Polyethylene Naphthalate Research Articles

Measurement of Thermal Diffusivity of Thin Film in Thickness Direction Using an Ordinary Dielectric Film as the Sensor

Accurate thermal parameters of thin films are beneficial for the engineering thermal design and thermal management of electronic devices to improve the operating stability and prolong service life. In this article, a novel method for measuring the thermal diffusivity of thin films is proposed based on the thermal pulse method (TPM) for mapping space charge distribution, whose thermal response current is strongly determined by the temperature profiles within thin film. A multi-layer thin film structure is adopted, in which the tested film layer is thermally coupled on the dielectric film substrate with thermal parameters known. The thermal pulse by laser pulse excites the tested film and then penetrates into the dielectric film substrate. By analyzing the thermal response current of the dielectric film substrate, one can deduce the temperature profiles in both layers and therefore the thermal diffusivity of the tested film. The proposed method can determine the thermal diffusivity of both insulating and electric conduction films with the thickness tens of micrometers in through thickness direction. The obtained values of the thermal diffusivity of polyimide (PI), bi-oriented polypropylene (BOPP), polyethylene 2,6-naphthalate (PEN), tin(Sn) foil, and lead (Pb) foil are well consistent with the data provided in the literatures. By the analyzing heat boundary conditions, the interface thermal resistance between the tested film and the dielectric film substrate can be also determined at the same time.

Comment on "Ultralow magnetostrictive flexible ferromagnetic nanowires" by G. Muscas, P. E. Jönsson, I. G. Serrano, Ö. Vallin, and M. V. Kamalakar, Nanoscale, 2021, 13, 6043-6052.

In a recent paper (G. Muscas et al.),1 the magnetomechanical behavior of cobalt (Co) magnetic nanowire arrays on a polymeric substrate (polyethylene naphthalate (PEN)) under bending was measured by magneto-optical Kerr effect (MOKE) magnetometry in situ. The authors showed that the magnetomechanical effects were very small and assigned this result to a low effective magnetostriction coefficient due to the nanostructuring. In this comment, we show by numerical calculations that it is the ongoing/current stress distribution within the system that generates this effect. Indeed, the nanostructures being very rigid with respect to the compliant substrate, the strains are mainly concentrated in the substrate and less than 3% of the macroscopic stress is transmitted to the nanostructures.

Anti-counterfeiting SERS security labels derived from silver nanoparticles and aryl diazonium salts.

The development of anti-counterfeiting inks based on surface-enhanced Raman scattering (SERS) labels have attracted great interest in recent years for their use as security labels in anti-counterfeiting applications. Indeed, they are promising alternatives to luminescent inks, which suffer from several limitations including emission peak overlap, toxicity and photobleaching. Most of the reported SERS security labels developed so far rely on the use of thiolate self-assembled monolayers (SAMs) for the immobilization of Raman reporters on metallic nanoparticle surface. However, SAMs are prone to spontaneous desorption and degradation under laser irradiation, thereby compromising the ink long-term stability. To overcome this issue, we develop herein a new generation of SERS security labels based on silver nanoparticles (Ag NPs) functionalized by aryl diazonium salts, carrying various substituents (-NO2, -CN, -CCH) with distinguishable Raman fingerprints. The resulting SERS tags were fully characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-vis absorption and SERS. Then, they were incorporated into ink formulations to be printed on polyethylene naphthalate (PEN) substrates, using handwriting or inkjet printing. Proof-of-concept Raman imaging experiments confirmed the remarkable potential of diazonium salt chemistry to design Ag NPs-based SERS security labels.

Localized and structured growth of polymer brushes using ink jet printing approach

Inkjet printing (IJP) technique has been used for the deposition of silica nanoparticles with controlled position and shape onto flexible polyethylene naphthalate (PEN) substrate. The printed silica areas have been chemically functionalized with a silane molecule bearing an ATRP initiator group. Surface-initiated atom transfer radical polymerisation (SI-ATRP) methodology has been betrothed to grow polymer brushes onto the silica printed areas. X-ray photoelectron spectroscopy (XPS) has been used after each step of functionalisation in order to determine the elemental surface composition. In addition, IJP has been used to design specific pattern at 250 micrometer scale. By combining maskless IJP technic and XPS line-scan mode, this work clearly demonstrates that the position and the pattern shape of printed areas can be controlled on demand, and that, structurally polymer brushes are only generated onto the functionalised silica printed areas.

