Saturated Vapor Research Articles

Co-solvent strategy for highly efficient perovskite solar cells by spray coating

The ultrasonic spray coating has been shown to be an effective technique for scaling up production. The nucleation and crystallization process of the perovskite film prepared by the ultrasonic spraying approach is more complicated than that by the spin coating, but they are essential to gaining efficient perovskite solar cells (PSCs). At the same time, the green solvent is the primary problem that must be solved in the process of PSCs commercialization. In this paper, the low boiling point and green solvent isopropyl alcohol (IPA) is introduced into the perovskite precursor solution to prepare FAPbI3 perovskite by ultrasonic spraying. The addition of IPA enhanced the saturated vapor pressure of the precursor solution, which can create the local chemical microenvironment on the film surface and subsequently retard the nucleation rate from 8.31 s to 8.54 s at nucleation stage. The local chemical improves the initial homogeneity of the sol–gel phase and then leads to improved structural and optoelectronic properties within the FAPbI3 film via sufficient crystallization from the sol–gel phase to α-FAPbI3. Ultimately, IPA-based PSCs exhibit the champion device efficiency of 22.43 %. The good long-term stability of PSCs (maintain more than 90 % of the initial efficiency after 1000 h, and keep 80 % after 400 h) in ambient conditions.

Topography formation driven by sublimation of pure species on icy airless worlds

Sublimation can drive morphologic changes on the surfaces of icy, airless worlds; the magnitude of these changes depends sensitively on their surface shape, subsurface geology, and volatility of the ice species present. To predict the steady-state and stability of the surface, we examine the molecular transport conditions and their constraints for several pure species sublimating from irregular surfaces in a free-molecular regime subject to variations in thermal conditions at or near the surface. We find that the temperature difference, ΔT∗ between the high and low points on the surface required for morphological instability changes of a given surface geometry increases as the volatility of the ice species increases. From Figure 4, for k=1 and Ts=150K, ΔT∗ is about 3K for H2O and 5K for CO2. Furthermore, we developed an analytical relationship between the saturation vapor pressure of a pure species, its surface geometry and temperature profile, and the required molecular transport conditions.

Novel method for recovering valuable metals from Sn ash: Vacuum carbothermal reduction-directional condensation

Sn ash recycling is an industry with positive development prospects, as it provides better-protected resources, promotes sustainable development, and lays a solid foundation for future development. In this study, an innovative vacuum carbothermal reduction-directional condensation process was developed. The thermodynamic analysis results indicated that the initial reaction pressure and temperature for the carbothermal reduction of the system was 1–10 Pa and 998–1063 K, respectively. The saturation vapor pressure, separation coefficient, and condensation temperature of Sn, Pb, and Zn in the reduced products differed significantly, and their separation could be achieved by controlling the volatilization and condensation temperatures. A single-factor experiment investigated the effects of carbon ratio, temperature, and time on the reduction efficiency, direct yield, and recovery rate. The optimal experimental conditions were the ratio of MeO to C of 4:1, temperature of 1373 K, and time of 120 min. Sn, Pb, and Zn products were obtained at different positions. This process shortens the traditional process, reduces the reduction cost of Sn, and enables the implementation of the process, making it environmentally friendly.

The Impact of Gravity Waves on the Evolution of Tropical Anvil Cirrus Microphysical Properties

AbstractAnvil cirrus generated by deep convection covers large fractions of the tropics and has important impacts on the Earth's radiation budget and climate. In situ measurements made with high‐altitude aircraft indicate a rapid transition in ice crystal size distributions and habits as anvil cirrus ages. We use numerical simulations to investigate the impact of high‐frequency gravity waves on the evolution of anvil cirrus microphysical properties. The impacts of both monochromatic gravity waves and ubiquitous stochastic mesoscale temperature fluctuations are simulated. In both cases, the interplay between wave‐driven temperature fluctuations, deposition growth/sublimation, and sedimentation causes accelerated removal of both small ice crystals (diameters less than about 10 μm) and large crystals (diameters larger than ≈30 μm). These changes are consistent with the observed evolution of anvil cirrus microphysical properties. The Kelvin effect (higher saturation vapor pressure over curved surfaces) is a critical factor in the anvil evolution, driving mass transfer from small to large ice crystals. The wave‐driven decrease in ice concentration is much faster for typical anvil cirrus detrained at ≃11.5–12.5 km than for less frequent anvils at 15.5–17.5 km because of the strong temperature dependence of deposition growth and sublimation rates. The simulations also show that waves, along with the Kelvin effect, drive growth of mid‐sized (5–20 μm) ice crystals, which is consistent with the observed transition to bullet rosette habits in aging anvil cirrus. We conclude that high‐frequency gravity waves, which are generally not resolved in large‐scale models, likely have important impacts on anvil cirrus microphysical properties and lifetimes.

