Reaction Rims Research Articles

Experimental metasomatic alteration of titanite in a series of metamorphic fluids at 700 °C and 200 MPa

Seven experiments exploring the reaction of titanite with various hydrothermal solutions have been carried out at 700 °C and 200 MPa for a run duration of 16 days. In experiments involving fluids consisting of NaCl+H2O, KCl+H2O, CaCl2+H2O, 2M NaOH, or 2M KOH, no reaction of the titanite with the fluid was observed other than a slight dissolution of the titanite. Experiments involving NaF+H2O and Ca(OH)2+H2O resulted in visible alteration of the titanite in texture and composition, coupled with the formation of perovskite. In the NaF+H2O experiment, perovskite, enriched with rare earth elements (REE), formed as euhedral to subhedral crystals on the surface of the recrystallized titanite. In the Ca(OH)2+H2O experiment perovskite took in minor amounts of REE, and formed as a reaction rim partially replacing the titanite via a coupled dissolution-reprecipitation reaction. Wollastonite, along with minor calcite, and grossular garnet, formed as an outer rim on the perovskite. In the NaF+H2O experiment major and trace elements were leached from the titanite, whereas in the Ca(OH)2+H2O experiment no leaching of major or trace elements was observed. Nb/Ta, Th/U, and Y/Ho were investigated as potential indicators of hydrothermal processes. While the Nb/Ta ratio was altered in the experimentally metasomatised titanite, the degree of alteration was the same for both fluids. In contrast, only small changes in the Th/U and Y/Ho ratios between the altered and original titanite were seen for either experiment. The formation of perovskite at the expense of titanite in NaF+H2O or Ca(OH)2+H2O fluids demonstrates how titanite reacts with these fluids in simple, low silica activity systems under mid to upper crustal P-T conditions.

Compositional zoning and evolution of symplectite coronas in jadeitite

Abstract Multistage fluid activities play an important role in the interaction between jadeitite and symplectite coronas; therefore, we studied the compositional zoning and evolution of representative Myanmar jadeitite. Under the influence of multistage Ca-, Na-, and Si-rich fluid activity, some minerals in Myanmar jadeitite formed symplectite coronas with concentric rings and multilayer metasomatic reaction rim structures. Additionally, the concentrations of Cr and Fe decrease from the core to the peripheral jadeite minerals, whereas the concentration of Si markedly increases. There is almost no Si or Ca in the chromite core, and the concentrations of Si and Ca increase sharply in rims composed of uvarovite. Due to Cr diffusion, the edge of the jadeite adjacent to kosmochlor is Cr-rich and Al-poor. The different element concentrations indicate that the uvarovite formed from the presence of a chromite and jadeite interaction, Si in the kosmochlor after metasomatism or an external Ca-rich fluid. One possible explanation for the formation of kosmochlor is the interaction between chromite and a Na- and Si-rich fluid. Also, Ca-rich fluid could have first interacted with chromite and formed uvarovite; subsequently, a Na-rich fluid could have entered and become saturated with kosmochlor, leading to the formation of kosmochlor surrounding the uvarovite.

Reaction Rims on Ilmenite and Chromite: Implications for Volatile Behavior and Crystallization Conditions of Kimberlite Magma

Abstract Significant uncertainty surrounds the crystallization conditions and the composition of kimberlite melts, including the role of volatiles (H2O and CO2) due to their hybrid nature, intense alteration, and volatile loss during emplacement. In this study, we address these uncertainties by investigating the interaction between oxides (ilmenite and chromite) and kimberlite magma. During kimberlite ascent, mantle minerals react with the magma and develop dissolution textures, compositional zoning, and rims of secondary mineral phases in response to crystallization conditions and the composition of kimberlite magma. We examined oxides from several lithologies within the BK1 and AK15 kimberlites of the Orapa cluster in Botswana, where diamonds demonstrate distinct dissolution styles in each lithological unit owing to differences in magma saturation with volatiles. Here we discovered a strong correlation of the reaction products on ilmenite and chromite with the dissolution style of diamonds in the same kimberlite unit. Diamonds with glossy, low-relief surface features indicative of fluid-rich magma occur in the kimberlite units where ilmenite and chromite develop reaction rims of Ti-bearing phases. Diamonds with corrosion sculptures implying a volatile-undersaturated magma occur in kimberlite units with heavily resorbed chromite and ilmenite completely replaced by a MUM (magnesio-ulvöspinel-magnetite)–perovskite symplectite. Furthermore, the composition of ilmenite reaction rims depends on kimberlite lithology, where MUM co-exists with perovskite or its break-down product anatase in the two coherent kimberlite units, or with perovskite and titanite in the massive volcaniclastic unit. We examine how decompression, cooling, degassing, or assimilation of crustal rocks by kimberlite magma could have shifted conditions from perovskite to titanite stability in the volcaniclastic kimberlite unit. We propose perovskite replacement by anatase-calcite pseudomorphs in the top coherent unit, from which diamonds exhibit an overprint of fluid resorption with a melt resorption. Composition of ilmenite reaction rims provides estimates of kimberlite crystallization temperatures of 730–1275 °C and oxygen fugacities of +0.5 to −3.5 relative to the nickel-nickel oxide buffer, which are validated through controlled experiments. Our study shows that preservation of ilmenite, the type of Ti-phase in its reaction rim, the relative rate of chromite dissolution, and compositional re-equilibration with kimberlite can help model the eruption process as well as the style and rate of diamond dissolution.