Контактные и адгезионные свойства пленок полиэтиленнафталата, модифицированных в разряде постоянного тока

The effect of the direct current discharge treatment on the contact properties of polyethylene naphthalate films has been studied. The change in the contact angles of wettability by water and glycerin, the work of adhesion, total surface energy, its polar and dispersion components on the time of plasma treatment at the anоde and cathode has been investigated. A significant increase in the hydrophilicity of the polymer surface and a good stability of the obtained characteristics during storage of modified films in air at room conditions are shown. The adhesion properties of the polymer were investigated using T-test method according to ASTM 1876. The data of peel resistance in contact with some adhesives for the initial and modified polymer were obtained. Atomic force microscopy was used to study changes in surface morphology under the influence of the direct current discharge treatment.

Printed dual-gate organic thin film transistors and PMOS inverters on flexible substrates: role of top gate electrode

We report printed single and dual-gate organic thin film transistors (OTFTs) and p-channel metal-oxide-semiconductor (PMOS) inverters fabricated on 125 µm thick flexible polyethylene naphthalate substrate. All the electrodes (gate, source, and drain) are inkjet-printed, while the parylene dielectric is formed by chemical vapor deposition. A dispenser system is used to print the active channel material using a blend of 2,7-dihexyl-dithieno[2,3-d;2′,3′-d′]benzo [1,2-b;4,5-b′]dithiophene and polystyrene in tetralin solvent, which gives highest mobility of 0.43 cm2 V−1s−1. Dual-gate OTFTs are characterized by keeping the other gate electrode either in grounded or floating state. Floating gate electrode devices shows higher apparent mobility and current ratio due to additional capacitance of the parylene dielectric. PMOS inverter circuits are characterized in terms of gain, trip point and noise margin values calculated from the voltage transfer characteristics (VTC). Applied top gate voltage on the load OTFT control the conductivity or threshold voltage (V Th) of the bottom TFT and shift the trip point towards the middle of the VTC curve, and hence increase the noise margin.

Inkjet Printed Ultra-Thin Conformal Zinc-Silver Battery

Flexible printed electronics and photonics technologies are in demand because they are cost-effective and quickly reconfigurable. Zinc-silver battery can help towards development of body conformal wearable electronics. The study evaluate planar sec-ondary Ag2O-Zn battery fabricated using the inkjet printing technology. Polyethylene naphthalate (PEN) is used as polymer substrate and carbon nanotubes material is used as current collectors. The demonstrated battery achieves an capacity of 4 mAh with active electrode area of 14 cm2 and thickness of 0.2 mm.

Efficient Polyester Hydrogenolytic Deconstruction via Tandem Catalysis.

Using a mechanism-based solvent-free tandem catalytic approach, commodity polyester plastics such as polyethylene terephthalate (PET), polybutylene terephthalate (PBT), and polyethylene naphthalate (PEN) are rapidly and selectively deconstructed by combining the two air- and moisture-stable catalysts, Hf(OTf)4 and Pd/C, under 1 atm H2 , affording terephthalic acid (or naphthalene dicarboxylic acid for PEN) and ethane (or butane for PBT) in essentially quantitative yield. This process is effective for both laboratory grade and waste plastics, and comingled polypropylene remains unchanged. Combined experimental and DFT mechanistic analyses indicate that Hf(OTf)4 catalyzes a mildly exergonic retro-hydroalkoxylation reaction in which an alkoxy C-O bond is first cleaved, yielding a carboxylic acid and alkene, and this process is closely coupled to an exergonic olefin hydrogenation step, driving the overall reaction forward.

Efficient Polyester Hydrogenolytic Deconstruction via Tandem Catalysis

AbstractUsing a mechanism‐based solvent‐free tandem catalytic approach, commodity polyester plastics such as polyethylene terephthalate (PET), polybutylene terephthalate (PBT), and polyethylene naphthalate (PEN) are rapidly and selectively deconstructed by combining the two air‐ and moisture‐stable catalysts, Hf(OTf)4 and Pd/C, under 1 atm H2, affording terephthalic acid (or naphthalene dicarboxylic acid for PEN) and ethane (or butane for PBT) in essentially quantitative yield. This process is effective for both laboratory grade and waste plastics, and comingled polypropylene remains unchanged. Combined experimental and DFT mechanistic analyses indicate that Hf(OTf)4 catalyzes a mildly exergonic retro‐hydroalkoxylation reaction in which an alkoxy C−O bond is first cleaved, yielding a carboxylic acid and alkene, and this process is closely coupled to an exergonic olefin hydrogenation step, driving the overall reaction forward.

