Reverse Rate Research Articles

Effects of direction reversals on patterns of active filaments

Active matter systems provide fascinating examples of pattern formation and collective motility without counterpart in equilibrium systems. Here, we employ Brownian dynamics simulations to study the collective motion and self-organization in systems of self-propelled semiflexible filaments, inspired by the gliding motility of filamentous Cyanobacteria. Specifically, we investigate the influence of stochastic direction reversals on the patterns. We explore pattern formation and dynamics by modulating three relevant physical parameters, the bending stiffness, the activity, and the reversal rate. In the absence of reversals, our results show rich dynamical behavior including spiral formation and collective motion of aligned clusters of various sizes, depending on the bending stiffness and self-propulsion force. The presence of reversals diminishes spiral formation and reduces the sizes of clusters or suppresses clustering entirely. This homogenizing effect of direction reversals can be understood as reversals providing an additional mechanism to either unwind spirals or to resolve clusters.

Preparation and Properties Study of Wood-Based Cushioning Materials

Traditional cushioning package materials, such as Expended Polystyrene (EPS) and Expanded Polyethylene (EPE), were made with petroleum-based plastics, which are harmful to the environment. It is crucial to develop renewable bio-based cushioning materials that can replace the aforementioned foams due to the rising energy demands of human society and the depletion of fossil fuels. Herein, we report an effective strategy for creating anisotropic elastic wood with special spring-like lamellar structures. Selective removal of lignin and hemicellulose by simple chemical treatment and thermal treatment of the samples after freeze-drying results in an elastic material with good mechanical properties. The resulting elastic wood has a reversible compression rate of 60% and a high elastic recovery (99% height retention after 100 cycles at 60% strain). Drop tests revealed that the elastic wood has excellent cushioning properties. In addition, the chemical and thermal treatments also enlarge the pores in the material, which is favorable for subsequent functionalization. By loading the elastic wood with a muti-walled carbon nanotube (MWCNT), electromagnetic shielding properties are achieved, while the mechanical properties of elastic wood remain unchanged. Electromagnetic shielding materials can effectively suppress various electromagnetic waves propagating through space and the resulting electromagnetic interference and electromagnetic radiation, improve the electromagnetic compatibility of electronic systems and electronic equipment, and ensure the safety of information.

Low perturbation limit decoherence analyzed by scaling the Double Quantum Hamiltonian

By varying the magnitude of the effective interaction between spins in relation to the perturbations, we study the decoherence behavior in a connected proton system. Making use of the Magnus expansion, we introduce a NMR pulse sequence that generates an average Hamiltonian with Double Quantum terms multiplied by a scaling factor, δ, with the possibility to take positive and negative values. The performance of the pulse sequence for different values of the scaling factors was validated in polycrystalline adamantane, by observing the evolution of the polarization. A time reversal procedure, accessible through the change of sign in the controlled Hamiltonian, was necessary to observe multiple quantum coherences. The spin counting develops a characteristic growth in two species of clusters for the scaled time. The influence of the scaling factor on the reversibility was observed through the behavior of the Loschmidt echoes, which decayed faster as the scaling factor increases. From the analysis of dynamics and its reversibility, we extracted characteristic times for the spin diffusion, T2δ and the intrinsic decoherence decay, T3δ for each scaling factor δ, and perturbation time scale, TΣ. Observing the dependence of reversibility vs. perturbation rates, both normalized with the spin diffusion rate, we find that in the limit of low perturbations, T2δ/T3δ deviates from the linear dependence on T2δ/TΣ that corresponds to strong perturbation. The asymptotic value T2/T3≈0.15 as T2δ/TΣ vanishes, gives evidence that the main source of irreversibility is the intrinsic decoherence associated to the chaotic many-body dynamics of the system.