Retrograde Assemblages in the Muscovite-Biotite Gneiss of Oluyole Southwestern Nigeria, an Indication of Shear-Zone Environment

Petrographic and whole-rock geochemical study of biotite-muscovite gneiss was determined in order to interpret the metamorphic evolution of the Basement Complex of Southwestern, Nigeria. The gneiss shows a millimetric banding, and in some cases the quartzo-feldspathic bands running up to 10 cm. The gneiss has mineral assemblage biotite + plagioclase + quartz + garnet + K-feldspar + muscovite + chlorite + ilmenite ±titanite. Chlorite occurs along cleavage planes of biotite, and in some cases forms reaction rims around porphyroblasts of garnet. K-feldspar crystals are surrounded by muscovite. Titanite crystals are sub-idioblastic to xenoblastic in form, and have inclusions of ilmenite. Titanite, where present, occurs in close association with biotite and opaque minerals (ilmenite). Also, titanite forms a reaction rim around apatite. Mylonitic texture, fine-grained matrix of mica and quartz ribbons were observed. In addition, there is stretching of the quartz crystals. The SiO2 content is greater than 60 wt %, while CaO ranges from 3.05-6.91 wt %. The M1 foliation comprise of mineral biotite some of which are included in the opaque mineral, M2 represents the metamorphism which gave rise to porphyroblasts of ilmenite, while the M3 gave rise to foliations that forms a wraparound structure on the porphyroblasts of ilmenite. The last metamorphism gave rise to retrograde minerals; chlorite, titanite, and muscovite. The study suggests that this area of the Basement Complex has been subjected to multiple deformations, as well as multiple episodes of metamorphism. The structures observed are similar to those associated with shear zone environment.

Heterogeneous dacitic magmas and the role of crustal assimilation in the Sierra Chichinautzin Volcanic Field, central Mexico: a perspective from crustal xenoliths

ABSTRACT The Sierra Chichinautzin Volcanic Field (SCVF) is constituted by diverse monogenetic volcanic structures with heterogeneous chemical composition. Dacitic magmas are widely distributed in this volcanic field and are the most felsic products. Tabaquillo lava is an example of such felsic rocks, it is porphyritic and highly crystalline, constituted by large phenocrysts of plagioclase and quartz (>1 mm long) + ortho and clinopyroxene + biotite and minor amphibole. Coarse-grained and equigranular clasts classified as ‘crystal-rich enclaves’ are also common in the lava flow, with variable compositions (basaltic andesite, andesite, and dacite) and ages of 0.35–0.36 Ma. The presence of metasandstone crustal xenoliths in the Tabaquillo lava flow, with a maximum sedimentation age of 150 Ma, attests to crustal assimilation of the Guerrero terrain rocks. Isotopic data of Tabaquillo lava and other volcanic rocks from the SCVF show notable variations (87Sr/86Sr = 0.70379–0.70474; 143Nd/144Nd = 0.51272–0.51288). Most of them lie in the mantle array but trending to the more radiogenic metasandstone xenolith and Guerrero terrain rocks (87Sr/86Sr = 0.71271 and 0.71627), suggesting that SCVF magmas have partially assimilated these rocks. Interaction between SCVF magmas with metasandstone, quartzite, and skarn rocks took place at depths > 1.3 km, imprinting geochemical and isotopic characteristics on the felsic magmas and produced the diverse compositional lithologies in the entire SCVF. Additionally, crystal-rich enclaves produced during previous magmatic pulses stalled at different depths, were later mixed with the ascending mafic magma, and subsequently incorporated into the crystal cargo that reached the surface. The common presence of quartz crystals (sometimes with reaction rims of clinopyroxene) found in many SCVF lavas could derive from the crystal-rich magmatic enclaves and/or from the metasandstone basement rocks.

