Abstract Understanding the filtration and storage properties of tight reservoirs is crucial for efficient resource exploitation, particularly in unconventional formations. This study presents two low-field nuclear magnetic resonance (LF-NMR) techniques: standard cut-off and modified differential approaches combined with mercury injection capillary pressure (MICP) and X-ray diffraction (XRD) studies to evaluate porosity and pore size distribution (PSD) in such formations. The differential technique involves subtracting the dry sample signal from a 100% water-saturated one, allowing the chemically bound water compound to be eliminated and facilitating PSD analysis. Through the application of the percolation theory, we established a power–law relationship between LF-NMR transverse relaxation time (T2) and MICP pore-throat diameter, enabling the derivation of PSD and pseudo capillary pressure curves. Our methodology was validated on a sample set representing tight sandstones, conglomerates, and extrusive rocks with high clay and iron mineral content, demonstrating the superior accuracy of the modified differential method in estimating effective porosity and absolute PSD in comparison with the standard approach. While the use of the percolation theory in PSD conversion was successful for rocks with unimodal distributions, it often failed for rocks with larger voids. The study also revealed that the relationship between the LF-NMR transverse relaxation times and MICP pore sizes is both nonlinear and challenging to describe with a universal equation, especially in the presence of para- and ferro-magnetic elements in the rock matrix. Despite obstacles to the complete elimination of the influence of these minerals on the T2 distribution, employing the modified differential LF-NMR method significantly mitigated this effect and offered a precise and noninvasive way of characterizing the petrophysical properties of tight reservoir rocks. Consequently, our studies offer a significant step toward a more precise assessment of pore structures in unconventional reservoirs that could be translated into more efficient strategies for locating geothermal heat and hydrocarbon resources.
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