Weathering Rates Research Articles

The Calcium Isotope (δ44/40Ca) Record Through Environmental Changes: Insights From the Late Triassic

AbstractCalcium isotopes (δ44/40Ca) are particularly useful in palaeo‐environmental studies due to the key role of carbonate minerals in continental weathering and their formation in seawater. The calcium isotope ratio can provide hints on past changes in the calcium fluxes, environmental shifts, ecological factors and alternatively diagenesis of carbonate rocks. The investigation of the Late Triassic calcium isotope record offers a great opportunity to evaluate such factors in a time interval that witnessed important environmental and ecological turnovers, such as the first appearance of calcareous nannoplankton, ocean acidification and periods of elevated extinction rates. In this study, we present a δ44/40Ca data set from the upper Norian (Upper Triassic) through the lower Hettangian (Lower Jurassic) interval. The isotope records reveal two globally significant signals: a ∼ 0.20‰ decrease through the early Rhaetian (Upper Triassic) and a small, negative (∼0.14‰) excursion corresponding to the emplacement of the Central Atlantic Magmatic Province, at the end of the Triassic. The possible explanations for these signals are changes in the isotopic ratio of the continental calcium influx to the ocean due to the high chemical weathering rate of carbonates and possibly ocean acidification, respectively. The considerable (∼0.15–0.30‰) offset in δ44/40Ca between study areas is likely the combined result of local differences in lithology and early marine diagenesis. The major evolutionary step represented by the first occurrence of calcareous nannoplankton did not have at this time a determining role on the calcium isotopic signature of the marine carbonates.

The Hydrochemistry, Ionic Source, and Chemical Weathering of a Tributary in the Three Gorges Reservoir

Riverine dissolved matter reflects geochemical genesis information, which is vital to understand and manage the water environment in a basin. The Ganjing River located in the hinterland of the Three Gorges Reservoir was systematically investigated to analyze the composition and spatial variation of riverine ions, probe the source and influencing factors, and assess the chemical weathering rates and CO2 consumption. The results showed that the total dissolved solid value (473.31 ± 154.87 mg/L) with the type of “HCO3−–Ca2+” was higher than that of the global rivers’ average. The hydrochemical parameters were relatively stable in the lower reservoir area of the Ganjing River, which was largely influenced by the backwater of Three Gorges Reservoir. The carbonate weathering source contributed 69.63% of TDS (Total dissolved solids), which generally dominated the hydrochemical characteristics. The contribution rates of atmospheric rainfall were relatively low and stable in the basin, with an average of 4.01 ± 1.28%. The average contribution rate of anthropogenic activities was 12.05% in the basin and even up to 27.80% in the lower reservoir area of the Ganjing River, which illustrated that the impoundment of Three Gorges Reservoir had brought great challenges to the water environment in the reservoir bay. The empirical power functions were tentatively proposed to eliminate the dilution effect caused by runoff discharge on the basis of previous studies. Accordingly, the rock weathering rate was calculated as 23.54 t/km2 in the Ganjing River Basin, which consumed atmospheric CO2 with a flux of 6.88 × 105 mol/y/km2. These results highlight the geochemical information of tributaries in the hinterland of the Three Gorges Reservoir, have significant implications for understanding the impact of impoundment, and provide data support for the integrated management of water resources in the Ganjing River Basin.

Aspect-dependent bedrock weathering, cliff retreat, and cliff morphology in a hyperarid environment

Deciphering aspect-related hillslope asymmetry can enhance our understanding of the influence of climate on Earth’s surface morphology and the linkage between topographic morphology and erosion processes. Although hillslope asymmetry is documented worldwide, the role of microclimatic factors in the evolution of dryland cliffs has received little attention. Here, we address this gap by quantifying aspect-dependent bedrock weathering, slope-rill morphology, and sub-cliff clast transport rates in the hyperarid Negev desert, Israel, based on light detection and ranging (LiDAR)-derived topography, clast-size measurements, and cosmogenic 10Be concentrations. Cliff retreat rates were evaluated using extrapolated profiles from dated talus flatirons and 10Be measurements from the cliff face and sub-cliff sediments. We document systematic, aspect-dependent patterns of south-facing slopes being less steep and finer-grained relative to east- and north-facing aspects. In addition, cliff retreat and clast transport rates on slopes of the south-facing aspect are faster compared to the other aspects. Our data demonstrate that bedrock weathering of the cliff face and the corresponding grain size of cliff-derived clasts delivered to the slopes constitute a first-order control on cliff retreat and sediment transport rates. We demonstrate that the morphology of the cliff and the pattern of bedrock weathering co-vary with the solar radiation flux and hence that cliff evolution in hyperarid regions is modulated by aspect-dependent solar radiation. These results help to better understand interactions between climate and dryland surface processes.

