Amount Of Residues Research Articles

Essential Oils from Azorean Cryptomeria japonica Female Cones at Different Developmental Stages: Variations in the Yields and Chemical Compositions

Cryptomeria japonica (Thunb. ex L.f.) D. Don (Cupressaceae) is widely cultivated in the Azores archipelago (Portugal) for landscaping and timber production, generating a huge amount of biomass residues. Among these, female cones (FC) emerge as a source of particularly valuable essential oils (EOs), namely, as promising broad-spectrum antimicrobial agents. However, phytochemical research on C. japonica FC EOs remains scarce. This study evaluated the EO yields and chemical compositions of immature and mature FC (IFC and MFC) from the same batch of Azorean C. japonica. IFC and MFC EOs, obtained via hydrodistillation, presented different yields (0.72% vs. 1.12% w/w, dry weight), and their composition, determined via gas chromatography/mass spectroscopy, revealed that the monoterpenes class was dominant (51.84% vs. 69.13%), followed by the sesquiterpenes (36.44% vs. 26.28%) and diterpenes (10.96% vs. 3.03%) classes. However, the correspondent oxygen-containing terpenes classes were 1.5–2.0 times higher in IFC. Thus, the maturation process revealed an increase in EO yield and α-pinene content (19.5% vs. 41.3%) but a decrease in other important bioactive terpenes/terpenoids (terpinen-4-ol, bornyl acetate, elemol, γ-eudesmol, phyllocladene, and nezukol) content. In conclusion, IFC and MFC EOs, due to their unique composition, may have differential commercial applications and, consequently, contribute to increasing the commercial potential of C. japonica’s EO industry.

Synthesis of geopolymer composites using bauxite residue-based spheres as aggregate: Novel and eco-friendly strategy to produce lightweight building materials

In this study, and for the first time, highly porous red mud-based geopolymer spheres were produced, through a very simple and scalable procedure, and used as lightweight aggregate in the synthesis of geopolymer composites. To further demonstrate the potential of this unexplored route, a comparison with composites containing expanded perlite and expanded vermiculite was also performed. The sample produced with 85 vol% of spheres showed the lowest geometric density (0.84 g/cm3) amongst the studied composites, coupled with a suitable compressive strength (1.0 MPa), low thermal conductivity (175 mW/m K), and excellent thermal stability after exposure to 1000 °C for 2h. The much lower production temperature (80 °C), compared with the commercial expanded aggregates (above 650 °C), and the reuse of significant amounts of bauxite residue (strategy aligned with the circular economy) enables the production of eco-friendly lightweight aggregates for the building sector.

Biochar from phytoremediation plant residues: a review of its characteristics and potential applications.

Phytoremediation is a cost-effective and eco-friendly plant-based approach promising technique to repair heavy metal-contaminated soils. However, a significant quantity of plant residues needs to be properly treated and utilized. Pyrolysis is an effective technology for converting residues to biochar, which can solve the problem and avoid secondary contamination. This paper reviews the generation, and physicochemical properties of biochar from phytoremediation residues, and its application in soil improvement, environmental remediation, and carbon sequestration. In spite of this, it is important to be aware of the potential toxicity of heavy metals in biochar and the environmental risks of biochar before applying it to practical applications. Future challenges in the production and application of residue-derived biochar include the rational selection of pyrolysis parameters and proper handling of potentially hazardous components in the biochar.

Hydrogel dressings with intrinsic antibiofilm and antioxidative dual functionalities accelerate infected diabetic wound healing

Chronic wounds are often infected with biofilm bacteria and characterized by high oxidative stress. Current dressings that promote chronic wound healing either require additional processes such as photothermal irradiation or leave behind gross amounts of undesirable residues. We report a dual-functionality hydrogel dressing with intrinsic antibiofilm and antioxidative properties that are synergistic and low-leaching. The hydrogel is a crosslinked network with tethered antibacterial cationic polyimidazolium and antioxidative N-acetylcysteine. In a murine diabetic wound model, the hydrogel accelerates the closure of wounds infected with methicillin-resistant Staphylococcus aureus or carbapenem-resistant Pseudomonas aeruginosa biofilm. Furthermore, a three-dimensional ex vivo human skin equivalent model shows that N-acetylcysteine promotes the keratinocyte differentiation and accelerates the re-epithelialization process. Our hydrogel dressing can be made into different formats for the healing of both flat and deep infected chronic wounds without contamination of the wound or needing other modalities such as photothermal irradiation.

