Residual Properties Research Articles

Test Research on Residual Mechanical Properties of Fiber-Reinforced Concrete Segments after High Temperature.

In order to research the residual mechanical properties of concrete shield tunnel segments after exposure to high temperatures, two types of concrete segments were designed: a self-compacting concrete segment and a mixed fiber (steel fiber and polypropylene fiber) self-compacting concrete segment. The mechanical properties of seven blocks of concrete segments (five segments after high-temperature exposure and two segments at room temperature) were tested to analyze the influence of different loading sizes and fibers on the development of cracks after high temperature, failure mode, crack width, deformation, and so on in the concrete segments. The results showed that the damage model of the segment after exposure to high temperature and the segment at room temperature were crushed in the pressurized zone, but the high temperature had little effect on the concrete in the pressurized area. The size of the preload at high temperatures had little effect on the remaining load capacity, and the effect on the number of cracks was mainly concentrated on the internal arc surface of the segment. After high-temperature exposure, the number of cracks on the sides and inner arc surface of the segment increased, and the development of cracks was concentrated as several major cracks at high temperatures. When fibers were incorporated, the cracks in the segment became obvious, where the cracks at the loading point became denser and the interval distance became smaller.

Investigation on the residual mechanical properties of glulam after exposure to elevated temperature

For structures that experience a fire event without collapse, determination of the residual capacity is required. The objective of this research is to determine the residual properties of glued laminated (glulam) timber after exposure to elevated temperature to enable post-fire structural evaluation. The residual compressive and shear properties of glulam were experimentally measured after exposure to a range of elevated temperatures (50, 100, 150, 200 and 250 ℃), considering also the effect of heating duration (30, 60 and 90 min) and cooling method (air cooling and water cooling). To account for transient temperature gradients, an effective temperature of the specimen was defined based on the dynamic time-temperature profile. For parallel-to-grain compressive strength, the reduction in residual strength remains within 20% of the initial strength as long as the effective temperature has not exceeded 170 ℃, but it drops severely to exceed 50% at 210 ℃. For shear strength, the permanent reduction is also within 20% after exposure to effective temperature lower than 190 ℃ and air cooling. Water-cooling leads to greater permanent reduction of mechanical properties compared with air-cooling. After first temperature exposure, additional cycles of heating-cooling (by air) do not further degrade the properties. Based on the test results, predictive formulae are proposed for the residual mechanical properties of glulam.

Using protein language models for protein interaction hot spot prediction with limited data.

Protein language models, inspired by the success of large language models in deciphering human language, have emerged as powerful tools for unraveling the intricate code of life inscribed within protein sequences. They have gained significant attention for their promising applications across various areas, including the sequence-based prediction of secondary and tertiary protein structure, the discovery of new functional protein sequences/folds, and the assessment of mutational impact on protein fitness. However, their utility in learning to predict protein residue properties based on scant datasets, such as protein-protein interaction (PPI)-hotspots whose mutations significantly impair PPIs, remained unclear. Here, we explore the feasibility of using protein language-learned representations as features for machine learning to predict PPI-hotspots using a dataset containing 414 experimentally confirmed PPI-hotspots and 504 PPI-nonhot spots. Our findings showcase the capacity of unsupervised learning with protein language models in capturing critical functional attributes of protein residues derived from the evolutionary information encoded within amino acid sequences. We show that methods relying on protein language models can compete with methods employing sequence and structure-based features to predict PPI-hotspots from the free protein structure. We observed an optimal number of features for model precision, suggesting a balance between information and overfitting. This study underscores the potential of transformer-based protein language models to extract critical knowledge from sparse datasets, exemplified here by the challenging realm of predicting PPI-hotspots. These models offer a cost-effective and time-efficient alternative to traditional experimental methods for predicting certain residue properties. However, the challenge of explaining why specific features are important for determining certain residue properties remains.

