Sedimentary Package Research Articles

Pre-Quaternary Evolution of the Eurasian Basin: Results of Interpretation of Seismic Profile ARC1407A

The work examined the tectonics and stratigraphy of the Eurasian basin in pre-Quaternary times based on the results of interpretation of the ARC1407A seismic profile and calculations of the theoretical position of linear magnetic anomalies. The sedimentary packages identified on the seismic profile and their stratigraphic adjustments are close to similar studies in the western parts of the Nansen and Amundsen basins. The age assignment of sedimentary strata corresponds to the results of drilling ACEX wells and the main stages of development of the Eurasian basin. The reference horizon of ~34 million years old, previously identified in some scientific works and associated with the cessation of spreading in the western part of the North Atlantic and the entry of the Greenland Plate into the North American Plate, has not been established, which is similar to studies in the western parts of the basins of the Eurasian Basin. For the western part of the Nansen Basin, a reference horizon with an age of ~38 Ma was identified for the first time, previously traced in the western part of the Amundsen Basin, the appearance of which is associated with one of the stages in the development of the Eurekan Orogeny. Also, for the western part of the Nansen Basin, within the ARC1407A section, a reference horizon with an age of ~26 Ma, previously traced in the western part of the Amundsen Basin, is established. The appearance of this boundary is associated with the beginning of unstable spreading in the westernmost segment of the Eurasian basin between the Yermak Plateau and the Morris Jesup Rise. The end of the long stratigraphic hiatus from 44.4 to 18.2 Ma in the ACEX well section clearly correlates with the appearance of sedimentary strata with an age of ~19.6‒18.3 Ma, which confirms the point of view about the beginning of the formation of the deep-sea connection between the North Atlantic and Eurasian basins. This event coincides with a fundamental stage in the restructuring of the movements of the Eurasian and North American plates, expressed in a change in the general direction of migration of the instantaneous opening poles from north-northwest to south-southeast. It is assumed that thick sedimentary deposits in the Nansen Basin and in the rift valley of the Gakkel ridge, observed on seismic section ARC1407A are glaciomarine Late Pliocene-Quaternary in age 2.7 Ma. Apparently these deposits are making up a significant volume of sediment in the eastern part of the Eurasian Basin and the Gakkel Ridge.

Tracing fluid infiltration into oceanic crust up to ultra-high-pressure conditions

Fluid–rock interaction within the altered oceanic crust and across the slab–mantle boundary during subduction facilitates element transfer, but the dynamics of fluid transport and fluid–rock exchange during upward fluid migration are still unclear. A study of metamorphic fluid–rock interaction within a section of subducted oceanic crust was carried out on eclogites and metasediments of the ultra-high-pressure Lago di Cignana Unit (NW Italian Alps). The P–T modeling of a quartzschist shows that garnet grew during the prograde and sporadically during the retrograde path and that phengite mainly records the peak to retrograde conditions. Microscale geochemical analysis of garnets has revealed a systematic evolution of oxygen isotopic composition with garnet major element zonation, with extreme within-sample core–rim variations in δ18O between 18 and 4‰ providing evidence for external fluid influx. Garnet in eclogites and calcschists, as well as garnet cores in quartz-rich lithologies, shows normal compositional zoning, as expected for prograde garnet growth, and a relatively constant oxygen isotopic composition. The outer garnet growth zones within a few metasediments show reverse or discontinuous zoning and progressively lower δ18O. Despite major element zoning, the isotopic composition of mica is homogeneous across chemical zoning in one eclogite and one quartzschist, but shows 6‰ variability in another quartzschist. In the underlying Zermatt–Saas serpentinites, antigorite from nine serpentinite samples shows some variation in δ18O, with average δ18O values for individual samples ranging from 1 to 6‰. These results provide evidence for two main stages of external fluid infiltration: (i) fluids from the dehydration of mafic lithologies entered the sequence at peak conditions around 3 GPa, as indicated by the oxygen composition of intermediate zones of mica and garnet, and (ii) low δ18O fluids from serpentinites infiltrated parts of the sedimentary package during exhumation prior to 1.5 GPa, as recorded by the 4‰ garnet outer rims. Samples recording external fluid infiltration are concentrated in the lower part of the sequence, indicating channelized fluid flow, suggesting focused fluid infiltration due to permeability contrasts between metasedimentary and eclogitic lithologies. Channelized fluid flow in the ultra-high-pressure metasediments of Lago di Cignana has not resulted in systematic decarbonation of the metasediments.