Structural Analysis and Petrography of High-Grade Gneisses and Associated Mafic / Ultramafic Dikes Around Salem, Southern India

Southern Granulite Terrane (SGT) of India preserves extensive high-grade granulite facies rocks of Archaean and Proterozoic age. The SGT is divided into number of blocks by several suture/shear zone. Structural investigations on the basement gneisses and younger mafic/ultramafic dikes have been carried out within the Salem block which is part of Northern Granulite Block (NGB), north of the Cauvery Suture Zone (CSZ). The present work emphasizes various scale fold styles and other structural patterns of the area, which includes regionally metamorphosed high-grade rocks as basement for the multiple ultramafic intrusions to the north of Cauvery Suture Zone (CSZ) which highlights the finite strain geometry, complex deformation pattern and high-grade metamorphism. Structural map of the study area is prepared showing two generations of folding, namely F1 whose axial trend is NE-SW, subparallel with general trend of gneissic foliation and are tight isoclinal folds while F2 which are open folds with axial trend NW-SE.E-W structural cross section across the foliation planes, characterizes antiformal and synformal fold patterns of the basement due to varying dip directions which also reflects type-3 interference pattern of folding. Mesoscopic scale shear zones of dextral kinematics in response to E-W collision during Paleo-Meso Archean time, delta type porphyroclasts, S-C fabrics with the dextral movement of CSZ system, Riedel shear, thrust imbricates implying duplex structures, rotation of mafic boudins along shear zones are the most prominent ductile structural features of this area. Brittle structures like different sets of cross cutting joints and faults indicate younger deformation as well. Petrography of major lithologies has classified them into amphibolite gneiss, migmatite gneiss, charnockites, granulites and mylonites as basement rocks to the younger pyroxenite intrusions. Typical textures like, perthite, granulose, reaction rims, sieve textures and microstructures like S-C fabrics, kink bands, rotated porphyroclasts, etc are observed within the basement rocks. Coarse grained textures with fractured porphyroclasts of garnets indicating the water interactions and retrogradations within the granulite facies rocks. Reaction rims observed in charnockites and granulites are indicative of retrogression during shearing. The coarse grained cummulate nature of pyroxenites neither represent deformation nor metamorphism. Keywords: Southern Granulite Terrane, Salem, Structural Analysis, Mafic/Ultramafics, Dikes, Petrography

Geology and geochemistry of the only independent tellurium deposit in the world

The article discusses both the regional and deposit geology including structure, strata, and igneous rocks, as well as the ore body and alteration of Dashuigou tellurium deposit at the Qinghai-Tibet Plateau, the only independent tellurium deposit in the world. There are over 30 minerals that make up the deposit‘s ore, including carbonates, silicates, oxides, sulfides including various tellurides and native element minerals. Euhedral, semi-euhedral, xenomorphic granular, metasomatic, metasomatic graphic, reaction rim, and solid solution separation are the main ore texture; while massive, vein/veinlet, stockwork, dissemination, breccia, and bird‘s-eye are the major ore structure of the deposit. Based on the ore structure, this deposit‘s ore can be divided into three categories: massive, veinlet-stockwork, and disseminated. The ores are further divided into eight subcategories in total based on the proportions of tellurium minerals, other sulfides, dolomite, quartz, and muscovite in it. Both geology and K-Ar isotope dating have confirmed that the pyritic (pyrrhotite + pyrite) vein and telluride vein are products of two different geological events that are far apart. The tellurium grade in the ores varies between 0.01% and 34.58%. All ores in this deposit are primary sulfide ores that have not been transformed by oxidation or weathering. Two paragenetic stages; namely, the pyritic stage and tellurium stage consisting of five sub-stages in total exist in the deposit. According to Laznicka‘s idea, the deposit‘s tonnage accumulation indices indicate that it is a super-large independent tellurium deposit.