Methodological Approaches to Determination of Antibiotics in Water at the Level of Hygienic Standards Using High-Performance Liquid Chromatography–Mass Spectrometry

Introduction: The use of antibiotics in medicine and veterinary medicine has led to their accumulation in the natural environment, including source water, and antimicrobial resistance of certain types of bacteria. The development of methods for analyzing antibiotics in aquatic environments is relevant for ensuring tap water quality control at the level of hygienic standards, as well as for studying the process of development and spread of antibiotic resistance. The purpose of the study is to develop a method for determining such antibiotics as macrolides, penicillins, and fluoroquinolones in water at the level of hygienic standards using HPLC/MS-MS. Materials and methods: To elaborate the method, testing was done by HPLC/MS-MS using a liquid chromatograph with a triple quadrupole mass spectrometer. Extraction of antibiotics from various types of water samples (tap, natural) was carried out by solid-phase extraction. Results: We have developed a selective and highly sensitive method for the determination of eight antibiotics in water samples. The extraction efficiency for analytes ranged from 72 to 100 % and measured concentrations – from 0.25 to 2.50 of hygienic standards when analyzing 10 cm3 water samples; the relative error in determining antibiotics in water samples without concentration was 20–24 %, and 24–34 % in case of concentration on Oasis® HLB sorbent. Discussion: Approaches to developing a method for quantification of antibiotics of the penicillin, macrolide and quinolone classes in water by HPLC/MS-MS using solid-phase extraction for sample preparation are considered. The results are consistent with the data of scientific, technical and methodological literature. The advantages of this method include shorter sample preparation time, high sensitivity, and a small sample size. Study limitations: The main limitations are a short sampling period and the insufficient number of water samples tested. Expanding the list of surveyed water bodies on different territories may become a direction for further research to assess the content of antibiotics in aquatic environments. Conclusion: Our method can be used in hygienic studies of residual amounts of antibiotics to assess source water quality.

Safety evaluation of the food enzyme bacillolysin from the non-genetically modified Bacillus amyloliquefaciens strain NZYM-NB.

The food enzyme bacillolysin (EC 3.4.24.28) is produced with the non-genetically modified Bacillus amyloliquefaciens strain NZYM-NB by Novozymes A/S. The production strain meets the requirements for qualified presumption of safety (QPS) approach to safety assessment. The food enzyme is intended to be used in eleven food manufacturing processes. Since residual amounts of total organic solids (TOS) are removed during two processes, dietary exposure was estimated only for the remaining nine food manufacturing processes. Exposure was estimated to be up to 1.327 mg TOS/kg body weight per day in European populations. As the production strain qualifies for the QPS approach and no issue of concern arising from the production process of the food enzyme was identified, the Panel considered that no toxicological studies other than the assessment of allergenicity were necessary. A search for the similarity of the amino acid sequence of the food enzyme to known allergens was made and no match was found. The Panel considered that the risk of allergic reactions by dietary exposure cannot be excluded (except for distilled alcohol production), but the likelihood is low. Based on the data provided, the Panel concluded that this food enzyme does not give rise to safety concerns under the intended conditions of use.

