PP Matrix Research Articles

Facile Production of Graphene/Polypropylene Composites with Enhanced Electrical and Thermal Properties through In Situ Artificial Latex Preparation

In order to obtain the unique properties of graphene-based composites, to realize homogeneous dispersion of graphene throughout the polymer matrix remains the key challenge. In this work, edge-oxidized graphene/polypropylene (EOGr/PP) composites with well-dispersed EOGr in PP matrix, synchronously exhibiting high electrical conductivity and thermal property, were simply fabricated for the first time using a novel strategy by in situ artificial PP latex preparation in the presence of EOGr based on solution-emulsification technique. The good dispersion state of EOGr in the PP matrix was demonstrated by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). A blue shift in Raman G peak of the EOGr nanosheets was observed in the EOGr/PP composites, indicating the strong interactions between the EOGr nanosheets and the PP matrix. The onset crystallization and crystallization peak temperatures increased as the EOGr loading increases due to its good nucleating ability. An improved thermal stability of EOGr/PP composites was observed as evaluated by TGA. The EOGr/PP composites showed an insulator-to-conductor percolation transition in between that of 1 and 2 wt% EOGr content. Such strategy provides a very effective pathway to fabricate high-performance nonpolar polymer/graphene composites with excellent dispersion state of graphene.

Improvement in the thermal and mechanical properties of PP/Clay nanocomposite using novel ethoxylated oxidized PE wax as a compatibilizer

AbstractAn ethoxylated polyethylene wax (E‐OPEW) was synthesized by PEGylation reaction between methoxy polyethylene glycol and oxidized PE wax. Clay nanoparticles were modified with different ratios of E‐OPEW and then compounded with PP by the melt mixing process. E‐OPEW and PP showed excellent compatibility, but at high percentages of wax (15%), incompatibility occurred between the two phases. In addition, the presence of modified clays in the PP matrix decreased the crystallinity percentage, though it did not change the melting temperature significantly. The results showed that functionalized wax is able to penetrate between clay platelets and increase the distance between them and improve their dispersion in the polymer matrix. Furthermore, it was observed that the distance between clay platelets increased by increasing E‐OPEW content. In addition, this result led to a significant improvement in the barrier properties of clay platelets and the thermal stability of the modified nanocomposite compared to other cases. Despite the improved dispersion of nanoparticles, the mechanical strength of nanocomposites decreased at a high percentage of E‐OPEW.

A simultaneous strategy for the preparation of acetylation modified cellulose nanofiber/polypropylene composites

In this study, a simultaneous method with nano-fibrillation of acetylation modified fibers (A-cellulose) and preparation of cellulose nanofiber (CNF)/apolar polymer composites are proposed. The A-cellulose and isotactic polypropylene (iPP) were initially mixed and then melt-compounding in a twin-screw extruder. Due to the reduction of hydrogen bonding force inside A-cellulose and the high shear force provided by the extruder, acetylated cellulose nanofiber (A-CNF) distributed with the state of a three-dimensional network in PP composites (ACPP) were successful prepared. The scanning electron microscopy (SEM) images of A-CNF, dynamic mechanical analysis (DMA) and X-ray diffraction (XRD) results of ACPP showed that the A-CNF had good interface compatibility with PP matrix, and had the effects of inducing PP crystallization, decreasing crystal size and increasing the ratio of γ crystals in composites, which could improve the mechanical and thermodynamic properties of composites.

Strain‐sensing behavior of flexible polypropylene/poly(ethylene‐co‐octene)/multiwalled carbon nanotube nanocomposites under cyclic tensile deformation

AbstractIn this study, the associations between the structural evolution and physical properties of polypropylene/poly(ethylene‐co‐octene)/multiwalled carbon nanotube (PP/POE/MWCNTs) composites were established. The MWCNTs particles preferentially migrating from PP matrix to disperse in POE phase, which contributed to a richer network structure, thus resulting in a significant improvement for electrical conductivity, as well thermal stability, and toughness property with the elongation at break from 300% to 800%. Furthermore, the online strain‐resistance analysis showed that introducing POE phase had a big advantage in improving the recovering resilience and stability of the conductive network structure of PP/POE/MWCNTs composites under a multi‐time circular tensile test with a strain of 5%. It was highlighted that the maximum and minimum electrical conductivity levels of PP/POE composites remained almost constant and even the ratio of the real‐time resistance to the initial one was negative just at the beginning of each circulation regarding the strain stretching and recovery. This was attributed to the oriented conductive network structure of PP/POE nanocomposites induced by the applied strain, thereby increasing the electrical conductivity. Overall, this research provides a basic guidance for preparing composites with ultrahigh flexibility and stability under a circular deformation, which is an essential element taken into consideration for smart sensors with high sensitivity.