Basin filling and magmatic response to the migration of two-stage rifts: New insights into the late Neoproterozoic tectonics of the northern Tarim Craton

The spatiotemporal evolution of late Neoproterozoic sedimentary basins and their tectono-magmatic context provide essential information regarding the continental rift process of the Tarim Craton during the fragmentation of the Rodinia supercontinent. However, the incomplete exposure of strata and magmatism in the distal continental margin hinders the understanding of different rift phases that trigger continental breakup. The Sawapuqi region is currently located at the northernmost margin of the Tarim Craton and presents an uninterrupted sedimentary sequence and volcanic rocks from the latest Precambrian to the Cambrian period. Herein, we perform an integrated analysis of the Sawapuqi sub-basin and provide critical insights into the Ediacaran stratigraphic and tectono-magmatic evolution that shed light on the final rifting phase. The Sawapuqi sub-basin preserves regressive and transgressive successions, ranging from thick-bedded siltstones and siliceous rocks at the lower unit of the Sugetbrak Formation, through shore gravel-bearing laminated sandstone accumulation (upper unit), and restricted platform stromatolitic carbonates (Qigebrak Formation), to Cambrian mature passive margin sedimentation. An alkaline basaltic layer is interbedded within the coarsening-upward sedimentary packages of the early Ediacaran, recording the final rift-related magmatic pulse in the northwestern Tarim margin. The geochemical signatures of these basalts suggest a relatively shallow-depth derivation from the enriched mantle reservoir in an intraplate setting. The detrital zircon provenance of the coarse-grained siliciclastic to pebbly feldspathic debris sandstone sequence of the upper Sugetbrak Formation indicates the hybrid sediment infills from local metamorphic basements and Neoproterozoic igneous rocks, with progressively increased contribution from the coeval granites in the northern periphery of the Tarim Craton. The stratigraphic evolution from syn-rift clastic rocks to post-rift carbonates and the transition of detrital provenance observed in the Sawapuqi sub-basin suggest the development of a breakup succession at the end of the early Ediacaran period. The margin-localized continental extension and mantle-derived volcanism during the early Ediacaran differed from the distributed extension and bimodal magmatism during the Cryogenian, indicating two-stage extensional modes and subsidences prior to the lithospheric breakup. The rift system of the latter stage, which migrated oceanwards, eventually led to the continental breakup in the northwestern margin of the Tarim Craton. Comparable late Neoproterozoic stratigraphy and magmatic pulses between the Tarim Craton and Yili-Central Tianshan Block (YCTB) support their reconstructions as two conjugate rifted margins. This study indicates that the rift-drift tectonics triggered by this prolonged episodic rifting between the Tarim Craton and the YCTB was closely associated with the final fragmentation of Rodinia.

Westward underthrusting of thick North American crust: The dominant thickening process that built the Cordilleran orogenic plateau

Abstract Quantification of the crustal thickening processes that construct orogenic plateaus is essential for interpreting their genesis. In the North American Cordillera, a 2.75–3.5-km-elevation, 200–250-km-wide plateau was constructed to the west of the Cretaceous–Paleogene Sevier fold-and-thrust belt (SFTB). The SFTB deformed a Mesoproterozoic to Mesozoic sedimentary package that thickened westward from a 2–3-km-thick platform section that was deposited above the ~40-km-thick craton to a 15–25-km-thick continental margin section that was deposited above middle to lower crust that had been significantly thinned during Neoproterozoic rifting. Shortening in the SFTB translated this thick sedimentary package as much as 265 km eastward, which resulted in the relative westward underthrusting of an equivalent length of thick cratonic basement beneath the hinterland region. Measurement of components of thickening with respect to the initial and final crustal thickness above and below the basal thrust décollement demonstrates that thickening accommodated by underthrusting outweighed thickening in the overlying SFTB by a factor of 1.5–3 and was likely the dominant thickening mechanism that constructed the broad hinterland plateau. In eastern Nevada, the reconstructed western edge of the underthrusted craton underlies the western limit of 2.75–3.5 km paleoelevations, which supports this interpretation. This analysis provides an important case study for underthrusting as a first-order thickening process in fold-and-thrust systems that deform sedimentary packages with a high pre-orogenic taper.

