• Plasmonic Au nanoparticles are synthesized in TiO 2 crystal by ion implantation. • Third-order optical nonlinearity tailoring is achieved through charge transfer between Au nanoparticles and TiO 2 . • Enhanced modulation depth and optimized saturation intensity suggest significant potential photonic applications. Gold nanoparticles (Au NPs) are synthesized inside TiO 2 crystal by Au + ion implantation. The incorporation of Au + ions in TiO 2 brings out the modification of optical features of the bulk due to the localized surface plasmon resonance (LSPR) effect. The linear absorption spectra of Au NPs dispersed in TiO 2 crystal possesses an absorption peak at 638 nm. The third order optical nonlinearities of TiO 2 with Au NPs are modulated with reduced saturation intensity and increased modulation depth, compared with pure TiO 2 bulk. Our results pave a way to use TiO 2 with embedded Au NPs for nonlinear photonic applications.
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