Rheological and mechanical properties of polypropylene/grape skin fiber composites

The use of natural fibers as fillers in polymer matrix composites is an alternative for reusing the fruit wastes that originated from the food industry. This work aimed to evaluate the effect of grape skin fiber (GSF) on the rheological and mechanical properties of polypropylene/GSF (PP/GSF) composites. The composites were prepared by extrusion followed by injection molding and characterized by rheological, morphological, and mechanical properties. Rheological measurement results showed an increase in viscosity at low frequencies. The relaxation time of the PP/GSF composites increased by about 415% with the increase in the GSF content from 1 to 3 phr. Capillary rheometry results indicated that the processability of PP was not compromised with the addition of GSF. Morphology analysis by scanning electron microscopy (SEM) indicated a good interaction between the PP matrix and GSF and a good dispersion/distribution of the fibers in the PP matrix. The impact strength decreased by about 14 and 17% with the addition of 1 and 3 phr, respectively, of GSF to PP whereas the elastic modulus remained almost unchanged.

Near-Infrared Laser Direct Writing of Conductive Patterns on the Surface of Carbon Nanotube Polymer Nanocomposites.

Near-infrared (NIR) laser annealing is used to write conductive patterns on the surface of polypropylene/multi-walled carbon nanotube nanocomposite (PP/MWCNT) plates. Before irradiation, the surface of the nanocomposite is not conductive due to the partial alignment of the MWCNT, which occurs during injection molding. We observe a significant decrease in the surface sheet resistance using NIR laser irradiation, which we explain by a randomization of the orientation of MWCNTs in the PP matrix melt by NIR laser irradiation. After only 5 s of irradiation, the sheet resistance of PP/MWCNTs, annealed with a laser at a power density of 7 W/cm2, decreases by more than 4 decades from ∼100 MΩ/sq to ∼1 kΩ/sq. Polarized Raman, TEM, and SEM are used to investigate the changes in the sheet resistance and confirm the physico-chemical processes involved. This allows direct writing of conductive patterns using a NIR laser on the surface of nanocomposite polymer substrates, with the advantages of a fast, easy, and low-energy consumption process.

Enhanced Mechanical and Thermal Properties of Modified Oil Palm Fiber-Reinforced Polypropylene Composite via Multi-Objective Optimization of In Situ Silica Sol-Gel Synthesis.

A multi-objective optimization of in situ sol-gel process was conducted in preparing oil palm fiber-reinforced polypropylene (OPF-PP) composite for an enhancement of mechanical and thermal properties. Tetraethyl orthosilicate (TEOS) and butylamine were used as precursors and catalysts for the sol-gel process. The face-centered central composite design (FCCD) experiments coupled with response surface methodology (RSM) has been utilized to optimize in situ silica sol-gel process. The optimization process showed that the drying time after the in-situ silica sol-gel process was the most influential factor on silica content, while the molar ratio of TEOS to water gave the most significant effect on silica residue. The maximum silica content of 34.1% and the silica residue of 35.9% were achieved under optimum conditions of 21.3 h soaking time, 50 min drying time, pH value of 9.26, and 1:4 molar ratio of TEOS to water. The untreated oil palm fiber (OPF) and silica sol-gel modified OPF (SiO2-OPF) were used as the reinforcing fibers, with PP as a matrix and maleic anhydride grafted polypropylene (MAgPP) as a compatibilizer for the fiber-reinforced PP matrix (SiO2-OPF-PP-MAgPP) composites preparation. The mechanical and thermal properties of OPF-PP, SiO2-OPF-PP, SiO2-OPF-PP-MAgPP composites, and pure PP were determined. It was found that the OPF-S-PP-MAgPP composite had the highest toughness and stiffness with values of tensile strength, Young’s modulus, and elongation at break of 30.9 MPa, 881.8 MPa, and 15.1%, respectively. The thermal properties analyses revealed that the OPF-S-PP-MAgPP exhibited the highest thermally stable inflection point at 477 °C as compared to pure PP and other composites formulations. The finding of the present study showed that the SiO2-OPF had the potential to use as a reinforcing agent to enhance the thermal-mechanical properties of the composites.