Valorization of Coffee Residue from Convenience Store and Retail Mass-Selling Store for Producing Highly Porous Carbon Materials and Taiwan Perspectives

In Taiwan, a considerable amount of coffee residue is produced from commercial activities without valuable utilization. To evaluate high-value valorization in the production of highly porous carbon materials, this study investigated the thermochemical properties of coffee residues and further pyrolysis for producing highly porous biochar products at an elevated temperature (i.e., 850 °C) and a moderate residence time of 30 min. Our findings indicate that this biomass has a relatively high calorific value (about 27 MJ/kg, dry basis) due to its low ash and high lignocellulose content. It can be also concluded that the non-activated biochar products are highly porous carbon materials with excellent pore properties (i.e., a BET surface area of about 800 m2/g and a total pore volume of 0.4 cm3/g), which are slightly lower than those of commercial activated carbon products. Based on the above-mentioned results and the high-value circular bio-economy promoted by regulatory policy in Taiwan, the prospects for the possible valorization of coffee residue from commercial shops are addressed here, focusing both on the reuse of plant-based residue (or agricultural waste) as a high-value bioresource in the production of biomass-based fuels and on carbon materials. The former includes solid recovered fuel (SRF) and biomass-to-biogas power. By contrast, the latter aims at the production of plant-based carbon as natural, edible colorants in accordance with the regulation of food safety and sanitation in Taiwan.

Studi pengaruh waktu dan suhu recovery limbah katalis nikel terpakai (spent catalyst) pasca proses hidrogenasi RBDPO dengan metode kalsinasi

Many palm oil processing industries use hydrogenation catalysts to optimize yields and produce quantities of catalyst residues containing metals harmful to the environment. Residue catalyst disposal also creates new problems for the industry because the category includes hazardous waste. Use of nickel catalyst at PT. Dua Kuda Indonesia in 2007 as much as 54 tons / year, 2014 as much as 108 tons / year and year 2018 as much as 216 tons / year. The price of nickel catalyst in Indonesia also has a fairly high value of about Rp. 120,000,000, - per ton. This study focused on the recovery of nickel catalyst activity by washing with etanol and activation catalyst wich calsinasi at temperatur 300°C, 400°C and 500°C. In the characterization stage, to see functional groups used Fourier Transform Infrared (FT-IR) instrument instrument, X-Ray Diffraction (XRD) crystallization test and structural test with Scanning Electron Microscope (SEM). The hydrogenated catalyst, tested quantity, quality of nickel catalyst with Iodine Value Test.

Removal of carbaryl residues from sesame and mint oil using nano-metal organic framework

Essential oils were used as anti inflammation, anti respiratory diseases, and anti infections, however, essential oils suffering from high amount of pesticide residues. This paper is an overview on possible methods used for the removal of pesticide residues from essential oils. Metal organic framework based calcium (Ca-MOFs) was chemically modified to be used directly in adsorption of carbaryl from contaminated oil. The carbaryl removal process from mint oil and sesame oil were investigated in details to reach the optimized conations of removal process. The capacity of equilibrium adsorption for carbaryl compounds from mint oil was 161.37 mg g−1, and the capacity was decreased in the case of sesame oil (121.41 mg g−1). Langmuir and Freundlich isotherm models were applied to understand the mechanism of carbaryl adsorption. Langmuir model showed the best fitting isotherm (R2 = 0.999). The mechanism of carbaryl removal from essential oil was depending on pi-pi stacking technique. Finally, the modified Ca-MOFs were best candidate for selective removal of carbaryl from essential oil without loss of oil characteristics as confirmed using GC and FTIR spectroscopy.

Risk Assessment of Metals in Black Fungus and Culture Substrates Based on Monte Carlo Simulation

Black fungus is the second-most consumed edible fungus in China. The establishment of a risk assessment mechanism for heavy metals in black fungus is particularly critical to the safety of edible fungi. To clarify a risk assessment mechanism of heavy metal pollution of edible fungi in northeast China, in this study, the contents of Pb, Cr, CD and As in 415 samples were determined, and a total of 1660 valid data were obtained. Then, based on Monte Carlo simulation, a non-parametric probability assessment system for heavy metals in black fungus was established and improved. The results showed that the residual amounts of As, Pb, Cd and Cr in black fungus were in the order of Cr > Pb > As > Cd. The background content of four heavy metals in the main raw materials was preliminarily clarified. Among them, the content of As is between 0.010–0.320 mg·kg−1, Pb is between 0.051–0.792 mg·kg−1, Cd is between 0.019–0.236 mg·kg−1, and Cr is between 0.06–3.41 mg·kg−1. These results indicate that the dietary exposure risk of heavy metals ingested by dried black fungus in Chinese minors and adults is basically safe, but at the high exposure levels of 97.5% sites and 99% sites, Cr is at the light pollution level, and the comprehensive pollution of four heavy metals is at the moderate pollution level. In addition, this study found that raw materials can cause heavy metal accumulation in black fungus, mainly from sawdust, followed by rice bran and wheat bran.