Fitness costs of pyrethroid resistance in the polyphagous pest mite, Halotydeus destructor, under field conditions

The redlegged earth mite, Halotydeus destructor, is an economically important pest of winter field crops and pastures in Australia, and has evolved field resistance to pyrethroid chemicals through a polymorphism in the voltage-gated parasodium channel leading to knockdown resistance (kdr). In this study, we quantified the rate of reversion to susceptibility of partially resistant H. destructor populations under field conditions in the absence of pesticide exposure. This was conducted over multiple years at two geographically distant locations with mite populations known to possess pyrethroid resistance. Fitness costs associated with pyrethroid resistance were identified through reductions in the frequency of kdr resistance alleles in the absence of pesticides. This was assessed using an amplicon sequencing approach targeting known resistance alleles. We also found that resistance can increase rapidly in frequency after only a single pyrethroid application in the field. Our results highlight that, once established in H. destructor populations, pyrethroid resistance will not easily be lost even after several years, emphasizing the importance of limiting the evolution of resistance in the first place. This helps to explain why pyrethroid resistance in H. destructor continues to persist at very high frequencies in the field and continues to expand within Australia despite the existence of fitness costs. Understanding field fitness costs associated with pesticide resistance is important when devising resistance management strategies for this pest.

Serological surveillance on potential Plasmodium vivax exposure risk in a post-elimination setting.

China was declared malaria free in June of 2021. In the post-elimination setting, vigilant surveillance is essential to sustain malaria free status. Serological surveillance has been recognized as an efficient tool for assessing the immunity levels and exposure risk in a population. In this study, a cross-sectional serological survey was conducted in Yingjiang County, China, in August-September, 2021. The study sites were villages along the borders with Myanmar, which have no local transmission since the last indigenous case registered in 2016. A total of 923 participants from six villages were enrolled. The majority was aged > 36 years (56.12%) and 12.46% (115/923) participants had experienced malaria infection at least once. A magnetic- bead-based assay was used to test antibodies against Plasmodium vivax antigen PvMSP-119 to evaluate the prevalence of antibody positive subjects. A reversible catalytic model was used to assess the risk of exposure. The prevalence of anti-PvMSP-119 IgG was 12.84% [95% confidence interval (CI): 9.22%-16.47%], 13.93% (95% CI: 10.11%-17.74%), and 3.57% (95% CI: 1.40%-5.75%) in three different line-of-defense areas, which differed significantly (P < 0.0001). The prevalence of anti-PvMSP-119 IgG increased with age and no statistically significant difference was detected between the sexes. The reversible catalytic model indicated that the seropositive conversion rate and seronegative reversion rate were 0.0042, 0.0034, 0.0032 and 0.0024, 0.0004, 0.0065 in the first-, second-line-of-defense area and total areas, respectively, and the fitted value did not differ significantly from the observed value (P > 0.1). Although this study found the prevalence of antibody-positive subjects and the seroconversion rate in this post-elimination setting were lower than that in transmission setting, the population still had an exposure risk. Serological surveillance should be considered in post-elimination settings to provide valuable information with which to evaluate the risk of malaria re-establishment.

Kumaraswamy Esscher Transformed Laplace Distribution: Properties, Application and Extensions

In this article, we introduce a new generalized family of Esscher transformed Laplace distribution, namely the Kumaraswamy Esscher transformed Laplace distribution. We study the various properties of the distribution including the survival function, hazard rate function, cumulative hazard rate function and reverse hazard rate function. The parameters of the distribution are estimated using the maximum likelihood method of estimation. A real application of this distribution on breaking stress of carbon fibres is also considered. Further, we introduce and study the exponentiated and transmuted exponentiated Kumaraswamy Esscher transformed Laplace distributions.

Entropy stabilization effect and oxygen vacancy in spinel high-entropy oxide promoting sodium ion storage

Rapid capacity decay is a crucial issue for conversion reaction anodes of sodium ion batteries (SIBs). Here, we introduced the concept of “high entropy” into the conventional transition metal oxides, successfully preparing spinel high-entropy oxide [(FeCoNiMn)1-xNax]3O4 (x = 0.05, 0.08, 0.12) (named after HEO 0.12, HEO 0.08, HEO 0.05) by spray pyrolysis. Due to the “entropy stabilization effect”, an electrode material exhibits respectable stability. Simultaneously, the precise adjustment of oxygen vacancy accomplished by ion substitution demonstrates that oxygen vacancy naturally in HEO not only provides additional active sites for Na+ accommodation and lowers the sodiation energy barrier enabling reversible Na+ intercalation, but also effectively propels charge transfer. As a result, the cooperation of the “entropy stabilization effect” and oxygen vacancy makes HEO 0.12 competitive in terms of cycling performance (average capacity decay of 0.069% cycle−1 at 1000 mA g−1), reversible specific capacity, coulombic efficiency and rate performance compared to those of counterparts. Significantly, the evolution of composition and structure during cycling suggests that the key inducing factors for the satisfactory cycling stability of HEO are the excellent reaction reversibility and structure durability, excavating the nature of the “entropy stabilization effect”. This work sheds novel insights into the development of anodes for SIBs.