Vapor-liquid equilibrium and thermodynamic properties of saturated argon and krypton from Monte Carlo simulations using abinitio potentials.

Vapor-liquid equilibria and thermodynamic properties of saturated argon and krypton were calculated by semi-classical Monte Carlo simulations with the NpT + test particle method using abinitio potentials for the two-body and nonadditive three-body interactions. The NpT + test particle method was extended to the calculation of second-order thermodynamic properties, such as the isochoric and isobaric heat capacities or the speed of sound, of the saturated liquid and vapor by using our recently developed approach for the systematic calculation of arbitrary thermodynamic properties in the isothermal-isobaric ensemble. Generally, the results for all simulated properties agree well with experimental data and the current reference equations of state for argon and krypton. In particular, the results for the vapor pressure and for the density and speed of sound of the saturated liquid and vapor agree with the most accurate experimental data for both noble gases almost within the uncertainty of these data, a level of agreement unprecedented for many-particle simulations. This study demonstrates that the vapor-liquid equilibrium and thermodynamic properties at saturation of a pure fluid can be predicted by Monte Carlo simulations with high accuracy when the intermolecular interactions are described by state-of-the-art abinitio pair and nonadditive three-body potentials and quantum effects are accounted for.

Purification of metallurgical-grade crude tellurium based on viscous distillation and gas-phase separation

A method for preparing high-purity tellurium based on viscous distillation and gas-phase separation was developed. By adjusting the condenser structure and condensing temperature to achieve viscous distillation, the dominant condensation zone for tellurium was controlled; hence, poorly volatile substances remained in the crucible, while selenium was separated from tellurium in the gas phase to achieve the purification of metallurgical-grade crude tellurium. Specifically, the saturated vapor pressure, mean free path of tellurium, impurity distribution, and morphologies of the condensate at different locations were investigated in detail. The results for a 500 g upscaled experiment showed that the direct yield of Te was 83.40%, the purity of Te reached higher than 99.9996 wt.% and the selenium content in the dominant condensation zone was reduced to 2.76×10−4 wt.% under the optimal experimental conditions of 5 Pa, 773 K and 90 min.

The effect of temperature on the pressure energy distribution in the process of near-wall single bubble collapse

At the interface between rotating components and the working medium in fluid machinery, cavitation in the liquid is induced. The temperature of the working medium has a significant influence on the cavitation. However, the effect of temperature on the pressure and pressure energy in the collapse of bubbles cannot be explained accurately. This study established cavitation models containing insoluble gases at different temperatures and iron walls. The Transferable Intermolecular Potential 4 Points-Fluctuating Bonds water model and the Reax force field were selected to study the influence of temperature on pressure energy and pressure in the process of bubble collapse. Employing the model, we examined variations in release pressure and the pressure energy associated with bubble collapse within the system at diverse temperatures. This investigation was conducted by establishing 24 monitoring points. The findings revealed that the near-wall single-bubble collapse process could be delineated into four distinct stages: the precollapse stage, the inertia stage, the rebound stage, and the collapse stage. These four stages manifest on both the pressure curve in the simulation and the curve depicting changes in the cavity area during the experimental phase. The influence of temperature on bubble collapse primarily stemmed from its impact on saturation vapor pressure and viscosity. This influence was observed during the precollapse process, where saturation vapor pressure played a dominant role, and in the collapse stage, where viscosity was predominant.