A novel synchronous fluorescence spectrometry combined with fluorescence sensitization for the highly sensitive and simultaneous detection of enoxacin, ofloxacin and tetracycline hydrochloride residues in wastewater

The synergistic effect of sodium dodecyl sulfate (SDS) and Mg2+ could significantly enhance the fluorescence intensity of enoxacin (ENO) at λex/λem = 269.2 nm/385.6 nm, ofloxacin (OFL) at λex/λem = 290.8 nm/466.2 nm and tetracycline hydrochloride (TCH) at λex/λem = 372.6 nm/514.8 nm. Moreover, when the wavelength difference (Δλ) was chosen 135 nm, the synchronous fluorescence spectra of the three antibiotic complexes could be well separated and the interference of the samples matrix were eliminated primely. Therefore, only one synchronous fluorescence scan was needed to simultaneously determine the three antibiotics. Based on these facts, a synchronous fluorescence spectrometry combining fluorescence sensitization for highly sensitive and selective determination of ENO, OFL and TCH residues in wastewater was developed for the first time. The experimental results showed that the concentrations of ENO, OFL and TCH in the range of 0.5–550 ng mL−1, 1–1500 ng mL−1 and 10–5500 ng mL−1 showed a good linear relationship with fluorescence intensity. The limits of detection were 0.0599 ng mL−1, 0.115 ng mL−1 and 0.151 ng mL−1, respectively. The recoveries of the actual sample were 87.50%–99.99 %, 93.00%–98.50 % and 85.70%–98.42 %, respectively. Overall, the novel synchronous fluorescence spectrometry established in the experiment has the advantages of high sensitivity, good selectivity, fast detection speed and high accuracy. It has been successfully applied to the detection of residual amounts of ENO, OFL and TCH in wastewater with satisfactory results.

Assessment of organic matter state and physical properties of postagrogenic sod-podzolic soil and its arable analogue

Land is often withdrawn from agriculture for various reasons, about 1/4 of the world’s fallow land is in Russia, mainly in the taiga forest zone. Some changes, determined by a combination of various factors, take place in fallow land. Therefore, in order to determine the expediency or priority of returning fallow land to arable land, it is relevant to assess the main indicators of its fertility. To this end, a comparative study of the organic matter and physical properties of an arable sod-podzolic soil and its post-agricultural analogue, which has been fallow for more than 20 years, was carried out. A reliable increase in the carbon content of the light fraction of organic matter in the 0-10 cm layer of the fallow soil was observed in comparison with the corresponding horizon of the arable analogue. In the 10-20 cm horizon this increase was manifested in the form of a tendency, also the tendency of increase in the content of organic carbon (total humus) in the former arable layer of the fallow soil was manifested. The increase in these indicators of the state of organic matter is apparently due to the increase in the amount of plant residues as a result of the succession of natural herbaceous vegetation compared to the amount of post-harvest residues on arable land. The fallow soil also showed an increase in the number of macroaggregates, agronomically valuable aggregates and the water holding capacity of macroand microaggregates compared to the arable soil. Obviously, such an improvement in the structural condition indicators is related to the increase in humus content and the absence of mechanical tillage, which favours the destruction of aggregates. The fallow soil in comparison with the arable soil had reliably lower density and density of solid phase, which is explained by higher content of light fraction of organic matter in it, as well as better structure. The obtained results allow to assess the nature of changes in fertility indicators of sod-podzolic soil as a result of staying in fallow condition. The indicator of the content of the light fraction of organic matter is an earlier indicator of the recovery of the fallow soil compared to the total carbon content in the soil, which allows to determine the expediency and priority of the return of fallow soils to arable land.

