Stability Problem Research Articles

Green Synthesis of Boric Acid Modified Bismuth Based Non-Toxic Perovskite Quantum Dots for Highly Sensitive Detection of Oxytetracycline.

In recent years, perovskite quantum dots (PQDs) have successfully attracted widespread attention due to their excellent optical properties. However, the instability and toxicity problems of perovskite quantum dots are the main obstacles limiting their applications. In this work, bismuth-based perovskite quantum dots were synthesized by a ligand-assisted reprecipitation method, based on which a novel boric acid-functionalized bismuth-based non-toxic perovskite quantum dots fluorescent sensor (Cs3Bi2Br9-APBA) that can be stabilized in the ethanol phase was prepared by a boron affinity technique. Based on the covalent binding interaction of Cs3Bi2Br9-APBA with oxytetracycline (OTC), a highly selective and sensitive method for the detection of OTC was developed, which effectively solved the problems of poor stability and toxicity in the application of perovskite quantum dots. Under the optimal conditions, the fluorescence intensity of the synthesized Cs3Bi2Br9-APBA was linear with the concentration range of 0.1 ∼ 18 µM OTC, and the detection limit could reach 0.0802 µM. The fluorescence detection mechanism was explored and analyzed by spectral overlap analysis, suppression efficiency study of observed and corrected fluorescence, and fluorescence lifetime decay curve fitting, the mechanism of OTC detection by Cs3Bi2Br9-APBA was identified as the inner filter effect (IFE). In addition, the sensor successfully realized the quantitative detection of trace OTC in the environment, and our study provides a new idea for the preparation of green perovskite materials with high stability and selectivity.

Evaluation of Cobalt, Nickel, and Palladium Complexes as Catalysts for the Hydrogenation and Improvement of Oxidative Stability of Biodiesel

Developing effective catalysts that can selectively hydrogenate C=C bonds in biodiesel samples is vital as it tackles the major problem of oxidative stability, which greatly limits the utilization of biodiesel as an alternative fuel. In this work, Co, Ni, and Pd catalysts stabilized with the bidentate nitrogen ligands N-(3-(triethoxysilyl)propyl)pyridin-2-ylmethylimine and N-(3-(triethoxysilyl)propyl)picolinamide were synthesized, characterized, and used as pre-catalysts in the transfer hydrogenation of C=C bonds in fatty acid methyl esters. The active catalysts from the Co, Ni, and Pd complexes sequentially hydrogenate the C18:2 chains to C18:1, which is further converted to C18:0 in the FAMEs of both methyl linoleate and jatropha biodiesel. The hydrogenation process was kinetically controlled, and after 3 h it yielded a biodiesel sample that contained 25.83% C16:0, 12.52% C18:2, 41.54% C18:1, 14.47% C18:0 and 3.0% C18:2 isomers. The un-hydrogenated jatropha diesel, hydrogenated jatropha diesel, and a B20 blend of jatropha were tested for susceptibility to oxidation reactions using the Rancimat method and FTIR spectroscopy, and the partial hydrogenation had improved the induction period by 3 h.

Prescribed-time practical stabilization via majorant systems

This paper provides a design methodology of simple control laws to solve the prescribed-time practical stabilization problem for a class of pseudo-linear systems with a single input, also unstable, subject to perturbations, nonlinear and discontinuous, but bounded. The perturbations on the dynamic matrix, such as a ratio of multi-affine polynomials of nonlinear functions or parameters, are not triangular, and a perturbation on the input of multiplicative type is also considered. The stated methodology is based on the majorant systems approach with optimized quadratic Lyapunov functions. The main advantages of the proposed control laws consist in the simplicity of their design and implementation and the reliable performance. Indeed, these control laws depend on a single design parameter, have constant gains, and guarantee the practical convergence with a prescribed relative error, also after a prescribed time. Some examples, also an engineering one, are provided to validate the obtained theoretical results and show the effectiveness and efficiency of the proposed control laws.

