Primary Augite Research Articles

Fluid-rock interaction related to alpine subduction of Allalingabbro deduced from large-size μXRF element maps

Alpine subduction of a block of olivine gabbro produced a plethora of different assemblages and local structures typical of high-pressure and low-temperature metamorphism. However, gabbro with the locally well-preserved igneous assemblage olivine - augite - plagioclase occurs in some domains of a 2 km long outcrop (Allalinhorn, western Alps).A large variety of hydrate minerals including zoisite, glaucophane, talc, Mg-chloritoid, chlorite, paragonite and muscovite formed during Alpine subduction of the metagabbro. The three primary igneous minerals have been replaced by hydration reactions during Eocene subduction. Talc, omphacite, and zoisite + jadeite and are the main minerals in the local domains after olivine, augite and plagioclase respectively. The rocks preserved the coarse grained igneous texture.An excellent overview of the complex coarse textures of the eclogite facies rocks has been provided by element distribution maps produced from up to 25 cm large polished slabs of typical samples of Allalingabbro using a μXRF instrument. The RGB images suggest that the minerals formed at the high-pressure in the presence of an aqueous fluid. The pseudomorphing reactions progressed close to volume conservation. The hydration reactions required an H2O fluid containing dissolved solids. The mapped distribution of elements including trace elements provides important clues on the origin and mobility of these elements in the hydration fluid. The homogeneously distributed immobile Cr in omphacite portrays primary augite. The irregular patchy Sr distribution resulted from small-scale migration of components replacing plagioclase by Sr-bearing zoisite and jadeite. Coherent Ni signals are related to the presence of talc. The talc occurs as a late infill of structures produced by dissolving olivine. Mg-chloritoid, kyanite and mica coat the former grain-boundary of olivine and plagioclase suggesting that olivine dissolved at eclogite facies conditions. Talc formed at distinctly lower pressures, however, as implied by computed model reactions. The olivine replacement structures are often larger than the size thin section and can be excellently studied by the large size μXRF patterns used in this study.The fractured surroundings of the locations of olivine provided the necessary hydraulic conductivity for hydration reactions to progress. The fractures and small veinlets contain late Ni-bearing talc. Cl is only present in very late vein amphibole suggesting that hydration fluids in the subduction zone transported dissolved components as hydrous complexes (and their dissociated ions). There is no evidence for the presence of a Cl-brine during subduction. In addition to primary olivine as a local Ni source, the element may also have partly been imported with the hydration fluid and originate from dehydration of ophiolitic serpentinites in the slab.

Dacite formation on Vesta: Partial melting of the eucritic crust

AbstractThe Dominion Range 2010 howardite pairing group contains an evolved lithic clast of dacite composition. The dacite contains an assemblage of plagioclase, quartz, and augite, with minor pigeonite, troilite, ilmenite, FeNi metal, K‐feldspar, and phosphates. Primary augite occurs as >1 mm oikocrysts enclosing plagioclase. Quartz is abundant, comprising approximately 30% of the clast. Textural and geochemical characteristics support the hypothesis that the dacite is a primary igneous lithology, and represents a partial melt of the eucritic crust. Numerical modeling (MELTS) suggests 10–20% partial melting of a Juvinas source could have produced the dacite lithology; quantitative trace element modeling further supports crustal partial melting as the magma source for the dacite. The dacite likely formed as evolved‐melt pockets, and thus represents a volumetrically minor lithology in the Vestan crust, although its formation provides direct support for a genetic relationship between Stannern and residual trend eucrites, and is the first identification of residual eucrite complementary melts. We propose the dacite clast is the first characterized sample of tertiary crust on Vesta.

Petrological and geochemical characteristics of metamorphic and igneous units from the allochthonous Madre de Dios Terrane, Southern Chile

The Denaro Complex, part of the Madre de Dios Terrane is composed of metamorphosed pillow basalts, metahyaloclastites, banded metalliferous and radiolarian metacherts, metapelites and redeposited calcareous metasandstones. The basaltic rocks show primary textures, minerals and structures. They are foliated especially in the vicinities of thrust faults, interpreted to have developed during the accretion of the terrane to the Gondwana margin. Composition of relic primary augite and chromite crystals plots into the MORB field of tectonic discriminant diagrams, as do the analyses of whole rock geochemistry, which indicates that these rocks are akin to volcanic rocks erupted along a constructive plate margin (N- and E-type MORBs), probably in a spreading axis-centered oceanic plateau or ridge. The metamorphic assemblages of pumpellyite–actinolite facies bear witness of metamorphism in a frontal accretionary wedge at elevated P and low T conditions, probably related to the Late Triassic–Early Jurassic Chonide event, which has been recognized elsewhere in the Patagonian Andes.

