Programmable Metamaterials Research Articles

Crystalline Gibbs Monolayers of DNA-Capped Nanoparticles at the Air–Liquid Interface

Using grazing-incidence small-angle X-ray scattering in a special configuration (parallel SAXS, or parSAXS), we mapped the crystallization of DNA-capped nanoparticles across a sessile droplet, revealing the formation of crystalline Gibbs monolayers of DNA-capped nanoparticles at the air-liquid interface. We showed that the spatial crystallization can be regulated by adjusting both ionic strength and DNA sequence length and that a modified form of the Daoud-Cotton model could describe and predict the resulting changes in interparticle spacing. Gibbs monolayers at the air-liquid interface provide an ideal platform for the formation and study of equilibrium nanostructures and may afford exciting routes toward the design of programmable 2D plasmonic materials and metamaterials.

The Zeuner diagram

We introduce two essential building blocks with binary stiffness for mechanical digital machines. The large scale fully compliant mechanisms have rectilinear and rotational kinematics and use a new V-shaped negative stiffness structure to create two extreme states of stiffness by static balancing. The use of a mechanical bistable switch allows us to toggle between near-zero-stiffness and high-stiffness states, effectively turning off and on stiffness. A stiffness reduction of 98.8 % and 99.9 % is achieved for linear and rotary motion over a range of 13.3 % (20 mm) and 0.4 rad (23°) respectively. Stiffness states can be reversibly changed by toggling the mechanical switch, or irreversibly by actuating the main stage.These binary stiffness mechanisms could set the stage for a new type of mechanical logic, adaptive and programmable metamaterials and other types of digital mechanical devices. Practical mechanical digital machines and materials require miniaturized and easily micro-manufactured components. We have therefore carefully considered scalability by integrating all required structures into a planar and monolithic architecture. This allows miniaturization and fabrication with conventional surface-micro-machining and additive manufacturing such as photolithography, two-photon lithography and fused deposition modeling.