Linking kimberlite magmatism in the Brazilian Platform with Pangea break-up events using in situ Rb-Sr in phlogopite

Kimberlite magmatism provides insights into periodic tectonothermal processes linked to the evolution of supercontinents. Paleozoic and Mesozoic kimberlites overlapping with the Pangea cycle are exposed in the Amazonian Craton (Pimenta Bueno field) and the Neoproterozoic Brasília Belt. Phlogopite in mantle xenoliths in kimberlites from the Amazonian Craton are characterized by low Cr2O3 (< 1 wt%) and an enrichment in TiO2 (> 2 wt%), akin to secondary phlogopite formed by kimberlite magma infiltration in the mantle. Low Ti-Cr (< 1 wt%) and high #Mg (91–92) grains are linked to extensive metasomatism of garnet peridotites resulting in clinopyroxene-phlogopite rocks. In situ phlogopite Rb-Sr isochron ages of 250–220 Ma constrain the emplacement of pipes in the Amazonian Craton with no age difference between distinct phlogopite compositions (higher and lower TiO2 phlogopite) and microstructures (porphyroclasts, neoblasts, reaction rims). Mantle xenoliths in kimberlite pipes from the Brasília Belt present high TiO2 (> 2 wt%) akin to secondary phlogopite formed by magma infiltration, and low Ti-Cr (1 wt%), and high #Mg (> 92) phlogopite akin to primary grains in equilibrium with garnet. In situ phlogopite Rb-Sr isochron ages from all Brasília Belt phlogopite types span 90–80 Ma, constraining the emplacement of diamondiferous and barren pipes, with no relic of older metasomatic events. The kimberlites from the Pimenta Bueno field (Amazonian Craton) are coeval with the beginning of the extension within Pangea that culminated with the Central Atlantic rifting. In fact, the Permian-Triassic kimberlites occur close to intracratonic basins that are crosscut by ca. 200 Ma dykes and sills of the Central Atlantic Magmatic Province. In situ phlogopite Rb-Sr isochron ages spanning 90–80 Ma in the pipes from central and southeastern Brazil (Brasília Belt) may be associated with propagation of far-field stresses linked to opening of the South Atlantic Ocean during the Pangea break-up.

The key to ancient Roman mortars hydraulicity: ceramic fragments or volcanic materials? A lesson from the Phlegrean archaeological area (southern Italy)

This research deals with mineralogical, petrographic, chemical, and microstructural characterization of raw materials from the Roman Dragonara cave (Phlegraean Fields, Campania region, Italy) through Polarized Light Microscopy (PLM), X-ray Powder Diffraction (XRPD), Field Emission Scanning Electron Microscopy coupled with an Energy Dispersive Spectrometer (FESEM/EDS), Simultaneous Thermal Analysis (STA) and Mercury Intrusion Porosimetry (MIP). The aim of this study was to asses mortars hydraulic properties along with provenance of raw materials and mortars recipe. A focus on the reactions between the surface of the ceramic aggregates and volcanic materials with binding matrix proved to be crucial to define their role in the mix design of mortars. Representative results showed that hydraulicity of the analyzed mortars is mainly due to volcanic materials rather than ceramic fragments. In fact, reaction active elements such as Reaction Rims (RR), Interfacial Transition Zones (ITZ) and particularly Ca-rich rims were usually found at the matrix-volcanic fragments interface. Moreover, porosity tests evidence that bedding mortars, which contain mainly volcanic material and only sporadically ceramic fragments have a higher closed porosity of binder matrix due to the good pozzolanic reactivity.

The dam that fly ash built.

When the first concrete was poured in 1949 for the Hungry Horse Dam (Montana, USA), pozzolan cements had already been used in several major North American dams, including Grand Coulee on the Columbia River (diatomaceous earth explored but ultimately not used), Friant on the San Joaquin River and Altus on the North Fork Red River (pumicite) and Bonneville on the Columbia River and Davis on the Colorado River (calcined clay). But Hungry Horse Dam stands out as the first dam constructed using coal combustion fly ash. Utilising 2.4 million cubic metres of concrete, the dam is located on the South Fork Flathead River, one of the tributaries feeding one of the nation's major waterways, the Columbia River, and closely related to the adjacent Glacier National Park. In this respect, Hungry Horse is directly connected to two momentous periods in modern history - the massive adoption in the 1950s of coal as fuel for power plants, and the ongoing threats to fresh water supply and the rapid retreat of alpine glaciers due to global warming. Two concrete cores from this dam, one with fly ash and one without fly ash, are examined microscopically to explore the long-term suppression of alkali-aggregate reaction by fly ash. The core without fly ash exhibits clear evidence of alkali-aggregate reaction, manifested by sandstone coarse aggregate particles with darkened reaction rims. Sandstone coarse aggregate particles of the same lithology in the core with fly ash are without signs of alkali-aggregate reaction. A detailed examination of the darkened rims indicates that alkali-silica reaction products fill the narrow gaps between adjacent sand grains in the sandstone. This alkali-silica gel infilling allows for optical continuity between adjacent sand grains and is responsible for the classic darkened rim associated with the alkali-aggregate reaction.