Thermochemical Co-Liquefaction of Fruit Pomace’s Blends in a Binary Solvent System Toward Value-Added Bioproducts

Abstract Poland belongs to the most meaningful producers of fresh food products in the European Union, e.g., apples, cherries, carrots, as well as currants. A significant part of these products are subjected to further processing, which results in the generation of an abundant amount of wet residues, such as pomace. The present paper aims to investigate the possibility of co-processing various industrial residues in the form of fruit pomaces through thermochemical liquefaction toward high-energy-density biocrude and biochar. More specifically, industrial wastes received from commercial juice production, i.e., blackcurrant, apple, and cherry pomaces, were converted under subcritical conditions of the water-isopropyl alcohol solvent system at fixed conditions. Particular focus was put on testing binary and ternary mixture feedstock systems and the possibility of predicting the bioproduct yield. Furthermore, the quality of the resultant biocrudes was analyzed by means of FTIR, GC-MS, and elemental analysis. For all separately studied raw materials and their binary and ternary mixtures, the dominant group fraction was biocrude with its yield ranging between 45.8 and 54.5 wt%. Produced liquids exhibit high energy density (HHV between 30.1 and 32.4 MJ/kg); thus, all of them pose perspective alternative fuels for generating heat and electricity. Also, the solid biochars presented a high energy density (HHV around 24–26 MJ/kg) and can be considered as an alternative energy carrier. The postulated approach aims to increase the flexibility and profitability of future technology of processing useless waste toward value-added bioproducts for the chemical and energy sectors.

Comparison of cover crop termination methods for small-scale organic vegetable production: effect on soil fertility and health

Termination methods and the timing of the termination of the cover crops are critical factors determining the efficacy of cover crops in improving soil fertility and quality. We hypothesized that different termination methods will produce varying quantities of organic residue which will affect microbial diversity and thereby nutrient cycling and availability. The objective of this study was to compare termination methods (roller-crimper, flail mowing, rotary mowing, sickle bar mowing, and occultation using black tarps) for fall-grown cover crop combination (hairy vetch-cereal rye) under organic vegetable production. Field experiments were carried out in three consecutive years (2018–2021) and soil samples were collected from 0 to 15 cm and processed for analysis. Soil organic matter content, nutrients, health parameters, enzymes, and microbial diversity were measured. Flail mowing significantly enhanced the potentially mineralizable nitrogen, available phosphorus, and active carbon. Total Phospholipid Fatty Acid (PLFA) analysis showed a 24% increase for flail mowed, 17% for rotary mowed, and 15% for sickle bar mowed termination methods. There was a significant increase in active carbon content which ranged from 38.9% (rotary mowed), 25.4% (sickle bar mowed), 23.5% (flail mowed), 16.4% for crimper rolled method, and with 2.8% (occultation) respectively. Individual termination methods had varying effects on select enzyme activities. Results indicated that integrating cover crops has the potential to modify soil microbial community structure and increase soil enzyme activities. In this study, flail mowing appeared to be a good method for managing cover crops of choice in terms of soil microbial functionality and fertility.

Simultaneous degradation of NSAIDs in aqueous and sludge stages by an electron-Fenton system derived from sediment microbial fuel cell based on a novel Fe@Mn biochar GDC

Electro-Fenton (e-Fenton) reactions boosted using microbial fuel cells (MFCs) can degrade contaminants with high efficiency, the treatment is generally performed in the aqueous phase and the sludge pollution is ignored in such MFCs. In this study, a sediment MFC e-Fenton (SMFC-e-Fenton) system was proposed for the degradation of nonsteroidal anti-inflammatory drugs (NSAIDs) in both aqueous and solid phases. A Fe@Mn-codoped biochar gas diffusion cathode was fabricated to produce hydroxyl radicals without any additional power input. The studied NSAIDs of ibuprofen (IBU), naproxen (NPX), and diclofenac (DCF) exhibited total degradation efficiencies (including aqueous and sludge phase) of 99.1%, 98.5%, and 80.6%, respectively, in the SMFC-e-Fenton system. Compared with sludge anaerobic digestion, the residual amounts of IBU, NPX, and DCF reduced from 10.2%, 24.6%, and 32.2% to 2.7%, 4.4%, and 8.5%, respectively, in the sludge phase. Moreover, the electricity generation and sludge reduction improved owing to the e-Fenton process. Using the SMFC-e-Fenton system, the effects of NSAIDs were reduced and the richness and diversity of the microbial community are maintained, improving the overall system performance. These results demonstrate that the SMFC-e-Fenton method is a high-efficiency, economic and environmental friendly technology for simultaneously treating NSAIDs in the aqueous and sludge phases.

