AbstractThe time‐of‐flight properties of magnetic wedge‐field sectors have been derived in a second‐order approximation. The following quantities were included: source slit width, radial and axial opening angles of the ion beam and relative energy spread. The transfer matrix elements of the time‐of‐flight (longitudinal) row were derived in terms of the initial and final angles and of K‐parameter dependence on the ion momentum and magnetic field. The longitudinal mass dispersion coefficient required in the time resolution formula was derived. The time‐of‐flight ion optical properties of a 60° symmetric, homogeneous magnetic sector mass spectrometer, already employed for time‐resolved ion momentum spectrometry studies, were compared with those of a wedge‐field, 180° deflecting stigmatic arrangement with K=0.7423. The time‐of‐flight aberrations were calculated from transfer matrix multiplications. The advantages of the wedge‐field geometry are: independence, up to second order, of the ion packet length upon the ion source slit width, independence to first order of the ion energy spread and stigmatic focusing in space. These factors ensure both improved sensitivity and time resolution.
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