Prostate-specific antigen kinetics contributes to decision making for biopsy referral: the predictive implication for PSA retest in patients with elevated PSA levels.

It is common to repeat prostate-specific antigen (PSA) measurements for men with PSA elevation before prostate biopsy. In this scenario, they may have considerable psychological distress in fear of the presence of cancer until retests. We assessed possible clinical factors causing transient PSA rise and explored the parameters predictive of subsequent PSA change. As interfering conditions, the history of ejaculation, bicycling, and any types of infections were assessed using the questionnaire. The pattern of PSA change was compared in association with the various clinical factors. Predictive significance of PSA kinetics such as coefficient of variation (CV) and PSA velocity (PSAV) for PSA values at retest was evaluated. The rate of reversion to the normal range was 38.3% at retest. The rate of 12.8% of men showed a large increase by ≥20%, whereas 38.2% of men showed a large decline by ≥20% from the baseline. Men with younger age (≤60 years), small prostate (<20cc), and prior history of ejaculation or infections showed significantly larger PSA decrease than their counterparts. Those with large CV or PSAV before the baseline more frequently showed PSA decrease below the age-specific cutoff or decline by ≥10% from the baseline at retest. These parameters associated with PSA kinetics had independent predictive values for relevant PSA change at retest. Ejaculation and any types of infections should be avoided before PSA tests. Men with large PSA fluctuation before the baseline are likely to show a significant PSA decrease at retest. This predictive information may help both physicians to determine whether to proceed to an immediate biopsy and patients to reduce their psychological burden.

Tectonic geomorphology and Quaternary fault slip rates in the Tsambagarav Massif, Mongolian Altai

AbstractThe NNW‐striking Mongolian Altai is a Late Cenozoic dextral strike–slip deformation belt affected by the far‐field stress caused by the collision between India and Eurasia. The Tsambagarav Massif is bounded by faults, has a triangular plan shape, and attains the highest elevation of the belt. This massif is adjacent to the central segment of the Hovd fault, which is the largest fault in the Mongolian Altai. Here, we use 10Be surface exposure dating, radiocarbon dating, and paleoseismic trenching to reveal deformation patterns and Quaternary slip rates for two range‐bounding faults: the Tsambagarav dextral reverse fault and the Lower thrust fault. The Lower thrust exhibits thrusting motion along the low‐angle structural fabric of the basement rock and cuts Quaternary alluvial fan deposits, vertically offsetting their surfaces by 3.9–5.1 m, with fault scarps extending several kilometres along‐strike. The Tsambagarav dextral reverse fault is characterized by strike–slip motion along the high‐angle structural fabric of basement rock. Various surface deformation features indicate recent dextral strike–slip, including displacements of Late Quaternary moraine by ~50 m. Dividing the measured displacements by 10Be surface exposure ages of alluvial fan surfaces (for the Lower thrust) and moraine (for the Tsambagarav dextral reverse fault) gives a reverse slip rate of 0.3–1.7 mm/yr for the Lower thrust and a horizontal slip rate of 1.7–2.6 mm/yr for the dextral reverse fault. Radiocarbon ages of animal bones in a pond deposit accumulated along an associated tensional crack indicate that the last earthquake that caused a surface rupture occurred between 1924 and 1708 cal yr BP. Our study suggests that strain partitioning has occurred on the faults of the Tsambagarav Massif.