Short-term oxidation and residual compression properties of needle-punched carbon/carbon composites

Needle-punched carbon/carbon (NP C/C) composite is widely used in rocket-engine nozzles and re-entry vehicles. Recyclable technology expedited the research on repeated oxidation and residual mechaincal properties of thermal-protection materials. In this study, the critical longitudinal compression strengths before and after oxidation are derived based on the Timoshenko beam theory. Three repetitions of short-term oxidation cycles and compression experiments are investigated. The average oxidation rate of this composite was 5∼6% in 10 min and kept linear increase. In-plane and out-of-plane compressive strengths of NP C/C composite diminish quasi-linearly due to oxidation at 1000°C, with their moduli decreasing in a periodically slow-sharp pattern. After three oxidation cycles, the levels of residual in-plane modulus and strength were 55.20% and 56.89%, respectively, while the resudual out-of-plane modulus and strength were 44.65% and 47.23%, respectively. The results showed that the material exhibited the pesudo-plastical behaviour after oxidation, cracks grew along the punched conical structures formed by the punching technology. In-plane and out-of-plane modulus were more sensitive than their strengths after first oxidation cycle.

The Engine Casing Machining Holes Repairing Based on Vibration Wire Feeding

The engine casing components operate in high-temperature and high-pressure environments. Process holes are drilled when defects occur. Welding is employed in the repair of process holes as a process for permanently joining materials. The traditional welding method relies on padding, which results in poor back formation of process holes. Additionally, the shape of the process holes imposes high requirements on the size of the droplet transition. The conventional approach of adjusting a welding current makes it difficult to achieve stable droplet transition and precise formation of small holes. It poses a challenge for the robotic welding process. To deal with this problem, the influence of the high-frequency vibration GTAW process on the directional transition of molten droplets is studied. The molten droplet directional transition process is developed. The impact of vibration energy on the molten pool is reduced. Welding repair experiments for process holes are successfully conducted. When the frequency is 3 Hz, the transition of droplets changes from a continuous one-droplet transition to a discontinuous liquid bridge transition. The residual height and mechanical properties of the repaired area are tested. The experimental results indicated that the residual height after dual-side repair is ≤0.7 mm. The X-ray and fluorescent penetration tests have a 100% first-pass qualification rate. The repaired area demonstrates a hardness of 480 HV and a room-temperature tensile strength of 1069 MPa. The repair process requirements for the casing are met.

Sorghum and cowpea intercropping response to woody residue amendments in Sahelian agro-ecosystems of Burkina Faso

In West African agro-ecosystems, soils are inherently low in soil organic carbon decreasing the capacity of soils to sustain crop productivity. Woody Residues instead of being burnt or exported out of the cropping systems, can be managed to optimize soil organic carbon build-up, nutrient cycling and crop productivity. The aim of this study was to determine the effect of woody residue amendments from Piliostigma reticulatum (D.C.) Hochst associated with sorghum-cowpea intercropping on the soil residual property and crop productivity. The investigation was carried out in two experimental sites in the Sudano-Sahelian (Gampela and Kulungu) area of Burkina Faso (West Africa). The experimental design was organized into four replicates consisting of two treatments of woody residue amendments: amended (WR+) and unamended (WR-) soils. The results for both sites showed an overall significant increase in numbers (+ 35%) and biomass (+ 64%) of cowpea nodules. The root and aerial biomasses at the flowering stage of cowpeas were significantly improved in amended soils (WR+) by 26% and 44%, respectively compared to unamended soils (WR-). In addition, the WR+ treatment increase significantly cowpea and sorghum yields by 41% and 25%, respectively, as well as water use efficiency (+ 40% and + 26%, respectively) compared to the WR- treatment. Moreover, our results exhibited a strong correlation (r = 0,95) between cowpea nodular biomass and sorghum grain yields, reflecting more contribution of cowpea ecosystem services (facilitation and complementarity) for associated sorghum productivity. However, despite favorable soil conditions (soil water and organic carbon content) that occurred by WR input, it was not sufficient to improve soil residual total nitrogen and available phosphorus. The woody residue management associated with cereal-legume intercropping is a promising option to sustain crop productivity in Sahelian agro-ecosystems.