The cryptic stratigraphic record of the syn‐ to post‐rift transition in the offshore Campos Basin, SE Brazil

AbstractRift basins typically comprise three main tectono‐stratigraphic stages; pre‐, syn‐ and post‐rift. The syn‐rift stage is often characterised by the deposition of asymmetric wedges of growth strata that record differential subsidence caused by active normal faulting. The subsequent post‐rift stage is defined by long‐wavelength subsidence driven by lithospheric cooling and is typified by the deposition of broadly tabular stratal packages that drape any rift‐related relief. The stratigraphic contact between syn‐ and post‐rift rocks is often thought to be represented by an erosional unconformity. However, the late syn‐rift to early post‐rift stratigraphic record is commonly far more complex since (i) the associated tectonic transition is not instantaneous; (ii) net subsidence may be punctuated by transient periods of uplift; and (iii) strain often migrates oceanward during rifting until continental breakup is achieved with crustal rupture. Previous publications on the Eastern Brazilian marginal basins have not historically used the tripartite scheme outlined above, with the post–pre‐rift interval instead being subdivided into rift, sag and passive margin tectono‐stratigraphic stages. In addition, the sag stage has been previously described as late syn‐rift, early post‐rift or as a transition between the two, with the passive margin stage being equivalent to the classically defined post‐rift, drift stage. Two (rather than one) erosional unconformities are also identified within the rift‐to‐sag succession. In this work, we use 2D and 3D seismic reflection and borehole data to discuss the expression of and controls on the syn‐ to post‐rift transition in the shallow and deep water domains of the south‐central Campos Basin, south‐east Brazil. We identified three seismic–stratigraphic sequences bounded by unconformities, named lower and upper pre‐salt and salt. The lower pre‐salt interval is characterised by wedge‐shaped packages of reflections that thicken towards graben and half‐graben‐bounding normal faults. This stage ends with the development of an angular unconformity, inferred to form as a result of the onset of the oceanward migration of deformation. The upper pre‐salt is typically defined by packages of subparallel and relatively continuous reflections that are broadly lenticular and thin towards fault‐bound basement highs, but that locally contain packages that thicken against faults. The pre‐salt to salt contact is defined by an erosional unconformity that is largely restricted to basement highs, and which is inferred to have formed due to base‐level fall and uplift associated with local fault reactivation, resulting in the formation of channels of possible fluvial origin. Based on its geometries and seismic facies, we conclude that the lower pre‐salt interval is syn‐rifting and syn‐tectonic, deposited during active continental extension and upper crustal faulting affecting the entire evolving margin, whereas the overlying upper pre‐salt is syn‐rifting and post‐tectonic in the Campos Basin, deposited when extension and faulting had migrated seaward to the future location of the spreading centre. The results of our study support the arising notion that the syn‐rift sequence does not only display syn‐tectonic sedimentary packages, and thus the tripartite tectono‐stratigraphic model for rift development is too simplistic and cannot be applied when assessing rifts in the context of the regional development of continental margins.

Basaltic sills emplaced in organic-rich sedimentary rocks: Consequences for organic matter maturation and Cretaceous paleo-climate

Many continental large igneous provinces coincide with climate perturbations and mass extinctions. When basaltic plumbing systems traverse carbon-rich sedimentary rocks, large volumes of greenhouse gases may be generated. We document how intrusive sills of the Mesozoic High Arctic Large Igneous Province affected surrounding fine-grained, organic-rich siliciclastic rocks of the Sverdrup Basin in the Canadian Arctic Archipelago. Petrographic and X-ray diffraction data from samples located near sills show the presence of high-temperature metamorphic phases (diopside, andalusite, garnet, and cordierite). Raman thermometry on organic matter yields peak temperatures of 385−400 °C near sill contacts, tailing off to far-field temperatures of ≤230 °C. Samples located >20 m from sills show no systematic change in vitrinite reflectance and have a VRo eq% value of ∼2.5%, which indicates a temperature of ∼210 °C. The finite element thermal modeling tool SUTRAHEAT was applied to the 17-m-thick Hare Sill, emplaced at 3 km depth at 1105 °C. SUTRAHEAT results show that contact-proximal rocks attain temperatures of >700 °C for a brief period (∼1 year). By 5 years, the Hare Sill is completely solidified (<730 °C), and the temperature anomaly collapses rapidly thereafter as the thermal pulse propagates outward. By 10 years, all rocks within 10 m of the Hare Sill are between 450 °C and 400 °C, rocks at 20 m from the contact attain 200 °C, yet far-field temperatures (>50 m) have barely changed. When multiple sills are emplaced between 4 km and 6 km depth, all rocks between sills reach ∼250 °C after 100 years, showing that it is possible to raise regional-scale background temperatures by ∼150 °C for the observed High Arctic Large Igneous Province sill density. Vitrinite reflectance data and pyrolysis results, together with SILLi thermal modeling, indicate that much of the hydrocarbon-generating potential was eliminated by High Arctic Large Igneous Province intrusions. The SILLi model yields ∼20 tonnes/m2 of organic equivalent CO2 (all carbon gas is reported as CO2) from the Hare Sill alone when emplaced into Murray Harbour Formation rocks with 5.7 wt% organic carbon, and ∼226 tonnes/m2 by emplacement of multiple sills throughout the 2-km-thick Blaa Mountain Group with 3 wt% organic carbon. On a basin scale, this yields a total of ∼2550 Gt CO2 from the Hare Sill, with ∼13,000 Gt CO2 being generated by the multiple sill scenario, similar to estimates from other large igneous provinces. Much of the Blaa Mountain Group rocks now have organic carbon contents of <1 wt%, which is consistent with large volumes of carbon-species gas having been generated, likely a mixture of CO2, CH4, and other species. However, organic-rich Murray Harbour Formation rocks show no obvious reduction in organic carbon content toward the Hare Sill intrusive contacts, which suggests that not all of the carbon was lost from the sedimentary package hosting High Arctic Large Igneous Province magmas. We suggest that some of the gas generated by contact metamorphism failed to drain out for lack of high-permeability conduits, and then back-reacted to form calcite cements and pyrobitumen during cooling.