Impacts of dissolved phosphorus and soil-mineral-fluid interactions on CO2 removal through enhanced weathering of wollastonite in soils

The weathering of silicate minerals removes carbon dioxide (CO2) from the atmosphere over geologic timescales and is also investigated as an engineered strategy to mitigate climate change on decadal timescales. “Enhanced rock weathering” (ERW) is a carbon dioxide removal strategy that involves spreading of pulverized, highly reactive silicate rock at the Earth's surface such as within agricultural and natural soils. The rate and efficacy of ERW in agricultural soils to remove CO2 is difficult to quantify owing to the complex geochemical environment including biological-mineral-fluid-atmosphere interactions and human interventions that occur. Column experiments containing wollastonite [CaSiO3] and soils were conducted to investigate the geochemical processes that remove CO2 during ERW, and to determine the potential impact of P-bearing fertilizers on CO2 removal. Columns containing wollastonite, soil, or 8:1 soil-wollastonite mixtures were irrigated with de-ionized water or a 1 × 10−4 M K3PO4 solution. Analysis of column effluent concentrations indicated that P was rapidly removed from solution and retained within the columns, with little difference in weathering rate between columns irrigated with water and those receiving the K3PO4 solution. Bulk wollastonite weathering rates were significantly enhanced in the presence of soils compared to columns with wollastonite alone. Cation concentrations in effluent from columns with soil-wollastonite mixtures were strongly impacted by adsorption to soil surfaces, complicating efforts to estimate CO2 capture. Based on wollastonite weathering rates estimated by Si release, a maximum of 255 kg CO2 t−1 amendment yr−1 was captured in the soil-wollastonite mixture columns. The majority of CO2 stored in the soil-bearing columns was most likely soil-generated rather than removed directly from the atmosphere. The results of this study indicate that adsorption to soils may limit the ability of P to enhance wollastonite weathering, that silicate weathering behaviour within soils differs substantially from that of pure mineral phases, and that CO2 budgets must be carefully constrained to assess the source of stored CO2. Moreover, leachate concentrations of cations and HCO3− may not serve as accurate indicators of the extent of silicate weathering, at least over the short term, due to the numerous processes that control their concentrations in soils, such as sorption to soil components.

Detecting short-term weathering of stone monuments by 3D laser scanning: lithology, wall orientation, material loss

• Short term non-linear weathering processes are detected by laser scanner. • Wall orientation and lithology control the weathering. • Ooidal porous limestone is more prone to weathering than bioclastic porous limestone. • Surfaces with alveolar weathering and granular disintegration can have a surface loss of up to 9 mm during one winter period. Stone deterioration is a non-linear process that is difficult to observe in a short period. The current study documents surface changes related to material loss using terrestrial laser scanner (TLS) and explains the differences in weathering of lithotypes and different wall orientations of various weathering forms. Ruins of a medieval church constructed from weathering-prone porous limestone were surveyed prior to and after a winter period in a five-month interval with two scan phases. Thirty-five stone surfaces of exposed and sheltered wall sections of different compass orientations were compared to assess the short-term material loss and weathering. The study revealed that more than 30% of the selected surfaces show a major surface retreat of more than 4 mm. Three to nine percent of the scanned areas show countable deterioration. The most significant material loss was recorded at rain exposed but partially wind protected walls facing Northeast. Lithology also controls the surface loss and the rate of weathering. Ooidal porous limestone is the most sensitive lithology to weathering. The minor heterogeneities of the stone ashlar and the co-existence of weathered and seemingly intact areas even within one stone block were also considered. Comparing two time-lapses allows for recognizing even minor surface loss. Scans could be made before and after the weathering threshold, but it cannot be predicted when the threshold is reached. Detecting short-term surface changes of monuments (weathering rate) using Terrestrial Laser Scanner

The History of Cenozoic Carbonate Flux in the Atlantic Ocean Constrained by Multiple Regional Carbonate Compensation Depth Reconstructions

