Reduction In Elastic Modulus Research Articles

Development of and study of boro-tellurite glasses for optical and radiation shielding applications

A new group of boro-tellurite glasses (BCa20, BCa17, BCa14, BCa11) was fabricated using the melt quench method for potential radiation shielding and optical applications. The mechanical, optical, and radiation shielding properties were studied with varying oxide compositions. A decrease in B2O3 and CaO content, with increasing TeO2, led to a reduction in elastic modulus and bulk modulus (from 69.638 to 61.331 GPa), as well as a decrease in packing density (0.673 to 0.636). The optical band gap also gradually reduced (from 3.637 to 3.504 eV), while Urbach energy increased (from 0.293 to 0.354 eV). Optical basicity increased, and optical electronegativity decreased, indicating a shift toward ionic bonding and reduced glass stability. Radiation shielding performance improved with the addition of TeO2, as confirmed by the linear attenuation coefficient (LAC) results using Phy-X software. These findings suggest potential for these glasses in radiation shielding and optical material applications.

Experimental study on the mechanical properties of C30 molybdenum tailings concrete after high-temperature and sulfate corrosion

In order to study the durability of molybdenum tailings concrete after a specific period of wet-dry cycle tests and exposure to high temperatures, this paper investigates the rule of change of the mechanical properties of molybdenum tailings concrete under the coupled influence of sulfate corrosion and high-temperature environmental conditions. A total of five C30 concrete prisms with molybdenum tailings content (0 %, 25 %, 50 %, 75 %, and 100 %) were considered in the tests, with sulfate solution concentrations of 0 g/L, 20 g/L, and 50 g/L, and exposure temperatures of 25° at room temperature and 400° at high temperature, respectively. The test results showed that the mass loss rate of concrete prisms with different molybdenum tailings substitution rates under sulfate corrosion and high temperature environment showed an increasing and then decreasing trend. The specimens with 25 % molybdenum tailings content still maintain high mechanical properties after wet-dry cycle tests of sulfate solution and high temperature, and the reduction of peak stress in this group is only 11 %, and the reduction of elastic modulus is 1 %; the rest of the molybdenum tailings content has a reduction of peak stress of about 25 %, and the reduction of modulus of elasticity is more than 10 %. The plastic deformation capacity of molybdenum tailings concrete decreases under the single-factor effects of wet-dry cycle tests of sulfate solution and high temperature effects, but the plastic deformability capacity of the specimens is enhanced under the combined effects of multiple factors. The stress-strain curve formulas for molybdenum tailings concrete under high temperature, wet-dry cycle tests of sulfate solution, and coupled wet-dry cycle tests of sulfate solution and high temperature were fitted. The results of this study can provide experimental data and valuable references for the engineering application of molybdenum tailings concrete under wet-dry cycle tests of sulfate solution and high temperature conditions, laying a foundation for further research.

Experimental study on axial compressive properties of bamboo scrimber after high temperature

This study examines the uniaxial compressive mechanical properties of after high temperature bamboo scrimber, taking into account the combined effects of temperature, constant temperature duration, and moisture content. A series of 46 uniaxial compression tests were conducted on bamboo scrimber under various conditions to investigate the failure modes after high temperatures. The analysis focuses on the changes in compressive elastic modulus and peak stress of bamboo scrimber parallel and perpendicular to the grain, in relation to temperature, constant temperature duration, and moisture content. The findings reveal that below 180℃, diagonal shear failure and Y-type shear failure are the primary failure modes for specimens parallel to the grain, while diagonal shear failure predominates for specimens perpendicular to the grain. Above 180℃, bond failure and eccentric crushing become the main failure modes for specimens parallel and perpendicular to the grain, respectively. The peak compressive stress decreases significantly beyond 180℃, with a slower decrease observed as moisture content increases. Constant temperature duration has a notable impact on peak stress, with longer durations resulting in lower peak stress at the same temperature. Although temperature has a lesser effect on the elastic modulus compared to peak stress, empirical formulas were derived to establish the relationship between compressive elastic modulus and peak stress reduction coefficient with variations in temperature, constant temperature duration, and moisture content based on the experimental data.