Discovery of carbonatite-syenite hosted REE-Nb mineralization in the Amaragh area, Gleibat Lafhouda (South Morocco): Hints toward an extended mineralized alkaline province

We report the results of a reconnaissance study of several small carbonatite and syenite bodies with very low topography (up to 1.5 m), that were recently discovered in the Archean basement in the Amaragh area near the Gleibat Lafhouda (GL) carbonatite, previously interpreted as a primary carbonatite. Two varieties of carbonatite have been identified: 1) brownish to greyish banded dolomite carbonatite, composed of dolomite as the main carbonate phase, and calcite, magnetite, apatite, monazite-(Ce), magnesite and minor bastnaesite-(Ce), 2) calciocarbonatite, mainly composed of calcite and several feldspar aggregates (the latter are interpreted as xenocrysts). The Amaragh syenites consist of small outcrops and show white to dark grey colors. The main outcrop is a nepheline syenite that contains coarse-grained rounded magnetites, rimmed by biotite and epidote within a feldspar and nepheline groundmass, suggesting fluid-mineral reactions. The other syenites consist mainly of alkali feldspar, albite, mica, amphibole and accessory apatite, epidote, and titanite. The host minerals of Nb and REE are pyrochlore and allanite. All syenite samples display a peraluminous composition and strong LREE enrichment with negative EuCN anomalies, except for two samples with a slightly positive EuCN anomaly, suggesting at least two types of differentiated syenites. All samples show strong postmagmatic and hydrothermal overprint, which is revealed by, for example, the occurrence of negative YCN and positive CeCN anomalies and mica-epidote mineral reaction rims between magnetite and feldspar. The close spatial association of the Amaragh carbonatite and syenite bodies with the GL carbonatites along with geochemical and mineralogical similarities and REE-Nb enrichment suggest a close petrogenetic relationship, pointing toward a single carbonatite-syenite alkaline complex that was probably formed in an extensional tectonic setting.

Petrogenesis and rare-metal mineralization of the Ririwai alkaline granitoids, north-central Nigeria: mineralogical and geochemical constraints

ABSTRACT The Ririwai anorogenic alkaline complex harbours extensive rare metal (Nb-Zr-Sn-Zn) mineralization. However, uncertainty still surrounds their origin and magmatic-hydrothermal processes responsible for their rare metal mineralization. The complex is composed of peralkaline arfvedsonite ± albite-bearing granites, mildly peralkaline fayalite-bearing granite porphyries, and weakly peraluminous biotite-bearing granites, all of which show diagnostic A1-type characteristics. Zircon U-Pb dating reveals emplacement ages between 181.4 ± 0.81 and 188.6 ± 7 Ma for the three rock units. Sm-Nd and Pb isotopes (εNd (t) = –0.6 to −5.4, 206Pb/204Pb = 17.68–17.93) constrained the Ririwai A-type granites to represent highly fractionated products of enriched mantle-derived magmas. Mass-balance modelling suggests that magma evolution was fuelled by extensive fractional crystallization of 50 ~ 60 vol.% K-feldspar, 30 ~ 35 vol% fayalite, 5 ~ 10 vol.% amphibole, and ~ 5 vol.% apatite under reduced and water-undersaturated (ΔFMQ = –1.55; logfo2 = –18.63; H2O = <2.0 wt.%) conditions and assimilation of ~ 50 vol.% crust. Whole rock and amphibole compositions revealed an increasing degree of fractionation from the fayalite-bearing granite porphyries through biotite-bearing granites to the arfvedsonite ± albite-bearing granites. This extended fractionation at the late stage of magma differentiation, facilitated by fluorine dissolution and concentration of excess HFSE and REE as alkali-fluorocomplexes in the fluorine-rich silicate melt, allowed the accumulation of economic rare metal pyrochlore and columbite mineralizations in the highly fractionated arfvedsonite± albite- and biotite-bearing granites, respectively. Nonetheless, the metasomatic reaction rim textures around the magmatic pyrochlore, coupled with the M-type lanthanide tetrad effect (TE1,3 >1.10) indicate the subsequent effect of hydrothermal processes. Tectonically, reactivated shear fractures and transcurrent faults following lithospheric stresses in a transtensional regime allowed magma uprising and emplacement of A-type granites in the Ririwai complex.