Influence of Gypsum on the Residual Properties of Fly Ash-Slag-Based Alkali-Activated Concrete

High-temperature exposures of concrete lead to serious damage in concrete structures, resulting in the significant decay of mechanical properties and spalling of concrete. Alkali-activated concretes (AAC) of blended aluminosilicate precursors and activators have been proven to have higher thermal endurance than conventional portland cement concrete. Incorporation of gypsum (GY) in alkali-activated systems has proven to positively impact the mechanical properties when adopted in controlled amounts. GY releases SO42- to the binder system, which helps in the formation of ettringites, along with Ca2+, which leads to the formation of hydrates. This causes a reduction in porosity and improves strength gain. Incorporation of GY into the fly ash-slag-based alkali-activated system further improves thermal endurance by retaining considerable residual strengths even after 800°C exposure. In the present study, the influence of GY on the residual mechanical properties of fly ash-slag-based AAC is investigated to explore the thermal endurance of the ternary mix at elevated temperatures. The mechanical properties of fly ash (FA), Ground Granulated Blast Furnace Slag (GGBS), and gypsum (GY) ternary blended AAC subjected to elevated temperatures are studied in comparison with conventional portland cement concrete (control mix). AAC design mixes with varying proportions of GY as a replacement to FA-GGBS precursor are tested for mechanical properties to obtain the optimum mix. The residual mechanical properties of the FA-GGBS-GY optimum ternary AAC mix are obtained after exposure to elevated temperatures up to 800°C. The morphology and microstructural characteristics of AAC are studied by Scanning Electron Microscopy (SEM) and Energy-Dispersive X-ray Spectroscopy (EDS) analyses to investigate the influence of gypsum on the thermal endurance of concrete when exposed to elevated temperatures. Improved thermal endurance is observed for AAC when FA-GGBS precursors are replaced with 5% of GY as compared to the thermal endurance of conventional portland cement concrete (PCC) of the same compressive strength. Doi: 10.28991/CEJ-2024-010-03-017 Full Text: PDF

How to successfully improve the biodiversity of city grasslands?

Urban grasslands (UG) are among the most common types of urban green areas. They are usually species poor, and spontaneous plant migration, which can increase biodiversity, is limited. To improve the range of ecosystem services provided by UG, various seed mixtures are applied during the establishment and restoration of UG. These mixtures vary in content, quality, and cost. High-quality seed mixtures are expensive and are usually only available in small amounts. Meanwhile, alternative methods of seed introduction (e.g., fresh hay application, seeds harvested by brush) have not been well studied in UG restoration, and inexpensive commercial mixtures could have low quality and lead to poor restoration outcomes. Here, we tested the effectiveness of different seed sources to create high-quality UG at two study sites. Based on the results, all seed addition methods increased the species richness of restored grasslands. The outcome of seed addition was satisfactory regardless of differences in residual vegetation species composition and soil properties between the sites. The species richness on plots that received a commercial mixture of flower meadow plants dedicated to pollinators decreased after overwintering. The alternative seed sources (fresh hay and seed incidentally collected during mowing) yielded grassland quality that was comparable to that on plots that received high-quality mixtures with known seed origin (a seminatural meadow mixture and a mixture with the addition of grasses).

The strengthening role of post-welded cryogenic treatment on the performance and microstructure of 304 austenitic stainless steel weldments

The metallurgical changes and micro defects after welding can influence the mechanical property, corrosion resistance and dimensional stability of the stainless steel wielding joints. It is necessary to explore an effective post-welded method to improve the service performance for stainless steel welding joints. Furthermore, the essential mechanism between microstructure changes and macro-property variation during this process needs deep reveal. Therefore, this paper aims at investigating the effects of different post-weld treatments including naturally aging, artificial aging and cryogenic treatment on the residual stress and mechanical properties of 304 stainless steel weldments. The microstructure evolution was also studied to reveal and establish the microstructure-performance relationship. The results showed that the distribution of residual stress was most uniform with lowest magnitude (decreased by up to 49%) after cryogenic treatment. At room temperature, weldments subjected to the three post treatments showed similar mechanical properties. At cryogenic temperature, cryogenic treatment exhibited an outstanding role on maintaining the mechanical properties of weldments. By contrast, the mechanical properties were obviously reduced by artificial aging. The transformation of δ-ferrite and the carbide precipitation in grain boundaries are the main reasons for the decrease of mechanical properties after artificially aging. Welding process was able to cause the transfer of the alloying elements and decrease the stability of austenite. Consequently, martensitic transformation can be induced during cryogenic treatment. The new formed martensite resulted in the refined microstructure and high mechanical properties of weldments, and also the release of residual stress after welding.