Pengaruh Inflasi, Bi-7 Day (Reverse) Repo Rate dan Earning Per Share terhadap Harga Saham PT Bank Syariah Indonesia Periode 2019-2022

This article discusses the effect of Inflation, BI-7 Day Reverse Repo Rate, and Earnings Per Share on stock prices. The dependent variable in this study is the Stock Price. Meanwhile, the independent variables in this study are Inflation, BI-7 Day Reverse Repo Rate, and Earnings Per Share.&#x0D; The sampling technique was carried out using the purposive sampling method, the total sample in this study amounted to 16 quarters of financial statements at PT. Bank Syariah Indonesia, Inflation Report and , BI-7 Day Reverse Repo Rate at Bank Indonesia and Yahoo Finance for the share price for the 2019-2022 period. Data processing is carried out by multiple linear regression analysis with prerequisite tests first.&#x0D; This article finds that partially Inflation and , BI-7 Day Reverse Repo Rate have a negatif direction but have no significant effect on the Stock Price. Meanwhile, Earnings Per Share has a positive and significant direction towards the Stock Price. Meanwhile, inflation, BI-7 Day Reverse Repo Rate, and Earnings Per Share have a simultaneous influence on stock prices.

Multiple Accessible Redox-Active Sites in a Robust Covalent Organic Framework for High-Performance Potassium Storage.

Covalent organic framework (COF) materials with porous character and robust structure have significant applied implications for K-ion battery (KIB) anodes, but they are limited by the low reversible capacity and inferior rate capability. Here, based on theoretical calculations, we identified that a porous bulk COF featuring numerous pyrazines and carbonyls in the π-conjugated periodic skeleton could provide multiple accessible redox-active sites for high-performance potassium storage. Its porous structure with a surface-dominated storage mechanism enabled the fast and stable storage of K-ions. Its insolubility in organic electrolytes and small volumetric change after potassiation ensured a robust electrode for stable cycling. As a KIB anode, this bulk COF demonstrated an unprecedentedly outstanding combination of reversible capacity (423 mAh g-1 at 0.1 C), rate capability (185 mAh g-1 at 10 C), and cyclability. The theoretical simulation and comprehensive characterizations confirmed the active sites are contributed by C═O, C═N, and the cation-π effect.

CO2 Pressure-Dependent Microstructure and Morphology of Carbon for Energy Storage: Unraveling the Role of CO2 in Green Synthesis of Carbon Materials

Advanced carbon materials have played an important function in the field of energy conversion and storage. The green and low-carbon synthesis of elemental carbon with controllable morphology and microstructure is the main problem for carbon materials. Herein, we develop a green and low-carbon method to synthesize porous carbon by reacting CO2 with LiAlH4 at low temperatures. The starting reaction temperatures are as low as 142, 121, and 104 °C for LiAlH4 reacting with 1, 30, and 60 bar CO2, respectively. For the elemental carbon, the porosity of elemental carbon gradually decreased, whereas its graphitization degree increased as the CO2 pressure increased from 1 bar to 60 bar. CO2 serves as one of the two reactants and the CO2 pressure can adjust the thermodynamic and kinetic properties of the formation reaction for synthesizing elemental carbon. The mechanism for CO2 pressure-dependent microstructure and morphology of carbon is discussed on the basis of the formation reaction of elemental carbon and gas blowing effect of H2 and CO2. The elemental carbon with different morphology and microstructure exhibits distinct electrochemical lithium storage performance including reversible capacity, rate capability, cycling stability, and Coulombic efficiency, owing to their different lithium storage mechanism. The elemental carbon synthesized at 30 bar CO2 delivers the highest reversible capacity of 506 mAh g−1 after 1000 cycles even at 1.0 A g−1. Advanced energy storage technology based on the green and low-carbon synthesis of carbon materials is a requisite for providing a stable and sustainable energy supply to meet the ever-growing demand for energy.

A Study on the Entire Take-Over Process-Based Emergency Obstacle Avoidance Behavior.

