of functional subpopulations of hematopoietic stem cells and multipotent progenitors.

Hematopoietic stem cells (HSCs) and multipotent progenitors (MPPs) play a pivotal role in maintaining lifelong hematopoiesis. The distinction between stem cells and other progenitors, as well as the assessment of their functions, has long been a central focus in stem cell research. In recent years, deep learning has emerged as a powerful tool for cell image analysis and classification/prediction. In this study, we explored the feasibility of employing deep learning techniques to differentiate murine HSCs and MPPs based solely on their morphology, as observed through light microscopy (DIC) images. After rigorous training and validation using extensive image datasets, we successfully developed a three-class classifier, referred to as the LSM model, capable of reliably distinguishing long-term HSCs, short-term HSCs, and MPPs. The LSM model extracts intrinsic morphological features unique to different cell types, irrespective of the methods used for cell identification and isolation, such as surface markers or intracellular GFP markers. Furthermore, employing the same deep learning framework, we created a two-class classifier that effectively discriminates between aged HSCs and young HSCs. This discovery is particularly significant as both cell types share identical surface markers yet serve distinct functions. This classifier holds the potential to offer a novel, rapid, and efficient means of assessing the functional states of HSCs, thus obviating the need for time-consuming transplantation experiments. Our study represents the pioneering use of deep learning to differentiate HSCs and MPPs under steady-state conditions. This novel and robust deep learning-based platform will provide a basis for the future development of a new generation stem cell identification and separation system. It may also provide new insight into the molecular mechanisms underlying stem cell self-renewal.

Janus Membranes with Asymmetric Superwettability for High-Performance and Long-Term On-Demand Oil/Water Emulsion Separation.

Current single-function superwettable materials are typically designed for either oil removal or water removal and are constrained by oil density, limiting their widespread applications. Janus membranes with opposite wettability on their two surfaces have recently emerged and present attractive opportunities for on-demand oil/water emulsion separation. Here, a combination strategy is introduced to prepare a Janus membrane with asymmetric superwettability for switchable oil/water emulsion separation. A mussel-inspired asymmetric interface introduction cooperating with the sequence-confined surface modification not only brings about an asymmetric superwettability Janus interface but also guarantees an outstanding stable interface and remarkable chemical stability surfaces. Specifically, the superhydrophilic surface with underwater superoleophobicity can separate surfactant-stabilized oil-in-water emulsions. Conversely, other surface displays opposite superhydrophobicity and superoleophilicity to treat surfactant-stabilized water-in-oil emulsions. Significantly, this superwettable Janus membrane presents superior long-term on-demand oil/water emulsion separation without obvious flux decline and high recovery ability because of its superwettability and superior stability. Furthermore, the asymmetric superwettability enhances the interfacial floatability at air-water interfaces, enabling the design of advanced interfacial materials. The as-prepared superwettable Janus membrane has established a cooperated separation system, overcoming the monotony of conventional superwettable membranes and expanding the application of these specialized membranes to oily wastewater treatment.

Nanofibrous Porous Organic Polymers and Their Derivatives: From Synthesis to Applications.

Engineering porous organic polymers (POPs) into 1D morphology holds significant promise for diverse applications due to their exceptional processability and increased surface contact for enhanced interactions with guest molecules. This article reviews the latest developments in nanofibrous POPs and their derivatives, encompassing porous organic polymer nanofibers, their composites, and POPs-derived carbon nanofibers. The review delves into the design and fabrication strategies, elucidates the formation mechanisms, explores their functional attributes, and highlights promising applications. The first section systematically outlines two primary fabrication approaches of nanofibrous POPs, i.e., direct bulk synthesis and electrospinning technology. Both routes are discussed and compared in terms of template utilization and post-treatments. Next, performance of nanofibrous POPs and their derivatives are reviewed for applications including water treatment, water/oil separation, gas adsorption, energy storage, heterogeneous catalysis, microwave absorption, and biomedical systems. Finally, highlighting existent challenges and offering future prospects of nanofibrous POPs and their derivatives are concluded.

Comparative Study of Four Acidic Extractants as Modifiers in the TBP/FeCl3 Solvent Extraction System for Lithium and Magnesium Separation

Comparative Study of Four Acidic Extractants as Modifiers in the TBP/FeCl₃ Solvent Extraction System for Lithium and Magnesium Separation

Some habits are more work than others: Deliberate self-regulation strategy use increases with behavioral complexity, even for established habits.