Behavior of high strength reinforcing steel rebars after high temperature exposure: Tensile properties and bond behavior using pull-out and end beam tests

High strength reinforcing steel (HSRS) is increasingly being adopted in the construction industry in North America due to its high load-carrying capacity, yet their behavior relative to normal grade rebars under external hazard events such as fire exposure still need further research. In current work, the first goal is to investigate the residual tensile properties of different types of HSRS and normal rebars including ASTM A706, A615, A1035CS, and A1035CM with grades of 420, 550, and 690 before and after high temperatures (350 °C and 700 °C), that simulates residual capacity after different levels of fire exposure. The second goal is to explore the residual bond strength of these rebars using both pull-out and end-beam tests after heat exposure, facilitating a comparison among test methods and evaluating their reliability under fire hazard conditions. The tensile test results indicated insignificant changes in the mechanical properties of all rebars after 350 ℃ heat exposure. However, there was a significant reduction of more than 30% in both yield and ultimate strength after 700 ℃ heat exposure for high grades like grade 690 of ASTM A1035. Among all rebar types and grades, only grade 420 of ASTM A706 retained most of its ductility and strength, making it the most reliable rebar among those tested against fire hazards. In the bond tests, splitting failure was observed at both ambient and after 500 °C heat exposure. Heat exposure resulted in a 73% reduction in bond strength across all rebars for the pull-out tests, with no significant variations between rebar types. On the other hand, end-beam tests indicated a 12.6% average reduction in bond strength with a 9% improvement in bond behavior for ASTM A706 grade 420. However, for ASTM A1035 CS grade 690 and ASTM A706 grade 550 there were slight reductions in bond behavior, with decreases of 9% and 14%, respectively. Compared to the end-beam test, the pull-out test results in a significant reduction in bond strength due to its high dependency on excessive compressive strength reduction resulting in brittle splitting failure. Based on comparison with empirical models, it is recommended not to use models derived from pull-out tests to estimate bond strength, as they tend to overestimate it. Instead, empirical models based on end-beam tests are recommended, since they show consistency with test results. It should be noted that although the bond strength based on splitting failure is primarily dependent on concrete properties, changes were observed in the bond behavior among different rebars, which can be attributed to changes in friction at the interface due to morphological changes in the rebar surface after heat exposure, as well as potential variations in thermal expansion properties, which need further research.

Residual Stresses and the Microstructure of Modeled Laser-Hardened Railway Axle Seats under Fatigue

Railway wheels are usually attached to axles by press-fitting; therefore, the mechanical processes taking place during operation can result in failure, with fatal consequences for the axle seats. This manuscript describes the effect of laser hardening on the residual stress state, microstructural parameters (lattice defects—dislocations, crystallites, microstrains, etc.), and mechanical properties of laser-hardened EA1N steel railway axles under fatigue life conditions. Differences were found between ground, single-track, and multi-track hardened surfaces. Tensile residual stresses, low dislocation densities and hardnesses, and different microstructures (tempered cubic martensite) were found at the overlapped tracks and at the boundary of the heat-affected zone and bulk surface compared with the hardened zone. As a result, the surface treatment of axle seats by laser hardening improved the fatigue failure resistance compared with untreated seats. Optimal properties of the integrity of the axle seat surface were achieved, including fatigue resistance, which seems to be positively influenced mainly by sufficient hardness and the appropriate microstructure. The influence of the other investigated parameters was not evident, and was reduced by the presence of fretting corrosion and press-fitting.