Nowadays, conditional automated driving vehicles still need drivers to take-over in the scenarios such as emergency hazard events or driving environments beyond the system's control. This study aimed to explore the changing trend of the drivers' takeover behavior under the influence of traffic density and take-over budget time for the entire take-over process in emergency obstacle avoidance scenarios. In the driving simulator, a 2 × 2 factorial design was adopted, including two traffic densities (high density and low density) and two kinds of take-over budget time (3 s and 5 s). A total of 40 drivers were recruited, and each driver was required to complete four simulation experiments. The driver's take-over process was divided into three phases, including the reaction phase, control phase, and recovery phase. Time parameters, dynamics parameters, and operation parameters were collected for each take-over phase in different obstacle avoidance scenarios. This study analyzed the variability of traffic density and take-over budget time with take-over time, lateral behavior, and longitudinal behavior. The results showed that in the reaction phase, the driver's reaction time became shorter as the scenario urgency increased. In the control phase, the steering wheel reversal rate, lateral deviation rate, braking rate, average speed, and takeover time were significantly different at different urgency levels. In the recovery phase, the average speed, accelerating rate, and take-over time differed significantly at different urgency levels. For the entire take-over process, the entire take-over time increased with the increase in urgency. The lateral take-over behavior tended to be aggressive first and then became defensive, and the longitudinal take-over behavior was defensive with the increase in urgency. The findings will provide theoretical and methodological support for the improvement of take-over behavior assistance in emergency take-over scenarios. It will also be helpful to optimize the human-machine interaction system.

High performance potassium-ion and lithium-ion batteries anode based on natural N-doped carbon microspheres

As an inexpensive and renewable anode material with the advantages of less intercalation-induced exfoliation, superior molecularly doping performance, and outstanding rate capacity, hard carbon material attracts extensive attention in lithium-ion batteries (LIBs) and potassium-ion batteries (KIBs). In this work, a series of glucosamine hard carbon microspheres (GCMs) are synthesized through facile and inexpensive hydrothermal and pyrolysis procedures. The obtained hard carbon microspheres as anode material provide favorable dual functionality for both LIBs and KIBs. The electrochemical performance of GCMs electrodes at various carbonation temperatures is fully evaluated. The as-prepared GCM-900 is an admirable anode for LIBs, with good reversible capacity (407.8 mAh/g at 0.1 A/g after 200 cycles) and rate performance. Correspondingly, the GCM-1100 is good for KIBs (269.9 mAh/g at 0.05 A/g and 161.9 mAh/g after 100 cycles at 0.1 A/g).

Forecasting and mitigation of global environmental carbon dioxide emission using machine learning techniques

Carbon dioxide emission has emerged as a major concern in the 21st century. The rising global average temperature and its impact on climate change has a major impact on the socioeconomic affairs of the world. This rise, directly causes the melting of the polar ice caps which in turn, brings about many other issues including extinction of polar animals, flooding of coastal regions, exposure to ancient microbial life and bacteria frozen in the snow which pose a risk of many more global pandemics and unseen diseases. An urgent need to control this carbon emission is required. The initial step in this process is to accurately identify the threat levels and milestones. Certain thresholds need to be mapped that express the most critical levels of CO2 such as – the risk point, point of no return, etc. This is the main issue that this paper aims to address. The paper also aims to suggest some methodologies to deal with the same issue. The flow of the experiment and paper is described in the following lines. Historical data was used to make a prediction for the year in which the earth will hit a particular threshold for carbon dioxide concentration in the atmosphere. This level must not be breached and is essential in the fight against climate change. Next, analysis and data are used to calculate the reduction needed in the emission levels in order to bring back the CO2 concentrations into a safer range. The study concludes that the critical level of CO2 - 500 ppm, will be achieved by the year 2047. This level is considered a point of no return. A reduction rate of 6.37% and reversal rate of 23.38% is required to bring the emissions back to safe levels. The study also concluded that various socioeconomic factors such as population, greenhouse gasses, combustion industries contribute the most to these emissions. The authors recommend that further research be carried out on this problem to ascertain further predictions on the point of no return so that an action plan can be developed accordingly. The authors also recommend that a shift to renewable energy sources be undertaken speedily and that carbon neutrality be a crucial goal of every organization.

Mild Cognitive Impairment, Reversion Rates, and Associated Factors: Comparison of Two Diagnostic Approaches.