An Unexpected Decline in Spring Atmospheric Humidity in the Interior Southwestern United States and Implications for Forest Fires

Abstract On seasonal time scales, vapor pressure deficit (VPD) is a known predictor of burned area in the southwestern United States (“the Southwest”). VPD increases with atmospheric warming due to the exponential relationship between temperature and saturation vapor pressure. Another control on VPD is specific humidity, such that increases in specific humidity can counteract temperature-driven increases in VPD. Unexpectedly, despite the increased capacity of a warmer atmosphere to hold water vapor, near-surface specific humidity decreased from 1970 to 2019 in much of the Southwest, particularly in spring, summer, and fall. Here, we identify declining near-surface humidity from 1970 to 2019 in the southwestern United States with both reanalysis and in situ station data. Focusing on the interior Southwest in the months preceding the summer forest fire season, we explain the decline in terms of changes in atmospheric circulation and moisture fluxes between the surface and the atmosphere. We find that an early spring decline in precipitation in the interior region induced a decline in soil moisture and evapotranspiration, drying the lower troposphere in summer. This prior season precipitation decline is in turn related to a trend toward a Northern Hemisphere stationary wave pattern. Finally, using fixed humidity scenarios and the observed exponential relationship between VPD and burned forest area, we estimate that with no increase in temperature at all, the humidity decline alone would still lead to nearly one-quarter of the observed VPD-induced increase in burned area over 1984–2019. Significance Statement Burned forest area has increased significantly in the southwestern United States in recent decades, driven in part by an increase in atmospheric aridity [vapor pressure deficit (VPD)]. Increases in VPD can be caused by a combination of increasing temperature and decreasing specific humidity. As the atmosphere warms with climate change, its capacity to hold moisture increases. Despite this, there is a decrease in near-surface air humidity in the interior southwestern United States over 1970–2019, which during the summer is likely caused by a decline in early spring precipitation leading to limited soil moisture and evaporation in spring and summer. We estimate that this declining humidity alone, without an increase in temperature, would cause about one-quarter of the VPD-induced increase in burned forest area in this region over 1984–2019.

Large-area and high-performance SSZ-13 membranes for N2/CH4 separation

Separating N2 from CH4 is challenging but critical for the purification of unconventional natural gas. Herein, large-area and high-quality SSZ-13 membranes were reproducibly produced on the 50-cm-long tubular alumina supports for the N2/CH4 separation for the first time. The effects of test parameters such as pressure drop, temperature, feed flow rate, water vapor and hydrocarbon impurities on separation performance of the membrane were investigated. A mathematic model for concentration polarization (CP) index was established to evaluate the extent of CP. The CP can be released by decreasing feed pressure and increasing feed flow rate. Separation performance of semi-industrial-scale SSZ-13 membrane was superior to most small-area zeolite membranes. The membrane showed excellent stability in the presence of 5–10 % ethane and propane and saturated water vapor. Selectivity and permeance of the membrane can be restored to its initial values when the impurities are removed. The up-scaling and high-quality membranes have the great potentials for the industrial application in natural gas purification.

Experiments to Improve the Efficiency of Obtaining Brass Nanoparticles by Evaporation by a Continuous Beam of High-Energy Electrons

Composite, copper and zinc containing nanoparticles and brass nanoparticles have been obtained by a high-performance method of evaporation of substances by a relativistic electron beam. The change in the stoichiometry of nanopowders produced by stepwise irradiation of a brass ingot placed in a single-zone graphite crucible is considered. It was found that the production of such particles depends on the concentration of saturated vapors of zinc and copper. A two-zone configuration of the crucible has been developed, which makes it possible to realize the simultaneous evaporation of the constituent components, thereby providing the conditions for the formation of uniform brass nanoparticles with a uniform distribution of elements and a high yield of nanopowder. X-ray diffraction analysis (XRD), Transmission electron microscopy (TEM), Energy dispersive X-ray analysis (EDX) were carried out, and the specific surface of the obtained nanoparticles was determined. The mechanism of formation of composite nanoparticles is discussed.

Complete Prevention of Bubbles in a PDMS-Based Digital PCR Chip with a Multifunction Cavity.

In a chamber-based digital PCR (dPCR) chip fabricated with polydimethylsiloxane (PDMS), bubble generation in the chambers at high temperatures is a critical issue. Here, we found that the main reason for bubble formation in PDMS chips is the too-high saturated vapor pressure of water at an elevated temperature. The bubbles should be completely prevented by reducing the initial pressure of the system to under 13.6 kPa to eliminate the effects of increased-pressure water vapor. Then, a cavity was designed and fabricated above the PCR reaction layer, and Parylene C was used as a shell covering the chip. The cavity was used for the negative generator in sample loading, PDMS degassing, PCR solution degassing in the digitization process and water storage in the thermal reaction process. The analysis was confirmed and finally achieved a desirable bubble-free, fast-digitization, valve-free and no-tubing connection dPCR.

