Tourmaline deposit in Sikait area (Southern Eastern Desert of Egypt [SEDE]) is closely associated with metapelitic schistose rocks that belong to Neoproterozoic time. The distribution of tourmaline was mostly controlled by Nugrus shearing, along with schist leucocratic rock varieties (leucogranite, pegmatite, and aplite dikes), which are syntectonically dissected by hydrothermal quartz veins. Local concentrations of tourmaline occur either as discontinuous tourmalinite bands/pockets or as disseminated isolated clusters of crystals within the metapelitic schistose rocks, pegmatites, and quartz veins. Chemical and mineralogical changes accompanying with tourmaline formation have been observed within the schistose rocks in contact with a pegmatitic bodies in Sikait area. Four mineral assemblages were identified on approaching to the pegmatite contact: (1) Quartz-Biotite-Potassium Feldspar-Chlorite assemblage (Q-B-K-C); (2) Quartz-Biotite-Tourmaline-Chlorite assemblage (Q-B-T-C); (3) Tourmaline-Quartz-Muscovite assemblage (T-Q-M); and (4) Tourmaline-Quartz assemblage (T-Q). Toward the pegmatite contact, K, Li, Rb, SiO2, CaO, MgO, Sr, and Ba are decreased, while Al2O3, B2O3, Na2O, Fe (tot), Zr, Y, and Th are moderately increased. Variations in the mineral assemblages and whole-rock chemistry within the four alteration zones appear to be controlled by boron metasomatism and potash leaching. The normalized rare earth element patterns of rock samples from the four alteration zones suggest a partial alteration of the original sedimentary patterns by the metasomatic-magmatic fluids. The alteration could be either a single phase of interactions between pegmatite fluid and schists with B-, Li-, Rb-carrying fluid or a couple of phases (B-, Mn-, Be-rich fluid and Rb-, Li-, K-rich fluid). In all cases, boron from the pegmatite-associated fluids reacts with the surrounding schistose rocks to breakdown of sheet silicate which acts as “traps” for Rb, Sr, Li, Ba, and K and hence leads to tourmaline-rich assemblages.
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