Effect of in situ fibrillation on polyethylene/poly(ethylene terephthalate)/multiwalled carbon nanotube electromagnetic shielding foams

AbstractIn this study, polyethylene (PP)/polyethylene terephthalate (PET)/multiwalled carbon nanotube (MWCNT) nanocomposites with nanofibrillary structure were processed by hot drawing‐assisted extrusion technology, and nonfoaming and microfoaming samples were processed by injection molding machine. Scanning electron microscope micrographs showed that when PET content was 2.5 wt%, PET fibers had a larger aspect ratio, which brought an outstanding promotion on microfoaming of PP matrix, and further details were provided by DSC and rheology analysis. When foaming sample loaded with 2.5 wt% PET and 3 wt% MWCNT, the best shielding effectiveness achieved 29.91 dB·cm3·g−1 in the test frequency range about 8.2–12.4 GHz. The results proved that the introduction of PET fibers optimized the microfoaming effect, and the uniform cell structure promoted the MWCNT dispersion and internal reflection of electromagnetic wave. Therefore, the shielding property is absorption‐dominated type and meets the requirements of lightweight and ultraefficient shielding demand of industry.

Synthesis and Characterization of Microcellular Injection Molded Polyolefin/Polycaprolactone Composites

This study investigated the effect of polycaprolactone (PCL) loading (0.5, 1, and 3 wt%) on the morphology, tensile strength, and thermal properties of microcellular injection molded PP/PCL and PPgMA/PCL composites. We used the filler, PCL, that is micro-material in size. Results showed that 0.5 wt% loading of PCL on foamed PP has the largest tensile strength. However, tensile strength was almost similar to that of PPgMA composites. Tensile strength depends on the filler dispersion in the matrix and cell size present on the foamed composites. Good dispersion resulted in good tensile strength. The elongation decreased on PP but increased on PPgMA composites. The highest degradation temperature for PP/PCL and PPgMA/PCL was noted for 3.0 wt% PCL loading and neat PPgMA respectively. Cell size decreased and cell density increased with the addition of PCL into the PP and PPgMA matrix.

Composites of Cysteamine Functionalised Graphene Oxide and Polypropylene

Abstract Cysteamine functionalised reduced graphene oxide (rGO) was grafted to polypropylene-graft-maleic anhydride (PP-g-MA) and subsequently melt blended with PP. The covalent bridging of rGO to PP-g-MA via the cysteamine molecule and co-crystallization are routes to promoting interfacial interactions between rGO and the PP matrix. A rheological percolation threshold was achieved for a nanofiller loading between 3 wt% and 5 wt%, but none detected for the composites prepared with un-functionalized rGO. At low loadings (0.1 wt%), functionalized rGO is well dispersed in the PP matrix, an interconnecting filler-filler, polymer-filler and polymer-polymer network is formed, resulting in increased tensile toughness (1 500%) and elongation at break (40%) relative to neat PP. Irrespective of whether the rGO was functionalised or not, it had a significant effect on the crystallization behavior of PP, inducing heterogeneous nucleation, increasing the crystallisation temperature (Tm) of PP by up to 10°C and decreasing the crystalline content (Xc) by ∼30% for the highest (5 wt%) filler loading. The growth of the monoclinic a-phase of PP is preferred on addition of functionalised rGO and b crystal growth suppressed.

Carbon nanotubes interaction with amorphous and semi‐crystalline domains of polypropylene in melt‐mixed composites: Influence of multiwall carbon nanotubes agglomerate and their modifications

AbstractPolypropylene (PP) and multi‐walled carbon nanotubes (MWCNTs) composites were prepared by melt‐mixing with two types of MWCNTs of varying agglomerate size. Agglomerate dominated dispersion was observed in the PP matrix, wherein N‐MWCNTs exhibit a finer dispersion as compared to D‐MWCNTs. Further, MWCNTs were encapsulated by Li‐salt of 6‐amino caproic acid in various proportions along with PP‐g‐maleic anhydride in order to achieve finer MWCNTs dispersion. Thermogravimetric analysis exhibited an increase in onset of degradation temperature and higher residual weight (%) at 500 °C of PP with increased MWCNTs concentration, which suggests the formation of a thicker “interphase.” Glass transition temperature of the PP phase was increased monotonically as a function of unmodified MWCNTs concentration, which suggests a strong interfacial interaction between PP and MWCNTs. An extensive analysis was carried out with modified MWCNTs based PP composites. Moreover, MWCNTs act as a strong hetero‐nucleating agent manifesting in smaller spherulite size of PP, wherein bulk crystallization temperature is increased to ~130 °C of the PP phase at 5 wt% MWCNTs content. The influence of unmodified and modified MWCNTs on the interaction between the PP chains and MWCNTs in the amorphous phase as well as in the crystalline domains are analyzed in PP/MWCNTs composites.