Application of improved fish school algorithm in variable frequency speed control system

In order to solve the problems of long adjustment time and poor stability of the commonly used speed current variable frequency negative feedback speed control system in engineering, the author proposes an improved fish school algorithm application method in variable frequency speed control systems. A fish swarm algorithm optimized based on the arena method is applied to a variable frequency speed control system, and the optimization algorithm is applied to the speed control system to screen the PI parameters that meet the requirements of the speed control system. The simulation results show that compared with manual parameter tuning, the controller parameters optimized by the improved fish school algorithm have better control performance. In the absence of overshoot starting, the starting time was shortened by 0.21s, and the system response speed was improved. When a sudden load of 6 N m is applied, the speed drop is reduced by 3 r · min−1, and the recovery time is shortened by 0.15 s, resulting in stronger anti-interference performance of the system. Conclusion: The new algorithm shortens the control time and improves the robustness of the system.

GAN-based image generation

Generative Adversarial Networks (GANs), as a deep learning model, have made significant progress in the field of image generation and style migration. This study aims to methodically investigate GAN-based image generation methods. First, this paper outlines the basic principles of GAN and its application in image generation, focusing on analyzing the structure and performance of representative models such as DCGAN, ProGAN and StyleGAN. This paper summarizes the improvement methods such as WGAN and LSGAN, and evaluates their efficacy in improving the stability of the model and the quality of the generated images in view of the problems of pattern collapse and instability faced by GANs in the training process. Finally, this paper discusses the limitations of current techniques and possible future directions, and suggests research prospects in the field of multimodal fusion and 3D image generation. The research in this paper provides a theoretical framework and useful suggestions for enhancing the application of GAN methods in image generation.

Nonplanar Nanographene: A Hydrocarbon Hole-Transporting Material That Competes with Triarylamines.

Hole-transporting materials (HTMs) are essential for optoelectronic devices, such as organic light-emitting diodes (OLEDs), dye-sensitized solar cells, and perovskite solar cells. Triarylamines have been employed as HTMs since they were introduced in 1987. However, heteroatoms or side chains embedded in the core skeleton of triarylamines can cause thermal and chemical stability problems. Herein, we report that hexabenzo[a,c,fg,j,l,op]tetracene (HBT), a small nonplanar nanographene, functions as a hydrocarbon HTM with hole transport properties that match those of triarylamine-based HTMs. X-ray structural analysis and theoretical calculations revealed effective multidirectional orbital interactions and transfer integrals for HBT. In-depth experimental and theoretical analyses revealed that the nonplanarity-inducing annulative π-extension can achieve not only a stable amorphous state in bulk films, but also a higher increase in the highest occupied molecular orbital level than conventional linear or cyclic π-extension. Furthermore, an in-house manufactured HBT-based OLED exhibited excellent performance, featuring superior curves for current density-voltage, external quantum efficiency-luminance, and lifetime compared to those of representative triarylamine-based OLEDs. A notable improvement in device lifetime was observed for the HBT-based OLED, highlighting the advantages of the hydrocarbon HTM. This study demonstrates the immense potential of small nonplanar nanographenes for optoelectronic device applications.

Nonplanar Nanographene: A Hydrocarbon Hole‐Transporting Material That Competes with Triarylamines

AbstractHole‐transporting materials (HTMs) are essential for optoelectronic devices, such as organic light‐emitting diodes (OLEDs), dye‐sensitized solar cells, and perovskite solar cells. Triarylamines have been employed as HTMs since they were introduced in 1987. However, heteroatoms or side chains embedded in the core skeleton of triarylamines can cause thermal and chemical stability problems. Herein, we report that hexabenzo[a,c,fg,j,l,op]tetracene (HBT), a small nonplanar nanographene, functions as a hydrocarbon HTM with hole transport properties that match those of triarylamine‐based HTMs. X‐ray structural analysis and theoretical calculations revealed effective multidirectional orbital interactions and transfer integrals for HBT. In‐depth experimental and theoretical analyses revealed that the nonplanarity‐inducing annulative π‐extension can achieve not only a stable amorphous state in bulk films, but also a higher increase in the highest occupied molecular orbital level than conventional linear or cyclic π‐extension. Furthermore, an in‐house manufactured HBT‐based OLED exhibited excellent performance, featuring superior curves for current density–voltage, external quantum efficiency–luminance, and lifetime compared to those of representative triarylamine‐based OLEDs. A notable improvement in device lifetime was observed for the HBT‐based OLED, highlighting the advantages of the hydrocarbon HTM. This study demonstrates the immense potential of small nonplanar nanographenes for optoelectronic device applications.