AbstractThe Atlantic is the only ocean basin almost entirely surrounded by passive margins, and a major global long‐term sink of carbonate carbon that has evaded subduction. Quantifying the history of carbonate accumulation in the Atlantic has been limited by the absence of well‐defined regional carbonate compensation depth (CCD) models. We determine the CCD for the northern North Atlantic, central North Atlantic, and South Atlantic, and use these reconstructions to compute the carbonate carbon mass and carbonate carbon flux in a tectonic framework at 0.5 m.y. intervals since 66 Ma. We find that the total carbonate carbon mass of the Atlantic has grown 2.5‐fold from ∼1,500 Mt at 66 Ma to ∼3,800 Mt at present day. The overall Cenozoic increase in carbonate carbon flux toward the present day is punctuated by “carbonate crash” phases in the mid‐Eocene at ∼44–38 Ma and in the mid‐late Miocene at ∼19–8 Ma. During these times the flux decreases from ∼45 to ∼25 Mt C/yr, likely caused by carbonate dissolution and reductions in productivity. Reduced carbonate carbon flux in the mid‐Eocene also coincides with reduced calcification rates of small coccolithophores previously observed offshore Africa. After ∼8 Ma the carbonate carbon flux rises to a Cenozoic maximum of ∼75 Mt C/yr at ∼3 Ma, possibly driven by enhanced flux of nutrients into the ocean. Our CCD curves and the resulting carbonate accumulation history are useful for calibrating ocean chemistry models, and constraining global terrestrial weathering rates, climate perturbations, and carbon cycle models.

Soil formation and mineralogical changes on basaltic lava vs scoria along a hydroclimatic gradient on Santa Cruz Island, Galápagos

Climate and parent material type are important soil forming factors. On Santa Cruz Island, Galápagos, the climate shows a pronounced altitudinal zonation from arid lowlands to humid highlands, and the volcanic parent materials, although chemically rather uniform (basaltic), show pronounced differences in porosity, including dense lava flows and very vesicular scoria deposits. In this study, the effect of these two driving factors on pedogenesis was investigated. Our results show that pH and effective cation exchange capacity (CECeff) decreased, but potential cation exchange capacity (CECpot), phosphate retention, and Alo + ½Feo as well as Alp/Alo increased with increasing elevation regardless of parent material type. Conversely, topsoil bulk density (BD) and organic carbon (OC) content did not show a clear altitudinal pattern on lava but decreased (BD) or increased (OC) with increasing elevation on scoria. Clay mineralogy changed from minor (2:1-type) mixed layer phases in the low-elevation arid zone to vermiculitic (lava) or kaolinitic mineralogy (scoria) at mid-elevation (humid), whereas short-range-order (SRO) minerals (allophane and ferrihydrite) dominated in the colloidal fraction of both lava- and scoria-derived soils under very humid conditions at high elevation. The sequence of soil types developed on lava was, with increasing elevation, Cambisol → Phaeozem → Andosol, while on scoria it was Regosol → Umbrisol → Andosol. Our results show that climate is the overriding factor controlling the major mineralogical and pedogenic changes in the studied environment; however, the higher porosity of the scoria parent materials considerably accelerated weathering and pedogenic processes compared to the denser lavas. Our study highlights the importance of the parent material’s physical nature in modulating rates of chemical weathering and pedogenesis.

Shift of major driver for chemical weathering from the natural control to human dominance since 1980s in the Taihu watershed, China.

Anthropogenic acidification has become a concerned problem in the Taihu region; however, how it affected the regional weathering rate, especially at the different sub-watershed levels has hardly been studied. To reveal the impact of human activities on watershed weathering and water chemistry in Taihu sub-watersheds, historical water chemistry data (1950s-1970s) and recent water samples (2018-2021) of the local river systems, as well as sediment samples of Taihu lake were collected and analyzed, and a linear addition mass balance method was used to determine the weathering rate at the sub-watershed level. The results indicated that, compared with 60years ago, the current weathering rate of carbonates and silicates in the Taoge water system (TG) was the highest, reaching 67.2 and 11.4 t·km-2·a-1, increasing by 4.1 and 2.7-folds, respectively; and meanwhile the carbonate and silicate weathering rates increased by 3.1 and 4.9-folds in the Nanhe water system (NH), and 5.2 and 3.4-folds in the Tiaoxi water system (TX), respectively. The increasing rate was significantly correlated to the atmospheric SO2 concentration in different sub-watersheds and was affected by the sub-watershed lithology, e.g., TX had a higher increase rate of silicate weathering due to the wider distribution of silicates in this sub-watershed than the other two. The sediment evidence of Na/K and Ca/Al on the profile in different lake parts, which was influenced by different influx river systems, confirmed that the overall intensity of watershed weathering was higher in TG than in the TX sub-watershed and was higher in the recent decade than 50-60years ago. The accelerated weathering rate was found to present a definite consistency with the social and economic development in the watershed. Combined analyses of the accelerated weathering rate in the watershed and sedimentation evidence indicated that the major driving force for the watershed weathering has shifted from carbonic acid under the natural condition to human-induced sulfuric acid since 1980s.