Environmental Hazards of Giant Reed (Arundo donax L.) in the Macaronesia Region and Its Characterisation as a Potential Source for the Production of Natural Fibre Composites.

This paper summarises the results obtained from the characterisation of giant reed (Arundo donax L.) plant and fibres. The research is part of a project developed in the Macaronesia region, of which the aim is to demonstrate the feasibility of using biomass from invasive plant species in the composites sector as a way of financing control campaigns and habitats conservation labours. An experimental procedure for the extraction of fibre bundles from this plant was developed, and the material obtained was characterised in terms of chemical composition, thermogravimetry and infrared spectra to evaluate its potential application in the production of polymeric composite materials as a strategy for the valorisation of residual biomass from this invasive species in Macaronesia. Thermoplastic matrix composites with fibre content up to 40 wt.% were produced and their mechanical properties under tensile, flexural and impact loading were determined. No references on the preparation of composite materials with polyolefin matrices and giant reed fibres have been found. Results obtained from mechanical tests show a good performance of the manufactured composites, with a significant increase in both flexural and tensile stiffness; the flexural modulus is almost tripled for PE-based composites and rises to 88% with respect to PP matrix. The ultimate flexural strength and the tensile and flexural yield strength are kept at acceptable values compared to neat polymer materials, although ultimate tensile strength and impact resistance are significantly affected when natural fibres are added.

Use of Organic Acids in Bamboo Fiber-Reinforced Polypropylene Composites: Mechanical Properties and Interfacial Morphology.

In obtaining wood polymer composites (WPCs), a weak interfacial bonding can cause problems during the processing and affect the mechanical properties of the resulting composites. A coupling agent (CA) is commonly used to solving this limitation. To improve the interfacial bonding between bamboo fiber (BF) and a polypropylene matrix, the effect of three organic acids on the mechanical properties and interfacial morphology were investigated. The BF/PP composites were prepared in five families: the first without CA, the second using a maleic anhydride-grafted polypropylene coupling agent, and the third, fourth, and fifth families with the addition of organic acids (OA) tricarboxylic acid (TRIA), hexadecanoic acid (HEXA), and dodecanoic acid (DODA), respectively. The use of OA in BF/PP improved the interfacial adhesion with the PP matrix, and it results in better mechanical performance than composites without CA. Composites coupled with MAPP, TRIA, DODA, and HEXA showed an increase in Young’s modulus of about 26%, 23%, 15%, and 16% respectively compared to the composite without CA incorporation. In tensile strength, the increase in composites with CA was about 190%, while in the flexural modulus, the coupled composites showed higher values, and the increase was more in composites with TRIA: about 46%. The improvement caused by tricarboxylic acid was similar to that promoted by the addition of maleic anhydride-grafted polypropylene (MAPP).

Influence of cyclic loads on the fiber-matrix-interaction of cellulose and glass fibers in polypropylene

The present study is focused on the characterization of cyclic loads on the fiber matrix adhesion of regenerated cellulose fibers (RCF) and glass fibers (GF) in a PP matrix with varying contents of maleic anhydride-grafted polypropylene (MAPP). Glass fibers were used for reference purposes. By means of the cyclic loaded single fiber pull-out test (SFPT) the interfacial shear strength (IFFS) and the critical fiber length (lc) are determined as a function of the applied loads, the number of cycles and the MAPP content. The results of the material-specific reduction of the IFSS were extrapolated to approximately predict the fatigue behavior of the composites.The investigations show the influence of cyclic loads in the single fiber pull-out test on the fiber–matrix adhesion for the first time. On the one hand, the results show that cyclic loading of the embedded single fibers leads to a significant reduction of fiber–matrix adhesion. On the other hand, it becomes clear that the number of cycles has the greatest effect on IFSS and thus on fatigue, while the various investigated setups (test speeds and forces) show the least effect.The transfer of the resulting findings to the integral fatigue properties of composites can contribute to a much more precise property and failure prediction in the future.