Effects of Humidity on Mycelium-Based Leather.

Leather is a product that has been used for millennia. While it is a natural material, its production raises serious environmental and ethical concerns. To mitigate those, the engineering of sustainable biobased leather substitutes has become a trend over the past few years. Among the biobased materials, mycelium, the fungal "root" of a mushroom, is one of the promising alternatives to animal leather, as a material with tunable physicomechanical properties. Understanding the effect of humidity on mycelium-based leather material properties is essential to the production of durable, competitive, and sustainable leather products. To this end, we measured the water sorption isotherms on several samples of mycelium-based leather materials and investigated the effects of water sorption on their elastic properties. The ultrasonic pulse transmission method was used to measure the wave speed through the materials while measuring their sorption isotherms at different humidity levels. Additionally, the material's properties were mechanically tested by performing uniaxial tensile tests under ambient and immersed conditions. An overall reduction in elastic moduli was observed during both absorption and immersion. The changes in the measured longitudinal modulus during water sorption reveal changes in the elasticity of the test materials. The observed irreversible variation of the longitudinal modulus during the initial water sorption can be related to the material production process and the presence of various additives that affect the mechanical properties of the leather materials. Our results presented here should be of interest to material science experts developing a new generation of sustainable leather products.

Experimental Study on Damage Constitutive Model of Rock under Thermo-Confining Pressure Coupling

Underground engineering frequently encounters the challenges of high temperatures and high confining pressures. The combined effects of temperature and confining pressure can significantly alter the mechanical properties of rock. Evaluating the impact of these factors on rock is a crucial aspect of engineering. This study investigates the mechanical properties of rocks under various temperature and stress conditions, focusing on the deformation and failure characteristics of four typical rock types: granite, red sandstone, gray sandstone, and shale under temperature-confining pressure coupling. The results indicate that high temperatures cause internal structural damage and crack propagation in rocks, leading to a reduction in compressive strength and elastic modulus. Conversely, high confining pressures can inhibit crack propagation and enhance rock deformation capacity. Additionally, significant differences were observed in the mechanical responses of different rocks; red sandstone and shale predominantly exhibited shear failure under the coupled effects of temperature and confining pressure, whereas granite and gray sandstone exhibited bulging failure. Based on the experimental results, an elastic modulus fitting model considering the temperature-confining pressure coupling effect was proposed, and the parameters of the Drucker–Prager criterion were modified. A constitutive model was constructed to accurately reflect the stress–strain state of rocks under the coupled effects of temperature and confining pressure. The constitutive model results show good agreement with the experimental findings.

Study on tensile damage evolution of Ti6Al4V alloy based on DIC technique

Abstract Both optical microscopy (OM) and scanning electron microscopy (SEM) were used to analyze the microstructure of the Ti6Al4V alloy and evaluate its tensile damage behavior. Using Lemaitre’s definition of damage, the variation rule of damage during the reduction of elastic modulus was obtained. Combining the digital image correlation (DIC) analysis approach allowed for an experimental investigation of the alloys’ tensile mechanical characteristics. The strains at 500 independent points were extracted using VIC-2D software. The damage factor of the whole strain field was established by equations and 3D graphics, and the damage evolution process was visualized and analyzed. The results show that the Ti6Al4V alloy has good plasticity, and its fracture mode is a ductile fracture. The sample’s modulus of elasticity falls, and the extent of damage increases as the stretching continues. The sample undergoes a localized violent deformation during the tensile process, as opposed to a homogenous deformation state. The harm progressively concentrates and increases at an increased rate.