Multi-constrained predictive optimal control for spacecraft attitude stabilization and tracking with performance guarantees

This paper investigates a novel predictive control approach for spacecraft attitude stabilization and tracking problems with consideration of performance constraints, angular velocity limitation and control saturation. First, the prescribed performance control (PPC) structure and barrier Lyapunov function (BLF) are utilized to design the cost function of optimal control problem. Subsequently, a multi-constrained predictive optimal controller for spacecraft attitude stabilization and tracking with performance guarantees is devised via exploiting an explicit receding horizon optimization control strategy under actuator saturation. Compared with the existing methods, the major merit of the proposed one lies in the semi-analytic solving scheme of optimal control problems with high computing efficiency and simultaneous handling of multiple constraints without increasing computational burden. Finally, two illustrative examples are employed to validate the effectiveness of the proposed control method.

DUAL LOOP VOLTAGE DROOP REGULATED CONTROLLER FOR DC MICROGRID USING HYBRID PSO AND GGO ALGORITHMS

Abstract DC microgrids are effectively employed in distribution network integration with renewable energy sources. The droop control technique is commonly utilized for DC microgrid regulation during load sharing. It minimizes the potential instability caused by disturbances such as input voltage changes, uncertainty parameters, and constant power load (CPL). Nevertheless, conventional droop control is inadequate in achieving precise current and satisfactory voltage regulation distribution for load sharing. The proposed approach comprises two separate loops for the DC bus voltage regulation and load current distribution, delivering a CVL and CPL to overcome the single optimization voltage controller technique. The primary loop uses the PSO algorithm to precisely manage the current load sharing among two parallel converters. Due to this the instability problems arising from disturbances, and it mitigated by the proposed topology. The multiobjective optimization technique provides notable resilience, rapid dynamic response, and robust stability over considerable variations in load. The secondary loop utilises the GGO algorithm to optimize the parameter to minimize the DC bus voltage regulation, voltage management, reasonable distribution of load power, and suitable reliability. The performance of the voltage regulation enhance & settling time for output voltage has been mitigated more than 31ms times through the proposed controller compared to conventional controller under the variation of CVL, CPL, and input voltage disturbance demonstrated in simulation results.

The impact of securities financing arrangements on the allocation of capital

Securities financing arrangements (SFA) allow investors to use short-term credit to leverage their investments in securities. Largely ignored by economists prior to the financial crisis of 2007–2008, research since that time has implicated SFA in creating financial instability. The creditors in the agreements have been compared to bank depositors who can create a liquidity crisis by withdrawing their funds. While not denying the instability problem, the focus of this paper is the effect of SFA on the allocation of capital in the real economy. I provide institutional context by tracing the evolution of SFA over the past four decades and relate the evolution to legislative changes initiated by the financial sector. Next, I outline a model to elucidate the essential features of a system of securitized finance that relies on SFA. With the aid of the model, I analyze the incentives inherent in the system and show how they can lead to a distortion in the allocation of capital. I conclude that SFA have served the interests of the financial community, but that they have not always delivered improvements to the wider economy.

Novel synthesis organic–inorganic heterojunctions of protonated g-C3N4/Fe3O4/AgBr/AgCl/AgI quinary magnetic photocatalyst with enhanced visible-light photocatalytic degradation of methylene blue in water

A novel magnetic quinary nanocomposite, protonated g-C3N4/Fe3O4/AgBr/AgCl/AgI, was synthesized using a wet chemical method. The multi-heterojunction photocatalyst with multi-carrier source and multi-channel carrier transport is constructed to enhance the photocatalytic degradation performance of pure g-C3N4. The design of the quinary nanocomposite is also an effective approach to solve the chemical stability problem of silver halides. The photocatalytic degradation efficiency under visible light irradiation was analyzed for methylene blue (MB) as the target organic pollutant. The quinary nanocomposite with 10 % g-C3N4 displayed high photocatalytic performance, with 83 % of MB degraded under 6 h LED white light irradiation. The effective quinary nanocomposite has good magnetic properties and can be magnetically separated to prevent secondary pollution of the photocatalyst in water. Parameters such as initial concentration of pollutant, initial solution pH, and light source were studied. Zeta potential results showed that the quinary nanocomposite could disperse homogenously to decrease aggregation in the solution. The photocatalytic degradation mechanism was investigated, and the mineralization results were analyzed based on liquid chromatography-mass spectroscopy (LC-MS) and total organic carbon (TOC). It was found that the hydroxyl and superoxide radicals were major reactive species by scavenging experiments. Additionally, protonated g-C3N4/Fe3O4/AgBr/AgCl/AgI nanocomposite showed excellent reusability after magnetic separation and regeneration, thus suggesting it to be a promising photocatalyst for treating wastewater containing organic contaminants.