Green cinnamaldehyde and thymol modified zinc oxide with double synergistic antibacterial effects in polypropylene

AbstractThe green cinnamaldehyde (CA) and thymol (THY) separately or successively modified O‐ZnO (O‐ZnO‐CA, O‐ZnO‐THY, and O‐ZnO‐CA‐THY) were prepared after (3‐aminopropyl) triethoxysilane (KH550) was grafted to the surface of ZnO (O‐ZnO) and characterized by FTIR, TGA, and SEM. Polypropylene composites (PP/O‐ZnO‐CA, PP/O‐ZnO‐THY, and PP/O‐ZnO‐CA‐THY) were prepared by melting the modified O‐ZnO and PP. The antibacterial tests showed that the antibacterial rate of PP/O‐ZnO‐CA and PP/O‐ZnO‐THY against S. aureus and E. coli was obviously enhanced. It indicated an excellent synergetic antibacterial effect of O‐ZnO and the little CA or THY grafted on the surface of O‐ZnO. The antibacterial effect of O‐ZnO‐CA and O‐ZnO‐THY was related to the hydrophobic and hydrophilic groups contained in CA and THY. Importantly, CA and THY in O‐ZnO‐CA‐THY exhibited another excellent synergetic antibacterial effect against both S. aureus and E. coli. The antibacterial rate of three PP composites containing 4 phr O‐ZnO‐CA‐THY against S. aureus and E. coli reached 95% and 90%, respectively. The mechanism was regarded as that CA and THY grafted onto the same O‐ZnO improved the contact probability between antibacterial agents and bacteria. Moreover, O‐ZnO‐CA, O‐ZnO‐THY, and O‐ZnO‐CA‐THY had excellent migration resistance in the PP matrix.

Polypropylene hybrid composites: Effect of reinforcement of sisal and carbon fibre on mechanical, thermal and morphological properties

Abstract Polypropylene (PP)/sisal fibre (SF)/carbon fibre (CF) hybrid composites were prepared by melt blending process at a variable weight percentage (wt%) of carbon: sisal fibre loading (20:10, 15:15, 10:20, and 5:25). MA-g-PP (MgP) as a compatibiliser was used to improve the dispersion of the fibres within the PP matrix. The composites were subjected to mechanical tests to optimize the fibre content of CF: SF. Incorporation of 20 wt% of CF and 10 wt% of SF with 5 wt% MgP resulted in higher mechanical performance of about 67.02 and 112% over that of PP/SF composite. Similarly, the impact strength was found to be optimum which enhanced to the tune of 39.62% as compared with PP/SF composites. Halpin Tsai model was used to compare the theoretical tensile modulus of PP/SF/MgP composites and PP/SF/CF/MgP hybrid composites with experimental evaluated values. Fracture toughness parameters such as K IC (critical stress intensity factor) and G IC (critical strain energy release rate) are determined for PP/SF/MgP composites and PP/SF/CF/MgP hybrid composites and compared by using single edge notch test. DSC study showed higher melting temperature (T m ) of PP/SF/CF/MgP composites as compared to PP revealing the enhancement in thermal stability. TGA/DTG study revealed the synergistic effect of the hybrid composite thus confirming the hybridisation effect of the system. DMA study showed that the hybridisation of CF and SF within the matrix polymer contributes to an increase in the storage modulus (Eʹ). Morphological observation by SEM confirmed that the carbon fibres and sisal fibres are well uniformly dispersed within the PP matrix, in the presence of MgP.

Microporous formation and evolution mechanism of PTFE fibers/isotactic polypropylene membranes by interface separation

Studying microporous formation and evolution mechanism plays a crucial role in fabricating high-performance microporous membranes. A formation mechanism of PP microporous membranes, different from those reported previously, was proposed based on the interface separation of PTFE fibers and PP matrix during sequential biaxial stretching. The experimental results indicated that the initial microcracks, which were filled by microfibrillated PP, were originated from PTFE fibers-PP matrix interfaces perpendicular to the longitudinal stretching direction. As the strain increased, microfibrillated PP was further elongated, ultimately forming microfibrillated PP membranes at a relatively low strain (200%). The subsequent transverse stretching caused the separation of fibrillated PP to form an excellent microporous structure. As a result, PTFE/PP membranes after biaxial stretching exhibited the narrower pore size distribution, higher porosity, higher N2 flux and pure water flux than β-PP membranes.