Sedimentary records in dry karstic valleys: The case of Mambaí, central Brazil

Karstic areas in Central Brazil show significant depositional and erosive facies placed within abandoned dry valley-systems and associated with fluviokarstic dynamics. These valleys have distinct depositional characteristics that offer sedimentary records of both past climatic events in the region and its current fluviokarstic system. The purpose of this paper is to point out and characterize such sedimentary packages, protected by dry valleys that were deposited up until the fluviokarstic transition, thus enabling the correlation of such sediments to past climatic events. The study is based on a combination of geomorphic and sedimentological analyses through the employment of multiple techniques, such as mineralogy, geochronology, stable isotopes, and granulometry, to the analysis of our case studies. These are the three dry valleys around the Ventura, Pedras and Extrema rivers, which in turn comprise the River Vermelho Basin, northeastern Goiás State. Our results suggest that the valleys contain fluvial deposits remnant from the transition of superficial fluvial flow to the underground karstic system. Records provide a general view of the depositional stages placed before and up until the period of fluvial capture in terms of their morphology, dynamics, and sediment architecture. OSL ages indicate that fluviokarstic processes had been in operation since 23 Ka, when the oldest river capture was found to have occurred. Depositions occurred in a reasonably continuous manner, mainly during the last 3.5 Ka, and concentrated around relatively dry and wet events, exhibiting typical depositional gaps in fluvial environments. Consequently, no relationship between the depositions and paleoclimatic events were observed for the analyzed fluviokarstic system.

Distribution of silicification intervals throughout the Barra Velha and Itapema formations: Host rock controls and chronology of silica precipitation (Pre-Salt, Santos Basin, Brazil)

The Barra Velha and Itapema formations, Aptian, Santos Basin, constitute large hydrocarbon reservoirs, mainly in carbonate rocks. These rocks host up to centimeter-thick silica bodies with a variety of textures and geometries along different carbonate facies, suggesting syngenetic, diagenetic, and hydrothermal processes in their formation. The mineralogical and textural changes related to these processes can directly influence the porosity and permeability of the reservoir rocks, turning the study of the silicified intervals important in the exploration and production of these deposits. We present here a systematic macroscopic and microscopic description of the silica bodies and its distribution through the carbonate facies the of Barra Velha and Itapema formations from the Sapinhoá and Búzios fields. Data allow us to identify four geometric types of silica bodies: tabular, irregular, oval and disseminated, which are composed of chalcedony, microcrystalline and macrocrystalline quartz. Tabular, oval, and irregular silica bodies are cross-cutted by mechanical compaction structures such as vertical fractures, boudins and faults. In addition, these bodies include relicts of the host rock lamination, which in turn deflects around them. Thus, silica precipitation must have been penecontemporaneous or in the early stages of diagenesis, before the main mechanical compaction stage. These features were not observed in the disseminated silica type, in the contrary, this type involves and overlaps oval and irregular bodies, indicating that this silica precipitation probably occurred in latter stages in relation to other body types. The genesis of disseminated bodies can then be related to diagenetic or hydrothermal processes during diagenesis. Therefore, the geometry of silica bodies and their spatial distribution are influenced by the host carbonatic petrofabrics and the chronology of silica precipitation within the sedimentary to diagenetic evolution of the sedimentary package. Finally, we present a systematics that can be easily applied to recognize these silica types in other exploration fields of pre-salt interval. The results presented here have great potential to be applied in the research on pre-salt intervals from other Brazilian and African basins since the host carbonate rocks are very similar and favor the development of similar silicification processes and results.