Insights into irradiation-affected structural evolution and mechanical behavior of amorphous carbon

The distinctive hybridization structure of amorphous carbon (a-C) imparts remarkable mechanical and tribological characteristics, making it highly relevant for lubrication applications, particularly in critical sectors such as nuclear energy. In this work, we employed molecular dynamics simulations to examine the effects of irradiation on the structural evolution and mechanical behavior of a-C. The findings indicate that with increasing irradiation doses, the short-range order within the a-C is disrupted, leading to a substantial increase in sp2 hybridization. Then, nanoindentation simulations revealed a reduction in both hardness and elastic modulus as a consequence of irradiation damage, associated with the transition in hybridization from sp3 to sp2 and the associated creation of free volume. Furthermore, nanoscratch mechanical testing showed a slight increase in the friction, primarily attributed to the weakened load-bearing ability of a-C after irradiation. Interestingly, a metastable transition from sp2 to sp3 hybridization was observed on the scratched surface, which was concurrently validated by experiments as Raman spectroscopy and TEM-EELS. This study provides a detailed atomic-level mechanism for the irradiation-induced damage on the structural bonding and mechanical properties of a-C, offering guidance for its performance in nuclear reactors and the aerospace industry.

From Waste to Styrene-Butadiene (SBR) Reuse: Developing PP/SBR/SEP Mixtures with Carbon Nanotubes for Antistatic Application.

Styrene-butadiene rubber (SBR) waste from the shoe industry was repurposed to produce polypropylene (PP)-based compounds, with the aim of evaluating their antistatic potential. Styrene-ethylene-propylene (SEP) was added as a compatibilizing agent, while carbon nanotubes (MWCNT) were incorporated as a conductive nanofiller. The polymer compounds were processed in an internal mixer, and injection molded. The properties evaluated included torque rheometry, melt flow index (MFI), impact strength, tensile strength, Shore D hardness, electrical conductivity, heat deflection temperature (HDT), and differential scanning calorimetry (DSC), along with scanning electron microscopy (SEM) for morphology analysis. The production of the PP/SBR/SEP (60/30/10 wt%) compound resulted in a ductile material, enhancing impact strength and elongation at break to 161.2% and 165.2%, respectively, compared to pure PP. The addition of SEP improved the compatibility of the PP/SBR system, leading to an increase in the torque curve and a reduction in the MFI. Furthermore, the SBR/SEP combination in PP accelerated the crystallization process and increased the degree of crystallinity, suggesting a nucleating effect. Carbon nanotubes, in concentrations ranging from 0.5 to 2 phr (parts per hundred resin), were added to the PP/SBR/SEP system. Only the PP/SBR/SEP/MWCNT compound with 2 phr of MWCNT was suitable for antistatic applications, exhibiting an electrical conductivity of 4.52 × 10-07 S/cm. This was due to the greater distribution of MWCNT in the PP matrix, as demonstrated by SEM. In addition, remains tough at room temperature, with a 166% increase in impact strength compared to PP. However, there was a reduction in elastic modulus, tensile strength, Shore D hardness, and HDT due to increased flexibility. SBR waste can be reintegrated into the production chain to produce antistatic polymeric compounds, obtaining a tough material at room temperature.

Engineering bioactive MWCNT-reinforced hydroxyapatite coatings on Ti29Nb5Zr alloy by plasma electrolytic oxidation method: A comprehensive approach to dental implant surface optimization

Titanium-niobium-zirconium (TiNbZr) alloys represent a promising class of newly developed titanium-based biomaterials, engineered to exhibit superior properties for biomedical applications. This study investigates the influence of hydroxylated multi-walled carbon nanotubes (MWCNTs) on the surface properties of hydroxyapatite coatings prepared by the plasma electrolytic oxidation (PEO) method for implant applications. The optimal concentration of MWCNTs in the PEO coating was determined based on the superior surface, electrochemical, and biological properties obtained. The incorporation of MWCNTs led to an enhancement in surface roughness from Ra 0.06 ± 0.02 to Ra 0.618 ± 0.03 µm, improved wettability with a decrease in contact angle from 63.03° ± 1.1–28.29° ± 0.07, and a reduction in elastic modulus from 77.20 ± 2.26 GPa to 54.50 ± 2.22 GPa. Furthermore, electrochemical corrosion resistance analysis revealed an increase in inner passivation resistance up to 2.24 × 10 ×7 Ω.cm2 with the addition of MWCNTs. Antibacterial activity analysis demonstrated that the optimal concentration of MWCNTs resulted in a 3.1-fold and 2.7-fold reduction in E. coli and S. aureus bacteria, respectively, compared to uncoated samples. Cell viability against MC3T3-E1 cells showed a 25 % higher viability with MWCNTs than uncoated substrates.