Hydrothermal alteration in the core of the Yaxcopoil‐1 borehole, Chicxulub impact structure, Mexico

Abstract Petrographic, electron microprobe, and Raman spectrometric analyses of Yaxcopoil‐1 core samples from the Chicxulub crater indicate that the impact generated a hydrothermal system. Relative textural and vein crosscutting relations and systematic distribution of alteration products reveal a progression of the hydrothermal event in space and time and provide constraints on the nature of the fluids. The earliest calcite, halite, and gaylussite suggest that the impactite sequence was initially permeated by a low temperature saline brine. Subsequent development of a higher temperature hydrothermal regime is indicated by thermal metamorphic diopside‐hedenbergite (Aeg3Fs18‐33En32‐11Wo47‐53) after primary augite and widespread Na‐K for Ca metasomatic alkali exchange in plagioclase. Hydrothermal sphene, apatite, magnetite + (bornite), as well as early calcite (combined 3 to 8 vol%) were introduced with metasomatic feldspar. A lower temperature regime characterized by smectite after probable primary glass, secondary chlorite, and other pre‐existing mafic minerals, as well as very abundant calcite veins and open‐space fillings, extensively overprinted the early hydrothermal stage. The composition of early and late hydrothermal minerals show that the solution was chlorine‐rich (Cl/F >10) and that its Fe/Mg ratio and oxidation state increased substantially (4 to 5 logfO2 units) as temperature decreased through time. The most altered zone in the impactite sequence occurs 30 m above the impact melt. The lack of mineralogical zoning about the impact melt and convective modeling constraints suggest that this unit was too thin at Yaxcopoil‐1 to provide the necessary heat to drive fluids and implies that the hydrothermal system resulted from the combined effects of a pre‐existing saline brine and heat that traveled to the Yaxcopoil‐1 site from adjacent areas where the melt sheet was thicker. Limonite after iron oxides is more common toward the top of the sequence and suggests that the impactite section was subjected to weathering before deposition of the Tertiary marine cover. In addition, scarce latest anatase stringers, chalcopyrite, and barite in vugs, francolite after apatite, and recrystallized halite are the likely products of limited post‐hydrothermal ambient‐temperature diagenesis, or ocean and/or meteoric water circulation.

Primary trapped melt inclusions in olivine in the olivine-augite-orthopyroxene ureilite Hughes 009

We describe the first known occurrence of primary melt inclusions in a ureilite. The ureilite is Hughes 009, one of a small number of ureilites whose primary mineralogy is olivine-augite-orthopyroxene, rather than olivine-pigeonite. Hughes 009 has a coarse-grained, equilibrated texture typical of ureilites, and homogeneous primary mineral compositions: olivine — mg 87.3; augite — mg 89.2, Wo 37.0, Al 2O 3 = 1.6 wt.%; orthopyroxene — mg 88.3, Wo 4.9. It shows only limited secondary reduction effects and no petrographically recognizable carbon phases, which indicates that its original carbon content was lower than in most ureilites. The melt inclusions occur in olivine crystals. They are concentrated in the central regions of their hosts, showing elongate (mostly 20–60 μm in maximum dimension), negative olivine crystal shapes and parallel alignment. These and other features indicate that they were trapped during initial growth of their hosts from a liquid, and are likely to be representative samples of that liquid. They consist of glass and single, subhedral crystals of high-Ca pyroxene, with minor Cr-rich spinel and metal-phosphide-sulfide spherules. They are surrounded by halos of olivine with rounded outlines defined by tiny bits of metal and thin arcs of glass. Pyroxenes within each inclusion show zonation patterns indicating that they nucleated at the olivine/ liquid interface with compositions close to that of the primary augite, and then grew inward with dramatically increasing Al 2O 3 (to 10.8 wt.%), Wo (to ≈50), TiO 2 and Cr 2O 3 contents. Glasses within each inclusion are relatively homogeneous. Glasses from all inclusions show well-defined trends of CaO, TiO 2, Cr 2O 3 , Na 2O and SiO 2 vs. Al 2O 3, (16–23 wt.%) that can be modelled as resulting principally from crystallization of various amounts of the pyroxene. The halos, which represent olivine that grew from the trapped melts, are zoned in Cr and Ca with concentrations decreasing inward, reflecting cocrystallization of pyroxene; they have homogeneous Fe/Mg identical to that of the primary olivine, indicating reequilibration with the host. We develop a petrologic model for the postentrapment history (crystallization, reaction and reequilibration) of the inclusions, based on which we reconstruct the composition of the primary trapped liquid (PTL). The PTL was saturated only with olivine. This result implies that Hughes 009 is a cumulate (consistent with the high Mn/Mg ratio of its olivine and a low abundance of graphite) and that the composition of the PTL is close to that of its parent magma. The low-pressure equilibrium crystallization sequence predicted by MAGPOX calculations for the PTL (olivine → augite → plagioclase → pigeonite) is not, however, consistent with the primary mineralogy of Hughes 009. If the conditions of these calculations are, indeed, appropriate, then complex processes such as magma mixing must have been involved in the petrogenesis of this ureilite. This conclusion is consistent with other evidence that the olivine-augite-orthopyroxene ureilites record a more complex magmatic evolution than is evident in the olivine-pigeonite ureilites. TEM investigations of microtextural features in all phases and XRD determination of Fe 2+-Mg site distribution in orthopyroxene have elucidated the cooling and shock history of this ureilite. Hughes 009 experienced an extremely high cooling rate (7 ± 5°C/h at the closure T of 630°C) late in its evolution, and two distinguishable shock events—the first at peak pressures of 5 to 10 GPa, resulting in mechanical polysynthetic twinning in augite and orthopyroxene and mild undulatory extinction in olivine; and the second at lower pressures, resulting only in brecciation and redistribution of metal. Its late history is similar to that of most ureilites, and probably reflects impact excavation.