Physico-chemical properties of macadamia nut shell post-gasification residues and potential agricultural application

In–depth information about the characteristics and potential use of post-gasification residues is the key to unlock the sustainability potential of biomass gasification. This study aimed to explicate the physico-chemical properties of residues after the gasification of macadamia nut shell using a commercial gasifier. The results revealed an important amount of carbon content remained in the residues, marking the low conversion efficiency of the process. The obtained residues were deemed unsuitable for use as adsorbents due to low surface areas with non-porous structures. However, the surface of the residues contained multiple carboxyl and hydroxyl functional groups. Also, a remarkable amount of K (up to 86 wt% of the char’s total inorganic elements) was observed to be evenly distributed on the char surface. The results solidified the possibility of utilizing the residues as bio-fertilizers, and provided essential data for the development of sustainable energy production processes using macadamia nut shell for gasification.

Investigation of the Mechanical Behaviors and Damage Mechanism of C/C Composites Impacted by High-Velocity Jets.

Carbon/Carbon (C/C) composites exhibit excellent mechanical properties at high temperatures, making them widely used in aerospace, such as the leading edges of spaceplane wings and the nose cones of hypersonic aircraft. However, damage caused by rain erosion to C/C composites affects their mechanical properties and poses significant challenges during operational service periods. A jet impingement test platform was employed to conduct single and multiple water-jet erosion tests on three-dimensional orthogonal C/C composite materials and to investigate the residual mechanical properties of the specimens after jet impact. The damage was characterized using optical microscopy, scanning electron microscopy, and X-ray computed tomography. The results showed that the damage types of the C/C composite materials under water-jet impingement included fiber bundle fracturing, delamination, and debonding. The extent of erosion damage was positively correlated with the jet velocity and diameter. The changes in the multi-jet damage indicated a cumulative expansion process, and z-directional fiber bundles exhibited superior resistance to jet impact damage propagation. The results of the three-point bending tests showed that the greater the initial impact damage, the lower the residual mechanical properties of the materials, and the residual strength of the specimen suddenly decreased when damage occurred at the back of the specimen.

Evaluation of plastic properties and equi-biaxial residual stress via indentation and ANN

This study presents a method for evaluating plastic properties and equi-biaxial residual stress (RS) simultaneously using the images of generated imprints in indentation tests and an artificial neural network (ANN). The ANN model is trained with data from finite element analysis (FEA) for establishing the relationship between material properties and the radial (ur) and vertical (uz) displacements resulting from indentation tests. To deal with the inherent noise in experimental data, an artificial random noise was added to the FEA data used for training the ANN model. By inputting parameters with artificial errors into the ANN model, the robustness of predicted values against potential testing errors was examined. Also, the accuracy of the predicted residual stresses and material properties from ANN are validated using tensile tests and indentation tests on the stress-induced specimens.

Impact of SCMs and fibres in ECC on the fire resistance of hot-jointed SCC/ECC composites

The influence of various supplementary cementitious materials (SCMs) and fibres on the fire resistance of composite systems that combine engineered cementitious composites (ECCs) in tension with self-compacting concrete (SCC) in compression was examined. The study was designed to determine the ideal ECC formulation for optimising mechanical properties and bonding performance at ambient and elevated temperatures. The SCC and ECC were hot-joined without vibration or surface preparation, using a fresh-to-fresh casting method. Modifications to the chemical composition of the ECCs included the addition of class F fly ash (FAF), class C fly ash (FAC) or slag, as well as polyvinyl alcohol (PVA) fibres or steel fibres. The samples were exposed to temperatures of 200°C, 400°C, 600°C and 800°C, followed by comprehensive testing to evaluate their flexural strength, tensile strength and interfacial properties. The results indicate that the incorporation of an ECC layer within the SCC system significantly improved mechanical strength and thermal stability, both at ambient temperatures and under high-temperature conditions. Notably, the addition of FAF (rather than FAC or slag) in the ECC layer offered superior thermal stability and ensured the retention of desirable residual mechanical properties. Moreover, steel fibre reinforcement greatly improved the SCC/ECC bonding, outperforming PVA reinforcement at elevated temperatures.