Miocene tropical storms: Carbonate framework approaches and geochemistry proxies in a reservoir model

The Bragantina Platform is an important sedimentary package that occurs in northwestern Brazil, typically around the equatorial western Atlantic coast. Most of the latest Neogene succession of this carbonate-siliciclastic platform consists of the Pirabas Formation of Miocene age (Burdigalian to Serravalian). High-energy coastal storms and hurricanes as a consequence of trade wind anomalies during the Neogene impacted the shallow-water inner marine heterozoan assemblage deposits of the Pirabas Formation. A chaotic overlap of benthic infauna and epifauna, and of demersal and pelagic species in the same section was analyzed using petrography, petrophysics, micro- and macropaleontology, taphonomy, and geochemistry in order to understand sedimentary and paleoenvironmental processes. The equatorial carbonate platform of Brazil reveals high-energy and multiple Miocene tropical storms. This high-energy wave environment caused severe damage to shallow-water heterozoan assemblages at the seafloor, resulting in chaotic faunal arrangements, and removing fine-grained particles thus improving the petrographic properties of the rock (porosity and permeability).

Correlation of Ground Penetrating Radar Data with Geotechnical Prospect Profiles: Reduto Case Study, Belém-PA, Brazil

The study presented in this manuscript aimed to relate the sedimentary strata imaged by the ground penetrating radar (GPR) method through numerical modeling with the mapping of sedimentary strata acquired through geotechnical surveys. The study aimed to expose how obtaining subsoil information through noninvasive/destructive electromagnetic waves is beneficial, as they are reliable and less costly than drilling holes beyond what is necessary to have a subsurface mapping. In this sense, physical-geological modeling was carried out. The information on the type of sediments, acquired through simple recognition surveys carried out in the city of Belém-PA, helped to create a model of a sedimentary package with its respective intrinsic physical properties. The result shows that the GPR recovered with good vertical and horizontal resolution at the beginning and end of the layers of the sedimentary package studied, proving to be very effective for locating geotechnical sounding points and safely reducing costs.

Multi-window spectrum analysis of Búzios oil field PSDM seismic data applied to frequency attenuation study

The intrinsic attenuation is often quantified using the inverse quality factor Q. Methods to estimate Q are mainly based on time domain or frequency domain and sensitive to amplitude and/or frequency band variations. In this sense, noise, signal artifacts or processing steps can alter the amplitude, frequency content and the waveform, what may lead to inaccurate calculations of Q. A way to better understand the frequency band variation in seismic data and verify patterns or problems occurring in the signal frequency band is performing layered or window-by-window spectrum analysis. This work describes a multi-window spectrum analysis method used to better understand the frequency attenuation process as the seismic wave travels through the sediments from the sea bottom down to the reservoir depths in a 3D Kirchhoff Pre-Stack Depth Migrated (PSDM) seismic data from Búzios oil field. To perform the spectral analysis in frequency domain, the PSDM volume was converted to time domain using the same interval velocity volume used to depth-migrate the data. The variation of frequency band as the signal propagates through the sediment package was analyzed dividing the studied crossline sections in 13 layers of 200 ms each, from sea bottom down to the base of pre-salt reservoir formations. The results suggest that most part of higher frequency loss has been occurred in post-salt package. This may be an indication of significant viscoelastic behavior or strong stratigraphic filtering of this interval. Sequentially, higher frequency content is lost slowly from salt top down to the last layer located inside pre-salt formation. Very slight frequency spectrum variation below salt top indicates elastic behavior of the salt formation and underling pre-salt formation in this interval. The spectrum analysis method proposed here has shown to be useful and efficient to identify intervals of different attenuation patterns in seismic data. Additionally, the frequency band study produced by our spectrum analysis can be used to quality-control Q-factor estimation computed by different methods.