Impact of chemical osmosis, diffusion osmosis and ionic diffusion on drilling mud salinity design

ABSTRACT Wellbore stability problems, especially in reactive shale formations, have gained much attention due to their high cost and technical complications. In this work, the blind use of only chemical osmosis to balance reactive shales, while drilling has been challenged through the use of linear swelling technique and water and ions gravimetric test. Moreover, the compatibility of various aqueous solutions with field shale samples was analysed and a proper mud salinity design method was proposed. Using Na+, K+ and Ca+2 and 100 shale samples and cuttings from a drilling site, a mud salinity (ion’s type and concentration) selection method was proposed. A field case was presented and it was shown that KCl solutions were appropriate to drill shale formations up to 9,717 ft. while NaCl solution was suitable to drill a deeper formation that spans from 9,817 to 10,381 ft. Moreover, CaCl2 solutions were not selected to handle these shales due to their high reactivity and excessive water and ions exchange. Besides chemical osmosis, results showed that water transport may occur due to diffusion osmosis and ionic diffusion. Also, the transport of ions by ionic diffusion was found to be a major destabilizing factor.

COF-derived porous nitrogen-doped carbon for removal of emerging organic contaminants and efficient uranium extraction from seawater

The development of adsorbents for efficient and highly selective seawater extraction of uranium was instrumental in fostering sustainable progress in energy and addressing the prevailing energy crisis. However, the complex background composition of the marine environment, including radionuclides, organic pollutants, and a large number of co-existing heavy metal ions, were non-negligible obstacles to the extraction of uranium from seawater. The present investigation successfully employed a self-templated approach to synthesize porous nitrogen-doped carbon (PNC) derived from COF, which exhibited tremendous potential as an adsorbent for pollutant removal in environmental treatment. LZU1@PNC not only retained the structural features of the original COF-LZU1, but also overcame the acid-base instability problem commonly found in COFs. Subsequently, the removal process of two typical water pollutants on the material was investigated using 2,4-DCP and [UO2(CO3)3]4-. The results demonstrated that LZU1@PNC exhibited superior removal performance for the target pollutants compared to COF-LZU1, owing to its larger specific surface area and abundant defect structure. After six desorption-regeneration cycles, LZU1@PNC still maintained a high removal rate of the target contaminants, demonstrating the stability of this material and its excellent recyclability. In addition, based on various characterization techniques, the removal mechanism of 2,4-DCP was presumed to be mainly electrostatic attraction, hydrogen bonding, and π-π stacking interactions. Conversely, the elimination process of [UO2(CO3)3]4- predominantly relied on surface complexation phenomena. The present investigation provided new perspectives and stimulated a broader study of other COF-derived carbon materials and their modifications as adsorbents for uranium extraction from seawater and other applications.

Energy-based methods and nanocarrier-based approaches for melasma treatment

Melasma is a chronic disease caused by excessive melanin production in the skin, affecting the quality of life, especially in women. As a kind of skin hyperpigmentation, it can be caused by sun exposure, genetics, hormones, drugs, or inflammation. Melasma treatment can be effective when the product penetrates well into the skin. As an essential skin barrier, the stratum corneum displays a significant role in topical and transdermal drug delivery. In this regard, numerous strategies have been developed to increase the skin permeability and efficiency of drugs. This review explores energy-based methods and nanocarrier-based approaches for melasma treatment, focusing on enhancing drug delivery to the viable epidermis and overcoming SC. Physical methods have some advantages like increasing the skin penetration and also some drawbacks, including frequent visits, high costs, and the need for advanced equipment and trained operators. Further, these methods are often combined with high energy and special technics. As an emerging physical-based method that could be used to treat patients with multiple medications, microneedle patch is drawing interest due to its ease of use, ability to pinpoint drug delivery, and fewer side effects. In addition, they can penetrate drug molecules into deeper layers of skin and provide more sustainable results compared to conventional methods. Nanocarrier-based systems like transferosome and ethosome (deformable liposomes) are also effective options for skin penetration and treating melasma and skin hyperpigmentation. Despite several benefits, such as high entrapment efficiency, good permeation, and increased bioavailability of drugs through the skin, their stability problems and limitations toward nanoparticle production on an industrial scale are the most significant drawbacks of this method. In the current review, we looked at the articles published between 2010 and August 2023 on energy-based methods and nanocarriers-based approaches have been used to treat melasma.