Cracking the Pericellular Matrix Code: Exploring how MMP-2, -3, and -7 influence matrix breakdown and biomechanical properties

IntroductionThe intricate process of articular cartilage remodeling, pivotal for both physiological functions and osteoarthritis (OA) progression, is orchestrated through a balance of matrix synthesis and breakdown, which is mediated by matrix metalloproteinase enzymes (MMPs). At the heart of this remodeling lies the pericellular matrix (PCM), a specialized microenvironment encapsulating each chondrocyte and composed mainly of collagen type VI and perlecan. The aim of this study was to assess the impact of MMP-2, -3, and -7 on the structural integrity and biomechanical attributes of the PCM. MethodsHuman articular cartilage explants (N=10 patients) were incubated with activated MMP-2, -3, or -7, individually or in combination. Structural alterations in the PCM were evaluated by immunolabeling. The biomechanical properties of the PCM were measured using atomic force microscopy (AFM). ResultsCollagen type VI structural integrity and fluorescence intensity uniformly decreased across all enzyme groups, while perlecan was selectively affected by MMP-3 and -7. AFM measurements demonstrated decreased PCM stiffness after incubation with individual MMPs, leading to an overall ~31 % reduction in elastic modulus for each enzyme. Combinations of enzymes induced comparable significant biomechanical alterations (~35 %), except for MMP-2+MMP-7. DiscussionThis study highlights the significant influence of MMP-induced alterations in PCM composition on biomechanical properties, mirroring characteristics observed in early OA. Each MMP showed specificity in breaking down PCM, and an intriguing interplay, especially between MMP-2 and -7, indicated reduced efficacy in lowering PCM stiffness. Overall, MMP-2, -3, and -7 directly induce functional and structural PCM modifications.

Behavior of self-sensing masonry structures exposed to high temperatures and rehydration

High temperatures can compromise the structural integrity of structural masonry. Therefore, assessing the post-fire mechanical behavior is crucial for selecting suitable rehabilitation methods. Recent research has proposed the application of self-sensing cementitious composites for monitoring strains, stresses, and damage of structural masonry in room temperature. No previous research has been found on the self-sensing performance of fire-damaged masonry prisms exposed to elevated temperatures, with or without subsequent rehydration. Masonry prisms with integrated self-sensing joints and blocks were produced and exposed to different maximum temperature levels, followed or not by rehydration. Then, experimental tests for determination of compressive strength, modulus of elasticity, gauge factor (GF) and damage-detection performance were carried out. The exposure to 300 ºC caused a 7.4 % decrease in compressive strength and a 44.5 % reduction in elastic modulus. Rehydration methods had negligible effects in this case. After 600 ºC, substantial reductions of 42.2 % in compressive strength and 81.5 % in elastic modulus occurred. In this case, rehydration led to a 15.9 % increase in compressive strength and a 117.4 % increase in elastic modulus. Regardless of the exposure temperature, the predominant rupture mode initiated by vertical cracks originating at the block-mortar interfaces. After 300 ºC, slight GF increases occurred due to the thermal decomposition of hydrates of the cementitious matrix, while exposure to 600 ºC resulted in high GF increases due to partial oxidation of nanomaterials and substantial microcracking propagation. Post-fire curing improved the GF by sealing microcracks with nonconductive rehydration products and enhancing tunneling conduction mechanisms. The self-sensing prisms also demonstrated the ability for real-time damage detection and quantification, providing valuable predictive insights into the propagation of damage.

