Purity Semi-insulating 4H-SiC Research Articles

The Role of Substrate Compensation on DC Characteristics of 4H-SiC MESFET with Buffer Layer: A Combined Two-Dimensional Simulations and Analytical Study

An analytical model of 4H-SiC metal semiconductor field effect transistor (MESFET) is proposed with buffer layer on high purity semi-insulating (HPSI) 4H-SiC substrate compensated by multiple deep level traps. The contribution of deep level traps (DLT) is projected and verified using two-dimensional simulations (Silvaco®). The modeled DC characteristics are compared with two-dimensional simulations performed on the same device as considered in the analytical model.The 4H-SiC MESFET is simulated with and without the effect of buffer layer and the electron concentration profiles in different regions are observed from two-dimensional simulations.The electron concentration profiles obtained at channel-substrate interface clearly shows that when the buffer layer is not present, the channel electrons get trapped by the deep level traps used for substrate compensation. It is also observed that the inclusion of buffer layer minimizes the extent of electron trapping by screening out the active channel from the substrate. However, the trapping phenomena take place in both the cases.We believe that the proposed model of 4H-SiC MESFET which includes the substrate compensation through multiple deep level traps may be useful for realizing SiC based monolithic circuits (MMICs) on HPSI substrates.

Shallow Incorporation of Nitrogen in HPSI 4H-SiC through the Laser Enhanced Diffusion Process

This paper investigates n-type doping of point-defect compensated high purity semi-insulating (HPSI) 4H-SiC using a pulsed laser (10 ns FWHM @ 260 nm) for the introduction of nitrogen to shallow depths. A thermal model is presented using COMSOL Multiphysics featuring nonlinear temperature dependent material properties and a volumetric heat source term that takes into account the laser absorption depth for common ultraviolet irradiating wavelengths. The temperature distribution in the material and the amount of time that the surface and near-surface regions are at high temperature determines how many laser pulses are required to dope to the desired depth, and simulation results are presented and fit to measured data. The simulations and measured data show that for shallow doping a short wavelength ultraviolet laser should be used to localize the heat at the surface so the dopant can’t diffuse deep into the material. The laser enhanced diffusion process has been used to incorporate nitrogen into HPSI 4H-SiC with a measured surface concentration greater than 1020 cm-3 and a nonlinear thermal model was built.

Characterization of Annealed HPSI 4H-SiC for Photoconductive Semiconductor Switches

Annealing of high purity semi-insulating (HPSI) 4H-SiC is investigated as a method to improve bulk photoconductive semiconductor switches through recombination lifetime modification. Five samples of HPSI 4H-SiC were annealed at 1810 °C for lengths of time ranging from 3 to 300 minutes. The recombination lifetime of the unannealed and annealed samples was measured using a contactless microwave photoconductivity decay (MPCD) system. The MPCD system consists of a 35 GHz continuous microwave probe and a tripled Nd:YAG pulsed laser. The recombination lifetime was increased from 6 ns, as received, up to 185 ns by annealing for 300 minutes. To experimentally verify switch improvements, identical switches from unannealed and annealed material were fabricated and tested at low voltage. The unannealed device generated a 15 ns pulse with a 2 ns rise-time. The annealed device conducted for upwards of 300 ns with a comparable 2 ns rise-time. The increased recombination lifetime resulted in lower on-state resistance and increased energy transfer.

Phase Locked BWO System for Open Resonator Measurement in D-Band

The combination of a D-Band phase-locked backward-wave oscillator (BWO) with a spectrum analyzer for measurement of permittivity and low loss-tangent is presented. For measuring low loss tangent material, such as CVD diamond and high purity semi-insulating (HPSI) 4H-SiC , at millimeter wave ranges, it is necessary to precisely measure an increase of a few kHz in a line-width of 200 kHz. We describe a phase-locked loop with frequency conversion that combines a BWO source and a microwave spectrum analyzer to obtain line-width measurements with less than 2 kHz (less than 1%) standard deviation in D-Band millimeter wave.

Optically Induced Transitions among Point Defects in High Purity and Vanadium-Doped Semi-Insulating 4H SiC

Optically Induced Transitions among Point Defects in High Purity and Vanadium-Doped Semi-Insulating 4H SiC