Rice residue management alternatives in rice–wheat cropping system: impact on wheat productivity, soil organic carbon, water and microbial dynamics

In the Indo-Gangetic Plains (IGP), rice–wheat cropping system (RWCS) predominates, producing large quantity of crop residue and its management is major concern. Farmers usually burn the residue to clear the field for succeding crop, and burning damages soil microbes, resulted in loss of soil organic matter. Hence, current study was conducted to assess the impact of different Happy seeder based residue management options on changes in microbial dynamics, enzyme activities and soil organic matter content and also to know that alternative method for attaining sustainable wheat productivity in sandy loam soils of Haryana, India. Results revealed that Zero tillage wheat (ZTW) with partial and full residue retention treatments sown with Happy seeder (after using chopper and spreader), and ZTW with anchored stubbles significantly enhanced soil microbial count by 47.9–60.4%, diazotropic count by 59.0–73.1% and actinomycetes count by 47.3–55.2%, grain yield by 9.8–11.3% and biomass yield by 7.4–9.6% over conventional tilled (CT) residue burning and residue removal plots. ZTW sown with surface retention of rice crop residue increased the organic carbon by 0.36–0.42% and the soil moisture content by 13.4–23.6% over CTW without residue load. Similarly, ZTW sown with Happy seeder with full residue enhanced alkaline phosphatase activity from 95.3 µg TPF g−1 soil 24 h−1 in 2018–2019 to 98.6 µg TPF g−1 soil 24 h−1 in 2019–2020 over control plots. Likely, microbial population and enzymatic activity showed strong positive correlation under variable residue retention practices. However, increased microbial population reduced the soil pH from 7.49 to 7.27 under ZTW with residue retention plots. The wheat yield enhanced by 9.8–11.3% during 2018–2019 and 2019–2020 under ZTW with Happy seeder with full residue load over residue burning and residue removal plots. ZTW sown with Happy seeder under full residue retention, achieved maximum net return 43.16–57.08 × 103 ₹ ha−1) and B-C ratio (1.52 to 1.70) over CTW without residue. Therefore, rice residue needs to be managed by planting wheat using appropriate machinery under ZT for sustaining higher productivity in RWCS and improve soil health and environment under IGP regions.

Ammonia removal and simultaneous immobilization of manganese and magnesium from electrolytic manganese residue by a low-temperature CaO roasting process.

A large amount of open-dumped electrolytic manganese residue (EMR) has posed a severe threat to the ecosystem and public health due to the leaching of ammonia (NH4+) and manganese (Mn). In this study, CaO addition coupled with low-temperature roasting was applied for the treatment of EMR. The effects of roasting temperature, roasting time, CaO-EMR mass ratio and solid-liquid ratio were investigated. The most cost-effective and practically viable condition was explored through response surface methodology. At a CaO: EMR ratio of 1:16.7, after roasting at 187°C for 60 min, the leaching concentrations of NH4+ and Mn dropped to 10.18 mg/L and 1.05 mg/L, respectively, below their discharge standards. In addition, the magnesium hazard (MH) of EMR, which was often neglected, was studied. After treatment, the MH of the EMR leachate was reduced from 60 to 37. Mechanism analysis reveals that roasting can promote NH4+ to escape as NH3 and convert dihydrate gypsum to hemihydrate gypsum. Mn2+ and Mg2+ were mainly solidified as MnO2 and Mg(OH)2, respectively. This study proposes an efficient and low-cost approach for the treatment of EMR and provides valuable information for its practical application.