As mild cognitive impairment (MCI) is typically used to identify prodromal stages of dementia, it is essential to identify MCI criteria with high diagnostic stability and prediction of dementia. Moreover, further investigation into pinpointing key factors for reversion is required to foresee future prognosis of MCI patients accurately. To explore disparities in diagnostic stability by examining reversion rates produced by two operationalizations of the MCI definition: the widely applied Petersen criteria and a version of the Neuropsychological (NP) criteria and to identify cognitive, lifestyle, and health related factors for reversion. MCI was retrospectively classified in a sample from the Swedish community-based study Good Aging in Skåne with the Petersen criteria (n = 744, median follow-up = 7.0 years) and the NP criteria (n = 375, median follow-up, 6.7 years), respectively. Poisson regression models estimated the effect of various factors on the likelihood of incident reversion. Reversion rates were 323/744 (43.4%, 95% confidence intervals (CI): 39.8; 47.0) and 181/375 (48.3% 95% CI: 43.2; 53.5) for the Petersen criteria and NP criteria, respectively. Participants with impairment in a single cognitive domain, regular alcohol consumption, living with someone, older age, and lower body mass index had a higher likelihood of reverting to normal. Reversion rates were similar for Petersen and NP criteria indicating that one definition is not superior to the other regarding diagnostic stability. Additionally, the results highlight important aspects such as multiple domain MCI, cohabitation, and the role of alcohol on predicting the trajectory of those diagnosed with MCI.

High‐Performance All‐Solid‐State Batteries Enabled by Intimate Interfacial Contact Between the Cathode and Sulfide‐Based Solid Electrolytes

AbstractAll‐solid‐state batteries (ASSBs) are considered the ultimate next‐generation rechargeable batteries due to their high safety and energy density. However, poor Li‐ion kinetics caused by the inhomogeneous distribution of the solid electrolytes (SEs) and complex chemo‐mechanical behaviors lead to poor electrochemical properties. In this study, LiNi0.8Co0.1Mn0.1O2 (NCM) (core) – Li6PS5Cl (LPSCl) SEs (shell) particles (NCM@LPSCl) are prepared by a facile mechano‐fusion method to improve the electrochemical properties and increase the energy density of ASSBs. The conformally coated thin SEs layer on the surface of NCM enables homogeneous distribution of SEs in overall electrode and intimate physical contact with cathode material even under volume change of cathode material during cycling, which leads to the improvement in Li‐ion kinetics without the increase in solid electrolyte content. As a result, an ASSBs employing NCM@LPSCl with 4 mAh cm−1 specific areal capacity exhibits robust electrochemical properties, including the improved reversible capacity (163.1 mAh g−1), cycle performance (90.0% after 100 cycles), and rate capability (discharge capacity of 152.69, 133.80, and 100.97 mAh g−1 at 0.1, 0.2, and 0.5 C). Notably, ASSBs employing NCM@LPSCl composite show reliable electrochemical properties with a high weight fraction of NCM (87.3 wt%) in the cathode.

Antisickling and Antihemolytic Mechanism of Spirulina platensis (Oscillatoriaceae): A Nutraceutical Commonly Used in Cameroon