Phase-field formulated meshless simulation of axisymmetric Rayleigh-Taylor instability problem

A formulation of the immiscible Newtonian two-liquid system with different densities and influenced by gravity is based on the Phase-Field Method (PFM) approach. The solution of the related governing coupled Navier-Stokes (NS) and Cahn-Hillard (CH) equations is structured by the meshless Diffuse Approximate Method (DAM) and Pressure Implicit with Splitting of Operators (PISO). The variable density is involved in all the terms. The related moving boundary problem is handled through single-domain, irregular, fixed node arrangement in Cartesian and axisymmetric coordinates. The meshless DAM uses weighted least squares approximation on overlapping subdomains, polynomial shape functions of second-order and Gaussian weights. This solution procedure has improved stability compared to Chorin's pressure-velocity coupling, previously used in meshless solutions of related problems. The Rayleigh-Taylor instability problem simulations are performed for an Atwood number of 0.76. The DAM parameters (shape parameter of the Gaussian weight function and number of nodes in a local subdomain) are the same as in the authors’ previous studies on single-phase flows. The simulations did not need any upwinding in the range of the simulations. The results compare well with the mesh-based finite volume method studies performed with the open-source code Gerris, Open-source Field Operation and Manipulation (OpenFOAM®) code and previously existing results.

Synthesis and performance study of amphoteric polymer suspension stabilizer for cementing slurry at ultra-high temperature

As the number of ultra-deep wells increases, maintaining the suspension stability of cement slurry at ultra-high temperatures becomes increasingly challenging; the development of a suspension stabilizer suitable for ultra-high temperature environments is imperative. Therefore, this study synthesized a temperature-resistant polymer suspension stabilizer (LHAP) using 2-acrylamide-2-methylpropanesulfonic acid (AMPS), N, N-dimethyl acrylamide (DMAA), 4-acryloylmorpholine (ACMO), and quaternary ammonium cationic hydrophobic long-chain monomer hexadecyl dimethylallyl ammonium chloride (DMAAC-16) as raw materials. It was applied to maintain the suspension stability of cement slurry at ultra-high temperatures. The molecular structure and molecular weight of LHAP were characterized and tested using infrared spectroscopy, nuclear magnetic hydrogen spectroscopy, and Ubbelohde viscometer. The thermal stability and viscosity-temperature performance of LHAP were measured using thermogravimetric analysis and rheometer, respectively. Through the segmented density difference testing of cement stone columns, the suspension stability effect of LHAP on cement slurry under high temperature was evaluated. The suspension stabilization mechanism of LHAP was studied through fluorescence probe testing, variable temperature UV visible light testing, variable temperature particle size distribution testing, Zeta potential analysis, Environmental Scanning Electron Microscopy (ESEM) analysis, and scanning electron microscopy (SEM) analysis. The results indicated that the polymer suspension agent LHAP had excellent temperature resistance, and the molecules didn’t undergo significant thermal degradation below 302 ℃. At high temperatures of 220 ℃, LHAP could maintain the suspension stability of cement slurry, and the segmented density difference of cement columns was less than 0.01 g/cm3. Mechanism analysis revealed that in addition to enhancing temperature resistance by introducing sulfonic acid groups and rigid rings, LHAP also effectively maintains the stability of the slurry suspension at ultra-high temperatures by coordinating electrostatic interactions and molecular associations. LHAP can effectively solve the settlement instability problem of cement slurry under ultra-high temperature, which is beneficial for improving the safety and quality of cementing construction in ultra-deep wells.

