Results from plasma wave experiments in spacecrafts give support to nonlinear interactions involving Langmuir, electromagnetic, and ion-acoustic waves in association with type III solar radio bursts. Starting from a general form of Zakharov equation (Zakharov, V.E., 1985. Collapse and self-focusing of Langmuir waves. Hand-book of Plasma Physics Cap.2, 81–121) the equations for electric fields and density fluctuations (density gratings) induced by a pair of counterpropagating Langmuir waves are obtained. We consider the coupling of four triplets. Each two triplets have in common the Langmuir pump wave (forward or backward wave) and a pair of independent density gratings. We numerically solve the dispersion relation for the system, extending the work of (Alves, M.V., Chian, A.C.L., Moraes, M.A.E., Abalde, J.R., Rizzato, F.B., 2002. A theory of the fundamental plasma emission of type- III solar radio bursts. Astronomy and Astrophysics 390, 351–357). The ratio of anti-Stokes ( AS ) ( ω 0 + ω ) to Stokes ( S ) ( ω 0 - ω * ) electromagnetic mode amplitudes is obtained as a function of the pump wave frequency, wave number, and energy. We notice that the simultaneous excitation of AS and S distinguishable modes, i.e., with Re { ω } = ω r ≠ 0 , only occurs when the ratio between the pump wave amplitudes, r is ≠ 1 and the pump wave vector k 0 is < ( 1 3 ) W 0 1 / 2 , W 0 being the forward pump wave energy. We also observe that the S mode always receives more energy.
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