Understanding the hydrochemical functioning of glacierized catchments of the Upper Indus Basin in Ladakh, Indian Himalayas.

Recent studies have endorsed that surface water chemical composition in the Himalayas is impacted by climate change-induced accelerated melting of glaciers. Chemical weathering dynamics in the Ladakh region is poorly understood, due to unavailability of in situ dataset. The aim of the present study is to investigate how the two distinct catchments (Lato and Stok) drive the meltwater chemistry of the Indus River and its tributary, in the Western Himalayas. Water samples were collected from two glaciated catchments (Lato and Stok), Chabe Nama (tributary) and the Indus River in Ladakh. The mildly alkaline pH (range 7.3-8.5) and fluctuating ionic trend of the meltwater samples reflected the distinct geology and weathering patterns of the Upper Indus Basin (UIB). Gibbs plot and mixing diagram revealed rock weathering outweighed evaporation and precipitation. The strong associations between Ca2+-HCO3-, Mg2+-HCO3-, Ca2+-Mg2+, Na+-HCO3-, and Mg2+-Na+ demonstrated carbonate rock weathering contributed to the major ion influx. Principal component analysis (PCA) marked carbonate and silicates as the most abundant minerals respectively. Chemical weathering patterns were predominantly controlled by percentage of glacierized area and basin runoff. Thus, Lato with the larger glacierized area (~ 25%) and higher runoff contributed low TDS, HCO3-, Ca2+, and Na+ and exhibited higher chemical weathering, whereas lower chemical weathering was evinced at Stok with the smaller glacierized area (~ 5%). In contrast, the carbonate weathering rate (CWR) of larger glacierized catchments (Lato) exhibits higher average value of 15.7 t/km2/year as compared to smaller glacierized catchment (Stok) with lower average value 6.69 t/km2/year. However, CWR is high in both the catchments compared to silicate weathering rate (SWR). For the first time, in situ datasets for stream water chemical characteristics have been generated for Lato and Stok glaciated catchments in Ladakh, to facilitate healthy ecosystems and livelihoods in the UIB.

Chemical weathering characteristics and controls in the Yarlung Tsangpo River Basin: Evidence from hydrochemical composition

The uplift of the Tibetan Plateau (TP) is thought to be closely related to the global climate. For the Yarlung Tsangpo River (YTR), the largest river on the TP, the hot spring input is an important source of solutes. Without considering hot spring input will lead to an overestimation of chemical weathering and CO2 consumption rate. Two sample series were collected in the basin before and after the monsoon season to evaluate the chemical weathering rates and controlling factors based on the hydrochemical composition. The results of improved forward model indicate that the highest contribution to the total cations comes from rock weathering (59%–99%, average value 93%), of which carbonate dissolution contributes the most (25%–79%, average value 61%), followed by evaporite dissolution (5%–42%, average value 19%) and silicate weathering (1%–29%, average value 13%). The hydrochemistry of tributaries in the middle reaches (Dogxung Tsangpo and Lhasa River) is affected by hot springs significantly, and the maximum contribution reaches 40%. The chemical weathering rates for the sub-basins show a sequence of Lhasa River > Dogxung Tsangpo > Nyang Qu, primarily controlled by lithology and runoff. For the mainstream above the YTR canyon and tributaries in the upper and middle reaches, chemical weathering is controlled by a transport limited regime, and the rest of the basin is governed by a kinetically limited regime. Overall, after deducting the hot spring input from the solutes, the silicate and carbonate weathering rates in the YTR Basin are 1.8 t/km2/yr and 6.3 t/km2/yr, respectively. The atmospheric CO2 consumption by silicate and carbonate weathering in the YTR Basin accounts for ∼0.17% and ∼0.28% of global, respectively, on ∼0.21% of the global land surface area. The carbon sink caused by chemical weathering and its effect on global carbon cycle in the YTR Basin are insignificant.