Energy-efficient biphasic solvents for industrial CO2 capture: Absorption mechanism and stability characteristics

The traditional CO2 capture process represented by monoethanolamine has excessive energy consumption, serious oxidative degradation and metal corrosion, which limits its potential for large-scale industrial applications. This study produced a highly effective biphasic 3-amino-1-propanol (MPA)–polyethylene glycol dimethyl ether (NHD)–H2O absorbent with easy modulation of phase separation and low levels of oxidative degradation and metal corrosion. The principal absorbent was MPA, and NHD served as the phase separation solvent. NHD's solvent effect decreased the energy barrier preventing MPA from forming zwitterions (MPA+COO−) and carbamate, thus promoting chemical absorption. The large polarity difference between the reaction products and NHD triggered phase separation, producing a low-polarity CO2-lean phase and a high-polarity CO2-rich phase; 97.41% of the absorbed CO2 accumulated in 43.7% of the CO2-rich phase solution. The sensible heat and latent heat of the MPA–NHD–H2O absorbent were relatively low because of the low saturation vapor pressure, high vaporization enthalpy, and excellent phase separation performance of NHD. The regeneration energy was as low as 2.66 GJ/t CO2, which was 30% less than that for monoethanolamine. Additionally, the oxidative degradation rate for the proposed absorbent was only 10.7% of that for monoethanolamine. This study provides a theoretical reference for application of the MPA–NHD–H2O biphasic absorbent.

Innovative approach for predicting daily reference evapotranspiration using improved shallow and deep learning models in a coastal region: A comparative study

Accurate and reliable estimation of Reference Evapotranspiration (ETo) is crucial for water resources management, hydrological processes, and agricultural production. The FAO-56 Penman-Monteith (FAO-56PM) approach is recommended as the standard model for ETo estimation; nevertheless, the absence of comprehensive meteorological variables at many global locations frequently restricts its implementation. This study compares shallow learning (SL) and deep learning (DL) models for estimating daily ETo against the FAO-56PM approach based on various statistic metrics and graphic tool over a coastal Red Sea region, Sudan. A novel approach of the SL model, the Catboost Regressor (CBR) and three DL models: 1D-Convolutional Neural Networks (1D-CNN), Long Short-Term Memory (LSTM), and Gated Recurrent Unit (GRU) were adopted and coupled with a semi-supervised pseudo-labeling (PL) technique. Six scenarios were developed regarding different input combinations of meteorological variables such as air temperature (Tmin, Tmax, and Tmean), wind speed (U2), relative humidity (RH), sunshine hours duration (SSH), net radiation (Rn), and saturation vapor pressure deficit (es-ea). The results showed that the PL technique reduced the systematic error of SL and DL models during training for all the scenarios. The input combination of Tmin, Tmax, Tmean, and RH reflected higher performance than other combinations for all employed models. The CBR-PL model demonstrated good generalization abilities to predict daily ETo and was the overall superior model in the testing phase according to prediction accuracy, stability analysis, and less computation cost compared to DL models. Thus, the relatively simple CBR-PL model is highly recommended as a promising tool for predicting daily ETo in coastal regions worldwide which have limited climate data.

Separation of arsenic from tin anode slime by vacuum distillation

Tin anode slime (TAS) is a high-value waste produced by electrolytic refining of crude tin. In order to reduce the discharge of harmful waste and realize rational recycling, a process of removing arsenic from TAS by vacuum distillation was proposed, and theoretical and experimental studies were carried out. The saturated vapor pressure of each element in TAS and the activation energy of arsenic evaporation during vacuum distillation was calculated. The evaporation temperature and holding time of vacuum distillation for arsenic removal were investigated. The effects of evaporation temperature and holding time on arsenic removal were discussed. The results showed that the residual arsenic content is 0.32–0.19%, and the removal rate of arsenic is 84.87–91.90% at 1153 K and the range of holding time is 30–120min. When the temperature is 1353 K and the holding time from 30 to 120 min, the residual arsenic content is 0.029–0.025% and the removal rate is 99.43–99.59%. The activation energy for the evaporation of arsenic from TAS in vacuum distillation is EAs = 52.76 kJ/mol. The removal of arsenic improves the recycling value of TAS, and provides ideas for treating harmful substances from industrial wastes and recovering valuable metals.