Soil organic matter and aggregate stability dynamics under major no-till crop rotations on the Canadian prairies

There is a need to develop and adopt novel, more resilient, or “climate-smart” cropping strategies on the Canadian prairies, which are crucial for sustainable agroecosystem management. To examine how crop rotation influences soil organic matter and aggregate stability (AS) dynamics, six crop rotations: (i) conventional (control), (ii) pulse/oilseed intensified, (iii) diversified, (iv) market-driven, (v) high-risk and high-reward, and (vi) soil health-enhanced were established in 2018 at three field sites: Lethbridge, Alberta and Swift Current and Scott, Saskatchewan under no-till management. After 4-year, soil organic carbon (SOC), total nitrogen (TN), particulate organic matter carbon (POM-C) and nitrogen (POM-N), or mineral-associated organic matter C (MAOM-C) and N (MAOM-N) concentrations were not significantly affected by crop rotation in the 0–7.5 cm soil depth. However, crop rotation significantly altered AS at two of three sites, with both soil health-enhanced and high-risk and high-reward rotations having the highest AS at Lethbridge and Swift Current. Across all three sites, strong positive correlations were found among SOC, TN, MAOM, and AS. Moreover, MAOM-C and MAOM-N showed stronger relationships with AS than POM, perhaps suggesting a positive feedback loop on the stability of SOC and aggregation. Overall, the inclusion of pulses in rotations showed the potential to sustain soil quality, likely by offsetting low residue quantity with better residue quality and diversity, thereby supporting SOC accrual and AS similar to or greater than conventional cereal- or oilseed-dominated rotations.

Functional Ingredients from Seafood Processing Wastes: Protein Hydrolysate and Biocalcium

The fish processing industry generally generates large amounts of byproducts, including skin, bone, scale, or meat residues, etc. These byproducts contain a wide range of nutritional components such as protein, lipid, mineral, etc. These leftovers can be converted to functional ingredients or nutraceuticals. To produce high value-added functional ingredients, the remaining proteins in fish processing leftovers are hydrolyzed, in which hydrolysate containing different peptides and amino acids can be generated. Frame or backbone as well as scale can be converted to fish biocalcium, which serves as a potential source of calcium and minerals. Nevertheless, potential processing or technology must be adopted to obtain desired products with target bioactivitities. This review covers production, characteristics, and bioavailability of fish protein hydrolysate (FPH) and fish biocalcium (BC). This review also focuses on the recent applications of the FPH and BC in drink and foods. Overall, the review points out the better exploitation of fish processing leftovers and simultaneously lower pollution caused by the improper discard or disposal of those wastes to environment. Also, consumers have more choices to consume functional ingredients or nutraceutical from marine resources.

Reactive Vapor-Phase Inhibitors for Area-Selective Depositions at Tunable Critical Dimensions.

Area-selective depositions (ASD) take advantage of the chemical contrast between material surfaces in device fabrication, where a film can be selectively grown by chemical vapor deposition on metal versus a dielectric, for instance, and can provide a path to nontraditional device architectures as well as the potential to improve existing device fabrication schemes. While ASD can be accessed through a variety of methods, the incorporation of reactive moieties in inhibitors presents several advantages, such as increasing thermal stability and limiting precursor diffusion into the blocking layer. Alkyne-terminated small molecule inhibitors (SMIs)─propargyl, dipropargyl, and tripropargylamine─were evaluated as metal-selective inhibitors. Modeling these SMIs provided insight into the binding mechanism, influence of sterics, and complex polymer network formed from the reaction between inhibitors consisting of alkene, aromatic, and network branchpoints. While a significant contrast in the binding of the SMIs on copper versus a dielectric was observed, residual amounts were detected on the dielectric surfaces, leading to variable ALD growth rates dependent on pattern-critical dimensions. This behavior can be controlled and utilized to direct film growth on patterns only above a critical threshold dimension; below this threshold, both the dielectric and metal features are protected. This method provides another design parameter for ASD processes and may extend its application to broader-ranging device fabrication schemes.