Influence of the expansive sites distribution on alkali-silica reaction expansion under applied stress: Crack orientation as a key factor for expansion transfer

The influence of the expansive site distribution of the alkali-silica reaction (ASR) on the expansion behavior under applied stresses was numerically investigated to verify the mechanical factor of expansion transfer. In the analysis, the aggregate and mortar phases were individually modelled by mesoscale discrete analysis. To reproduce expansive site distribution and time-dependent behavior, expansive phase model, pressure development model, and creep model were developed. As a result, expansion transfer was observed for the model based on the reaction rim assumption and the crack effect model under applied stress of less than 10 MPa. A detailed numerical investigation identified that the cracks under applied stress in the reaction rim model are modified more easily than those in the gel pocket model, despite crack generation being inhibited. Consequently, expansion transfer was found to be significantly influenced by the crack orientation because of the mechanical interactions at the expansive sites under applied stress.

Magmatic Evolution of Dago Volcano, West Java, Indonesia

Dago Volcano is a product of Miocene Sunda Arc volcanism located southeast of the capital city of Jakarta. The morphological change from flat lava flow to steeper lava morphology implies a process of magma evolution under Dago Volcano. This research provides an overview of the magma evolution that occurs on this volcano. The methods used include volcanostratigraphic analysis, petrographic analysis, mineral chemistry, and whole-rock geochemistry. The volcanostratigraphy of Dago Volcano is composed of two eruption centers and a flank eruption forming lava and cinder cones products. The mineralogical associations of Dago Volcano products include plagioclase, olivine, and clinopyroxene. The mineral textures of Dago edifices show zoning, sieve, and reaction rims textures. Geochemically, the Dago Volcano product has a magma affinity of med-K calc-alkaline with quite high levels of MgO, Ni, and Cr approaching the characteristics of primitive magma. The magma evolution process of Dago Volcano includes fractional crystallization and magma mixing which originates from the same magma source.

Petrographic and geochemical evidence of calc-silicate xenolith – magma interaction in the western Bushveld Complex, South Africa

Abstract Underground workings at Rowland Shaft, Lonmin Platinum, near Marikana have exposed a large (&amp;gt;7 x 5 m) calc-silicate xenolith in mottled anorthosite ~20 m below the UG 1 chromitite of the upper Critical Zone. The xenolith comprises a monticellite + forsterite + spinel assemblage that is consistent with a metamorphic Tmax of ≥975°C being reached at P ~1 kbar and XCO2 ~1. Internal variations in the modal proportions of these phases are interpreted as an artefact of sedimentary layering in the xenolith. The xenolith is flanked by a 20 to 30 cm wide magmatic skarn that contains several small, cm- to dm-scale, calc-silicate fragments displaying the same peak assemblage as the main xenolith, as well as a dm-scale chromitite autolith and mm- to dm-scale lenses and stringer-like masses of fine-grained uvarovite. The skarn matrix is mineralogically zoned, with an up to 10 cm wide clinopyroxenite layer proximal to the xenolith contact and calc-silicate fragments grading outwards into a gabbroic, plagioclase-clinopyroxene assemblage in which plagioclase becomes progressively more dominant distally. Notwithstanding its pseudo-ophitic texture, the distal skarn matrix displays a range of features consistent with crystallisation of magma contaminated by Ca from the decomposing xenolith under elevated fO2 conditions, including: (a) the unusual mineral compositions (zoned aluminian-ferrian diopside and anorthite, An&amp;gt;99), (b) the presence of calcite as inclusions in plagioclase and as a minor interstitial phase, (c) corroded wollastonite inclusions in clinopyroxene, and (d) thin grossular reaction rims between clinopyroxene and plagioclase. This chemical evolution is further substantiated by zoned spinel grains comprising Cr-rich cores and Al-enriched rims, which are, in turn, enclosed in garnet aggregates that grade outwards from uvarovite to grossular. Local development of grossular-vesuvianite symplectite indicates limited retrograde hydrous (XCO2 &amp;lt;0.1) fluid influx under subsolidus conditions (T &amp;lt;750°C). Bedding in the xenolith displays a steep westerly dip, approximately orthogonal to the magmatic layering. This, together with evidence in the skarn of both plastic shear strain and out-of-sequence magmatic autoliths, suggests that the xenolith underwent density-driven foundering within the RLS magma from an initial location above the UG 1 chromitite layer.