Coupling chemical transport modeling and diagnostic ratio analysis for predicting PAH fingerprint in coal tar and creosote contaminated soils

ABSTRACT This article illustrates the use of a fate and transport model and a diagnostic ratio analysis to determine chemical signatures of polyaromatic hydrocarbons (PAHs) in coal tar and creosote residues in soil. The fate and transport model, based on diffusion, convection – advection of PAHs, helps determine their weathering rates in two soil types and provides an insight on the air – soil exchange of PAHs. Time-averaged volatilisation flux, estimated from the model, was used to determine the residual composition of the 16 priority PAH (non-alkylated PAHs) in coal tar and creosote contaminated soils. Expectedly, lower molecular weight (MW) PAHs volatilised faster than higher MW PAHs. In the absence of water movement towards the surface, vapour diffusion is the primary mechanism of transport, and the flux was observed to be high ranging from 8.52–2167.3 x 10−7 kg m−2 day−1. Higher flux was observed for clayey soils. At high values of organic carbon (foc), the flux was observed to be lower due to the binding of PAHs to the soil. The mass flux was higher with water movement (0.6–1036.5 x 10−3 kg m−2 day−1) indicating that diffusion along with wicking were the key mechanisms for PAH losses from soil residues. The modelled volatilisation flux for the PAHs was observed to be within the range of the flux values (for soils and sediment) reported in literature. Double diagnostic ratio analysis was used to compare chemical signatures of the modelled residues to PAH data in actual PAH contaminated soils. The diagnostic PAH ratios of the modelled weathered coal and creosote residues and the actual soil samples correlated well, especially for 5- and 6-ringed PAHs. A good correlation between the modelled and actual diagnostic ratios suggested that the mathematical model can be used to supplement physical sampling and analysis, thereby providing one additional line of evidence for source apportionment.

Peering into the unseen: Novel methods in identifying shell taxa from archaeological micro-fragments

Archaeomalacological analysis is generally undertaken on recovered macro-remains to characterize the overall composition of faunal remains in a deposit. Given the susceptibility of shell middens to a variety of taphonomic processes, it is assumed that the prior presence of shell in deposits may therefore occasionally be missed. Deteriorated micro-remains can mix indistinguishably into surrounding sediments and make their analyses and identification difficult, particularly in older deposits and in environments that experience rapid rates of weathering. This paper explores whether microscopic remains of deteriorated molluscs can be distinguished from other microscopic remains at the coastal rock shelter site of Waterfall Bluff in Mpondoland, South Africa. The methodology uses a multi-scalar approach integrating shell mineralogy and microstructure using the taxonomic distinctiveness of these features. The diagnostic features (e.g., morphology, hinges, spires, and apertures) used for identifying macro-remains are absent in micro-remains, therefore unique methods of identification are needed to identify these microscopic mollusc fragments. Through mineralogical analyses and scanning electron microscope (SEM) imaging, the nacreous remains of Mytilidae shell were identified from previously unidentified degraded shell remains as well as sediment samples from Waterfall Bluff. These methods thus recovered ‘invisible’ evidence of shellfish remains providing further evidence of continued coastal foraging from Marine Isotope Stage 3 to the early Holocene (ca or ⁓ 40 ka to 10 ka) on the south-eastern African coast.

Quantification of CO2 removal in a large-scale enhanced weathering field trial on an oil palm plantation in Sabah, Malaysia