Influence of interlayers on the interfacial behavior of Ag films on polymer substrates

With the wider use of flexible electronics and sensors it is necessary to better understand how the substrate chemistry as well as the use of relatively brittle interlayers influences the electro-mechanical and interfacial behavior of electrically conductive thin films. Here, silver (Ag) films sputter deposited on polyimide (PI) and polyethylene naphthalate (PEN) with and without a titanium (Ti) adhesion layer were studied with in-situ electrical resistance measurements during uniaxial straining to study the electro-mechanical response with the cracking factor. Additionally, a molybdenum (Mo) stressed overlayer was utilized with the tensile induced delamination method to quantitatively measure the adhesion energies of the different material systems. It is demonstrated that the substrate chemistry, in terms of the mechanical behavior and number of C = O groups, plays a significant role in how through thickness cracks elongate and how the Ag and Ti may chemically bond to the polymer substrates. In general, a Ti interlayer degrades the electrical behavior, but can improve the interface adhesion of Ag to PI substrates. For PEN substrates, Ti is found to lower the adhesion compared to Ag alone. This new knowledge on the material interactions can be used to improve future flexible electronic thin film systems.

Effect of Substrates on Femtosecond Laser Pulse-Induced Reductive Sintering of Cobalt Oxide Nanoparticles.

Direct writing of cobalt/cobalt oxide composites has attracted attention for its potential use in catalysts and detectors in microsensors. In this study, cobalt-based composite patterns were selectively formed on glass, polyethylene naphthalate (PEN), and polyethylene terephthalate (PET) substrates via the femtosecond laser reductive sintering of Co3O4 nanoparticles in an ambient atmosphere. A Co3O4 nanoparticle ink, including the nanoparticles, ethylene glycol as a reductant, and polyvinylpyrrolidone as a dispersant, was spin-coated onto the substrates. Near-infrared femtosecond laser pulses were then focused and scanned across the ink films to form the patterns. The non-sintered nanoparticles were subsequently removed from the substrate. The resulting sintered patterns were found to be made up of Co/CoO composites on the glass substrates, utilizing various pulse energies and scanning speeds, and the Co/CoO/Co3O4 composites were fabricated on both the PEN and PET substrates. These results suggest that the polymer substrates with low thermal resistance react with the ink during the reductive sintering process and oxidize the patterns more easily compared with the patterns on the glass substrates. Such a direct writing technique of cobalt/cobalt oxide composites is useful for the spatially selective printing of catalysts and detectors in functional microsensors.

Direct comparison of PEN and TPB wavelength shifters in a liquid argon detector

A large number of particle detectors employ liquid argon as their target material owing to its high scintillation yield and its ability to drift ionization charge over large distances. Scintillation light from argon is peaked at 128 nm and a wavelength shifter is required for its efficient detection. In this work, we directly compare the light yield achieved in two identical liquid argon chambers, one of which is equipped with polyethylene naphthalate (PEN) and the other with tetraphenyl butadiene (TPB) wavelength shifter. Both chambers are lined with enhanced specular reflectors and instrumented with SiPMs with a coverage fraction of approximately 1%, which represents a geometry comparable to the future large scale detectors. We measured the light yield of the PEN chamber to be 39.4,pm ,0.4(stat),pm ,1.9(syst)% of the yield of the TPB chamber. Using a Monte Carlo simulation this result is used to extract the wavelength shifting efficiency of PEN relative to TPB equal to 47.2,pm ,5.7%. This result paves the way for the use of easily available PEN foils as a wavelength shifter, which can substantially simplify the construction of future liquid argon detectors.

Effect of Surfactant Addition on Organic Transparent Conductive Films Fabricated by Inkjet Printing Method

Recently, active research has been conducted on the development of flexible electronic devices. Hence, the transparent conductive film (TCF), an essential component of the device, must also be flexible. However, the commonly used indium tin oxide (ITO) TCF lacks flexibility and contains rare metal, making resource depletion an issue. Therefore, we focused on poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) (PEDOT:PSS), which has high flexibility and conductivity. Flexible TCFs have been fabricated by coating PEDOT:PSS on polyethylene naphthalate substrates using an inkjet printer. However, the current issue in such fabrication is the effect of the interface state on the transparency and conductivity of the thin film. In this study, we investigated the effect of surfactant in addition to polar solvents on the properties of thin films fabricated with PEDOT:PSS ink. Although the electrical conductivity was reduced, the transmittance remained above 90%. Thus, these results are comparable to those of ITO TCFs for practical use in terms of optical properties.