Investigation on the reactivity of recycled brick powder

Knowing the reactivity of recycled brick powder (RBP) is fundamental for its correct and efficient utilization. In this work, the dissolution behavior of RBP in NaOH solution and the degree of reaction in cement matrix were studied to investigate the reactivity of RBP. The results revealed that the main active species of RBP, Si and Al, showed obvious lasting dissolution with a significant non-steady state dissolution stage, indicating that the reaction proceeds slowly. The dissolution mechanism controlled by the phase boundary reaction, with activation energies of 82.74 kJ/mol and 75.79 kJ/mol for Si and Al dissolution, respectively, further confirmed this finding. The strength activity index, thermogravimetric analysis, selective dissolution, BSE-IA-Mapping and MAS NMR all confirmed reactivity of RBP. Additionally, reaction rims were observed around RBP particles in cement paste. The low Ca/Si and Ca/Al ratios and their significant increases in a direction from the particle boundary to the paste demonstrate that the rim was a hybrid phase composed of the original RBP components and the reaction products.

Grain boundary widening controls siderite (FeCO3) replacement of limestone (CaCO3)

The microstructure of minerals and rocks can significantly alter reaction rates. This study focuses on identifying transport paths in low porosity rocks based on the hypothesis that grain boundary widening accelerates reactions in which one mineral is replaced by another (replacement reaction). We conducted a time series of replacement experiments of three limestones (CaCO3) of different microstructures and solid impurity contents using FeCl2. Reacted solids were analyzed using chemical imaging, small angle X-ray and neutron scattering and Raman spectroscopy. In high porosity limestones replacement is reaction controlled and complete replacement was observed within 2 days. In low porosity limestones that contain 1–2% dolomite impurities and are dominated by grain boundaries, a reaction rim was observed whose width did not change with reaction time. Siderite (FeCO3) nucleation was observed in all parts of the rock cores indicating the percolation of the solution throughout the complete core. Dolomite impurities were identified to act as nucleation sites leading to growth of crystals that exert force on the CaCO3 grains. Widening of grain boundaries beyond what is expected based on dissolution and thermal grain expansion was observed in the low porosity marble containing dolomite impurities. This leads to a self-perpetuating cycle of grain boundary widening and reaction acceleration instead of reaction front propagation.

Chemical Modification of Lherzolite Xenoliths Due to Interaction with Host Basanite Melt: Evidence from Tumusun Volcano, Baikal Rift Zone

To investigate the process and chemistry of mineral reaction zone formation, we conducted detailed petrographic observations and chemical analysis of rocks and minerals of spinel lherzolite xenoliths from basanites of Tumusun volcano (Baikal Rift Zone). The reaction zones gradually disappear from contact toward the center of the xenoliths. The influence of basanite melt on major and trace element composition of secondary minerals of reaction zones is notable only at a distance up to 100–200 μm from the contact. At a distance of 0.3–1.0 mm from the contact, the major and trace composition of secondary clinopyroxenes from the orthopyroxene reaction zone indicates their formation from a melt formed by dissolution of orthopyroxene and influenced by the element diffusion from basanite melt. Inside xenoliths, the secondary minerals have Mg# values equal to or higher than Mg# of primary minerals, and secondary clinopyroxenes inherit their depleted or enriched REE pattern from primary pyroxenes. The compositional variations in secondary clinopyroxenes testify melt heterogeneity. Clinopyroxene rims have slightly higher LILE and similar abundances of other trace elements compared to clinopyroxene cores. This is consistent with the model developed from experimental studies: due to the interaction with basanite, incongruent dissolution of orthopyroxene occurs to form a melt which circulates in lherzolite and leads to pyroxenes and spinel dissolution. Diffusion of elements from basanite results in lherzolite enrichment in K, Na, Rb, Ba, La, and Ce, which are incorporated in feldspars and clinopyroxene of reaction zones as well as in feldspar veinlets. Non-dissolved mineral cores are homogenous and similar in major and trace element composition to primary minerals without reaction rims.