We tested the hypothesis that complex behaviors are commonly supported by self-regulation strategies, even when those behaviors are supported by strong instigation habits. Goal-directed and habit-mediated processes arise from separable systems that have been suggested to seldomly interact. Self-regulation strategy use was lower for habitually instigated simple behaviors compared to nonhabitually instigated simple behaviors. However, participants' use of self-regulation strategies increased with the increasing complexity of behaviors, even when complex behaviors were habitually instigated. The difference in the extent of strategy use between habitually and nonhabitually instigated actions was absent when behavioral complexity was particularly high. These results point to a qualitative distinction-while simple behaviors may progress in a relatively automatic and unthinking manner, complex behaviors receive frequent support from self-regulation strategies, even if they are instigated habitually.

Facile Preparation of Cellulose Beads with Tunable Graded Pores and High Mechanical Strength.

Cellulose-based hierarchical porous beads exhibit significant application potential in adsorption and separation systems due to their degradation and biocompatibility. However, the current fabrications of cellulose beads show poor mechanical properties and a difficult-to-regulate hierarchical porous structure, reducing their lifespan of use and limiting their application in fine separation. Here, we reported the facile creep-drop method to prepare cellulose beads that enabled systemic regulation of the macro-size, micropore structures, and mechanical properties by optimizing injection nozzle diameter, the composition of the coagulation bath, the temperature of the coagulation bath, and cellulose concentration. Notably, during the molding process, the H2SO4-Na2SO4 composite solidification bath endowed cellulose beads with a dense shell layer and a loose core layer, which achieved the integration of mechanical properties and high porosity. The cellulose beads exhibited high porosity (93.38-96.18%) and high sphericity (86.78-94.44%) by modulating the shell thickness of the cellulose beads. In particular, the cellulose beads exhibited excellent mechanical properties with a high compressive strength of 544.24 kPa at a 5% cellulose concentration. It is expected that these cellulose beads with tunable microstructures can realize their potential for applications in the fields of wastewater treatment, chemical engineering, bioengineering, medicine, and pharmaceuticals.

Algebraic curves as a source of separable multi-Hamiltonian systems

In this paper we systematically consider various ways of generating integrable and separable Hamiltonian systems in canonical and in non-canonical representations from algebraic curves on the plane. In particular, we consider St\"ackel transform between two pairs of St\"ackel systems, generated by 2n-parameter algebraic curves on the plane, as well as Miura maps between St\"ackel systems generated by (n+N)-parameter algebraic curves, leading to multi-Hamiltonian representation of these systems.

Rheumatology High Blood Pressure Protocol Reduces Disparities, But Delays Remain for External Primary Care.

To address high blood pressure (BP) in rheumatology patients, we previously implemented BP Connect, a brief staff-driven protocol to address high BP. Although timely follow-up and hypertension rates improved for patients with in-system primary care (PC), many receive PC and rheumatology care in separate health systems. In this cohort study, we compared rates of timely PC follow-up for high BP across-system health maintenance organizations (HMOs) before and after BP Connect implementation. All adult patients with high rheumatology clinic BP and PC in that HMO were eligible. BP Connect's protocol engaged the staff in remeasuring high BP (≥140/90 mm Hg), advising cardiovascular disease risk, and connecting timely PC follow-up, which for patients with PC across system includes written follow-up instructions. After an eligible rheumatology visit, the next HMO PC visit with BP was used to determine rates and odds of timely follow-up before and after using multivariable logistic regression. Across 1327 rheumatology visits with high BP and across-system PC (2013-2019), 951 occurred after 2015 BP Connect implementation; 400 had confirmed high BP. Primary care follow-up rose from 20.5% to 23.5%. The odds of timely PC BP follow-up insignificantly changed (odds ratio, 1.19; confidence interval, 0.85-1.68). For visits with Black patients, the odds of timely follow-up did significantly increase (1.95; confidence interval, 1.02-3.79). Timely follow-up for Black patients did improve, highlighting protocol interventions for more equitable health care. In contrast to our prior in-system study, BP Connect did not significantly improve follow-up with an across-system PC, indicating a need for direct scheduling. Future directions include piloting direct across-system scheduling.

S100Z is expressed in a lateral subpopulation of olfactory receptor neurons in the main olfactory system of Xenopus laevis.