Modeling studies show that large-scale deployment of enhanced rock weathering on croplands has the potential to reduce levels of atmospheric carbon dioxide by the end of the century. There is, however, a pressing need to verify model predictions through long-term field trials. Here we report results from the first 3 years of an ongoing enhanced weathering field trial, carried out on an oil palm plantation in Sabah, Malaysia. Crushed silicate rock was applied to three hydrologically isolated catchments, and three adjacent (paired) reference catchments were left untreated. The drawdown of atmospheric CO2 was quantified via the export of alkalinity in stream waters and changes in soil carbonate content. The amended and reference catchments were found to have a similar extent of CO2 drawdown via alkalinity export [respectively, 3.8 ± 0.8 (1 SD) and 3.7 ± 0.6 (1 SD) tCO2 ha−1] when all catchments were averaged over the study period (October 2018 to July 2021). However, differences were observed between the different catchment pairs (plots): two of the plots displayed a similar extent of CO2 removal for both the amended and reference catchments, but the third amended catchment had a higher extent of CO2 removal of ~1 tCO2 ha−1 relative to its adjacent reference catchment. The difference in CO2 removal rates determined for this plot can likely be attributed to increased weathering of silicate minerals in the amended catchment. Soil carbonate concentrations were on average <0.2 wt% CaCO3, but we report a small increase of ~0.03 wt% CaCO3 in the top 30 cm of soil in the amended soils relative to the reference catchments. The magnitude of CO2 drawdown via alkalinity export determined for these agricultural catchments is around an order of magnitude higher than in natural forested catchments in Sabah and similar to that of basaltic catchments. We show that these high weathering rates are primarily driven by weathering of carbonate fertilizers. The data presented from this field trial provide vital contextual information on the real-world efficacy and practicalities associated with the implementation of enhanced weathering for atmospheric CO2 removal that will help to inform further trials as well as wider-scale deployment.

The Cenozoic Seawater Conundrum: New constraints from Mg isotopes in island dolostones

The Mg/Ca ratio of seawater increased from ∼1.5 to its present value of 5.4 over the Neogene, indicating a fundamental imbalance in the Mg–Ca cycle during the late Cenozoic. The imbalance in Mg–Ca cycles since the late Cenozoic, however, is contrasted by an arguable constancy in the Mg isotope compositions of seawater (δ26Mgsw) reconstructed from several low-resolution carbonate records. Addressing such Cenozoic Seawater Conundrum requires reliable seawater Mg isotopic records. The Xisha Islands in the South China Sea host large Cenozoic dolostone sequences that record seawater chemistry over the past 23 Myr. This study reports the Mg isotopic and trace elemental compositions of island dolostones in the well-studied Xike-1 drill core from the Xisha Islands. Petrographic, C–O–Sr isotopic, and paleomagnetic data from the drill core samples collectively support a “fluid-buffered”, syn-depositional origin for the dolostones. The dolostones from the Xike-1 core have a narrow range of δ26Mg (−2.83‰±0.12‰), confirming that δ26Mgsw have been stable around the modern value (−0.83‰) since the late Cenozoic. This record provides a new opportunity to better understand the Mg–Ca cycle during the late Cenozoic. We ran numerical models of global seawater Mg–Ca contents and δ26Mgsw with the most recently published flux and isotope fractionation data. The results show that the contrast between the constancy of δ26Mgsw values and the dramatic increase in seawater Mg/Ca ratios cannot be explained by a single mechanism (i.e., a decrease in the rate of phyllosilicate formation on the seafloor alone). Instead, processes involving different Mg fluxes need to be coupled to explain the observed trends in Mg content and isotopic compositions of Cenozoic seawater. The solution to the Cenozoic Seawater Conundrum includes simultaneous decreases in the rates of both clay formation and dolomitization on the seafloor, or an increase in the rate of both continental weathering together with decreased seafloor clay formation. Our study underlines the sensitivity of the Mg cycle to the interactions between climate, continental weathering, and seafloor processes during the late Cenozoic.

Tectonics and shore platform development: Rates and patterns of erosion on recently uplifted mudstone and limestone rocks at Kaikōura Peninsula, New Zealand

On tectonically active coasts, there is a dearth of erosion data documenting how rock coasts adjust (either fast or slow) in response to marine and subaerial processes immediately after coseismic uplift. Here we report erosion rates and evidence of reshaping of shore platform morphology at Kaikōura Peninsula, South Island, New Zealand, following the November 2016 Kaikōura 7.8 (Mw) earthquake, that uplifted platforms by ~1 m and extended their widths. High-resolution topographic data obtained from quarterly surveys over four years using a micro-erosion meter (MEM) and Structure-from-Motion Multi-View Stereo (SfM-MVS) surveys have provided rates of erosion and visual representation of surface morphologies. MEM data revealed variations in erosion, weathering and deposition rates across lithology, tidal positions, and platform elevation after the uplift. After four years, surface downwearing rates for all platforms were on average 2.25 mm/yr, a 104% increase from the pre-uplift rate of 1.10 mm/yr. Average lowering rates on limestone, hard, and soft mudstone platforms were 1.19 mm/yr, 2.31 mm/yr, and 3.21 mm/yr, respectively. Results show a change in patterns of erosion rates and faster rates on mudstone than limestone lithologies, but both faster when compared to pre-uplift rates. Previously reported seasonal trends in erosion rates have disappeared because post-uplift erosion rates are similar during the summer and winter. In contrast, statistically significant differences in lowering rates now exist across rock lithology and elevation. On one MEM site on the harder mudstone platform, a large increase from a pre-uplift erosion rate of 0.43 mm/yr to 19.23 mm/yr (1-year after uplift) and subsequent decline to 1.54 mm/yr after four years demonstrates the role of block detachment not previously seen in the MEM data from Kaikōura. For the first time, we complement MEM data with SfM-MVS-derived orthomosaics to provide evidence of changing rock morphology and processes such as granular disintegration, flaking and algal growth. Results from this study demonstrate how tectonism can fundamentally alter the way in which rock shore erosion rates are influenced by waves, tides, and weathering processes.