Discrete Measurements of the Least Horizontal Principal Stress from Core Data: An Application of Viscoelastic Stress Relaxation

Summary The emerging Paradox Oil Play in southeastern Utah is among the most significant unconventional plays in the western USA. The mean total undiscovered oil resources within just the Pennsylvanian Cane Creek interval of the Paradox Basin are believed to exceed 215 million barrels. However, to date, less than 5% (~9 million barrels) of the total Cane Creek resource has been produced from fewer than 40 wells, and only approximately one-half of those are horizontal wells. More than 95% of production is from the central Cane Creek Unit (CCU). Natural fractures are a key feature of many production wells, but stimulation by induced hydraulic fractures is not consistently successful. We hypothesize that more effective production in this play will rely on better fundamental characterization, especially on better quantification of the state of stress. Approximately 110 ft of core, well logs, and a diagnostic fracture injection test (DFIT) were acquired from the State 16-2 well within the CCU. With these data, we applied two methods to constrain and clarify the state of stress. The first technique, the Simpson’s coefficient method, provides lower bounds on the two horizontal principal stresses and relies on only limited data. Alternatively, the viscoelastic stress relaxation (VSR) method is used to estimate the least horizontal principal stress, building on observations that principal stresses become more isotropic as the viscous behavior of a rock is more pronounced. Results of these two methods support the hypothesis that the state of stress in the CCU of the Paradox Basin is nearly lithostatic and isotropic. Other factors consistent with this hypothesis include high formation pore pressure, which tends to reduce the possible stress states by changing the frictional failure equilibrium; lack of induced fractures in the core, which should be present in the case of stress anisotropy; and interbedded halite layers, which given their high degree of ductility, probably lead to greater VSR for the entire sedimentary package.

Offshore Fault-related Fold along the Eastern Marginal Zone of Ishikari Lowland, Hokkaido, Japan

Distributions, characteristics, and activities of offshore fault-related folds which comprise the southern part of the Eastern Boundary Fault Zone of Ishikari Lowland (EBFIL) are clarified by conducting a high-resolution multi-channel seismic reflection survey. To determine termination point of the fault zone, we placed seven survey lines perpendicular to the fault-related folds with a total line length of 107.5 km. We choose a compact water gun (15 cubic inch) as the seismic source to obtain high-resolution imagery of the Late Quaternary and investigate activity of the fault zone. Based on seismic facies, we distinguished packages of offshore sediment (unit 2, 3 and 4, in descending order), which separated by downlap surfaces and correlated to the Middle to the Late Pleistocene. They are progressively deformed by the active fault and compose series of fault-related folds (Fo1, Fo2 and Fo3). Traces of these folds are figured out from the seismic sections obtained by this study and existing surveys. Deformation related to these folds are clearly recognized in the topography of the unit 4 base. The reliefs of strata indicate that the Fo2 fold should have uplifted seafloor at a rate of 0.09-0.20 m/ky since 300 ka. The structures, spatial distributions and growth-rates of the folds suggest that Fo1 and Fo2 should compose series of anticline developing at the front of EBFIL. Besides, Fo2 fold would compose the southern termination of the fault zone. This study has successfully demonstrated that densely operated high-resolution seismic survey can figure out distribution and activity of offshore active faults in the Late Quaternary, even at the outside of shelf.

Evidence for an Extreme Cooling Event Prior to the Laschamp Geomagnetic Excursion in Eifel Maar Sediments

We present a timeseries of flood and slumping phases in central Europe for the past 65,000 years from event layers in sediment cores from infilled Eifel maar basins (Germany). Palynological, petrographic and organic carbon (chlorins) records are used to understand the precise timing of these events. Periods of increased flood activity seem to coincide with Heinrich stadials in marine sediment records, which are associated with cold and more arid climate conditions, indicating a vegetation response within the maars’ catchment areas. This multi-proxy correlation reveals prominent slumps at different maar sites during Greenland Stadial (GS) 12. The stratigraphy is based on sediment records from the Auel infilled maar and we thus call this event Auel Cold Event (ACE). Frozen and fractured sediment packages within the slump suggest deep frost or permafrost conditions for the region during the stadial. The results agree well with sediment archives and archeological sites across Europe that report severely cold and arid conditions for the stadial. This supports the assumption that GS12 was indeed one of the coldest periods of the last glacial cycle rather than the Heinrich stadials. Based on our age model, the ACE occurred at 43,500 yr b2k (years before the year 2000), which coincides with the initial weakening of Earth’s magnetic field strength prior to the Laschamp geomagnetic excursion.