Sickle cell anaemia (SCA) is a widespread genetic disease in Africa, associated with chronic hemolytic anaemia and vaso‐occlusive and infectious complications. The most commonly used means of management and treatment such as blood transfusions and allografting are expensive and predispose patients to the risk of infections. This research study aimed at evaluating the antisickling and antihemolytic activities of aqueous extracts of Spirulina platensis from Cameroon for optimising the management of this disease using natural substances. The Spirulina platensis harvested in Nomayos‐Yaounde was dried, crushed, and macerated for 24 h in distilled water and the filtrate was freeze dried. The determination of the inhibition rates of falciformation induced by 2% sodium metabisulfite (MBS) and the sickling reversibility rate was carried out at different concentrations (100, 200, 400, 800, and 1600 μg·mL−1) of the spirulina extract at different time intervals (2 h, 4 h, and 24 h). Aspirin, hypotonic solution, Triton X‐100, and hydrogen peroxide were used as hemolytic inducers and the antihemolytic activity of the extract was studied at 800 μg·mL−1 and 1600 μg·mL−1 using the colorimetric method. The extraction yield was 14.015%. The maximum duration of induced falciformation was 2 h 30 min and the percentage of falciformation increased from 27.99 ± 3.15% (at the initial time) to 91.44 ± 3.70%, giving a falciformation induction rate of 69.3%. The falciformation inhibition rate after 2 h 30 min ranges from 15.10 ± 0.60% to 66.09 ± 4.69% for the concentration of 100 μg·mL−1 to 1600 μg·mL−1 of the spirulina extract. This rate of inhibition of falciformation was found to be dose‐dependent. The best concentration of the extract was 1600 μg·mL−1. The reversibility rate of falciformation at 800 μg·mL−1 and 1600 μg·mL−1 varied from 37.54 ± 6.35% to 82.34 ± 5.63% as a function of time. 1600 μg·mL−1 was the most active concentration after 24 h. In addition, the extract improved the Fe2+/Fe3+ ratio with an increase in the rates of 69.78 ± 8.81 and 69.78 ± 13.82 at 800 μg·mL−1 and 1600 μg·mL−1, respectively. According to each inducer at 800 μg·mL−1 and 1600 μg·mL−1, respectively, of the spirulina extract, the following rates of inhibition of hemolysis were found: 53.03 ± 9.46% and 96.67 ± 5.77% (aspirin); 80 ± 8.66% and 71.25% (hypotonic solution); 36.56 ± 9.53% and 45.67 ± 22.55% (Triton X‐100); 24.26 ± 9.55% and 36.76 ± 1.27% (hydrogen peroxide). At the end of this study, the best antickling activities were obtained at the concentrations 800 μg·mL−1 and 1600 μg·mL−1. It also has antihemolytic properties on various hemolysis inducers at concentrations 800 μg·mL−1 and 1600 μg·mL−1 with inhibition rates varying from 36% to 96%.

Effect of speed fluctuations on the collective dynamics of active disks.

Numerical simulations are performed on the collective dynamics of active disks, whose self-propulsion speed (U) varies in time, and whose orientation evolves according to rotational Brownian motion. Two protocols for the evolution of speed are considered: (i) a deterministic one involving a periodic change in U at a frequency ω; and (ii) a stochastic one in which the speeds are drawn from a power-law distribution at time-intervals governed by a Poissonian process of rate β. In the first case, an increase in ω causes the disks to go from a clustered state to a homogeneous one through an apparent phase-transition, provided that the direction of self-propulsion is allowed to reverse. Similarly, in the second case, for a fixed value of β, the extent of cluster-breakup is larger when reversals in the self-propulsion direction are permitted. Motility-induced phase separation of the disks may therefore be avoided in active matter suspensions in which the constituents are allowed to reverse their self-propulsion direction, immaterial of the precise temporal nature of the reversal (deterministic or stochastic). Equally, our results demonstrate that phase separation could occur even in the absence of a time-averaged motility of an individual active agent, provided that the rate of direction reversals is smaller than the orientational diffusion rate.

Optimized crystal orientation for enhanced reaction kinetics and reversibility of SnSe/NC hollow nanospheres towards high-rate and long-term lithium/sodium storage.

The development of anode materials with high theoretical capacity and cycling stability is very important for the electrochemical performance of lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs). Herein, SnSe/NC hollow nanospheres with different crystal orientations were prepared by regulating the high-temperature selenization of the PDA@SnO2 precursor for lithium/sodium storage. In SnSe/NC hollow nanospheres, the physical buffering and chemical bonding of the nitrogen carbon matrix and SnSe nanoparticles could inhibit volume expansion and polyselenide loss, thus maintaining long-term structural stability. More importantly, electrochemical tests and DFT calculations show that the diffusion energy barrier of Li+/Na+ is significantly reduced at the SnSe (400) rather than the usual (111) facet, which is conducive to the uniformity of ion insertion into SnSe, thus effectively enhancing the reaction kinetics and reversibility of lithium/sodium storage. Therefore, SnSe/NC hollow nanospheres with rich SnSe (400) and good dispersion formed at 550 °C delivered the best reversible specific capacity and rate performance. After a long period of 900 cycles, the capacity retention of lithium/sodium ion batteries is close to 84.88% and 77.05%, respectively. Our findings provide valuable insights into the design of metal selenides for advanced LIBs/SIBs.