Polystyrene shell-based “coconut-like” and “pomegranate-like” microencapsulated phase change materials: Formation mechanism, thermal conductivity/stability enhancement and their application in thermal management

Encapsulation of phase change materials (PCMs) using polystyrene (PS) can be an effective solution to the leakage of PCMs, but the low thermal conductivity/stability of the prepared microencapsulated phase change materials (MEPCMs) remain unresolved. Here, we investigated the formation mechanism of PS shell-based MEPCMs via Pickering emulsion polymerization: coconut-like and pomegranate-like MEPCMs were obtained for the first time before and after the introduction of divinylbenzene (DVB), and the thermal conductivity and stability of the former were lower than that of the latter with the same graphene nanosheets (GNSs). Among them, MEPCM-4–7 wt% GNSs (St:DVB=1:1) has the highest thermal conductivity of 0.9358 W∙m−1∙k−1 (222.47 % higher than MEPCM without GNSs) and optimal anti-leakage performance. The thermal stability (thermogravimetric results) is slightly weaker than MEPCM-3–7 wt% GNSs (St:DVB=5:1), but has the highest thermal reliability (the melting enthalpy only decreases by 0.19 % after 100 cycles). The phase change composites (PCCs) was prepared by dispersing MEPCMs in PDMS matrix and applied to the simulated chip thermal management, which can achieve a 10.85 % decrease in the chip equilibrium temperature compared with PDMS. The method of improving the heat transfer properties and thermal stability of MEPCMs based on their structure provides a new idea to solve the problem of low thermal conductivity and stability of MEPCMs, and the prepared PCCs show great potential for practical applications in the field of thermal management.

Separation and reattachment fixed Reynolds-stress model for iced airfoil and wing simulations

Differential Reynolds-stress models (RSMs) are the higher level of Reynolds-averaged Navier-Stokes (RANS) modeling and generally considered to have more potential than eddy viscosity models (EVMs) when applied to separated flows. Nevertheless, some peculiarities have been observed in simulating flows over iced wings. The first is the numerical stability problem caused by non-streamlined wall surfaces. To weaken this, a wall-boundary-natural scale λ=ω−1/8 is introduced into SSG/LRR RSM in this paper. The second is to remedy the problem of the unsatisfactory non-equilibrium characteristic in separating shear layer (SSL), a correction determined by anisotropy of Reynolds normal stresses is developed. The last focuses on the unphysical backbending of the streamlines near stagnation/reattachment (SR) points. Since the SSL correction will worsen this defect, a SR correction is carried out to blended with it. Four two-dimensional iced airfoils and a three-dimensional iced wing are simulated and then the above measures are confirmed to be the positive.

Kinetic and hydrodynamic post-Newtonian equations in the Brans–Dicke theory

Abstract A kinetic theory for the post-Newtonian Brans–Dicke theory is developed. The Boltzmann equation and the equilibrium Maxwell-Jüttner distribution function are determined from the knowledge of the components of the metric tensor and Christoffel symbols in the post-Newtonian Brans–Dicke theory. The hydrodynamic equations for the mass density, momentum density and mass-energy density are obtained from a transfer equation derived from the Boltzmann equation. The problem of self-gravitating fluid instabilities in the post-Newtonian Brans–Dicke theory is investigated.

A high-power hybrid carbon nanotube/three-dimensional reduced graphene oxide glucose/O2 enzymatic biofuel cell

Long-lasting, high-performance enzymatic biofuel cells (EBFCs) are among the most promising candidates for renewable and green power generation. There are two main drawbacks to EBFCs: 1) short enzyme lifetime due to the enzyme's (protein) denaturation; and 2) low electron transfer efficiency as the enzyme's active site is deeply buried inside the non-conductive protein structure of the enzyme. In this study, a hybrid of carbon nanotubes (CNT) and three-dimensional graphene (3DG) was used to immobilize the glucose oxidase (GOx) on the surface of a glassy carbon electrode (GCE) to fabricate a modified bioanode in a glucose/O2 EBFC. This facile and low-cost CNT/3DG hybrid is a solution to the problems of instability, short lifespan, and poor electron transport in EBFCs. The exceptional electrocatalytic activity of the porous CNT/3DG hybrid is demonstrated by its effective immobilization of GOx and ability to collect energy from glucose oxidation by direct electron transfer (DET) while preserving the structure of the enzyme. The CNT acts like a tiny electrical wire that reaches and harvests the electron directly from the flavin adenine dinucleotide (FAD) (the redox center of GOx) and transfers it to the electrode surface, thus enhancing the performance of the EBFC. The immobilized GOx lifetime was increased to 210 days with a maximum power density of 253.36 µWcm-2 at 0.65 V. These results demonstrate the attractive capability of the CNT/3DG hybrid in the development of efficient biofuel cells and biosensors that employ enzymes in their structures.