Average QP and QS estimation in marine sediments using a dense receiver array

A new spectral ratio method has been used to compute average P- and S-wave quality factors, [Formula: see text] and [Formula: see text], for the sedimentary sequence below the “V”-shaped Oseberg permanent reservoir monitoring (PRM) system. Quality factors are important for a more accurate characterization of the subsurface and to obtain additional information on the physical processes within the earth, such as fluid content and partial melt. However, few methods compute the average Q-value in sediments for P and S waves in a region, which can be used as a constraint for attenuation models in more sophisticated inversion techniques such as full-waveform inversion or attenuation tomography. To address this, a spectral ratio method using two receiving stations, one installed on sediment and one installed on bedrock, has been developed. This has resulted in quality factor estimations ranging from approximately 64 to 137 for P waves and 29 to 123 for S waves using a subset of the 172 ocean-bottom nodes in the Oseberg PRM system and a seismometer in Bergen, Norway. The [Formula: see text] values are more scattered and hence more uncertain than the [Formula: see text] values due to the P-wave signal being close to the background noise level. In the study area, local earthquakes of magnitude as low as [Formula: see text] 2.4 can be used to obtain [Formula: see text] values and earthquakes of magnitude lower than 2.1 to find [Formula: see text] values, with the possibility of using lower magnitude events if the epicentral distances to the receivers are similar and smaller. Using this method, the average quality factor in sediment packages, for a variety of regions, can be estimated using appropriate raypath configurations connecting source and receiver.

Variable element enrichment sources and contributions to volcanic rocks along the Lesser Antilles Island Arc

Understanding relationships between different components involved in subduction-related recycling of sediment at arc volcanic systems has long been a focus of study. It is generally understood that volcanic arc lavas incorporate materials from the down-going slab including fluids, fluid mobile elements (FME), and fluid modified large ion lithophile elements (LILE), largely derived from subducted sediments and serpentinized ultramafic rocks. Past studies have presumed bulk sediment contributions rather than addressing localized variations in sediment composition. We examine trace element variability along the Lesser Antilles Island Arc (LAIA) and show that sediment inputs via fluid transfer to the mantle wedge are necessary to explain high B (up to 50 ppm), high B/La ratios, and higher As, Cs, Rb in the central LAIA. In contrast, the northern portion of LAIA is enriched in Ba, Sr and U/Th, with low FME. Grenada has low FME abundances, low Ba/La, but higher Sm/La. Our results suggest that modification of LAIA mantle source by fluid addition is important for the central islands but find that sediment enrichment is more likely in the northern section of the LAIA. Li/Yb ratios suggest the Grenada signature is chemically more comparable to sediment from DSDP Site 144 (Demerara Rise), while Martinique magmas in the central LAIA are affiliated to sediments from Site 543 (offshore Dominica). Unexpectedly, the northern portion of LAIA is not directly relatable to Site 543 sediments but instead trends back toward a sediment source similar in composition to Site 144 but with lower B, lower La/Sm and higher Ba. Binary mixing models suggest the northern islands are likely influenced by small amounts of sediment melt similar to average Site 144 sediments, but with Ba concentrations ranging from 1,250 to 1,500 ppm. Trace element ratios then likely result from different levels of contribution from sediment packages both spatially and temporally along the arc, with some variation evident among samples from the same island. We suggest that the process of recycling subducted sediment along the arc is variable along the length of the LAIA, wherein the trace element relationships are likely strongly influenced by the types of sediment being subducted along strike.

The lithostratigraphical context of the English Chalk Rock (Turonian)

Correlations of borehole geophysical logs in the middle and upper Turonian Chalk Group are used to consider recent proposals for a revision in understanding of a unit of hardgrounds (Chalk Rock) and associated stratigraphy developed across parts of southern England. Along the northern edge of the London and Wessex basins, geophysical logs reveal a laterally continuous framework of correlatable inflection patterns in the New Pit Chalk, with the package of sediment immediately below the Chalk Rock showing a trend of lateral thinning and increasingly condensed sedimentation westwards into areas where the oldest of the Chalk Rock Hardgrounds (Ogbourne Hardground) is present. However, apart from local absence of the Glynde Marls Complex near the top of the New Pit Chalk, there is no evidence for the presence of a major erosion event. This questions recent interpretations of microcrinoid data, reportedly showing that the Ogbourne Hardground lithifies a stratigraphical level in the lower part of the New Pit Chalk, with the middle and upper parts of this unit corresponding with a hiatus and related short-lived globally significant sea level fall. Macrofossil biostratigraphy supports the geophysical log interpretations, with evidence of both younger and older parts of the New Pit Chalk below the Ogbourne Hardground. The data are consistent with the Ogbourne Hardground in Wiltshire and Berkshire representing a highly condensed equivalent of thickened nodular chalk fabrics at the base of the Lewes Nodular Chalk in the eastern Chilterns.