A nonlinear elastic-plastic model describing the bending and fracture behavior of Caragana korshinskii Kom. branch wood

ABSTRACT Caragana korshinskii Kom. branch (CKB), a vital biomass source in northwest China, has not been thoroughly studied in terms of its bending fracture mechanics. This research aims to establish a nonlinear constitutive model that clarifies the fracture behavior of CKB when subjected to bending loads. The nonlinear bending fracture process of CKB was characterized through a three-point bending test, revealing stages of elastic deformation, elastic-plastic transition, and plastic fracture. A power-enhanced elastic-plastic model combined with continuous damage mechanics theory was used to develop an intrinsic bending fracture model, from which the equations governing bending damage evolution were derived. The model's accuracy was validated with simulations in Abaqus/Explicit, showing that CKB from various growth sites demonstrated distinct nonlinear bending behaviors. At the critical damage strain, cumulative damage led to a reduction in the effective elastic modulus, with the bending fracture curve exhibiting a power function trend. The parameters of the nonlinear elastic-plastic constitutive model were derived through curve fitting, yielding coefficients of determination (R²) exceeding 0.99. The consistency between the trends observed in actual tests and simulations, along with a peak bending force error of 7.7%, validated the finite element model's reliability and confirmed the intrinsic model's accuracy.

The effects of physiologically relevant environmental conditions on the mechanical properties of 3D-printed biopolymer nanocomposites

The demand for synthetic bone graft biomaterials has grown in recent years to alleviate the dependence on natural bone grafts and metal prostheses which are associated with significant practical and clinical issues. Biopolymer nanocomposites are a class of materials that display strong potential for these synthetic materials, especially when processed using additive manufacturing technologies. Novel nanocomposite biomaterials capable of masked stereolithography printing have been developed from functionalized plant-based monomers and hydroxyapatite (HA) with mechanical properties exceeding those of commercial bone cements. However, these biomaterials have not been evaluated under relevant physiological conditions. The effects of temperature (room temperature vs. 37 °C) and water absorption on the physical, surface, and mechanical properties of HA-containing biopolymer nanocomposites were investigated. Exposure to relevant conditions led to substantial impacts on material performance, such as significantly reduced mechanical strength and stiffness. For instance, a composite containing 10 vol% HA and functionalized monomers had 26 and 21% reductions in compressive yield strength and elastic modulus, respectively. After 14 days incubation in phosphate buffered saline, the same composition displayed a 62% decrease in compressive yield strength to 28 MPa. This manuscript demonstrates the relevance and importance of evaluating biomaterials under appropriate physiological conditions throughout their development and provides direction for future material development of HA-containing biopolymer nanocomposites.

Enhancing flexibility and durability of PVC with liquid epoxidized natural rubber: Innovative UV treatment to mitigate plasticizer migration

AbstractThis manuscript elucidates the preparation and utilization of liquid epoxidized natural rubber (LENR) with 50 mol% epoxidation level (LENR50) as a polymeric plasticizer for poly(vinyl chloride) (PVC), and further immobilization of the plasticizer in the plastic matrix through subsequent ultraviolet (UV)‐curing treatment. The plasticizing effect induced by LENR50 at 50 wt% loading was evident with a reduction of Tg from a high of 72.0 to 11.4°C. Positive enhancements were also documented in the mechanical properties of the LENR50‐plasticized PVC, specifically the big improvement in elongation at break and elastic modulus, from 106% to 430%, and from 646 to 7 MPa, respectively. The UV‐treated PVC/LENR film also exhibited superior resistance to migration compared with formulations with conventional plasticizers such as di‐2‐ethylhexyl phthalate (DEHP) and triethyl‐2‐acetyl citrate (ATEC). A similar outcome was recorded in the leaching resistance test, where LENR50 had the best resistance to leaching in four different solvents (water, soap solution, ethanol, and toluene). The LENR50‐plasticized PVC film recorded the lowest weight loss following 24 h immersion in both hydrophilic and lipophilic solvents. The findings from this study suggest that LENR50 could serve as an efficient bio‐based polymeric plasticizer for PVC.Highlights LENR as bio‐based polymeric plasticizer for PVC. Significant reduction in Tg and elastic modulus of PVC plasticized with LENR. UV treatment improved tensile strength and elongation at break of LENR/PVC film. UV‐treated PVC/LENR has superior plasticizer migration and leaching resistance.