In contrast to other S100 protein members, the function of S100 calcium-binding protein Z (S100Z) remains largely uncharacterized. It is expressed in the olfactory epithelium of fish, and it is closely associated with the vomeronasal organ (VNO) in mammals. In this study, we analyzed the expression pattern of S100Z in the olfactory system of the anuran amphibian Xenopus laevis. Using immunohistochemistry in whole mount and slice preparations of the larval olfactory system, we found exclusive S100Z expression in a subpopulation of olfactory receptor neurons (ORNs) of the main olfactory epithelium (MOE). S100Z expression was not co-localized with TP63 and cytokeratin type II, ruling out basal cell and supporting cell identity. The distribution of S100Z-expressing ORNs was laterally biased, and their average number was significantly increased in the lateral half of the olfactory epithelium. The axons of S100Z-positive neurons projected exclusively into the lateral and intermediate glomerular clusters of the main olfactory bulb (OB). Even after metamorphic restructuring of the olfactory system, S100Z expression was restricted to a neuronal subpopulation of the MOE, which was then located in the newly formed middle cavity. An axonal projection into the ventro-lateral OB persisted also in postmetamorphic frogs. In summary, S100Z is exclusively associated with the main olfactory system in the amphibian Xenopus and not with the VNO as in mammals, despite the presence of a separate accessory olfactory system in both classes.

Next-Generation 3,3'-AlkoxyBTPs as Complexants for Minor Actinide Separation from Lanthanides: A Comprehensive Separations, Spectroscopic, and DFT Study.

Progress toward the closure of the nuclear fuel cycle can be achieved if satisfactory separation strategies for the chemoselective speciation of the trivalent actinides from the lanthanides are realized in a nonproliferative manner. Since Kolarik's initial report on the utility of bis-1,2,4-triazinyl-2,6-pyridines (BTPs) in 1999, a perfect complexant-based, liquid-liquid separation system has yet to be realized. In this report, a comprehensive performance assessment for the separation of 241Am3+ from 154Eu3+ as a model system for spent nuclear fuel using hydrocarbon-actuated alkoxy-BTP complexants is described. These newly discovered complexants realize gains that contemporary aryl-substituted BTPs have yet to achieve, specifically: long-term stability in highly concentrated nitric acid solutions relevant to the low pH of unprocessed spent nuclear fuel, high DAm over DEu in the economical, nonpolar diluent Exxal-8, and the demonstrated capacity to complete the separation cycle with high efficiency by depositing the chelated An3+ to the aqueous layer via decomplexation of the metal-ligand complex. These soft-N-donor BTPs are hypothesized to function as bipolar complexants, effectively traversing the organic/aqueous interface for effective chelation and bound metal/ligand complex solubility. Complexant design, separation assays, spectroscopic analysis, single-crystal X-ray crystallographic data, and DFT calculations are reported.

Octadecyl and sulfonyl modification of diatomite synergistically improved the immobilization efficiency of lipase and its application in the synthesis of pine sterol esters.

Phytosterols usually have to be esterified to various phytosterol esters to avoid their disadvantages of unsatisfactory solubility and low bioavailability. The enzymatic synthesis of phytosterol esters in a solvent-free system has advantages in terms of environmental friendliness, sustainability, and selectivity. However, the limitation of the low stability and recyclability of the lipase in the solvent-free system, which often requires a relatively high temperature to induce the viscosity, also increased the industrial production cost. In this context, a low-cost material, namely diatomite, was employed as the support in the immobilization of Candida rugosa lipase (CRL) due to its multiple modification sites. The Fe3 O4 was also then introduced to this system for quick and simple separation via the magnetic field. Moreover, to further enhance the immobilization efficiency of diatomite, a modification strategy which involved the octadecyl and sulfonyl group for regulating the hydrophobicity and interaction between the support and lipase was successfully developed. The optimization of the ratio of the modifiers suggested that the -SO3 H/C18 (1:1.5) performed best with an enzyme loading and enzyme activity of 84.8mg·g-1 and 54 U·g-1 , respectively. Compared with free CRL, the thermal and storage stability of CRL@OSMD was significantly improved, which lays the foundation for the catalytic synthesis of phytosterol esters in solvent-free systems. Fortunately, a yield of 95.0% was achieved after optimizing the reaction conditions, and a yield of 70.0% can still be maintained after six cycles.