Southern Ocean biogenic blooms freezing-in Oligocene colder climates

Crossing a key atmospheric CO2 threshold triggered a fundamental global climate reorganisation ~34 million years ago (Ma) establishing permanent Antarctic ice sheets. Curiously, a more dramatic CO2 decline (~800–400 ppm by the Early Oligocene(~27 Ma)), postdates initial ice sheet expansion but the mechanisms driving this later, rapid drop in atmospheric carbon during the early Oligocene remains elusive and controversial. Here we use marine seismic reflection and borehole data to reveal an unprecedented accumulation of early Oligocene strata (up to 2.2 km thick over 1500 × 500 km) with a major biogenic component in the Australian Southern Ocean. High-resolution ocean simulations demonstrate that a tectonically-driven, one-off reorganisation of ocean currents, caused a unique period where current instability coincided with high nutrient input from the Antarctic continent. This unrepeated and short-lived environment favoured extreme bioproductivity and enhanced sediment burial. The size and rapid accumulation of this sediment package potentially holds ~1.067 × 1015 kg of the ‘missing carbon’ sequestered during the decline from an Eocene high CO2-world to a mid-Oligocene medium CO2-world, highlighting the exceptional role of the Southern Ocean in modulating long-term climate.

An alternative interpretation of small-bodied turtles from the “Middle Purbeck” of England as a new species of compsemydid turtle

A series of small-sized fossil turtles were collected from Beckles’ Pit, Durlston Bay, Dorset, United Kingdom in 1856 from a sediment package referable to the Early Cretaceous (Berriasian) Purbeck Group. The two primary accounts that previously documented these turtles concluded that they represent the juveniles of the coeval early pleurosternid Pleurosternon bullockii. A brief, third account, however, suggested that these may represent a new species of compsemydid turtle. We here highlight a series of discrete morphological characters that consistently distinguish the small-bodied turtles from Beckles’ Pit from large-bodied Pleurosternon bullockii, in particular the arrangement of the bones and scutes along the anterior margin of the shell. As these characters are otherwise used to diagnose new species of turtles, in particular compsemydids, and to establish the phylogeny of fossil turtles, we side with the latter interpretation and name a new taxon of early compsemydid, Tongemys enigmaticagen. et sp. nov. The early record of compsemydid is restricted to the Early Cretaceous of Europe, but is extremely fragmentary. We suggest that this may be a bias towards the collection and identification of small turtle remains, but also that a re-study of Early Cretaceous continental turtle faunas is likely to yield further material.

Litho- and biostratigraphy of a late Oligocene–Early Miocene succession in the Weber area, southern Hawke’s Bay, and implications for early Hikurangi subduction-margin evolution

ABSTRACT A deep-marine sedimentary succession of Whaingaroan to Altonian age (Early Oligocene–Early Miocene), cropping out near Weber, southern Hawke’s Bay, records abrupt changes in depositional paleoenvironments and sedimentary lithofacies. Highly calcareous early Waitakian (latest Oligocene) Weber Formation (Mangatu Group/Waka Supergroup) is unconformably overlain by terrigenous-dominated late Waitakian–Otaian (Early Miocene) Coast Road or Whakataki formations (Tolaga Group/Māui Supergroup). Most notably, in some localities, lowermost parts of the Coast Road Formation (Mangapuku Mudstone Member) contain prominent matrix-supported extra-formational olistoliths of centimetre to decametre scale derived from the underlying Weber Formation. Deposition of these blocks is attributed to deep-water collapse of parts of rapidly growing, over-steepened, reverse-fault-controlled thrust ridge(s). The onset of Coast Road and Whakataki formation deposition and associated abrupt changes in sedimentary lithofacies correlate to prominent Early Miocene lithological, mineralogical, and paleoenvironmental changes elsewhere along the Hikurangi Margin. We attribute these bio- and lithostratigraphic changes as evidence for significant shortening and upper-plate reverse faulting marking the onset of subduction beneath eastern North Island during the mid-Waitakian (c. 23 Ma). Proposed lithostratigraphic revisions presented herein help clarify depositional events and correlative sedimentary packages within the Miocene Hikurangi margin.