A novel and efficient technology of depositing Al2O3 film for OLEDs thin film encapsulation

Organic light-emitting diode devices (OLEDs) industry is developing rapidly, however, OLEDs are very sensitive to oxygen and water, determining how to achieve better barrier effect is one of the main challenges of flexible OLEDs technology. Based on the filtered cathode vacuum arc (FCVA) technology, a dense aluminum oxide (Al2O3) film with a thickness of about 100 nm was grown at room temperature for OLEDs encapsulation. The composition, structure, surface roughness, refractive index, light transmittance and other physical properties of the film were analyzed. The water vapor transmission rates (WVTRs) of the films were tested at 85 °C and 85% relative humidity (R.H.). Photoluminescence spectrum (PL) test was carried out to study the luminescence ability of tris(8-hydroxyquinoline) aluminum (Alq3) before and after the deposition of Al2O3 film. The results show that the amorphous Al2O3 film with dense structure prepared by FCVA has high visible light transmittance. The Al2O3 film reduces the WVTRs of the polyethylene naphthalate (PEN) film by four orders of magnitude and maintains the light-emitting performance of the organic light-emitting layer. These results indicate that the FCVA technology is a feasible method for preparing barrier films of flexible OLEDs.

In-situ electrochemical polymerization of aniline on flexible conductive substrates for supercapacitors and non-enzymatic ascorbic acid sensors

Polyaniline, as a kind of conductive polymer with commercial application prospects, is still under researches in its synthesis and applications. In this work, polyaniline was fabricated on flexible substrates including carbon cloths and polyethylene naphthalate by in situ electropolymerization method. The synthesized flexible electrodes were characterized by scanning electron microscopy, High resolution transmission electron microscope, atomic force microscope, Fourier transform infrared, x-ray diffraction, and x-ray photoelectron spectroscopy. Owing to the conductivity and the reversible redox property, the polyaniline/carbon cloth electrodes show excellent properties such as decent supercapacitor performance and good detection capability toward ascorbic acid. As supercapacitors, the electrodes exhibit a specific capacitance as high as 776 F g–1 at a current density of 1 A g–1 and a long cycle life of 20 000 times in the three-electrode system. As ascorbic acid sensors, the flexible electrodes demonstrate stable response to ascorbic acid in the range of 1–3000 μM with an outstanding sensitivity (4228 μA mM–1 cm–2), low detection limit (1 μM), and a fast response time. This work holds promise for high-performance and low-cost flexible electrodes for both supercapacitors and non-enzymatic ascorbic acid sensors, and may inspire inventions of self-powered electrochemical sensor.

Dielectric barrier discharge jet processed TiO2 nanoparticle layer for flexible perovskite solar cells

For attaining good-performance perovskite solar cells (PSCs), the carrier collection from the perovskite material to the transport layer plays a prominent role; herein, we demonstrate an atmospheric pressure plasma treatment technique to enhance the interface properties between the active perovskite layer and electron transport layer (ETL). A scan-mode low-temperature helium dielectric barrier discharge (DBD) jet is applied to process the TiO2 nanoparticle layers for the flexible n-i-p PSCs made on ITO-coated polyethylene naphthalate substrates. When the surface of TiO2 nanoparticle ETL is treated by the DBD jet at a scan rate of 2 cm s−1 and scan height of 5 cm by ten times, the photoelectrical conversion efficiency of the cell is enhanced from 12.30% to 13.66%. The performance improvement can be attributed to the increase of hydrophilic O–C = O functional groups on the surface of the TiO2 nanoparticle layer and the reduction of charge transfer resistance of the cell revealed by x-ray photoelectron spectroscopy and electrochemical impedance spectroscopy, respectively. The results show that the low-temperature DBD jet treatment is a promising technique for processing flexible photovoltaic devices.

Chitosan-Based Flexible Memristors with Embedded Carbon Nanotubes for Neuromorphic Electronics.

In this study, we propose high-performance chitosan-based flexible memristors with embedded single-walled carbon nanotubes (SWCNTs) for neuromorphic electronics. These flexible transparent memristors were applied to a polyethylene naphthalate (PEN) substrate using low-temperature solution processing. The chitosan-based flexible memristors have a bipolar resistive switching (BRS) behavior due to the cation-based electrochemical reaction between a polymeric chitosan electrolyte and mobile ions. The effect of SWCNT addition on the BRS characteristics was analyzed. It was observed that the embedded SWCNTs absorb more metal ions and trigger the conductive filament in the chitosan electrolyte, resulting in a more stable and wider BRS window compared to the device with no SWCNTs. The memory window of the chitosan nanocomposite memristors with SWCNTs was 14.98, which was approximately double that of devices without SWCNTs (6.39). Furthermore, the proposed SWCNT-embedded chitosan-based memristors had memristive properties, such as short-term and long-term plasticity via paired-pulse facilitation and spike-timing-dependent plasticity, respectively. In addition, the conductivity modulation was evaluated with 300 synaptic pulses. These findings suggest that memristors featuring SWCNT-embedded chitosan are a promising building block for future artificial synaptic electronics applications.