Removal of rubidium from brine by an integrated film of sulfonated polysulfone/graphene/potassium copper ferricyanide

A novel integrated film of sulfonated polysulfone/graphene/potassium copper ferricyanide (KCuFC/SPSG) was used for selectively extracting rubidium ion (Rb+) from brine. To form KCuFC/SPSG, the precursor film of sulfonated polysulfone/graphene (SPSG) was synthesized by phase conversion process, which was alternately immersed in 0.1 mol·L–1 CuSO4/K4[Fe(CN)6] by in-situ adsorption coupled co-precipitation method. Various data such as nuclear magnetic resonance spectrometer, Fourier transform infrared spectroscope, X-ray photoelectron spectroscope, X-ray diffraction, scanning electron microscope and energy dispersive spectroscopy all verified that abundant KCuFC were uniformly located on the film. The resulting KCuFC/SPSG was used in film separation system. As the solution was fed into the system, the Rb+ could be selectively adsorption by KCuFC/SPSG. After the saturation adsorption, 0.5 mol·L–1 NH4Cl/HCl was fed into the film cell, Rb+ could be quickly desorbed by ion-exchange between Rb+ and NH4+ in the lattice of KCuFC. The purpose of separating and recovering Rb+ from the brine can be achieved after the repeated operation. The effects of pH, adsorption time and interferential ions on the adsorption capacity of Rb+ were investigated by batch experiments. The adsorption behavior fits the pseudo-second order kinetic process, while KCuFC has a higher adsorption capacity (Langmuir maximum sorption 165.4 mg∙g–1). In addition, KCuFC/SPSG shows excellent selectivity for Rb+ even in complex brine systems. KCuFC/SPSG could maintain 93.5% extraction efficiency after five adsorption/desorption cycles.

Separable Representations for Duration and Distance in Virtual Movements.

To navigate through the environment, humans must be able to measure both the distance traveled in space, and the interval elapsed in time. Yet, how the brain holds both of these metrics simultaneously is less well known. One possibility is that participants measure how far and how long they have traveled relative to a known reference point. To measure this, we had human participants (n = 24) perform a distance estimation task in a virtual environment in which they were cued to attend to either the spatial or temporal interval traveled while responses were measured with multiband fMRI. We observed that both dimensions evoked similar frontoparietal networks, yet with a striking rostrocaudal dissociation between temporal and spatial estimation. Multivariate classifiers trained on each dimension were further able to predict the temporal or spatial interval traveled, with centers of activation within the SMA and retrosplenial cortex for time and space, respectively. Furthermore, a cross-classification approach revealed the right supramarginal gyrus and occipital place area as regions capable of decoding the general magnitude of the traveled distance. Altogether, our findings suggest the brain uses separate systems for tracking spatial and temporal distances, which are combined together along with dimension-nonspecific estimates.

Minimum work associated with separating nitrogen from air: An exergy analysis

Background Nitrogen is essential for a variety of industries, including heat treatment, laser cutting, fire protection, and food packaging. Many companies in these industries obtain nitrogen via on-premises air separation processes. The three main processes for separating nitrogen from ambient air are cryogenic distillation, membrane separation, and pressure-swing adsorption (PSA). Improvements to these processes will likely focus on increasing efficiency, resulting in reduced environmental impact owing to less electrical power demand and opportunities for economic incentives. Regardless of the process utilized, a minimum theoretical amount of work input is required to obtain nitrogen gas at different pressures and concentrations compared to ambient conditions. Methods An equation was derived to evaluate the total exergy (including thermo-mechanical and chemical exergy) of product and exhaust mixtures resulting from air separation, indicating the minimum theoretical work input as a function of the product pressure, purity, and process recovery rate. This analysis considered an air separation system as a black box, with the input, output, and exhaust assumed to be ideal gas mixtures of nitrogen and oxygen at 15°C. The analysis applies to cryogenic distillation if the product and exhaust mixtures return to the gas phase. Results In general, the minimum required work input increases with product purity and recovery rate. Plots of minimum theoretical work versus product purity and recovery rate were made for two product pressures (atmospheric and 800 kPa) to show the behavior of the derived equation. Conclusions The analysis allows for direct efficiency (based on the second law of thermodynamics) comparisons between existing processes and future technological innovations in the field of air separation. Actual air separation systems have low efficiencies compared to ideal systems; actual PSA systems were estimated to have second law efficiencies of 5.5–11.2%. Therefore, there is great potential for improvements to current air separation systems.