A Study for Estimating the Overall Heat Transfer Coefficient in a Pilot-Scale Indirect Rotary Dryer

An experimental study and dimensional analysis of the effective heat transfer coefficient in a continuous-indirect rotatube dryer using forest biomass as the granular material isare developed in the present work. The study employed a factorial design 33 to investigate the effects of feed flow frequency (20–35–50 (Hz)), drum rotational velocity (6–8–10 (rpm)), and saturated vapor pressure (4–5–6 (bar)) on the heat transfer coefficient. During steady state conditions, the moisture content profiles and inlet and outlet temperatures were measured within the experimental region, and parameters, such as the effective heat transfer coefficient, solid retention change, and moisture content ratio were studied. The results showed that heat transfer was optimized with high solid feeding rates, low pressure, and low rotation, with solid feeding being the predominant factor. The moisture content profiles revealed a change in the hydrodynamic behavior, with the center point of the experimental region being the least optimal. The dimensional analysis yielded a Nu number as a function of Pe, Fr, and the feeding dimensionless number. A new dimensionless energy efficiency number improved the coefficient correlation from 85.88 (%) to 94.46 (%), indicating the developed model potential to predict dimensionless variables and scale continuous-indirect rotatube dryers.

Response of Vegetation to Drought in the Source Region of the Yangtze and Yellow Rivers Based on Causal Analysis

The vegetation and ecosystem in the source region of the Yangtze River and the Yellow River (SRYY) are fragile. Affected by climate change, extreme droughts are frequent and permafrost degradation is serious in this area. It is very important to quantify the drought–vegetation interaction in this area under the influence of climate–permafrost coupling. In this study, based on the saturated vapor pressure deficit (VPD) and soil moisture (SM) that characterize atmospheric and soil drought, as well as the Normalized Differential Vegetation Index (NDVI) and solar-induced fluorescence (SIF) that characterize vegetation greenness and function, the evolution of regional vegetation productivity and drought were systematically identified. On this basis, the technical advantages of the causal discovery algorithm Peter–Clark Momentary Conditional Independence (PCMCI) were applied to distinguish the response of vegetation to VPD and SM. Furthermore, this study delves into the response mechanisms of NDVI and SIF to atmospheric and soil drought, considering different vegetation types and permafrost degradation areas. The findings indicated that low SM and high VPD were the limiting factors for vegetation growth. The positive and negative causal effects of VPD on NDVI accounted for 47.88% and 52.12% of the total area, respectively. Shrubs were the most sensitive to SM, and the response speed of grassland to SM was faster than that of forest land. The impact of SM on vegetation in the SRYY was stronger than that of VPD, and the effect in the frozen soil degradation area was more obvious. The average causal effects of NDVI and SIF on SM in the frozen soil degradation area were 0.21 and 0.41, respectively, which were twice as high as those in the whole area, and SM dominated NDVI (SIF) changes in 62.87% (76.60%) of the frozen soil degradation area. The research results can provide important scientific basis and theoretical support for the scientific assessment and adaptation of permafrost, vegetation, and climate change in the source area and provide reference for ecological protection in permafrost regions.

Combined Effects of Meteorological Factors, Terrain, and Greenhouse Gases on Vegetation Phenology in Arid Areas of Central Asia from 1982 to 2021

Spatiotemporal variations in Central Asian vegetation phenology provide insights into arid ecosystem behavior and its response to environmental cues. Nevertheless, comprehensive research on the integrated impact of meteorological factors (temperature, precipitation, soil moisture, saturation vapor pressure deficit), topography (slope, aspect, elevation), and greenhouse gases (carbon dioxide, methane, nitrous oxide) on the phenology of Central Asian vegetation remains insufficient. Utilizing methods such as partial correlation and structural equation modeling, this study delves into the direct and indirect influences of climate, topography, and greenhouse gases on the phenology of vegetation. The results reveal that the start of the season decreased by 0.239 days annually, the length of the season increased by 0.044 days annually, and the end of the season decreased by 0.125 days annually from 1982 to 2021 in the arid regions of Central Asia. Compared with topography and greenhouse gases, meteorological factors are the dominant environmental factors affecting interannual phenological changes. Temperature and vapor pressure deficits (VPD) have become the principal meteorological elements influencing interannual dynamic changes in vegetation phenology. Elevation and slope primarily regulate phenological variation by influencing the VPD and soil moisture, whereas aspect mainly affects the spatiotemporal patterns of vegetation phenology by influencing precipitation and temperature. The findings of this study contribute to a deeper understanding of how various environmental factors collectively influence the phenology of vegetation, thereby fostering a more profound exploration of the intricate response relationships of terrestrial ecosystems to environmental changes.