Linking Archaean climate change with gold metallogeny

First large-scale concentration of gold to ore grade in Earth’s crust took place at around 2.9 Ga in quartz-pebble conglomerates, well before endogenous deposits, such as porphyry and epithermal systems or orogenic-type deposits, started to play a significant role from ca. 2.75 Ga onwards. The conglomerate-hosted gold placers, typified by those in the Mesoarchaeaen Witwatersrand Basin in South Africa, are thought to have been sourced from the leaching of background levels of gold in the Archaean continental crust, promoted by deep chemical weathering under a reducing acidic atmosphere. Gold dissolved in meteoric waters was trapped by possibly acidophile microbes, fossil remnants of which are preserved as kerogen layers in the 2.9 Ga lower Central Rand Group of the Witwatersrand Supergroup. Mechanical reworking of the delicate microbial mat-bound gold led to rich gold placers from 2.9 Ga onwards. Well-endowed gold placers older than 2.9 Ga are conspicuously missing, although suitable siliciclastic host rocks, even containing relics of former microbes, are known from continental sediment sequences as old as 3.22 Ga. A review of climate-sensitive rock types and geochemical data on the extent of chemical weathering reveals that the period from 2.96–2.91 Ga was cold, with repeated glaciations as evidenced by glaciogenic diamicite, whereas warmer and (or) wetter climates reigned from 2.90 to 2.78 Ga. In concert with the temporal distribution of placer gold accumulation, the conclusion is reached that chemical weathering rate, dictated by climate, was a key determining factor in the exogenous binding of Au into sedimentary deposits.

The efficacy of enhancing carbonate weathering for carbon dioxide sequestration

Enhanced weathering is a geoengineering strategy aiming to increase continental weathering rates, thereby increasing the delivery of atmospheric carbon (as HCO3-) to the oceans. Most enhanced weathering studies focus on the capacity of silicate rocks (e.g., basalt) and minerals (e.g., olivine, Mg2SiO4, or wollastonite CaSiO3) to remove atmospheric CO2. However, carbonate minerals (e.g., calcite, CaCO3) could provide an additional, rapid way to increase HCO3- export to the oceans. Recent studies suggest that 0.84 Gt C yr−1 could be removed from the atmosphere through the enhanced dissolution of calcite in soils, provided carbonic acid is the main dissolution agent. What is not clear is whether atmospheric CO2 dissolved in soils can be transported by rivers, which typically have lower [pCO2], to the oceans. This difference in calcite solubility between soils (where weathering occurs) and rivers (where HCO3- is transported) may lead to large amounts of secondary carbonate formation during transport, releasing the CO2 consumed through dissolution. Here, we present a modeling study comparing the estimated soil dissolution capacity (SDC) in 149 of Earth's largest river basins, to the potential transport capacity of carbon (PTCC) in corresponding rivers. We find the SDC can only be exported to the oceans, without secondary carbonate precipitation, if rivers are in disequilibrium with respect to calcite (i.e., SIc = 1). In this instance, 0.92 Gt C yr−1 may be sequestered above background weathering rates, which is ~20% of annual increases in atmospheric carbon. If rivers are at equilibrium with calcite (i.e., SIc = 0), approximately two-thirds of the carbon dissolved in soil waters are lost due to calcite precipitation in rivers, and just 0.26 Gt of additional atmospheric C yr−1 can be transported to the oceans. Overall, the efficacy of enhanced carbonate weathering is a function of the capacity rivers have for transporting the products from carbonate weathering to the oceans, rather than the dissolution capacity of soils. These findings have implications for the efficiency of enhancing silicate weathering for ocean alkalinity enhancement, as secondary carbonate precipitation during transport is not always considered.