Probing the interaction behavior of Nano-Resveratrol with α-lactalbumin in the presence of β-lactoglobulin and β-casein: spectroscopy and molecular simulation studies

The main purpose of this research was to evaluate the role of α-lactalbumin (α-LA), β-lactoglobulin (β-LG), and β-Caseins (β-CN) in the binding interaction between Nano Resveratrol (Nano Res), as binary and ternary systems. This investigation was fulfilled through the application of multi-spectroscopic, transmission electron microscopy (TEM), field emission scanning electron microscope (FE-SEM), conductometry, isothermal titration calorimetry (ITC), and molecular dynamics (MD) simulation techniques. Fluorescence spectroscopy observations illustrated the effectiveness of Nano Res throughout the quenching of α-LA, (α-LA-β-LG), and (α-LA-β-CN) complexes, confirming the occurrence of interaction through the combination of static and dynamic mechanisms. An enhancement in the temperature of all three complexes caused a decrease in their Ksv and Kb values, which indicates the static and dynamic behavior of their interactions. The obtained thermodynamic parameters proved the dominance of electrostatic interaction as the binding force of both binary and ternary systems. The observed properties of Tyr or Trp residues in proteins through the data of synchronous spectroscopy at Δλ = 15 and 60 nm, respectively, demonstrated the closer positioning of (α-LA-β-CN) complex to the proximity of Trp residues when compared to the two other cases. According to the resonance light scattering (RLS) measurements, the detection of a much greater RLS intensity in (α-LA-β-CN) Nano Res complex suggested the production of a larger complex. Furthermore, the conductometry outcomes displayed an increase in molar conductivity and therefore approved the occurrence of interaction between Nano Res and proteins in both binary and ternary systems. The spherical shape of Nano Res was confirmed through the results of FE-SEM and TEM analyses. The conformational changes of proteins throughout the binding of Nano Res was evaluated by circular dichroism (CD) technique, while molecular docking and MD simulations affirmed the binding of Nano Res to α-LA, (α-LA-β-LG), and (α-LA-β-CN) complexes as binary and ternary systems. These In Silico study data confirm the results of in vitro assessments. The occurrence of changes in the secondary structure of β-galactosidase was implied through the increased enzyme catalytic activity induced by the interaction of different lactose concentrations. Communicated by Ramaswamy H. Sarma

Mechanical Behavior of Polyurethane Insulation of CRT Leads in Cardiac Implantable Electronic Devices: A Comparative Analysis of In Vivo Exposure and Residual Properties.

Left ventricle leads are designed for the purpose of long-term pacing in the left ventricle. This study investigated the leads that use polyurethane as an outer insulator and SI-polyimide as an inner insulator. Polyurethane is commonly used for the outer insulation of cardiac leads due to its flexibility and biocompatibility. SI-polyimide (SI-PI) is a high-performance material known for its electrical insulation properties and is used for the inner insulation to maintain the integrity of the electrical pathways within the lead. Ten leads were received from the Wright State University Anatomical Gift Program. The duration of in vivo implantation varied for each lead, from less than a month to 108 months, with an average in vivo duration of 41 ± 31 months. We used the Test Resources Q series system for conducting our tests, as well as samples prepared to ensure compliance with the ASTM Standard D 1708-02a and the ASTM Standard D 412-06a. During the test, the load was applied to the intact lead. Before conducting individual tests, each lead was carefully inspected for surface defects. After conducting the tests, the load to failure, percentage of elongation, percentage of elongation at 5 N, ultimate tensile strength, and modulus of elasticity were calculated. There was no significant difference in load to failure, the percentage of elongation to failure, ultimate tensile strength, and modulus of elasticity (p-value = 0.82, p-value = 0.62, p-value = 0.82, and p-value = 0.12), respectively, when compared to in vivo exposure time. On the other hand, the percentage of elongation at 5 N force showed a significant difference (p-value = 0.0066) after 60 months in an in vivo environment. As the duration of in vivo exposure increased, the load to failure, percentage of elongation, ultimate tensile strength, and modulus of elasticity decreased insignificantly. The residual properties of these left ventricle leads remained relatively stable after 108 months of in vivo exposure duration, with no statistically significant degradation or changes in performance.

