Measured time-of-flight (TOF) distributions, corresponding to speed- and angle-resolved differential cross sections for the reaction D + H2 > HD + H, are compared with recently published 3-D quantum calculations. The comparison is made in the man- ner least susceptible to distortion: the energy-, angle- and state-resolved theoretical results in center-of-mass (c.m.) coordinates are projected onto the laboratory angle-time axis, and averaged over all experimental resolution parameters to predict the mea- sured TOF distributions. Features directly visible in the experimental data are: (1) relative populations of the v 1 = 0 and v 1 = 1 product vibrational states, (2) the extent of HD product rotational excitation, and (3) the ratio of differential cross sections near 180 ° c.m. to those near 70° c.m. Significant discrepancies with theory are found with respect to features (2) and (3).
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