The possibility of process gas obtaining for the synthesis of carbon nanomaterial from the products of charcoal gasification with air containing water vapor or natural gas additives was considered. To compensate for the heat costs for the decomposition of hydrogen-containing additives and maintain the temperature level of the fuel gasification process at a constant level, the temperature of preheating the air mixture with additives, or the supply of oxygen to the mixture, was calculated. The H2/CO ratio in the obtained gas was calculated, depending on the content of various additives in the air. The ratio of H2/CO in the generator gas depends both on the total content of oxidants O2 + H2O in the air and on their ratio. If the ratio O2/H2O = 1.43, then regardless of their total content in the air, the temperature of the carbon gasification process remains at the same level as in the case of using only air without additives. Methane has been found to be a more efficient additive than steam, as it requires significantly less additional heat to maintain the process temperature at the desired level. In addition, methane decomposition produces twice as much hydrogen as an equal volume of steam. Carbon nanomaterial was obtained from the products of charcoal air gasification on the created laboratory instalation. Freshly reduced iron acted as a catalyst. Multi-walled carbon nanotubes with a diameter of 80–250 nm were synthesized. Bibl. 14, Fig. 5, Tab. 1.
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