Bending Fracture Behavior of Flexible Organic Lead Halide Perovskite Films Depending on Composition and Morphology

Organic-inorganic halide perovskites receive great attention due to their superb optoelectronic properties such as high efficiency over 25% demonstrated on a glass-based solar cell. Since flexible optoelectronics are considered to be more beneficial to territorial and space applications than the rigid counterparts due to lightweight and bendable characteristics, flexible perovskite optoelectronics need to be developed. However, mechanical properties of perovskite films depending on compositions has not been studied. We report here on bending fracture behavior of the flexible perovskite films depending on the substitution ratio (x) in four different compositions of (FAPbI3)1-x(CsPbBr3)x, (FAPbI3)1-x(MAPbBr3)x, FA1-xCsxPbI3, and FA1-xMAxPbI3 (FA = formaminidinium). The spin-coated perovskite films on the indium-tin-oxide (ITO)-coated polyethylene naphthalate (PEN) substrates show different morphology depending on x and composition. At certain values of x, that is mixed cation and/or mixed anion, a wrinkled morphology is obtained with different amplitude and wavelength in the sinusoidal surface structure. Based on applied and critical strains, fracture energy and fracture toughness are estimated, where the mixed compositions with enhanced wrinkled morphology show an improved bending fracture behavior as compared to the pure FAPbI3 or MAPbBr3. The highest fracture energy of 186.2 J/m2 along with fracture toughness of 3.559 GPa∙(m1/2) is obtained from (FAPbI3)0.75(CsPbBr3)0.25 due to highly enhanced wrinkled morphology.

SERS substrates based on self-organized dimple nanostructures on polyethylene naphthalate films produced via oxygen ion beam sputtering

Surface-enhanced Raman spectroscopy (SERS) utilizes metal nanostructures to enhance the intensity of Raman signals. Although many methods have been developed for fabricating SERS nanostructures, most involve multiple steps. Herein, we employed oxygen ion beam sputtering (IBS), a one-step technique suitable for processing flexible substrates in roll-to-roll processes for mass production, Specifically, one-step oxygen IBS was used to fabricate self-organized dimple nanostructures, whose area and roughness could be controlled using the ion irradiation energy density, on the surfaces of polyethylene naphthalate films. Gold nano-tips for SERS were subsequently obtained by evaporating gold onto the dimple nanostructures. Finite-difference time-domain (FDTD) simulations revealed that nano-tip structures with spacings of less than 10 nm increased the localized E-field enhancement, which improved the SERS signal. Fabrication at a low energy density (5.8 J/cm2) produced more nano-tips with spacings of less than 10 nm, corresponding to a density of 61.4 nano-tips/μm2. SERS analysis conducted with methylene blue at 638 nm and 785 nm demonstrated that the Raman signal intensity was stronger for SERS substrates fabricated with low energy density (5.8 J/cm2) than for substrates fabricated with high energy density (17.3 J/cm2), because of the high density of nano-tips on the former substrate.

Exploring Nanomechanical Properties of Soot Particle Layers by Atomic Force Microscopy Nanoindentation

In this work, an experimental investigation of the nanomechanical properties of flame-formed carbonaceous particle layers has been performed for the first time by means of Atomic Force Microscopy (AFM). To this aim, carbon nanoparticles with different properties and nanostructures were produced in ethylene/air laminar premixed flames at different residence times. Particles were collected on mica substrates by means of a thermophoretic sampling system and then analyzed by AFM. An experimental procedure based on the combination between semi-contact AFM topography imaging, contact AFM topography imaging and AFM force spectroscopy has been implemented. More specifically, a preliminary topological characterization of the samples was first performed operating AFM in semi-contact mode and then tip-sample interaction forces were measured in contact spectroscopy mode. Finally, semi-contact mode was used to image the indented surface of the samples and to retrieve the projected area of indents. The hardness of investigated samples was obtained from the force–distance curves measured in spectroscopy mode and the images of intends acquired in semi-contact mode. Moreover, the Young’s modulus was measured by fitting the linear part of the retraction force curves using a model based on the Hertz theory. The extreme force sensitivity of this technique (down to nNewton) in addition to the small size of the probe makes it extremely suitable for performing investigation of mechanical properties of materials at the nanoscale. The experimental procedure was successfully tested on reference materials characterized by different plastic behavior, e.g., polyethylene naphthalate and highly oriented pyrolytic graphite. Both hardness and Young’s modulus values obtained from AFM measurements for different soot particle films were discussed.