Residue-Free and Recyclable Starch-Based Flocculants for Dye Wastewater Flocculation.

Flocculants are crucial agents in wastewater treatment because they can remove oppositely charged impurities effectively and swiftly. However, flocculation also inevitably causes secondary contamination due to the residual properties, nonreusability, and nondegradability of traditional flocculant molecules. Herein, an ecofriendly starch-based flocculant, i.e., 2,4-bis(dimethylamino)-[1,3,5]-triazine-6-starch, was synthesized via a preactivation-etherification strategy. The large molecular weight property of the flocculant produced by this method enhances the intermolecular hydrophobic association, achieving complete phase separation of all flocculant molecules from water and residue-free flocculation for the first time. Importantly, a large molecular weight tertiary amine starch-based flocculant (LMTS) exhibits a remarkable flocculation capacity of over 1800 mg·g-1 for dye wastewater, which is significantly higher than that of traditional polyacrylamide and polyaluminum chloride flocculants. Furthermore, the LMTS flocculant could be recycled by pH adjustment, and its structural stability ensured sustained reusability. This high-performance residue-free biomass-based flocculant offers a green advance for wastewater treatment.

Valorization of Coffee Residue from Convenience Store and Retail Mass-Selling Store for Producing Highly Porous Carbon Materials and Taiwan Perspectives

In Taiwan, a considerable amount of coffee residue is produced from commercial activities without valuable utilization. To evaluate high-value valorization in the production of highly porous carbon materials, this study investigated the thermochemical properties of coffee residues and further pyrolysis for producing highly porous biochar products at an elevated temperature (i.e., 850 °C) and a moderate residence time of 30 min. Our findings indicate that this biomass has a relatively high calorific value (about 27 MJ/kg, dry basis) due to its low ash and high lignocellulose content. It can be also concluded that the non-activated biochar products are highly porous carbon materials with excellent pore properties (i.e., a BET surface area of about 800 m2/g and a total pore volume of 0.4 cm3/g), which are slightly lower than those of commercial activated carbon products. Based on the above-mentioned results and the high-value circular bio-economy promoted by regulatory policy in Taiwan, the prospects for the possible valorization of coffee residue from commercial shops are addressed here, focusing both on the reuse of plant-based residue (or agricultural waste) as a high-value bioresource in the production of biomass-based fuels and on carbon materials. The former includes solid recovered fuel (SRF) and biomass-to-biogas power. By contrast, the latter aims at the production of plant-based carbon as natural, edible colorants in accordance with the regulation of food safety and sanitation in Taiwan.

Low-Velocity Impact and Post-Impact Residual Flexural Properties of Kevlar/EP Three-Dimensional Angle-Interlock Composites.

In this study, five three-dimensional angle-interlock fabrics with different warp and weft densities were fabricated using 1000D Kevlar filaments. The Kevlar/EP composites were prepared by vacuum-assisted molding techniques. The low-velocity impact property of the composite was tested, focusing on the effects of the warp and weft densities, impact energy, impactor shape, and impactor diameter. The damage area, dent depth, and crack lengths in the warp and weft direction were used to evaluate the impact performance, and the specimens were compared with plain-weave composites with similar areal densities. The dominant failure mode of the conical impactor was fiber fracture, while the dominant failure mode of the hemispherical impactor was fiber-resin debonding. The cylindrical impactor showed only minor resin fragmentation. The residual flexural strength of the composite after impact was tested to provide insights into its mechanical properties. The study findings will provide a theoretical basis for the optimization of the design of impact-resistant structures using such materials and facilitate their engineering applications.