Microwave‐Assisted Confining Flame‐Retardant Polypropylene in Carbon Nanotube Conductive Networks for Improved Electromagnetic Interference Shielding and Flame Retardation

Electrical conductive polymer composites (CPCs) with segregated structure can achieve better electrical conductivity with low content of conductive filler. Nevertheless, the undesirable properties of these CPCs, such as ease of burning, high smoke generation, weak interfacial adhesion, and poor mechanical performance, have restricted their practical applications. Herein, a promising microwave‐assisted strategy is developed for the fabrication of a flame‐retardant and electrically conductive polypropylene/ammonium polyphosphate/carbon nanotube (PP/APP/CNT) composite. Highly conductive networks can be set via the microwave‐selective heating, which results in an electromagnetic shielding effectiveness (EMI SE) of 32.1 dB of the composite with 7 wt% content of CNTs. Furthermore, the conductive segregated CNT network also serves as an excellent char‐forming agent to enhance the nonflammability and overcome the melt dripping issue of the pure PP matrix. As a result, the segregated conductive PP composites with 7 wt% CNTs and 15 wt% APP exhibit melt dripping and prompt self‐extinguishment, achieving the V‐0 rating level in the UL‐94 test. In brief, the well‐defined microwave‐assisted process provides a promising approach to fabricate various CPCs with simultaneously improved EMI shielding and flame‐retarding properties.

Upgrading Recycled Polypropylene from Textile Wastes in Wood Plastic Composites with Short Hemp Fiber.

This research reports the manufacturing and characterization of green composites made from recycled polypropylene obtained from the remnants of polypropylene non-woven fabrics used in the textile industry and further reinforced with short hemp fibers (SHFs). To improve the interaction of the reinforcing fibers with the recycled polymeric matrix, two types of compatibilizing agents (maleic anhydride grafted, PP-g-MA, and maleinized linseed oil, MLO) were added during melt-processing, the percentage of which had to remain constant concerning the amount of fiber loading to ensure complete reactivity. Standardized test specimens were obtained by injection molding. The composites were characterized by mechanical (tensile, impact, and hardness), thermal (DSC, TGA), thermomechanical, FTIR, and FESEM microscopy tests. In addition, color and water uptake properties were also analyzed. The results show that the addition of PP-g-MA to rPP was satisfactory, thus improving the fiber-matrix interaction, resulting in a marked reinforcing effect of the hemp fibers in the recycled PP matrix, which can be reflected in the increased stiffness of the samples. In parallel to the compatibilizing effect, a plasticizing effect was obtained by incorporating MLO, causing a decrease in the glass transition temperature of the composites by approximately 6 °C and an increase in ductility compared to the unfilled recycled polypropylene samples.

A Study of Fabrication Technique, Structural and Morphological Behavior of Polypropylene Reinforced with Short Natural Fiber Banana

With regard to the environmental aspect it would be very interesting if natural fibers like banana, jute, and coir could be used instead of artificial fibers and synthetic products as reinforcement in some applications. Banana .Natural fibers have many advantages compared to other man made fibers. The natural fiber composites may be used in everyday applications such as lampshades, suitcases, paperweight, helmets, shower and bath units. Polypropylene composites were fabricated with untreated and alkali treated jute fiber with 10-25% loading of fiber by weight and were designated at Polypropylene Banana Composite (PPBC). The composites of biodegradable Polypropylene (PP) reinforced with short jute natural fiber was prepared by melt mixing followed by hot press molding. The micro structural analysis and morphologies of the composites were studied via infrared spectroscopy (IR) and Scanning electron microscopy (SEM) techniques respectively. The extensive application of infrared spectroscopy is mainly due to the concept of group vibration. Any structural change like substitution or addition of groups or atoms in a molecule affects the relative mode of vibration of the group. This causes change in IR spectral band position, change in relative intensities and appearance of new bands and disappearance of any band and splitting of a single band into two or more bands. Infrared spectroscopy can also be used to increase the utility of fiber. It deals with the interaction of infrared light with matter. The former can indicate the presence of functional groups qualitatively and the latter can provide a semi quantitative measure of their concentrations. Electron Microscopy is most widely used to obtain information regarding the morphology of fiber surfaces, especially SEM (Scanning Electron Microscopy). Using SEM, it is easy to determine the differences of fiber surface topography after and before treatment, and hence the formation of fiber polymer composites. Fiber deboning was also observed for untreated and treated fiber pp matrix composite. It reveals that bonding between the fiber and the matrix at the interface may be improved. These indicate that there are some kinds of interfacial contact between fiber and pp matrix due to fiber treatment. The SEM can have a magnification range from a few times to several hundred thousand times.