Relative importance of magmatic and hydrothermal processes for economic Nb-Ta-W-Sn mineralization in a peraluminous granite system: The Zhaojinggou rare-metal deposit, northern China

Highly evolved granitic melts typically experience late-stage melt-melt and fluid-melt immiscibility as well as fluid-melt and fluid-rock interaction. These processes are particularly important in the formation of deposits of the rare metals Nb, Ta, W, and Sn. We document the relation between immiscibility and alteration processes and the partitioning behavior of rare metals for the Zhaojinggou rare-metal deposit of northern China. This deposit shows a systematic change from a magmatic to a hydrothermal system, including the reaction of the exsolved fluid with earlier crystallized granite and the formation of late-stage quartz veins. The magmatic stage (Stage I) includes biotite alkali-feldspar granite (BAG) with moderate Nb-Ta mineralization. Extreme fractional crystallization of BAG eventually resulted in melt-melt immiscibility and the separation of a hydrosaline melt. Fractional crystallization of this hydrosaline albite granite (AG) melt finally exsolved a magmatic fluid. Therefore, the magmatic-hydrothermal transition (Stage II) includes a melt-dominated Stage IIa with strong Nb-Ta-Sn mineralization in AG and a fluid-dominated Stage IIb with minor Nb-Ta-Sn mineralization in muscovite and biotite greisen. Late hydrothermal processes (Stage III) formed quartz veins with important W mineralization. There are several texturally and chemically distinct generations of cassiterite and columbite-group minerals (CGM) in BAG and AG reflecting crystallization from an evolving magma. The porous and patchy-zoned reaction rims of tantalite-(Mn) and wodginite on CGM in AG are the result of fluid-melt interaction. Texture and compositions show that wolframite in AG is hydrothermal and formed through interaction of early exsolved magmatic fluids with the host granite. CGM and cassiterite in the biotite greisen and Ta-rutile in the muscovite greisen, as well as wolframite and scheelite in quartz veins that formed when fluid-rock interaction reduced the availability of H+ or F− or the temperature of the fluid decreased. The distribution and importance of mineralization demonstrate that Nb, Ta, W, and Sn strongly partitioned into the hydrosaline melt during melt-melt immiscibility and that W partitioned into the magmatic fluid during fluid-melt immiscibility. Exsolved magmatic fluids interacted with earlier crystallized rocks mobilizing rare (Nb, Ta, and Sn) and base (Fe and Ti) metals from Li-Fe mica, providing the ore elements for subordinate Nb-Ta-Sn mineralization in AG and in biotite and muscovite greisen. Thus, magmatic processes (with later metal redistribution by magmatic fluids) dominantly control economic Nb-Ta-Sn mineralization, whereas hydrothermal processes mainly control the formation of economic W mineralization.

Dating individual zones in phenocrysts from the 2016–2017 eruption of Bogoslof volcano provides constraints on timescales of magmatic processes

We investigate the rates of magmatic processes using clinopyroxene diffusion chronometry on volcanic products erupted in August 2017 at the end of the 9-month eruption of Bogoslof volcano. The eruptive products contain plagioclase, clinopyroxene, and amphibole, all of which exhibit sharp chemical boundaries and are occasionally observed in multi-phase crystal clots with shared zoning boundaries across different mineral phases. At the shared boundaries in crystal clots, clinopyroxene and plagioclase continued to grow but abruptly changed composition from Mg# 81.7 ± 5.8 to 72.9 ± 3.0 and An82.5±1.4 to An61.3±5.7, respectively. Additionally, the sharp boundary marks where amphibole became unstable and began forming a reaction rim. Synthesizing these observations, we were able to determine that the shared boundaries formed as a result of rapid decompression during magma ascent, followed by storage in a shallow cryptodome, where magma accumulated prior to erupting.In order to determine the timescales of magma ascent and subsequent crystal residence times, we applied diffusion chronometry on zoned clinopyroxene phenocrysts using Mg# concentrations at 1056 °C determined from FeTi oxide pairs. Our diffusion modeling results show that diffusion began at the stepwise boundaries in clinopyroxenes no more than180 days before the final explosive event.These results were then used to calculate crystal growth rates for shared plagioclase and amphibole rims, as shared zones in crystal clots indicate that the boundaries in all three phases formed contemporaneously. We calculate growth rates of plagioclase crystals (1.7 ± 0.99 × 10−6 um/s) and amphibole reaction rims (2.8 ± 0.47 × 10−6 um/s). The calculated natural growth rate of plagioclase was then used to constrain additional magmatic timescales from growth rate chronometry, results of which support our diffusion timescales.Our results indicate that the distinct boundaries in all three mineral phases formed due to ascent-driven decompression followed by shallow emplacement of mafic magma that occurred continually throughout the course of the eruption. By subtracting diffusion timescales from the date that the samples were erupted, the oldest crystal boundaries correspond to March 2017, seemingly correlating with increases in both seismicity and SO2 emissions. These observations may suggest that our petrochronometric results are supported by interdisciplinary observations.