Petrology and comparative thermal and mechanical histories of clasts in breccia 62236

Lunar breccia 62236 contains large lithic fragments of troctolite, norite, and anorthosite. The mafic phases, olivine, inverted pigeonite, and augite, fill interstitial areas between larger plagioclases and appear to be cumulate phases with extensive adcumulus growth. Pyroxene compositional homogeneity indicates that cation exchange during cooling was limited to an area of about 1 mm. Primary augite and pigeonite both contain 30 μm‐wide lamellae of the other along ‘001’. Pigeonite inverted to orthopyroxene without retaining any crystallographic orientation and subsequently exsolved fine lamellae of augite on (100). Profiles across orthopyroxene‐augite interfaces obtained in the analytical transmission electron microscope show an increase of ∼5% wollastonite in augite within 0.5 μm of the interface, suggesting that short‐range cation exchange continued to temperatures below 500°C. The entire sample has undergone heterogeneous shock deformation. Shock melting of the troctolitic clast suggests pressures of 200–300 kb and well‐developed basal twinning in augite from the norite clasts suggests pressures of 50–300 kbars. The present evidence indicates that 62236 contains parts of a slowly cooled microlayered adcumulate that has been heterogeneously shocked several times and combined into the present breccia.

The position of the augite syenite and pulaskite in the Ilimaussaq intrusion, South Greenland

The augite syeni1e is generally recogni?.ed as the earliest intrusive phase of 1he llimaussaq intrusion. 1l has been proposed that the agpaitic nepheline syenitcs. which constitute the major part of the intrusion, are products of in siiu differentiation of a primary augite syenitic magma. Recent field and laboratory investi­ga1ions demonstrate. however. thal there was a clear break between the consolidation of the augite sycnite and the emplacemem of the agpaitic rocks. The latter have most probably formed from a second pulse of magma injection and have been cmplaced by spalling off of rafts of augite syenilc and other rocks from the walls and roof of the chamber.

Phase Relations and Crystallization Sequence in a Contact-Metamorphosed Rock from the Gunflint Iron Formation, Minnesota

Portions of the Gunflint Iron Formation, originally a ferruginous sediment, were metamorphosed by the intrusion of the Duluth Complex to assemblages containing: pigeonite (Wo10En24Fs66)+olivine (Fo13Fa37)+Fe-Ti oxide (Mt62Usp34Hc4)+plagioclase (An94Ab6)+ vapor+augite (Wo40En20Fs40) or cummingtonite Fe/(Fe+Mg) ˜ 0.69; quartz was present but probably was not in equilibrium with olivine. Comparison with synthetic phase-equilibrium studies indicate conditions of initial recrystallization of T≥ 800 °C, Ptotal ≥ 2kb, fo2 slightly below that of the pure fayalite-magnetite-quartz assemblage, and PH2O < Ptotal. During the slow cooling process following initial recrystallization, the phases present underwent a complex series of exsolution, inversion, oxidation, and hydration reactions. Pigeonite initially exsolved augite along (001), then inverted to orthopyroxene, which then exsolved augite along (100). The augite exsolved only pigeonite on (001) during its cooling history. The Fe-Ti oxide for the most part oxidized to an intergrowth of magnetite and ilmenite, although unoxidized portions later exsolved ulvöspinel. Cummingtonite exsolved actinolite, forming irregular patches of the latter. Olivine, orthopyroxene, and augite reacted with plagioclase to form retrograde amphiboles. Orthopyroxene had difficulty nucleating during this slow cooling process, forming only at widely spaced points in mosaics of primary pigeonite grains, and never nucleating within primary augite grains. The resulting orthopyroxene grains are much larger than the original pigeonite grains.