AbstractThe temperature of homogeneous 2,6‐dimethylpyridine/water mixtures of off‐critical composition near the lower critical point of the system (|x1 — x1,c| < 0.01; x1, mole fraction of 2,6‐dimethylpyridine) is raised by a fast temperature jump (Joule heating pulse) bringing the system closer to its temperature of phase separation. The delayed increase of intensity of scattered light is measured as function of time at different scattering angles (ϑ = 20°, 30°, 40°) and different temperature differences (Tp — Tf) (TP and Tf, temperature of phase separation and final temperature of the sample after the temperature jump). The measured relaxation curves are single exponentials. The relaxation times decrease with increasing values of |x1 — x1,c|. It is found that for kζr < 0.4 (ζr, correlation length of local concentration fluctuations at Tf; k, absolute value of scattering vector) the structure factor of mixtures of off‐critical composition relaxes as expected on the basis of linear response within the accuracy of the measurements (τhyd/τexp = 1;τhyd, hydrodynamic relaxation time; τexp, experimental relaxation time). For the calculation of τhyd it is assumed that the change of τhyd with composition and temperature is caused only by changes of τf with composition and temperature. The restricted linear model of the critical equation of state is used to obtain τf as function of these variables. The data are used to calculate τhyd.
Read full abstract