Provenance Studies of Alluvial Tin Deposits in Parts of Ropp Younger Granite Complex, Northcentral Nigeria

The study area in this research is within the Ropp Complex, part of the Nigerian Mesozoic Younger Granite province. The study aims to interpret the depositional environment and establish the provenance of the alluvial cassiterite deposits in the study area. Boreholes/mining pits were logged for this study, and stanniferous sandstone samples were collected, which were used for textural and mineralogical studies. The mineral assemblages documented in the samples include ilmenite (3% to 27%). Cassiterite (2 to 14%), Zircon (2 to 16%), magnetite (0 to 17%), tourmaline (5 to 11%), rutile (2 to 8%) and monazite (2 to 7%).The ZTR Index calculated from the result of heavy minerals analysis for the selected pieces is 59%. Mineralogical studies revealed that quartz is the most dominant detrital mineral averaging about 93-99%, indicating that the stanniferous sandstones are compositionally matured and have experienced a high degree of chemical weathering. The quartz grains have grain sizes ranging from coarse to very coarse. They are poorly sorted, sub-angular to sub-rounded, with low sphericity. This also indicates a closeness to the source and textural immaturity. The occurrence of relatively very few feldspar grains suggests a slow sedimentation rate, very high rate of chemical weathering and composition maturity. The bivariate plots, univariate grain size parameters and probability plots, and the absence of fossils and trace fossils suggest deposition in a fluvial environment. The results of the granulometric analysis indicate that the study area's stanniferous sandstone was deposited in a fluvial environment by a low-energy fluvial (river) depositional system and the deposition in proximal (close to the source). This study suggests that the Basement complex and Younger Granite are the sources of the stanniferous placer deposits.

The triple oxygen isotope composition of marine sulfate and 130 million years of microbial control

The triple oxygen isotope composition (Δ'17O) of sulfate minerals is widely used to constrain ancient atmospheric pO2/pCO2 and rates of gross primary production. The utility of this tool is based on a model that sulfate oxygen carries an isotope fingerprint of tropospheric O2 incorporated through oxidative weathering of reduced sulfur minerals, particularly pyrite. Work to date has targeted Proterozoic environments (2.5 billion to 0.542 billion years ago) where large isotope anomalies persist; younger timescale records, which would ground ancient environmental interpretation in what we know from modern Earth, are lacking. Here we present a high-resolution record of the [Formula: see text]O and Δ'17O in marine sulfate for the last 130 million years of Earth history. This record carries a Δ'17O close to 0o, suggesting that the marine sulfate reservoir is under strict control by biogeochemical cycling (namely, microbial sulfate reduction), as these reactions follow mass-dependent fractionation. We identify no discernible contribution from atmospheric oxygen on this timescale. We interpret a steady fractional contribution of microbial sulfur cycling (terrestrial and marine) over the last 100 million years, even as global weathering rates are thought to vary considerably.

Understanding the early Paleozoic carbon cycle balance and climate change from modelling

The Ordovician global cooling trend observed by several temperature proxies, which coincides with one of the most significant evolutionary diversifications on Earth, is yet to be fully understood. This study presents new simulations of pCO2 and surface temperatures using a spatially resolved climate-carbon cycle Earth system model fed with refined continental reconstructions and new estimates of solid Earth degassing. First, in order to quantify the respective roles of paleogeography and degassing, the impact of continental drift alone is investigated. This is done by calculating its imprint on continental weathering rates throughout the Ordovician under a constant pCO2, and by testing different topography inputs. Secondly, the sensitivity of the Earth's climate to paleogeography and carbon degassing changes is investigated by coupling the climate and carbon cycles in the GEOCLIM model. Based on our experiments we show that, although Early Ordovician high temperatures can be replicated within error margins, our new constraints cannot explain the intense cooling over the Mid to Late Ordovician, even if a progressive enhancement in Earth surface weatherability is taken into account. By using GEOCLIM in an inverse modelling approach, we calculate that the theoretical degassing necessary to reach proxy-derived temperatures for the Early Ordovician is three-to-five times higher compared to modern values. Further, in order to simulate the following Ordovician cooling trend, the solid Earth degassing must be reduced to modern-day values in only 30 Myrs. We conclude that, if accepting the veracity of the high Early Ordovician temperatures, alternative sources but also sinks of carbon must be considered to explain the climatic shift over the period.