Assessment of the utilization of cement-treated geotextile as a reinforcement element for highway base layer under cyclic loading

This study conducted large-scale cyclic loading experiments on the base layer overlying a weak subgrade soil. Geotextile and cement-treated geotextile were utilized to reinforce the base material and to separate the interface of soils between the base layer and the subgrade. The results obtained from the repeated loading tests using geotextile and cement-treated geotextile were analyzed and evaluated in terms of some benchmark indicators such as total deformation, permanent deformation, elastic deformation, percentage of elastic deformation, traffic benefit ratio (TBR), elastic modulus (MR), improvement factor (If), and rut depth reduction ratio (RDR). Based on the experimental results, the use of cement-treated geotextile as a base layer reinforcement element or as an interfacial separation element demonstrated better performance compared to the use of geotextile. Utilization of a cement-treated geotextile as both reinforcement and separation element resulted in an RDR value of 49.26 % after 5000 cycles. Additionally, using a cement-treated geotextile for both reinforcement and separation increased the TBR value to 14.62 at 27 mm deformation, decreased the permanent deformation value from 53.67 mm to 27.23 mm, and approached approximately 2 improvement factor values, compared to using the geotextile solely for separation.

Weakening of olivine by hydrogen implantation: Results of nano-indentation tests and some applications to planetary materials

Sticking of the dust grains is a critical step in planet formation. To investigate the solar wind effect on the dust mechanical properties, we conducted hydrogen implantation experiments (using beam energies of 10 keV, 20 keV and 50 keV) on olivine single crystals and determined the elastic modulus and the hardness as a function of depth by nano-indentation tests. The near surface regions of the samples (to ∼600 nm) show a substantial decrease in both hardness (up to ∼85%) and modulus (up to ∼74%), indicating a large degree of mechanical weakening. The depth extent of the weakened region increases with implantation energy while the degree of weakening decreases with implantation energy. TEM (transmission electron microscopy) observations of the samples show that the depth where damaged region occurs increases with the implantation energy used. The results are interpreted based on the physics of ion-solid interaction during implantation. According to our results, we expect that olivine-like dust exposed to solar wind would display a similar mechanical weakening in the surface (∼ 74% reduction in elastic modulus, ∼ 85% reduction in hardness). Mechanical weakening by solar wind implantation would enhance the sticking of the dust in the disk if dust have been effectively exposed to the solar wind. The present results are also applied to interpret observations of some planetary materials.

Effect of sample dimensions on the stiffness of PA12 Lattice materials fabricated using Powder Bed Fusion

Powder Bed Fusion fabrication techniques, including selective laser sintering, have made the fabrication of lattice meta-materials consisting of periodic cells formed by interconnected struts possible. It is generally observed that cell size has a strong influence on the lattice’s effective Young’s modulus, following in the case of typical polymers used for printing a trend of the smaller the softer. However, there is no clear understanding of the origin of the effective elastic modulus reduction with lattice cell size. In this paper, an integrated study is performed to unravel the reasons behind this effect. The analysis performed encompasses mechanical characterization (compression tests and nanoindentation), microstructure characterization (X-ray tomography, DSC, SAXS, and WAXS), and numerical analysis of the effect of defects (FFT and Finite element simulations of cells with roughness and defects) of PA12 printed single cells of different sizes and full lattice specimens containing many cells. It is found that the effect of porosity and roughness is not enough to explain the reduction of the effective elastic modulus with the cell size, suggesting that this effect is necessarily a combination of the defects, incomplete melting of particles and the changes of PA12 nanostructure induced by the different printing conditions as function of full specimen size . The results of the micro- and nanostructure characterization validate this assumption.