Thermal and Viscous Irreversibilities Analysis in a Liquid Metal Phase Change Counter Flow Heat Exchanger

Sodium, a liquid metal, is utilized in a heat exchanger system coupled to a nuclear reactor to produce hydrogen. The subcooled liquid metal enters a counterflow heat exchanger, undergoes a phase change, and exits as superheated vapor. The sodium heating process occurs through heat exchange with superheated helium vapor in three phases: subcooled liquid, saturated vapor, and superheated vapor. This article analyzes the thermal and hydraulic performance of the three stages of the heat exchanger through thermal and viscous irreversibilities using analytical simulation. The solution obtained is based on applying the thermal efficiency method and the second law of thermodynamics. The thermodynamic Bejan number, the relationship between thermal irreversibility and total irreversibility, allows a cost-benefit analysis when determining thermal performance and viscous dissipation. The essential physical quantities used in the analysis are the lengths and internal diameters of the three segments of the heat exchanger. The results are analyzed and compared with previous analytical work published in the literature. Numerical and graphical results are obtained for temperature profiles, thermal effectiveness, heat transfer rate, thermal irreversibilities, pressure drops, viscous irreversibilities, entropy generation rate, and Bejan numbers. It is demonstrated that the cost-benefit is highly advantageous when the diameter used for the internal tubes of the three segments is equal to the diameter of the saturated sodium vapor section, corresponding to ¼ of the speed of sound in the tube.

Cryogenic RPWELL: a novel charge-readout element for dual-phase argon TPCs

The first operation of a cryogenic Resistive Plate WELL (RPWELL) detector in the saturated vapor of liquid argon is reported. The RPWELL detector was composed of a Thick Gas Electron Multiplier (THGEM) electrode coupled to a metallic anode via Fe2O3/YSZ ceramics (Fe2O3 in weight equal to 75%), with tunable bulk resistivity in the range 109–1012 Ω·cm. The detector was operated at liquid argon temperature in saturated argon vapor (90 K, 1.2 bar) and characterized in terms of its effective charge gain and stability against discharges. Maximum stable gain of G≈17 was obtained, without discharges. In addition, preliminary results from novel 3D-printed thermoplastic plates doped with carbon nanotubes are presented.

Wet-to-dry transition description in the mixture of working fluids

The organic rankine cycle performance and some similar processes depend on many factors. One of them is the category of the working fluid, influencing the performance through the phase/phases during and at the end of the expansion process. Droplet formation for wet fluids and superheated for dry fluids motivated the researchers to seek isentropic working fluids, where expansion could proceed and terminate in a saturated vapour state. The shape of the T-s diagram is a material property; it cannot be changed for real pure fluids, but small jumps can be initiated by replacing one working fluid with a chemically very similar one, like Propane (a wet one) with Butane (a dry one). Our study presents a much smoother transition, using mixed working fluids prepared from chemically similar materials to obtain almost ideal zeotropic mixtures. The main point of our study is to show the wet-to-dry transition for mixtures and prove or disprove the existence of compositions where the fluid can show T-s diagram resembling the ones for ideal isentropic working fluids. For this purpose, Propane was mixed with other alkanes, such as Butane, Pentane, and Hexane, in various compositions, and the thermophysical properties of fluids were calculated by using the REFPROP software program. Wet-to-dry transitions were shown for the Propane/Hexane mixture at (0.6584 + 0.3416 mass fraction), while (0.5823 + 0.4177 mass fraction) and (0.6436 + 0.3564 mass fraction) was the transition mixture for Propane/Butane and Propane/Pentane respectively. Consequently, when exceeding the mentioned composition range, the fluids switch from wet to dry without forming a composition showing ideal isentropic properties. Therefore, isentropic working fluid (showing an infinite slope for the saturated vapour branch in a finite, nonzero temperature range) was not found during this transition.