Effects on dentin nanomechanical properties, cell viability and dentin wettability of a novel plant-derived biomodification monomer

ObjectivesTo evaluate the effects of dentin biomodification agents (Proanthocyanidin (PAC), Cardol (CD) and Cardol-methacrylate (CDMA) on dentin hydrophilicity by contact angle measurement, viability of dental pulp stem cells (DPSCs) and nanomechanical properties of the hybrid layer (HL). MethodsCDMA monomer was synthesized from cardol through methacrylic acid esterification. Human extracted third molars were used for all experiments. For nanomechanical tests, specimens were divided in four groups according to the primer solutions (CD, CDMA, PAC and control) were applied before adhesive and composite coating. Nanomechanical properties of the HL were analyzed by nanoindentation test using a Berkovich probe in a nanoindenter. Wettability test was performed on dentin surfaces after 1 min biomodification and measured by contact angle analysis. Cytotoxicity was assessed by a MTT assay with DPSCs after 48 and 72 h. Data were analyzed with Student's t test or Two-way ANOVA and Tukey HSD test (p < 0.05). ResultsCD and CDMA solutions achieved greater hydrophobicity and increased the water-surface contact angles when compared to PAC and control groups (p < 0.05). PAC group showed a greater reduction of elastic modulus in nanoindentation experiments when compared to CD and CDMA groups (p < 0.05) after 4 months of aging. CD inhibited cell proliferation compared to all further materials (p < 0.05), whilst CDMA and PAC indicated no cell cytotoxicity to human DPSCs. SignificanceCardol-methacrylate provided significantly higher hydrophobicity to dentin and demonstrated remarkable potential as collagen crosslinking, attaining the lowest decrease of HL’s mechanical properties. Furthermore, such monomer did not affect pulp cytotoxicity, thereby highlighting promising feasibility for clinical applications.

Enhancing sustainability in concrete production: A novel compression casting technique for optimizing cement usage

Cement manufacturing is a major source of carbon dioxide (CO2) emissions. This study focuses on using the compression casting method to reduce the cement content in concrete manufacturing. No such work is present in the existing literature. For this purpose, five concrete mix designs of normal concrete (NC) and compression cast concrete (CCC), targeting compressive strengths of 50 MPa, 30 MPa, 25 MPa, 20 MPa, and 15 MPa, were considered. Moreover, considering the reduced cement content, five additional concrete mixes of NC and CCC were also prepared. All concrete specimens were tested in axial compression to study the stress-strain behavior. The findings reveal that CCC specimens exhibit higher stress-strain curves compared to NC specimens for the same mix design. The post-peak behavior of CCC specimens is observed to be more brittle than that of NC specimens. The reduction in density, compressive strength, and elastic modulus with the increase in the water-to-cement (w/c) ratio is more pronounced in NC specimens than in CCC specimens. The results indicate that the compression casting method allows for a reduction in cement content by approximately 25–50 % while achieving the desired compressive strengths, ranging from 30 to 50 MPa. A correlation is clearly demonstrated to determine the potential cement savings for specific concrete strengths. In summary, adopting compression casting technology effectively lowers cement requirements, leading to cost and carbon emission reductions in the construction sector and significantly enhancing the durability of concrete materials.

Mechanical properties of steel fiber-reinforced geopolymer concrete after high temperature exposure

Adding a certain amount of steel fibers can overcome the brittleness defects in geopolymer concrete and improve the mechanical properties, which has a broader application prospect. However, the research on the material properties of steel fiber-reinforced geopolymer concrete (SFGPC) after high temperature exposure is still very limited. Therefore, tests on 114 cubes and 57 prisms after exposure to high temperatures were conducted in this paper. The main variables were temperature (20 °C, 200 °C, 400 °C, 600 °C, and 800 °C), steel fiber volume content (0, 1 %, and 2 %), and concrete type (SFGPC and steel fiber-reinforced ordinary Portland cement concrete (SFOPC)). The results indicated that SFGPC with a steel fiber content of 1 % at 800 °C experienced a 53.6 % reduction in compressive strength, a 58 % reduction in splitting tensile strength, a 93.9 % reduction in elastic modulus, a 45.9 % reduction in toughness index, and a 274.5 % increase in peak strain, compared with room temperature. The 1 % fiber content enhanced the compressive strength by 10.3 %−36.5 %, the splitting tensile strength by more than 16 %, the peak strain by 9.6 %−32.7 %, and the toughness index by 24.4 %−64.6 % compared to the absence of fiber content. Based on the room temperature model, a constitutive model of SFGPC under uniaxial compression after high temperatures was developed.